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By Michael D. Fenton

Social and political movements that had been gathering momentum over several years continued in 1993 to dramatically affect and inspire uncertainty on the global mineral industry. Privatization of government-controlled mineral industries continued throughout the world, especially in Africa, Asia, Central Eurasia, Eastern Europe, Latin America, and Western Europe. The reasons for privatization varied among regions and countries, but the trend was universal and was not expected to end soon. Regional trade blocks were being developed and expanded. The European Union (EU), the North American Free Trade Area (NAFTA), the Association of Southeast Asian Nations (ASEAN) , the Asia Pacific Economic Cooperation (APEC) , and the Latin American Southern Cone Common Market (MERCOSUR) were expected to contribute to reduced internal tariffs and increased minerals trade. Minerals consumption within the politically unstable former Soviet Union (FSU) decreased significantly without a simultaneous cutback in production, while its exports flooded the world's mineral markets. These exports into Western Europe and Japan, still in economic recession, depressed minerals and metals prices worldwide, especially for aluminum, magnesium, nickel, and potash. Increasingly restrictive environmental laws and land-access limitations in Australia, Canada, Western Europe, and the United States tended to discourage mineral resource development. However, the number of undeveloped countries in Latin America and Asia that encouraged exploration and development by revising mining and tax laws and regulations increased, thereby increasing investment opportunities for foreigners.

Jan 1, 1995

By Kenneth B. Higbie

Expenditures to advance scientific technology in general reached an all time high in 1965 with some $22.2 billion estimated to have been allocated by government and industry. Federal Government expenditures were estimated at $15.4 billion, with almost 90 percent of the funds devoted to programs involving defense, atomic energy, and outer space efforts. With this massive effort in the United States and a very impressive effort elsewhere in the world, there is little wonder that many new metallurgical developments were announced in the technical press during the year. No effort has been made to cover all aspects of the industry, but a few of the developments are described in this chapter.

Jan 1, 1966

By J. W. Horne

The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the non-condensable gases evolved when crude shale oil is distilled under pressure. Hydrogen sulphide is one of the components found in the complex mixture of Gases produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills. The study required a complete extraction of all the hydrogen sulphide from the gas stream after it left the water-cooled distillate condensers and before the gas stream entered the charcoal absorber for removing the light naphtha. In devising the method it was necessary to take into account a constant variation of velocity, pressure, and percentage of sulphide in the total gas stream coming from the still. Ordinarily, the quantitative determination of hydrogen sulphide in gas is made by analyzing small samples taken at regular intervals. This estimation can be accomplished by use of the Bunts gas burette as modified by Tutriler, or by a similar method. In the industries where the flow of gas is constant and of uniform composition, this practice is sufficiently accurate for plant control. For experimental work where many variables have to be taken into consideration, as in the case at band; these methods are not applicable.

Jan 1, 1931

By J. D. Hadden

The Bureau of Mines conducted drilling studies in the Pocahontas No. 3, the Pittsburgh, and a western coalbed to establish the gas migration characteristics for each. Gas pressures in the Pittsburgh coalbed were about 260 lb/in2 and in excess of 550 lb/in2 in the Pocahontas No. 3. Caving in drill holes prevented pressure measurements in the western coalbed. The Pittsburgh coalbed contained intersecting "clay veins" which formed gas pressure cells. Although these geological features hamper mining, they can be used to control the flow of methane into a mine working. Methane control techniques are proposed for the Pittsburgh and Pocahontas No. 3 coalbeds.

Jan 1, 1969

By Wilbur I. Duvall

In a previous report, entitled A Gage and Recording Equipment for Measuring Dynamic Strain in Rock, a control circuit for a drum camera was described. The purpose of this control circuit was to provide a means for firing seismic caps, synchronizing the firing of the cap with the opening of the camera shutters and generating an electrical impulse at the instant of detonation. The operation of this circuit depended on the following two characteristics of seismic caps: (1) these caps contain a bridge, which breaks at the instant of detonation, and, the firing delay time of the cap is a function of the firing current. During the course of the Bureau's studies, considerable difficulty was experienced from "firing hash", i.e., spurious vibrations that appeared on the records at the time of detonation. The cause of most of this "firing hash" was traced to the intermittent grounding of the cap leads at the time of detonation. As the cap leads were still connected to the firing battery, the grounding of the leads permitted current to flow through the rock to the gage and to return to the firing battery through the shield on the gage cables. The intermittent flow of current along the cable shield produced potentials on the gage leads that were recorded as the "firing hash." To eliminate this difficulty, it is necessary to remove the firing voltage from the cap leads the instant the cap detonates. This report supplements the previous report and describes an improved circuit that can be used to fire seismic caps, remove the firing voltage from the cap leads the instant the cap fires, control the firing delay time in the cap, and generate reference signals at the time current starts flowing in the cap circuit and at the time the cap detonates. These reference signals can be used to determine the firing delay time of seismic caps and the time at which the seismic wave is generated by the explosion.

Jan 1, 1950

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By M. G. Pelipetz

High-pressure, high-temperature hydrogenation of coal has been known and practiced for many years. A full' understanding of the mechanism in this process by which coal is converted to oil and gas must rest on a critical interpretation of the manner in which external variables influence the rate and the course of the coal-hydrogenation reactions. Same Bureau of Mines studies on the effect of temperature, catalyst, and rank of coal on these reactions have been published. The effect of pressure was not studied in this earlier work, and the effect of reaction time was complicated by the interruption of long reaction periods in order to refill the autoclave with hydrogen. It is the purpose of this paper to present data from more recent autoclave experiments that extend the results of Storch, et al, on the kinetics of coal hydrogenation. These data must be explained by any comprehensive theory of coal hydrogenation; their detailed evaluation, however, will be deferred until a later publication.

Jan 1, 1949

By L. A. Stewart

"SUMMARYThis paper describes most of the chrysotile-asbestos deposits of Arizona. Mining methods are discussed briefly and asbestos-mill flowsheets are incorporated. Arizona asbestos mines are the only sources on the American continents of naturally iron-free chrysotile spinning fiber that is so urgently needed for electric-cable coverings, especially on warships.Asbestos was first recorded and recognized in Arizona in 1872, and a minor amount was produced from a deposit in the Grand Canyon in 1900. The discovery of a deposit in the Salt River district in 1912 initiated intensive prospecting, and deposits soon were developed. The total Arizona production of all grades of asbestos through 1953 is estimated at 30,000 to 35,000 tons.The deposits of the Central Arizona region, which are discussed in this paper, are scattered over nearly 2,000 square miles. The annual output is relatively small, because the asbestos occurs in thin, discontinuous veins and only in areas where intrusions of diabase are adjacent to or crosscut certain favorable units of the pre-Cambrian Mescal limestone. This stratigraphic limitation, combined with other essential geologic conditions, tends to restrict the size of the deposits.Virtually all of the deposits are in rugged, mountainous country, and many of the mines are on steep canyon walls. In the average mine, production of 1 ton of commercial asbestos requires removal of 30 to 40 tons of waste rock. Mining and transportation costs consequently are high.Several deposits of chrysotile that is somewhat harsh and of moderate tensile strength have been known for years but were not worked because of the former exacting demands of industry for high-strength, soft asbestos. However, improve¬ments in asbestos fiberization and spinning technique, combined with the urgent need for asbestos, have made this so-called semisoft fiber desirable, and deposits of this type now are being exploited."

Jan 1, 1955

By John Jordan, Tesarik, Steven J. Knoll, Theodore J. Williams, David K. Denton, Douglas F. Scott

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because this condition can result in failures of ground that lead to both injuries and death. Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health studied two methods for identifying stress in rock. A seismic tomographic survey, finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology were integrated to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. Electromagnetic (EM) emissions were also investigated in the Galena Mine, a deep underground mine in Idaho, in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results of this research indicated that (1) seismic tomography appears to be a useful tool for determining relative stress in underground pillars, while (2) EM emissions do not appear to be significant precursors of impending catastrophic ground failure.

Jan 1, 2004

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

6. Development of Mine Sealant Material Systems 6. 1 Introduction The preliminary evaluation of material systems described in Section 3 led to the selection of the following four promising systems for further development: System A: Aggregate, Fly Ash System System B: Aggregate, Fly Ash, Urethane Foam System System C: Aggregate, Bulkhead, Light Expansive Concrete System D: Aggregate, Self-Supporting Thick Slurry Preliminary laboratory tests indicated that the building of effective bulkheads from one borehole would be extremely difficult. Two extra boreholes would be required adding to the overall cost of the system and making the system less attractive. Tests with light expansive concrete showed that bulkheads would be required, the material would not support itself. As a result, further development of this system was terminated. Foam concrete was selected as the most suitable material to be developed into a self-supporting, rapid-setting slurry. A laboratory investigation of its use for mine sealing was conducted during this program; the results are summarized in Section 6. 5 and details of the laboratory program are presented in Appendix B.

Jan 1, 1973

By LB. Berger

"INTRODUCTION The use of gasoline engines as the motive power for lift trucks, tractors, and other types of mobile equipment operated in enclosed spaces, such as industrial plants and warehouses, may create a hazard because of the carbon monoxide present in the exhaust gases of the engines; gasoline-powered equipment should not be used in mines or tunnels. Because the equipment is mobile, local ventilation usually is impracticable, and general ventilation of the spaces is nec-essary to dilute and remove the carbon monoxide. To estimate the rate of ventilation required in such situations, information is necessary on the concentration of carbon monoxide in the exhaust gas and the rate at which exhaust gas is produced under given operating conditions. The purpose of this paper is to present data that may be used in making estimates of ventilation requirements.COMPOSITION OF GASOLINE-ENGINE EXHAUST GASThe exhaust gas of a gasoline engine consists mainly of carbon dioxide, carbon monoxide, hydrogen, oxygen, and unburned hydrocarbons (usually reported as methane), together with the nitrogen present as a residue from the air sup-plied for combustion. 3/ The exhaust also contains water vapor resulting from combustion of the hydrogen of the fuel. The water-vapor content is not included in exhaust-gas analyses calculated on a ""dry"" basis and is not involved in the estimation of ventilation requirements."

Jun 1, 1947

By E. J. Gleim

For many years mining men have sought for a portable device that would be direct reading and permit more positive detection of methane than was possible with flame safety lamps, which depended so largely on the training, skill, and personal ability of the user. Through the years, after the discovery that methane contributed to many mine explosions, considerable effort and large sums of money have been expended in searching for and developing instruments that would be practical, and, at the same time, reliable and safe to use. Very early in the history of the Bureau of Mines, some of its engineers were unsuccessful, after many trials, in attempts to develop such an instrument. Commercial firms, however, persisted in research until today a number of instruments are on the market that have proved to be practical in coal-mine service. It is hoped, however, that further research will bring about improvements in accuracy and other desirable features. BUREAU OF MINES STANDARD FOR METHANE DETECTORS The Bureau of Mines recognized the need for establishing minimum requirements on which to base official approval of suitable Instruments. This standard was prepared as Schedule 8. It was revised before being issued in printed form. The revision was published as Schedule 8A in 1920 and was revised on two other occasions. The present edition, known as Schedule BC, was issued October 31, 1935.

Jan 1, 1954

By W. R. Huff

Yield stress and plastic viscosity values, determined from shear rate-shear stress relationships, were found to be a linear function of coal concentration for coal-water slurries containing 40, 45, 50, and 55 weight-percent of powdered coal. In the laminar region, the flow is described by an equation derived from the fact that the square root of the shear stress varied linearily with the square root of the shear rate. In the turbulent region, the friction factor was found to be inversely proportional to the velocity to the 0.12 power.

Jan 1, 1965

By Robert H. Lambeth

The Madison RARE II study area has four prospects with identified resources. These are listed in table 1 and are described in the following text. A high potential for Sillimanite exists at the Placer Creek occurrence (fig. 1, no. 7) and potential for phosphate rack in all areas underlain by the Phosphoria Formation. Some prospects exhibit minor potential for copper, lead, zinc, silver, and gold in the southern portion and very minor potential in the northern portion. Deposits in the northern end also have low potential for rare earth, asbestiform anthophyllite, or kyanite group minerals (including sillimanite).

Jan 1, 1982

By T. E. Gray

This report describes the preparation characteristics of the more significant coal beds in Allegheny County, Pa. It is one of a series planned to determine coals suitable for producing metallurgical coke, either as mined or after beneficiation. More than 7 million tons of coal was produced in Allegheny County in 1957. Of this, more than 5 million tons was cleaned mechanically in nine cleaning plants. The Bureau of Mines estimated that, as of January 1, 1953, more than 384 million tons of recoverable coal remained in the county in beds 28 inches or thicker.

Jan 1, 1959

By C. W. Dwiggins

The Bureau of Mines characterized the chemical and physical properties of metallo-organic materials in petroleum to determine their effect on petroleum production and refining. The structures and physical properties of porphyrins and materials that normally contain metalloporphyrins such as crude oils and asphaltenes were investigated using elemental analysis, NMR analysis, absorption spectrometry, and small-angle X-ray scattering. Petroleum fractions greatly enriched in metalloporphyrins were obtained using asphaltene precipitation, liquid extraction, and large-scale liquid-solid chromatography. Selected fractions containing porphyrins were further purified by chromatographic methods, crystallization, and demetalation followed by chromatography. Nonporphyrin metals could not be appreciably concentrated from the bulk of the asphaltene.

Jan 1, 1969

By William R. Sharp

This Bureau of Mines report details a technique for aiding the engineer with the long-range design of an underground mine. The method is based upon the assumption that sufficient data are available to assign numeric values to some finite number of mineralized blocks; assignment of numerical values is problem dependent. By assigning appropriate weighting schemes, the algorithm developed in this report may be used to solve the optimal end-of-life underground mine layout, design least-cost electrical layout networks and efficient material handling networks, find least risk escape routes in the event of an accident, etc. The method is based upon the assumption that sufficient cost and geologic data is available to build a detailed mineral block inventory of the mineral deposit. It is further assumed that the cost assigned to any minable unit is independent of the neighboring blocks. The basic approach relies upon concepts and ideas from the theory of networks. To make the approach user oriented, a computer program is included and discussed. The computer code is written for an orthogonal, three-dimensional set of blocks. Computational costs and experience indicate that the program could be of great benefit in evaluating large complex mineral properties from the viewpoint of predesigning an underground mine layout.

Jan 1, 1974

By Aarne Visnapuu

Experimental modifications have been made by the Bureau of Mines on standard pneumatic rock drills to reduce the noise of the air exhaust, drill steel resonance noise, and noise radiated by the drill body. A close-fitting case and muffler around the drill body, consisting of a metallic honeycomb skeleton filled with viscoelastic absorber on the inside and a durable outer shell, provide both exhaust and drill body noise muffling and absorption. Drill steel resonance noise is reduced by a constrained-layer treatment consisting of a tubular metal cover bonded to the ouside of the rod by a viscoelastic filler. Damping alloy components have been developed to reduce metallic resonance noise. Combined, these modifications have reduced the drilling noise level in granite from 115 dbA to 97 dbA. Data are presented on the individual and combined effects of these modifications on drilling noise and performance.

Jan 1, 1975

By John D. Corrick

Three species of chemosynthetic iron- and sulfur-oxidizing autotrophic bacteria have been isolated from the leaching waters of copper mining areas. These species are: The sulfur-oxidizing Thiobacillus concretivorus, the iron-oxidizing Ferrobacillus ferrooxidans, and a sulfur- and iron-oxidizing bacterium closely resembling Thiobacillus ferrooxidans, INTRODUCTION Among several suggested new processes for treating marginal ores in the United States, none is more intriguing than the possibility of extracting metals from low-grade materials by the action of microorganisms One phase of a Federal Bureau of Mines investigation toward developing such a procedure was to isolate and identify specific chemosynthetic iron and sulfur. oxidizing autotrophic bacteria native to certain domestic copper deposits where leaching is practiced. The bacteria or microorganisms considered important to this investigation are those capable of producing solutions of ferric sulfate and sulfuric acid. Solutions of this type are excellent solvents for some copper minerals By establishing the presence of these bacteria at certain copper-leaching areas, strength would be given to a theory that microbial activity is partly responsible for the oxidation that takes place at these areas. Their presence also advances possibilities for controlled use of microbial action in metal extraction processes. Leathen4/ has demonstrated that one of the chemosynthetic iron-oxidizing bacteria, Ferrobacillus ferrooxidans, can oxidize 200 parts per million of ferrous iron to the ferric state in 3 days,

Jan 1, 1961

The following are abstracts from papers presented at the 4th Symposium on Respirable Dust in the Mineral Industries and· were produced through research funding under the Generic Mineral Technology Center for Respirable Dust. Full articles appear in the proceedings published in July 1996 in Applied Occupational and Environmental Hygiene. (Volume 11, Number 7). The two addresses included in the proceedings point to the progress, prospects, problems, and perspectives on control of respirable dust and dust-related disease in the mineral industries. The symposium papers deal with respirable dust issues that are longstanding such as characterization, health effects, control of airborne coal dust, new and emerging issues such as iron toxicity, diesel particulates, and sampling. The papers were grouped into the following topics: continuous dust monitoring, encompassing the development of a fixed-site monitor that will provide continuous information on instantaneous and time-weighted respirable dust concentrations; mechanisms involved in the generation of dusts in mine environments, important for dust control at the source; characterization and control of diesel emissions (particularly diesel particulates) in mine atmospheres; mining systems effects and models; dust control in mine working faces and in milling environments; characterization of the physical, chemical mineralogical, and biological properties of the dust and their relevance to health effects and sampling; dust-lung interactions, encompassing results from several biomedical studies dealing with acute and chronic inhalation of airborne dusts and associated lung responses; the role of iron in causing lung injury; and therapeutic strategies for ·the control of pulmonary disease. All papers submitted to the organizers were peer-reviewed. In the proceedings, we have not differentiated among the platform and poster papers; rather, they have been grouped into the above topical areas. Taken together, these papers reveal significant progress in the control of dust generation, characterization of dust, understanding of dust-lung interaction, and mining and milling practices to reduce dust exposure - all essential for reducing dust-related occupational hazards at the workplace.

Jan 1, 1998