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By L. B. Pankratz

Heat contents were measured for Na2CaSi04 and Na2Ca2S02 between 298° and 1,300° K, for Na2Ca2Si309 between 298° and 1,500° K, and for Na4CaSi3O9 between 298° and 1,350° K. Copper-block drop calorimetry was employed. Reversible, first-order transitions were found for Na2CaSi04 and Na2Ca2Si309. The transition for Na2CaSi04 is at 830° K with a heat absorption of 160 cal/mole; that for Na2CagSi309 occurs at 750° K with a heat absorption of 1,550 cal/mole. Results for the other two silicates showed no irregularities. A table of heat content and entropy increments above 298.15° K and heat con-tent equations are included for use in thermodynamic calculations.

Jan 1, 1968

The National Institute of Occupational Safety and Health has classified diesel exhaust as a potential human carcinogen. Though standards for diesel particulate matter (DPM) in the work place have not been established, concern for the health of miners is prompting mine operators to consider methods for reducing worker exposure to diesel exhaust. Approach One of many methods for reducing DPM being investigated by the Bureau of Mines is the use of additives in diesel fuel to improve combustion. Research Results Three fuel additives have been tested in Caterpillar and Deutz diesel engines which are similar to types used in underground mines. One iron-based additive containing ferrous picrate had no effect on emissions. A second iron-based additive containing ferrocene reduced DPM between 5 and 45 pet depending on engine operating conditions. The 37-pct reduction for an 8-minute duty cycle, which includes a wide range of transient loads and speeds, is considered to represent in-mine performance.

Jan 1, 1990

Provide a method of detecting and locating miners trapped underground following a mine disaster. Approach Develop a surface deployed system which senses the vibrations caused by a trapped miner pounding on the roof of the mine and effectively determines the miner's location. How It Works If trapped underground, a miner would strike the roof of the mine with any implement at his disposal. This pounding causes vibrations in the ground which are transmitted to the surface where they are sensed by receiving transducers called geophones. Multiple geophones are positioned together for noise cancellation purposes in a form called a subarray. Seven

Jan 1, 1981

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 4 Description of Subroutines There are thirteen subroutines in the program: PROGIO HOIST MINER SMOKE STENCH MSMOK

Jan 1, 1976

By Thomas O. Llewellyn

Laboratory semicontinuous and continuous heavy liquid cyclone separation pilot plant tests were made to determine the feasibility of producing a high-grade kyanite concentrate from a kyanite-quartz rock sample from Graves Mountain, Ga. Use of a three-stage heavy liquid cyclone circuit demonstrated that a 96.4-to 99.0-percent kyanite concentrate could be obtained with recoveries of 95.5 to 96.7 percent. The test work showed that by steam stripping with 6.9 tons of steam per ton of ore and two stages of detergent scrubbing the residual TBE content of kyanite cyclone products was 0.22 pound per ton of ore.

Jan 1, 1971

By L. A. Johnson

This Bureau of Mines report presents the analysis of three cores from the Asphalt Wash area of the P.R. Spring tar sand deposit of northeastern Utah. Two tar sand zones are indicated in the Asphalt Wash Area. Total net thickness of the tar sand ranges from 23 to 39 ft, with occurrences between 56 and 263 ft in depth. The sand has average porosity of 24.7 pct of bulk volume, average permeability before and after extraction of 87.5 and 596 md, respectively, and average oil saturation of 58.1 pct of pore volume. Oil gravity averages 10.9° API.

Jan 1, 1975

By Joseph A. Perry

One goal of the Bureau of Mines is to develop technology tp insure a dependable supply of minerals to the United States. To support this goal, the Bureau's Albany Research Center has modified a commercial atomic absorption spectrophotometer to rapidly determine trace levels of mercury by cold-vapor atomic absorption spectrophotometry. Such diverse materials as ores, mill products, stream water, sediments, and flue dust have been analyzed. A very high dynamic range of 0.2 ng/ml to 1 µg/ml of mercury in solutions is routinely analyzed by this instrument.

Jan 1, 1981

By Fred Leighton

The least squares method of rock noise source location presented is shown to be more accurate and reliable than standard direct solution methods. This method is particularly effective in improving solutions from rock noise locations outside of geophone array boundaries. A least squares solution for a medium .in which the seismic velocity is the same in all directions is also presented. In this special case, one can solve for both the source coordinates and the velocity.

Jan 1, 1972

By David E. Morse

Burundi, a small central African republic located between Tanzania and Zaire, remained essentially a nation of small family farms in 1978-79 with approximately 95% of the population engaged in subsistance agriculture. Coffee and tea continued as the nation's major export commodities. Mineral exports, small tonnages of cassiterite, wolframite and bastnasite, accounted for an estimated 3% of total exports in 1978 and 2% in 1979, or $2 million2 in both years. Burundi's major mineral imports in 1978-79 were cement, iron and steel, and refined petroleum products. Abnormal weather conditions, a drop in world coffee prices in 1978, and the conflict in neighboring Tanzania and Uganda in late 1978 and early 1979 combined to re-strict economic growth in Burundi during 1978-79. The gross domestic product (GDP) posted a gain of 6.7% in real terms for 1978 and an estimated 2.5% for 1979 which was significantly less than the 13.7% recorded in 1977, a time of high world coffee prices. The manufacturing and construction sectors were hard hit in 1979 by the conflict between Burundi's eastern neighbors because of transport disruptions which made building materials and manufacturing inputs almost unobtainable.

Jan 1, 1981

By M. O. Magnuson

As part of an experiment in the restoration of lands strip-mined for coal, revegetation studies were conducted at three backfilled strip-mine sites in north-central Pennsylvania. The sites were subdivided into plots that were given varying amounts of lime and fertilizer. In tests conducted cooperatively with State and Federal agronomy experts, the plots were then planted with a variety of trees, shrubs, and grass-legume mixtures. Initial tree and shrub survival was not appreciably affected by lime and fertilizer applications where the spoil pH was above 4.5. Of 14 species of trees and shrubs tested, Norway spruce, black locust, Japanese larch, pitch pine, and white pine were the hardiest. The ground-cover percentage of grass-legume mixtures in the second growing season was substantially increased by using lime and fertilizer. Mixtures comprised partly of fescue were the most satisfactory.

Jan 1, 1968

Provide exhaust face ventilation to remotely-controlled continuous mining machines making extended advances without exposing workers to unsupported roof. Approach Modify the sprayfan to move additional air to and from the coal mine face. Unmodified, sprayfans are capable of ventilating the face with 20-foot brattice setbacks. Additional sprays on the rear of the mining machine allow setbacks to be extended up to 40 feet.

Jan 1, 1988

Develop new technolgies and techniques which enable recovery of strategic and critical minerals such as cobalt from domestic resources, thereby easing the U.S. dependence upon foreign producers for these valuable commodities. Approach The Bureau of Mines, through research, developed a process which uses mineral beneficiation techniques to recover cobalt-rich products from Missouri lead ores. Before development of this process, cobalt was lost as an impurity in the copper, lead, and zinc concentrates and in the mill tailings because the technology to recover it with minimum impact on present production did not exist.

Jan 1, 1989

By Pablo Velasco

Ecuador had limited mineral output, al-though the Government attempted to stimulate metallic mineral exploration and also evaluated a gypsum and a phosphate deposit. A pilot plant to exploit gold deposits was established, and there was extensive gold exploration activity in southern Ecuador. Domestic output of iron and steel declined sharply. Among all minerals, petroleum output was the dominant factor with both exports and production increasing significantly over that of 1988. Crude oil exports contributed 63% of total export earnings and about 70% of the central Government's revenue.

Jan 1, 1986

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

By C. M. Frost

Crude shale oil produced by gas combustion retorting of Green River oil shale was hydrocracked over a cobalt molybdate catalyst at operating pressures of 500, 1,000, 1,500, and 3,000 psig, an operating temperature of 8900 F, and a liquid hourly space velocity of 1.0. Hydrogen feed rate was maintained at 6,000 scf/bbl. The volume-percent yields of total liquid product were directly proportional to the operating pressure. Weight-percent conversion and volume-percent yields of gasoline were directly proportional to the log of the operating pressure. Catalyst deposit percentages were inversely proportional to the log of the operating pressure. Nitrogen and sulfur removal rates as well as saturation of the liquid products increased as the operating pressure was increased.

Jan 1, 1973

By Ben A. Kornhauser

Petroleum production was the principal component of the mineral industry, followed by cement production and some salt output. The French Central Fund for Economics Cooperation loaned $9.15 million2 to the Communauté Electrique du Benin (CEB), which served Benin and Togo, toward financing the construction of a dam on the Mono River at Nangbeto, Togo. The dam was to supply hydroelectric power to reduce the energy dependence of the two countries and to irrigate crops. Nine other international financial organizations, including the International Bank for Reconstruction and Development (World Bank). the African Development Bank, the Arab Bank for African Economic Development, and the French Aid and Cooperation Fund, contributed to the estimated $140 million cost of the dam. The CEB also was to contribute to the financing. Contracts amounting to $60 million already had been awarded to West German and Canadian firms. The dam was expected to be completed in 1987.

Jan 1, 1986

Compare the dust control efficiency and bit life of surface coal mine drills using standard water injection and water injection with water separation. Approach A research study was conducted to determine if a water separation technique affects wet suppression dust control. Dust control efficiency and bit life of surface coal mine drills were compared during tests using both standard water injection (wet drill bit cutting) and water injection with water separation (dry drill bit cutting). Background Surface coal mine blast hole drills typically generate a substantial amount of dust during the drilling cycle. One method used to control this dust is the injection of water into the bailing air. This is known as wet suppression.

Jan 1, 1988

By C. M. Mason

Mechanical mining produces large quantities of very fine coal dust called float dust. The associated increase in hazard requires a reexamination of the Bureau of Mines method of evaluating the incendivity of explosives in coal dust-gas-air mixtures. A technique recently developed by Bureau of Mines laboratories for evaluating the incendivity of explosives in coal dust-air mixtures was applied, with modifications, to coal dust-air-natural gas mixtures. A series of permissible explosives were evaluated by this modified technique. Results indicate that the modified technique could be the basis of a more discriminatory procedure than that presently in use.

Jan 1, 1968

By A. Mayton, A. Brien, W. Porter, O&apos

In 2004, management at Unimin's Gleason, TN operation began implementing ergonomic interventions specifically targeted to reduce risk of musculoskeletal injuries (MSIs). Together with corporate and site management, Unimin identified work site hazards and began to modify work practices/equipment. Some interventions were relatively simple and were implemented immediately. Others, like improvements to a mobile shredder, were more complex but were eventually resolved through a participatory approach with employees, management, manufacturers and NIOSH. This paper discusses ergonomic interventions that were successfully implemented using a bottom-up approach to reducing the risk of injury.

By C. H. Elder, Maurice Deul

A 5-hole pattern was drilled from the surface at a site near Oak Grove, Jefferson County, Ala., to degasify the gassy Mary Lee coalbed in advance of mining. Gas and water production was monitored for 1 year, 4 months to allow gas flow to stabilize fully. A thickened water stimulation treatment was designed and applied in one hole of the pattern to evaluate this degasification technique for the Mary Lee coalbed. A gas production rate of 70,000 ft3 /day after stimulation treatment indicates that the use of vertical boreholes coupled with hydraulic fracturing in advance of mining the Mary Lee coalbed would provide for more rapid degasification and could provide a possible source of natural gas.

Jan 1, 1974