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By Jack C. White

Studies were made to determine the character and distribution of the copper lost in copper mill tailings. Acid soluble (oxide) and acid insoluble (sulfide) copper were determined for heavy-liquid sink and float products of screen-sized fractions from 12 copper mill tailings. In most of the tailings studied, the coarse-size fractions are higher in copper grade than the respective bulk tailings, high in sulfide copper, and low in oxide copper. Oxide copper occurs predominantly in the minus 325-mesh "slimes." Microscopic examination of heavy-liquid sink products indicated that recovery of liberated copper sulfide minerals is complete in most mills, and that copper minerals not being recovered are locked with gangue particles. Additional copper could probably be recovered from most tailings by size classification, scavenger froth flotation of the coarse fraction, and regrinding of the concentrate to achieve liberation of the locked sulfides.

Jan 1, 1971

Lower the respirable dust exposure of longwall shearer operators with improved water spray systems on the shearer. Approach Orient sprays (rather than relocate them) so that dust is held against the face. How It Works Research by the Bureau has indicated that shearer operator dust levels depend largely on how fast dust from the upwind drum spreads into the walkway. Water sprays on the shearer body can greatly affect the spreading of this dust because each spray moves air like a small fan, generating strong cross-currents of air around the shearer. Poorly designed spray systems, especially those with nozzles pointing upwind, will stir up much more dust than they sup-press. On the other hand, Improved systems may be designed to hold the dust cloud against the face while also suppressing It. In such arrangements the water is sprayed downwind and used with screens made from conveyor belting.

Jan 1, 1981

Provide respiratory protection and a clean work environment for stationary or semimobile workers at minerals processing plants. Approach An Overhead Air Supply Island (OASIS) was developed which filters, conditions, and evenly disperses an envelope of clean air over a worker's head, thereby insuring reduced dust levels and a clean work environment. How It Works The concept for the OASIS derives from an earlier Bureau development of a canopy air curtain for continuous mining machines (see Technology News #21). In this application, the benefits of a reliable, self-contained, self-cleaning industrial-duty air filtration and distribution system are extended to the minerals processing field. The OASIS draws dust-laden room air into a filtration system, removing the dust and delivering clean air to a specific 16-square-foot area. It consists of: ? a self-cleaning primary filter ? a heater (cooling coil optional) ? an airflow distributor and secondary filter (combined)

Jan 1, 1985

By Franklin D. Cooper

The value of nonfuel mineral raw materials produced in the United States in 1978 was $20 billion. In 1979, total value increased to an estimated $24 billion, up 20% from 1978. Of the principal metallic ores produced in 1979, about half showed increased quantitative output and all showed increased value per ton compared with that of 1978. Most nonmetallic commodities showed increases in quantitative output and in average value per ton. Because of its decreasing share of the world market, the domestic mineral industry's concerns were the increasing costs of capital, labor, and energy; withdrawals of public lands from mining; and the increasing cost of environmental regulations that tended to deter or delay investment in the Nation's capacity for producing essential minerals.

Jan 1, 1980

By D. N. Nilsen

The U.S. Bureau of Mines investigated the use of unsupported liquid emulsion membranes (LEM's) for the extraction of copper from relatively dilute aqueous solutions (=0.3 and 2.5 g/L Cu), The performance characteristics of the three main unit operations of an LEM circuit (emulsion generation, metal extraction, and emulsion breaking) were assessed in laboratory-scale batch tests. In single-stage extraction tests using 2.5-g/L Cu feed solution, emulsion membranes extracted up to 94 pct of the copper from solutions without pH adjustment and 99.7 pct when the pH was maintained at about 2.5. Simulated two-stage crosscurrent and countercurrent circuits extracted all but 3 and 4 ppm of the original copper content, respectively. Extraction data from solutions containing mixtures of metals indicated a strong preference for Cu2+ extraction when oxime-type extractants were used in the LEM; however, some coextraction of Fe 3+ and Zn2+ was experienced. An electrostatic coalescer was used to break the copper-loaded emulsions for separation of the component phases. Up to 96 pct of the contained stripping solution (internal solution) containing the extracted copper was separated from the organic phase of the emulsion membrane. The recovered organic phase was recycled without apparent problems.

Jan 1, 2010

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981

Improve the safety, reliability and overall effectiveness of mine stench warning systems and to provide a means of remote control stench injector operation. Approach Industrial gas odorants were analyzed for their suitability for use in mine stench warning systems. A prototype stench injector capable of precise flowrate control was designed, fabricated, and tested using the odorant chosen as having the most favorable properties. Based on the results of the field tests, a second generation injector was developed. The second generation unit features optional remote control operation, and in addition, is simpler to refill and is less expensive than the original injector. A complete second generation system, consisting of two manually operated injectors and one remote controlled injector was in-mine tested through actual mine fire drills. How It Works Ethyl mercaptan mixed with Freon is the predominant stench agent used in the U.S. underground metal and nonmetal mines. However ethyl mercaptan's toxicity,

Jan 1, 1982

Minimize the effects of underground mine conveyor belt fires by developing methods to prevent automatic fire suppression system failures. The Problem Fire protection is achieved by prevention, early detection, and planned fire-fighting response. Automatic fire suppression systems are one form of planned fire-fighting response. When these systems are properly designed, installed, and maintained they can effectively control fires. Conveyor belt fires account for about 20% of underground coal mine fires. Fire protection requirements have been established for underground locations because of potential for start and spread of fire and the restricted personnel egress in a fire situation. Belt conveyor systems arc potentially dangerous because of the high fire incidence rate, high temperatures, dense smoke, toxic gases, and rapid flame-spread rate. While investigating the conveyor fire suppression problem, the Bureau identified automatic fire suppression system reliability as a potentially serious deficiency within the mining industry. Table 1 lists common failure modes fur three Fire suppression system types. This table summarizes findings of Mine Safety and Health Administration electrical inspectors responsible for inspection of belt protection automatic fire suppression systems. Batteries, contact points, control wires, and electric servocontrols are all prone to failure. Figure 1 shows rock-dust-contaminated relay contact points. This condition is dangerous because of the chance of intermittent failures, which might allow systems to pass annual functional testing, yet fail during actual fire emergencies.

Jan 1, 1989

By A. F. Colombo

Infrared spectroscopy employing attenuated total reflectance (ATR) techniques on thin films of dried gelatinized starch solution was used during Bureau of Mines research to determine the structural and impurity differences in starch products and to correlate these characteristics with the flotation response of a nonmagnetic taconite. All of the starch products evaluated gave spectrograms which were characteristic of the anhydroglucose monomer and its polymerization product. Distinct infrared absorption peaks caused by the protein molecule were observed and were used to classify the starches. Correlation of laboratory flotation of calcium-activated gangue from a Mesabi Range nonmagnetic taconite and infrared spectra produced from gelatinized starches showed that protein impurities and linear chain structure limited the effectiveness of starches as iron mineral depressants. Starch products having spectrograms similar to pure amylopectin were generally good depressants for iron oxides, were effective at about one-half the addition that was required for starches that gave infrared responses similar to pure amylose, and yielded acceptable iron concentrates containing 61.5 percent iron and 6.5 percent silica.

Jan 1, 1969

By C. N. Schuette

"The production of silica and magnesia crucibles in the induction furnace was attempted and achieved in the laboratory of the Pacific Experiment Station of the United States Bureau of Mines. This work was undertaken at the request of other stations for laboratory crucibles of a certain specified wall thickness and capacity.The essential new parts of this work are the development of a technique for the high-frequency furnace production of silica crucibles of greater wall thickness than could be readily fabricated from commercial fused silica, and for heavy-walled magnesia. crucibles of great density and mechanical strength. A considerable bode of patent literature on the Production of fused silica ware in resistor-type furnaces was examined, but it furnished no significant help for the present problem. Similarly sintered magnesia refractories are often made for technical purposes, but for use at temperatures of 2000o C. or over, the material must be sintered at higher temperatures than can be attained by combustion firing, and the very great shrinkage encountered at these temperatures requires special methods. Small crucibles. of magnesia fused in the electric arc have been made by Tritton and Hansen,3 but the practical size of such containers is very limited.Many different methods of making crucibles in the induction furnace were tried before satisfactory results were obtained. The following description covers only the most satisfactory method, which produced crucibles of excellent quality in a reasonable time and with a moderate expenditure of power and materials."

Oct 1, 1929

Provide an economic alternative to drill-blast excavation with the same ability to excavate openings of varied orientation, shape, and size. Approach Develop an efficient, adaptable, mechanical excavation machine that produces unconfined tensile failure in rock. How It Works A drill-split fragmentation machine that combines a drill and a unique splitter has been developed. The drill and splitter are mounted on a carriage that positions the splitter in a hole immediately after it is made by the drill. The splitter creates force loads that cause the rock to fragment, and the process is repeated for excavation. The unique splitter applies both radial and axial loads to the rock mass, which produces an excavation action comparable to pulling a plug. This excavation action distinguishes the radial-axial splitter from typical demolition splitters, which require a free surface parallel to the axis of the splitter toward which to break rock.

Jan 1, 1989

Improve underground long-hole drilling efficiency and safety by developing a lightweight, easily transportable drilling pust that can be adjusted to fit a range of mine opening heights. Background Standard one-piece commercially available steel posts weigh approximately 10 pounds per foot. Transporting these posts underground and carrying them over obstacles and through small mine doors is very difficult. Because the length of a one-piece post cannot be adjusted, variations in mine opening height at the drilling site must be accommodated. This is accomplished by stacking several wooden blocks to form a base for the post, resulting in a dangerously unstable drilling setup. The only alternative to this unstable setup is to obtain a longer post. There problems can be reduced by the use of a two-piece telescoping aluminum post having a 3-foot adjustment range in 6-inch increments. The two-piece extendable post will be easy to transport and carry underground. It will fit any opening height within its adjustment range. One large wooden block is used as a base and one cap block is used at the top to bear against the mine roof. This arrangement results in a stable, rigid setup.

Jan 1, 1990

By C. M. K. Boldt

This U.S. Bureau of Mines report presents a study of three typical tailings samples as potential cemented backfill in underground mines. The testing series was unique in that the pulp densities of the samples were all above 75 pct solids. Test results included dry density; slump; percent settling after 28 days of curing; tensile strength after 28, 120, and 180 days of curing; and unconfined compressive strengths after 7, 28, 120, and 180 days of curing. The physical properties of the various test mixtures were further analyzed using linear and nonlinear statistical methods to produce correlations and mathematical equations. Physical properties were used to determine the influence of mix additives and as input for numerical modeling studies of backfill. The mathematical relations were used as a predictive tool in determining the suitability of various materials as backfill.

Jan 1, 1989

By Richard Hammer

Various alternating current (ac) methods can localize faults in mining power cables. Several methods considered by the Bureau of Mines in this report are the Murray loop for short circuits, wherein a bridge provides proportional distance to the fault; capacitance measurements for open conductors; inductance measurements for shorted conductors; phase comparison, high speed recordings of voltage and current in the faulted state are compared with normal voltage and current with the difference being a function of impedance change and impedance change being a function of fault location; and standing wave measurements, detecting the resonance of the length of cable to a fault (either short or open). Portable capacitance bridges are presently available for the second method, and the fourth method is well developed for use on large power distribution systems. Because it utilizes pulses rather than ac, the time domain reflectometer (TDR) method of fault locating was not included in this investigation. However, a comparative evaluation between this versatile method and the Murray loop might prove advantageous in locating high resistance faults.

Jan 1, 1977

By J. R. Wait, D. A. Hill

A survey of the literature on ELF and VLF atmospheric noise has been made. Most measurements have concentrated on the vertical electric field and the horizontal magnetic field rather than the vertical magnetic field which is of interest in transmission between horizontal loops. The limited vertical magnetic field data indicates that the vertical component is generally 10 to 20 dB below the horizontal component. Three laterally inhomogeneous earth models have been analyzed for conversion of horizontal to vertical magnetic field. The rough surface model examines surface effects, the inhomogeneous thin sheet model treats volume effects, and the buried cylinder model treats localized man-made effects. All three models predict the possibility of significant conversion from horizontal to vertical magnetic field. A thin sheet model has also been used to examine transmission from a buried magnetic dipole source. It is found that the pre- dicted fields more nearly model the measured data than does the homogeneous half-space model.

Reduce dust at the auger mine face by modifying airflow patterns, around the minim machine. Approach Limited clearance between an auger miner and the mine root restricts airflow across the face and causes dust rollback. Directional sprays arc used to direct air across the face, thereby reducing dust rollback and increasing dust dilution (fig. 1). Laboratory and underground studies were used to test and optimize effectiveness of the directional sprays. Results of Laboratory Study Laboratory experiments were conducted in a simulated auger gallery equipped with a full-scale mock auger miner and bridge conveyor. A dual curtain configuration was used to direct the, ventilation, which averaged 2,700 cfm throughout the experiment. Testing variables included spray location, pressure, spacing, orientation, and number. Figure 2 shows the optimized directional spray system, also called the auger clearer spray system. The system consists of three sprays mounted alone the intake side of the miner. Sprays arc spaced 16 to 24 inches apart, and angled 30° toward the return side of the miner. The 24-inch spacing moved about 7% more air across the face than the 16-inch spacing; however, it resulted in some additional misting on the return side of the miner. A 30° orientation was more effective than a 60° orientation for moving air across the face and minimizing misting on the return side of the miner. Flat fan sprays arc used because their spray paths arc not obstructed by the top of the miner and mine roof, A 50° fan angle is used to minimize misting on the intake side of the miner.

Jan 1, 1989

Control surface stream loss by identifying and selectively sealing water loss zones in stream channels overlying underground mines. Approach Electromagnetic terrain conductivity surveys, coupled with stream gaging, are performed within a stream channel to identify saturated fracture zones associated with loss of stream water. This information is used to target locations for the injection of expandable polyurethane grout. The grout is injected two to three feet beneath the surface of the strcambed, across each loss zone, to seal the fractured strcambed and restore stream flow across the damaged area. How It Works Multiple zones of infiltration (natural and induced) normally exist in stream channels overlying mined areas, causing water handling and/or acid drainage problems in the mines as well as loss of stream flow. It is typically difficult to accurately locate these loss points. Therefore, Conventional methods of stream repair, such as using plastic membranes or clay and rock rip-rapping, are applied to long lengths of a stream channel. The two step approach developed by the Bureau of Mines First quickly and accurately locates loss zones using electromagnetic ground conductivity survey and gaging instruments. Conductivity is measured at fixed spacings (typically 25-50 ft depending on the instrument and desired observation depth), Ground conductivity increases when saturated conditions exist at depth. These apparent flow loss zones are confirmed by gaping, to eliminate possible effects due to unobservable metal debris adjacent to or buried in the stream sediment.

Jan 1, 1991

"""Hazard"" is the general expression used by safety engineers to denote risk, or the danger to property or human beings from the contingencies peculiar to different industries. Where a business, family, or individual is subjected to possible financial loss from any particular hazard, it is customary and is considered good practice to insure for reimbursement of possible loss. Accordingly, we take out insurance for earthquakes, for fire, for accidents, etc., and are charged a different premium for each. The premium rate is based on our relative exposure to the hazard in comparison to the total loss to our particular class of business in our geographical location over a given period.Insurance, then, must be considered as the experience of a group rather than of an individual, and any individual may be fortunate or unfortunate over stated periods. Through the law of averages, the probability of loss because of exposure to hazard is becoming more accurately measured as experience is accumulated and data are analyzed.Lion human life came to have a financial value in the eyes of the law, and employers were held liable for losses through accidents to employees while on duty, insurance companies began to underwrite the accident risks of the different employers and divided them into classes based on the amount of risk involved. Premiums for compensation insurance are based on relative exposure, which is measured by pay roll. The premium is rated in proportion to the severity of losses established by statistical studies.' It soon became evident that the accident experience of employers in the some industry varied widely; that is, there were good and bad risked in the same line of business. This resulted in ""experience rating"" of premiums, meaning thereby that an employer with experience in accident cost was premium rated in proportion to his losses over a stated period (usually three or more years)."

Feb 1, 1926

Promote safer and more efficient mine operations by providing communications between personnel located anywhere in the mine. Approach A radio communications system was designed which takes advantage of existing mine wiring such as telephone lines or electric power cables. The existing wiring distributes radio signals throughout the mine, making communications possible between roving miners, vehicle operators, dispatchers, and other personnel. How It Works Research has shown that medium frequency (MF) signals (300 KHZ-3 MHZ) can couple onto and re-radiate from nearby conductors. This effect is known as parasitic coupling and re-radiation. In a mine, these conductors include electric power cables, control lines, telephone lines, trolley lines, as well as metal water and air pipes Since all underground mines require these conductors for normal operations, the necessary network already exists and expands automatically as the mine is developed. A radio communication system has been developed that uses the parasitic coupling and re-radiation characteristic of MF. Using this system, whole mine radio coverage can be achieved without the need to install or maintain communication lines. The system consists of mobile transceivers for roving personnel and vehicles, and fixed-location base radio stations and repeaters.

Jan 1, 1982

By B. Dimitriades

The Bureau of Mines measured the reactivities of 19 hydrocarbons known to be prominently present in automotive exhaust and ambient air in a smog chamber. Results agreed well with those obtained using two other smog chambers. Reactivity scales were developed for hydrocarbons and aldehydes using the results of this work and those of a previous study. Application of the reactivity scales to automotive exhaust samples gave fair agreement between predicted and observed rate-of-N02-formation values; however, predicted and observed ozone yields were neither in agreement nor did they correlate well. This lack of correlation for ozone yield was attributed to the inappropriateness of (1) the individual component reactivity data, (2) the reactivity classification scheme used, and (3) the linear summation method. In seeking to understand this problem and to develop more appropriate reactivity scales, the data were examined from a reaction mechanism standpoint, and further studies were suggested.

Jan 1, 1975