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By P. D. Bergman

To assess the efficacy and economics of producing power from coal, four open-cycle magnetohydrodynamic (MHD) processing schemes were selected for study. Each involved a different mode of coal combustion and level of gas cleanliness. The options considered were: (1) coal burned in a slagging combustor; (2) suspension gasification with slag removal prior to combustion; (3) parallel cyclone combustors, one operating fuel rich and the other operating with excess air; and (4) suspension gasification by the hot exhaust gases from the MHO duct with ash removed prior to combustion. Option 1 has the highest ash content in the combustion plasma and as a result would have the greatest operational difficulties associated with it. Options 2 and 4 have the cleanest MHD combustion plasma. For coal priced at $4/ton, the power generating cost of option 4,11.78 mills/Kw-hr, is the highest, with Option 1, at 9.04 mills/kW-hr the lowest. These costs may be compared with a conventional power cost of 9.92 mills/kW-hr for the late seventies. Capital costs of three of the four options were competitive with those of conventional thermal power plants employing stack gas S02 cleanup systems. Option 2 has the most favorable combination of operating characteristics and power cost. It was concluded that a clean, high-temperature working fluid can probably be produced from coal without leading to depressed system efficiencies and exorbitant capital costs.

Jan 1, 1973

By Ernest R. Rodriguez, Allen D. Look

"INTRODUCTION The underground mine of the Miami Copper Co. has operated since 1927 without a fatality from blasting or the handling of explosives. To improve safety and efficiency, electrical blasting has been used exclusively since 1934. During the period January 1, 1934, to December 31, 1948, inclusive, over 4,000 tons of explosives were used to produce 60,925,071 tons of ore with 896,760 feet of development footage and 2,591,788 square feet of undercut area.The purpose of this paper is to recount the company's precautions to insure safe handling of explosives at this operation, where safety involves careful planning rather than ""trial and error.""GENERAL INFORMATIONThe Miami Copper Co. operates on underground mine in a large, low-grade, Porphyry copper deposit near Miami, Ariz. The deposit contains numerous fractures and planes of weakness, which contribute to ease of working the ore bodies by the block-caving method of mining.An individual stope-caving method is used with stoles 150 feet by 200 to 300 feet and 30- to 50-foot pillars between stapes. After the stope is undercut, the ore is drawn through the draw raises on the grizzly level, and thence through the transfer raises to the ore chutes on the haulage level.Access to the mine is by four active shafts, three of which are primarily for ventilation. No. 5 shaft is used for both hoisting and service. There are four operating levels in the mine. The elevations of the grizzly levels are governed by the contour of the bottom of the ore body and therefore vary in different locations in, the mine.Grizzly levels are on the 850, 900, and 975 levels. The 1,000 level is the haulage level. This mine operates in very low-grade ore and requires economical handling of large tonnages safely and efficiently."

May 1, 1950

By J. F. Barkley

As part of the work of serving as Chairman of Subcommittee 3, Health and Industrial Requirements, of the American Society of Mechanical Engineers' Committee on Air-Pollution Controls, the author assembled the following information on accepted maximum permissible concentrations of air pollutants from the standpoints of health, damage to vegetation, damage to property, and requirements of industrial processes. A search in technical literature was made followed by direct inquiry to all State governments as to their regulations. The subcommittee membership - G. D. Clayton, senior sanitary engineer, Public Health Service, United States Department of Health, Education, and Welfare, Detroit, Mich., Dr. L. Greenburg, commissioner; Department of Air Pollution Control, New York, N.Y., Dr. M. Katz, Defence Research Chemical Laboratories, Ottawa, Ontario, Canada, and Dr. H. H. Schrenk, research director, Industrial Hygiene Foundation of America, Inc., Mellon Institute, Pittsburgh, Pa. - reviewed the information and made very helpful comments and corrections.

Jan 1, 1954

By Steven J. Page

The increasing concern for dust control in metal and nonmetal mining prompted the Bureau of Mines to investigate the dust suppression technique of applying foam to face drilling and crushing operations in a gypsum mine. Previous attempts to achieve effective dust control on face drills using other techniques, such as dry collection and boom-mounted external water sprays, have not been successful. The largest problem encountered when using these techniques has been the lack of sustained effective dust capture at the face. Results for two faces studied show that injection of the foam through the drill steel provided an average dust reduction of 95 pct. However, the use of foam on the crusher provided no dust reduction at the operator's position (because of good local ventilation) and a 27-pct average dust reduction for two feeders at a location midway between the operator's position and the crusher. The conclusions obtained from this study are that (1) foam can be an extremely effective dust control technique when used on localized dust sources such as dust generated within a blasthole during drilling, and (2) foam is only marginally effective as a dust control technique when used on nonlocalized dust sources such as dust generated during the feeder-and-crusher operation.

Jan 1, 1981

By G. W. Eiger

Bureau of Mines laboratory tests show that ilmenite concentrates with titanium dioxide contents as low as 33 wt--pct can be beneficiated to produce a crystalline substitute for natural rutile suitable for direct chlorination. The synthesized product prepared by a three-step procedure was comparable with natural rutile in titanium content. Reduction smelting of ilmenite removes iron as a pig iron byproduct, and the remaining slag phase is greatly enriched in titanium. Oxidation of the slag in the presence of phosphorus¬bearing slag additive converts the titanium-bearing phases to discrete rutile crystals and a glass phase containing most of the associated impurities. Rutile is separated from the glassy impurities by attrition scrubbing ground slag in dilute phosphoric or sulfuric acid solutions. Tests made in a laboratory fluid-bed reactor show that synthetic rutile responds to chlorination at the same rate as natural rutile and that more than 95 pct of the titanium contained in the feedstock was extracted as titanium tetrachloride.

Jan 1, 1974

By Hylton R. Brown

Advertisements and articles in technical and trade journals announce the approach of a new age, in which plastics, light metals, laminated wood, and numerous other products or byproducts will be used in the construction of automobiles, airplanes, and furniture and equipment used in our factories, offices, and homes. Undoubtedly, after the war there will be many such developments which will introduce new manufacturing methods and new hazards to challenge the safety engineer. Already we know, from experience in laboratories and pilot plants where these new products are being tested, that there will be many fire and explosion hazards to be overcome. The danger of dust explosions may be one of the principal hazards, because thetic resins and other materials used in the plastics industry, as well as metal powders, wood dust, and other finely divided substances, are capable of forming explosive mixtures in air. Heavy losses of life and property have been caused by dust explosions in flour and feed mills, starch factories, and grain elevators, and it will be well to consider the possibilities that such losses may occur in any new industry and to provide all possible safeguards against hazards. Fortunately, we have learned something about the behavior of dust explosions and know something about the ease of ignition, limits of Explosive concentration, end pressure developed. Our efforts should now be directed toward the application of this knowledge in the development of safe operating practices.

Jan 1, 1945

By Robert H. Dickson

This paper describing the mining practices at the Verde Central mine at Jerome, Ariz., is one of a series being prepared by the United States Bureau of Mines on mining practices, methods and costs in various mining districts of the United States. ACKNOWLEDMENTS The costs contained in this paper were prepared by R. J, Huddleston, chief clerk, Verde Central Mines, Inc.

Jan 1, 1931

By Oliver Bowles

[In an endeavor to promote greater efficiency in the lime industry, the United States Bureau of Mines is preparing a series of preliminary reports dealing with particular problems of the industry. Through the circulation of these reports, it is hoped that sufficient interest may develop among lime-plant operators to prompt them to discuss with the bureau their our experiences with these problems. By such an interchange of ideas, it is believed that conclusion may be reached which will be of practical benefit to try entire industry. The first report, "Stripping problems it Limestone quarries of the Shenondoah Valley", Serial No. 2401, was issued during October, 1922. This report t is the second of the series. It is hoped that may operators will contribute additions to the information now at hand.]

Jan 1, 1922

By S. H. Katz

Artisans and laborers in mineral industries where the air is dusty with particles of reel: are subject to a peculiar pulmonary disease known as miners' phthisis or stone cutters' consumption. In granite cutters the disease is specifically designated as granite pneumoconiosis. Very fine particles of the harder rocks are especially injurious when inhaled into the lungs. It is estimated particles about one micron (1/23000 part of an inch in diameter) are most injurious, because larger particles are more readily removed by the cilia and,wet surfaces of the respiratory passages before reaching the lungs, while smaller particles either do not readily lodge or are more easily eliminated. Silica, of which quartz and flint are composed, and which forms a large part of granite, is one of the hardest of the common rock-forming materials. It is also very insoluble when silica lodges in the lungs elimination is difficult. Rock constituents of granite other than silica are probably injurious but in a lesser degree, and this is also probably true of limestone and the softer rocks. Ultimately a worker who daily inhales much granite dust has considerable deposited in his lungs. If he continues at his trade the lung tissue becomes harder and less elastic, he finds himself short winded, and in extreme cases death may come either directly or indirectly as a result of lung failure.

Feb 1, 1921

By Raja V. Rarnani, Robert L. Frantz

"Co-Directors, Generic Mineral Technology Center for Respirable DustEarly in the 1980s, the U.S. Bureau of Mines initiated the concept of the Generic Center, incorporating it into its mining research program, and in 1983, the Generic Mineral Technology Center for Respirable Dust was established. The Generic Center concept was first envisioned by the U.S. Bureau of Mines as a way to bring together the various different scientific, engineering and medical research interests in the respirable dust area to effect a coordinated and efficient organization for advancing knowledge in that field. The result was a combination of the collective talents and skills of more than 100 scientists, engineers, medical personnel and graduate students, through the formation of a consortium of five major research universities, including medical facilities, to perform respirable dust research. The Generic Mineral Technology Center for Respirable Dust consortium comprises The Pennsylvania State University (with its Hershey Medical Center) and West Virginia University (with its Medical Center) as the lead universities and the University of Minnesota, Massachusetts Institute of Technology and Michigan Technological University as affiliates.Although respirable dust-related disease remains the nation's worst industrial hazard, the fundamental understanding of all aspects of respirable dust associated with the mining and milling industries, including the interaction of dust and lungs, has grown significantly over the past near-decade toward the larger effort to reduce the incidence and severity of disease caused by respirable dust. Continued progress toward making the mine work environment cleaner and healthier remains the immediate objective of the Respirable Dust Center.The Respirable Dust Center's research program and technology transfer activities, described in this paper, exemplify the Generic Center concept first envisioned by the U.S. Bureau of Mines. Interdisciplinary and interactive studies continue to result in significant progress toward making mine atmospheres cleaner and healthier."

Jan 1, 1995

By Walter W. Fisher

Cement copper was flash roasted in a vertical tube furnace to convert the copper to acid-soluble oxides as part of a postulated process for refining cement copper by oxidation roasting, acid leaching, and electrowinning. The results of the study showed that the oxidation was a linear function of oxygen concentration between 0 and 20 percent, but above 20 percent oxygen there was no further increase in oxidation. Therefore, air was the optimum oxidizing atmosphere in this flash roasting system. The oxidation followed a parabolic rate law as the roasting temperature was increased from 400° to 800° C. Extrapolation of the data, based on the parabolic law, indicated that at 400°, 500°,600°,700°, and 800° C, the roasting times required for complete conversion to soluble oxides were 75, 37, 21, 7.7, and 4.6 seconds, respectively. Cyclic-roasting test results did not substantiate the predictions obtained through data extrapolation.

Jan 1, 1973

By Harold J. Bennett

This report deals with the processing and marketing of iron and steal scrap in the intermountain States of Arizona, Colorado, New Mexico, Utah, and Wyoming and the northwestern Plains States of Nebraska, North Dakota, and South Dakota. The quantity and quality of iron and steel scrap consumed in both the steel mills and iron foundries in these States in 1964 were decided by (1) the type of facilities used to produce an end product; (2) the availability of a dependable source of iron and steel scrap at competitive prices; and (3) the, ratio of the cost of iron in iron ore to iron in scrap. In recent years the quantity of scrap used per ton of steel ingot produced has decreased. The major individual. consumers of iron and steel scrap were the steel mills in Arizona, Colorado, and Utah, foundries in Utah and Arizona, and copper leaching, operations in Arizona, New Mexico, and Utah. About 2 million tons of iron and steel scrap was used by the iron and steel industry in 1964. Although there has been a decline in the amount of scrap used per ton of steel ingot produced because of changes in steelmaking methods, there has been a slight increase in the overall quantity of scrap used because of the increase in ingot production. It is estimated that the scrap consumption in the steel industry will increase by 19 percent by 1980. In addition to the scrap consumed by the steel industry, 273,000 tons of ferrous scrap were used by copper-leaching operations. Thirty-one percent of the ferrous scrap used by the steel industry in 1964 was purchased from dealers and other sources. The CF&I Steel Corp. (formerly The Colorado Fuel and Iron Corp.) at Pueblo, Colo., complemented its blast- and open-hearth-furnace operations with basic-oxygen converters in 1962. The basic-oxygen and open-hearth furnaces were charged with 30 and 90 percent scrap, respectively. Future use of the open-hearths would probably be used to supplement ingot production requirements. Because it was more economical to use less scrap and a high molten-metal charge, the United States Steel Corp. at Geneva, Utah, which uses the open-hearth process to make steel, charges the furnaces with 25 to 35 percent scrap. The Allison Steel Manufacturing Co. at Tempe, Ariz., uses a 100 percent scrap charge in its electric furnace. Although it was estimated that there were 327,000 tons of various grades of motor vehicle scrap generated in 1963, no estimates were made concerning the total quantity and grade of scrap available in the area. Most of the scrap used in the steelmaking industry originated within the area. It was advantageous to sell scrap generated in eastern Nebraska, North Dakota, and South Dakota to markets in the Midwest because of freight costs.

Jan 1, 1967

By Robert S. Sanford

The Broughton and Ring magnetite deposits in Essex County, N. Y., are thought to be in a mineralized belt that extends from the Lake Sanford mining district to Lake Champlain and passes through the Mineville district. The country rook is syenite-gneiss, similar to that in the Mineville area. The Bureau of Mines conducted a vertical magnetometer survey of the area. On the Broughton properties there are no indications, magnetically, of magnetite in any degree of concentration. 'On the ding properties a number of sharp, localized magnetic anomalies were observed. One core-drill hole was bored to a, depth of 48.3 feet, also, to test one of the strongest anomalies. The field work was in progress from December 1943 to July 1944. Although no iron ore was intersected by' the drill hole, it showed that the amphibolite rook, at a depth of 6 to 100 feet below the surface, contained enough magnetite and iron sulfides to account for the anomalies recorded by the magnetometer survey.

Jan 1, 1949

By R. V. Ramani, R. Bhaskar

"One of the primary means of control of health hazards from respirable contaminants in mine atmospheres is through design and operation of mines to meet mine health and safety regulations and recommended practices. A U.S. National Academy of Sciences study concluded that for significant progress in coal mine dust control, research should be directed more toward obtaining fundamental understanding of the origin, transport and characteristics of respirable coal mine dust. Theoretical and experimental studies on transport of dust · in mine airways, particularly coordinated efforts to validate theory with practice, are scarce. Some empirical models, developed on the basis of experimental data, are available but these models cannot be applied to new conditions. The purpose of this paper is to present the results of theoretical and experimental studies on the transport and deposition of dust in mine airways. This study is a part of an ongoing research project in the Generic Mineral Technology Center on Respirable Dust.In the paper, the assumptions of the modeling phase of the project and the development of a convectiondiffusion equation for dust transport in mine airways are outlined. The important aspect of the modeling effort is the capture of the deposition phenomenon. The experiments performed under controlled conditions in a typical mine airway, as well as under normal mine operating conditions, are discussed. The comparison of the model predictions with experimental results are made to identify critical areas of agreements and deviations. The implications of the findings and areas for further research and development are presented."

Jan 1, 1990

By Lippe D. Sadwin

This report describes a high-speed streak camera technique for measuring the lateral shock pressure generated by a cylindrical explosive charge detonated from one end. Experimental data show that the magnitude of the lateral pressure is approximately 50 percent that of the pressure generated from the terminal end of the charge for three explosives studied.

Jan 1, 1965

By John Nagy

This circular has been prepared for the guidance of safety engineers, shot firers, and coal-mine inspectors concerning multiple blasting with short-delay (millisecond-delay) detonators. These special precautions are suggested in addition to those normally followed in blasting, as outlined in the Federal Mine Safety Codes 5 6/ and in Miners' Circular 58.7/ INTRODUCTION The use of short-delay blasting has been proposed for promoting safety and increasing the rate of production in coal mining. Ideally, short-delay blasting, as compared with equivalent single-shot blasting, reduces exposure of the shot firer to dust, fumes, and weakened roof; as compared with equivalent simultaneous blasting, it reduces roof disturbance.

Jan 1, 1959

By J. M. Stuve

Calorimetric data for the dissolution of scandium sesquioxide and scandium trichloride in 4.360 molal hydrochloric acid were used to evaluate the standard heat of formation of ScCl3(c). The heat of reaction for Sc(c) + 1.5Cl2(g) = ScCl3(c) at 298.15° K was computed as -225,440 ±340 cal/mole.

Jan 1, 1965

By W. A. Grosh

The Bureau of Mines began a comprehensive investigation of the old lead diggings in the Wisconsin portion of the Upper Mississippi lead-zinc field in September 1947 to determine whether enough lead was present in shallow deposits to justify exploitation by modern open-pit methods. Because of the large number of areas of surface diggings, it was necessary to limit the investigation to only a few representative areas. Initial studies, therefore, included test pitting and hand auger-drill sampling at two sites n Grant County and one site in Lafayette County to determine whether further extensive sampling in that area was warranted. Results indicated that certain portions of the area contained substantial amounts of lead and, zinc; accordingly, more detailed sampling was undertaken, and the results will be described in a later report. Another phase of the general investigation was drilling and test pitting at the Nigger Jim Lafayette County. This 10 the third of the series and summarizes the work on the White property to develop the western extension of the Big Dick ere body, where four churn-drill holes totaling 679 feet were drilled. Inclusion of the White property in the study was justified because old reports indicated (1) production of ore from mines in the vicinity disclosed a high ratio of lead to zinc, (2) ore was present in the west heading of the Big Dick mine when it closed, and the attitude of the Big Dick ore body was such that a vertical hole would encounter ore that might be present.

Jan 1, 1950

By S. H. Katz

"At the annual meeting of the International Association of Fire Engineers at Kansas City, Mo., in June, 1919, the Bureau of Mines offered to cooperate with municipal fire departments for the purpose of obtaining information regarding composition of the air in burning buildings. (Katz, S. H., Statement made at Convention of International Assoc. of Fire Engineers: Fire and Water Eng., vol. 66, July 16, 1919, pp. 129-30, also Fireman's Herald, vol. 78, July 12, 1919, pp. 48.) The gas-mask laboratory of the Bureau's experiment station at Pittsburgh sent vacuum bottles for taking samples to fire chiefs in twenty-five cities, who had signified their intention to aid in this work. It was hoped to obtain one hundred or more samples, because statistics in quantity are necessary for drawing reliable conclusions concern-in the likelihoods of encountering irrespirable as in burning buildings. This far, eleven samples have been received by the laboratory. Results of analyses and pertinent data regarding these samples are given in the accompanyingEight of the eleven samples contained, no carbon monoxide; seven of the eight were taken above the ground level and one below ground. One sample taken above ground contained 0.03 per cent carbon monoxide, and this quantity is not dangerous to breathe for a limited time. Of the three samples taken below ground, one contained no carbon monoxide; the other two contained 0.10 and, 0.35 per cent, respectively. This indicates that in a burning building, the hazard from carbon monoxide is much greater below the ground level. The cause undoubtedly lies in the poorer ventilation that is usually found in cellars or basements. Abundance of ventilation provides the necessary air for complete combustion, or if incomplete combustion does occur, the carbon monoxide generated by the fire is greatly diluted with fresh air and swept away by the current. It may be noted that the highest proportion of carbon monoxide was found in a cellar where a fire as burning among piled cases. The difficult access of air to the burning parts facilitated the formation and lib ration of carbon monoxide. The smoke here was very light and no difficulty was experienced in breathing. Some of the air containing dense smoke showed little change from normal air by analysis. Thus the density of smoke or the irritation and difficulty it causes in breathing are no indication of the presence of poisonous gas. None of the samples shows important oxygen."

Nov 1, 1920

By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan

"IntroductionInhalation of crystalline silica is often associated with the development of pulmonary disease (Ziskind et al., 1976). Recently, it has been proposed that freshly sheared silica .may have surface properties that make it more reactive with lung tissue than aged silica, and that this unique reactivity ·of freshly crushed silica enhances its pathogenicity. A recent study in our laboratory strongly supports this theory (Vallyathan, et al., 1988a; 1988b). We found that grinding of silica cleaves bonds in a silica tetrahedral lattice generating reactive free radicals sites on the surface of the silica particles. The presence of surface radicals on freshly ground silica was monitored by electron spin resonance (ESR) spectroscopy. The ESR signal generated from fresh silica in air is characteristic of Si-0 and Si radicals. Evidence, i.e., the ESR signal after the addition of a spin trap (DMPO) and its sensitivity to ethanol, indicates that these silicon-based surface radicals can react with water to form hydroxyl radicals (OH). Results also indicate that these surface radicals make fresh silica more cytotoxic than aged silica; i.e., fresh silica causes more membrane damage as evidenced by hemolysis and lipid peroxidation. Therefore, the presence of reactive sites on the surface of freshly cleaved silica may play a significant role in its pathogenicity.If surface· free radicals are related to cytotoxicity, then screening dusts for the existence of such radicals may predict their relative pathogenicity. Since an ESR spectrometer is not available to many laboratories, the objective of this study was to develop a quick and simple technique to monitor the existence of reactive surface sites on dust. The technique chosen was the measurement of chemiluminescence using a liquid scintillation counter; i.e., an instrument which·would be accessible to most investigators."

Jan 1, 1989