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By Gopala N. Krishnan

The most promising candidate for the recovery of alumina from non-bauxitic sources is the leaching of clay by HCL acid followed by crystallization of aluminum chloride hexahydrate (ACH) by hydrogen chloride sparging. Hydrothermal precipitation of boehmite ( ?-A100H) from aluminum chloride solution will simplify the process, will reduce energy consumption and will eliminate corrosion problems involved in calcination of ACH to obtain alumina. This report summarizes the results of Phase I of a program to study the precipitation of boehmite from AlC13 solutions. The amount of boehmite precipitation from dilute A1C13 solutions (5 wt%) is . negligible below 200°C. Above 200°C the precipitation increases with increasing temperature approaching 40% at 300°C. Addition of HCl acid to the dilute A1C13 solution even in small quantities drastically reduces boehmite precipitation. Solution impurities such as Fe, Ca, Mg, or Na substantially promote the precipitation of boehmite. No precipitation is observed from concentrated A1C13 solution (30wt%) representing the leach liquor.

Jan 1, 1980

By Stephen W. Lambert

The Bureau of Mines examined the wellbore of a vertical gas drainage well in the Mary Lee coalbed to determine the results of specific completion procedures in coal. A jet-slotting tool was used to cut four vertical slots through the casing about 1 ft below the coalbed. Even though stimulation treatment pressure was excessive, hydraulically induced channels were contained entirely within the target coal zone. Sand-filled, induced channels were horizontal, inclined, and vertical, and were propagated in directions similar to bedding planes, rock joint, and coal cleat directions measured in the mine. Variable gas flow rates, recorded during the productive life of the well, were attributed to chronic downhole pump malfunction and the slotted casing below the production zone.

Jan 1, 1978

By Oliver Q. Leone

Electrorefining tests using titanium-nitrogen alloys as anode material showed that no significant quantity of nitrogen was transferred to the cathode deposit. The nitrogen of the anode remained in the scale, and the titanium-nitrogen alloy was anodically insoluble in the electrolyte when the nitrogen content was 11 weight-percent.

Jan 1, 1966

By L. M. Demers, D. C. Kuhn, N. El-Ayouby, C. F. Stanley

"Oxygenated metabolites of arachidonic acid (MJ are produced by the alveolar macrophage (AM) and have been shown to mediate inflammatory reactions. We therefore assessed the production of eicosanoids by AM harvested from the lungs of rats ex· posed to a bituminous coal dust for 2 wk in an inhalation chamber in order to determine if AA metabolism was altered in a manner that may promote an inflammatory response in the lung. Exposure to coal dust resulted in a 66% increase in the number of AM harvested, an increase in thromboxane A2 (TxA;i) and leukotriene 84 (LTB,j) production to 222% and 181% of control values, respectively, and a decrease in prostaglandin E2 (PGE:i) production to '62% of control values. In AM harvested from rats allowed to breath clean air for 2 wk following coal dust exposure, PGE2 production returned to control levels but TxA2 and LTB4 production remained elevated. The TxA2 synthesis inhibitor UK 38,485 reduced TxA2 production in dust-exposed AM both immediately and 2 wk following exposure. Thus, exposure of rats to coal dust significantly alters the metabolism of AA in AM, with potentially important aspects of AA metabolism remaining altered even after a 2-wk recovery period. Based on the established role of eicosanoids in inflammatory and fibrotic processes, these results suggest that the alteration of AM eicosanoid production as a result of the inhalation of coal mine dust may be an important factor in the pathophysiology of coal workers' pneumoconiosis.The authors are grateful to Joan Greenwood and Barbara Scheetz for their excellent technical assistance and to Brenda Pavone for the preparation of the manuscript. This research was supported by the U.S. Department of The Interior's Mineral Institute Program administered through the Generic Mineral Technology Center for Respirable Dust under grant 1135142.Request for reprints should be sent to Douglas C. Kuhn, Ph.D., Department of Pathology, The M.S. Hershey Medical Center, Hershey, PA 17033.INTRODUCTIONPulmonary alveolar macrophages (AM) are activated by foreign particles and microorganisms that enter the small airways (Kass et al., 1966; Herscowitz, 1985). This defensive reaction involves phagocytosis, lysosomal enzyme release, and the generation of reactive oxygen species by the AM (Snella, 1986; Rich et al., 1987). A number of agents, including phorbol esters, zymosan, adenosine diphosphate, organic hydroperoxides, and calcium ionophore, have been shown to activate the AM in vitro (Badger, 1986; Marshall and Lands, 1986; Snella, 1986). The AM response to these activators appears to be mediated in part by the oxygenated metabolites of arachidonic acid (AA) (Bertram et al., 1988; Demers et al., 1987; Mcleish et al., 1987).The AM may metabolize AA through cyclooxygenase- and lipoxygenase- catalyzed pathways to produce a variety of eicosanoids including prostaglandin (PG) E2, thromboxane (Tx) A2, leukotriene (LT) B4, LTC4, LTD4, and several hydroxyeicosatetraenoic acid derivatives (HETEs) (Willis, 1970; Camp et al., 1983; Poubelle et al., 1986). The production of these eicosanoids may enhance the. defensive ability of the challenged lung since they stimulate chemotactic cell recruitment to the site of invasion, enhance extravasation of circulating immune cells, and promote local vasodilatation. However, continued stimulation of the AM population, with the consequent production of proinflammatory eicosanoids, may ultimately enhance the disease process by contributing to chronic bronchoconstriction, fibrosis, and the persistent release of toxic oxygen species."

Jan 1, 1990

By David P. Lindroth

The objective of this research by the Bureau of Mines was to determine the technical feasibility and associated pilot data for drying minus 1/4-in coal with microwave energy at a frequency of 2.45 GHz. The drying data were obtained experimentally on three coal types: bituminous, subbituminous, and lignite. The experiments were performed with a custom-designed conveyorized microwave oven having a continuous power capability of 12 kW. Drying efficiencies near the theoretical maximum of 1.54 kg of water per kilowatt hour of energy input were achieved for two coals and two sizes; overall drying efficiencies averaged 77 pct.

Jan 1, 1986

By R. J. Leary

The natural gas-air burner described in this report was designed and constructed to meet the thermal requirements of a convective process for heating steel scrap. This process involved downward combustion of natural gas with air, blending the combustion products with diluent air, and then passing this tempered stream of gases downward through a porous bed of steel scrap contained in the furnace chamber. The scrap would be heated to a temperature limited by the adiabatic flame temperature of the gas stream in a period that depended on the rate at which heat was supplied per unit of bed cross section. The temperature of the gas stream would be limited to that beyond which an objectionable degree of oxidation would occur; for carbon steel this limit had been found to vary from 1,900° to 2,100° F. with the superficial velocity of the gas stream. The productivity of the process was dependent on the rate of heat input per unit of furnace cross section; for the 3-foot-diameter experimental furnace an input of 680,000 B.t.u. per hour was desired. The burner described was designed to meet these conditions of temperature and heat input. It provided for three streams of entering gases: (1) A primary air-fuel mixture too rich to be combustible, that is, above the upper flammable limit; (2) secondary air for combustion of the primary mixture; and (3) tertiary air, principally for cooling the combustion products to the temperatures desired for process operation. Downward combustion of the primary and secondary streams occurred in a flame stabilized on an annular port, while tertiary air flowed in an annular path surrounding the port and also through an axial channel whose wall formed the inner ring of the annular port. This burner performed beyond the designed heat-input rates while producing stable flames, which were adjusted readily to the temperatures desired. Gas-stream temperatures were easily controlled to within 15° F. of the desired value by simple manual adjustment of the flow valves.

Jan 1, 1959

By James S. Browning

The Bureau of Mines conducted laboratory and small--scale continuous tests of weathered mica pegmatite ores from Hart County, Ga., to determine the technical feasibility of recovering commercial-grade mica concentrates by flotation. Two modifications of the Bureau-developed anionic-cationic method were used. In one method, sodium carbonate and calcium lignin sulfonate were used for pH control and quartz depression; this method yielded mica concentrates containing 98.5 percent mica with a recovery of 91.4 percent. In the other modification, lime and sodium silicate were used with the calcium lignin sulfonate; concentrates containing 98.9 percent mica with a recovery of 86 percent were obtained.

Jan 1, 1966

By T. M. Barczak

One of the primary goals of Bureau of Mines research is to reduce the cost of coal mining by improving the efficiency of longwall supports. One method of achieving this goal is the optimization of stress distribution within the support structure, resulting in a lower overall weight, more fully stressed shield. However, before stress optimization can be initiated, load conditions must be defined that cause maximum stress in the various support components. A finite-element model of a longwall shield was used to identify these critical load conditions. These load conditions were then evaluated in the Bureau's mine roof simulator (MRS) by instrumentation of a longwall shield and measurement of strains in each of the shield components. The critical (canopy-base contact) load conditions were identified that can cause structural failure at less than rated shield (hydraulic yield) capacity. Comparisons were made between full-contact and partial-contact load conditions. Other parameters investigated included the stiffness of the contact material, changes in shield geometry, rate of load application, and effects of horizontal constraint. Conclusions were drawn regarding the structural integrity of the major shield components and potential for stress optimization.

Jan 1, 1987

By A. B. Needham

Graphite is a raw .material of considerable importance in both waxy and peace. Two types of graphite, classified according to particle size as flake and fines, are used, but the former is in much greater demand. The principal wartime use of graphite is in the manufacture of crucibles for melting brass and special alloys of copper and steel. Other uses in both peace and war are as lubricants, for foundry facings, and in paints, electrodes, batteries, motor and generator brushes, and a variety of other commodities. . This paper describes the operations of the Southwestern Graphite Co. of Los Angeles, Calif., which produces both flake and fine graphite from a property in Burnet County, Tex.

Jan 1, 1946

By J. A. Herdlick

The Star mine, near Neihart, Cascade County, Mont., has been in continuous operation since the construction of a 50-ton bulk flotation mill in 1939. The mine was examined by G. N. Bennett, an engineer of the Bureau of Mines, in November 1942. At that time the life of the operation appeared to be limited and a program of crosscutting and core drilling were recommended. The program had as its objective the investigation of a promising undeveloped area lying west of the Star vein and, if possible, the development of enough reserves in this area to insure continuous operation during the war emergency. Development of additional reserves would then justify necessary changes in the mill in order to eliminate the heavy penalties imposed for excess zinc in the bulk concentrates. The Bureau of Mines work began in February 1944 and was completed in September 1944. The project was started by Wilder R. Brinton and continued by Thomas W. Oster, mining engineers in the Bureau's Montana district office. Beneficiation tests on are and concentrates were made after completion of the underground work. This report presents the factual data obtained during all phases of the Bureau's investigation.

Jan 1, 1949

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By Paul M. Tyler

The value of mica depends chiefly upon the size of the flat sheets into which it can be split and also upon whether it is clear or stained. Muscovite (white mica) and philogopite (amber mica) are the micas of commerce. Biotite (black mica) and other varieties are virtually unsalable. Vermiculite, an altered mica having the extraordinary property of expanding greatly when heated, preferably should not be classed commercially as mica. Mica is marketed as (1) cut or uncut block, (2) sheet, (3) splittings, and (4) wet or dry ground mica. In the United States, mica that will not yield flat films over about 1-1/2 inches square, or that is ruled, rumpled, or flawed in any way, can be sold only as scrap, its sole use being for making ground mica. Only sizes that will yield rectangles 1-1/2 by 2 inches or larger can be classed as sheet quality; slightly smaller sizes may be classed as punch, and under certain circumstances still smaller sizes, down to about 1 inch square, may be used for splittings, which are mostly a thousandth of an inch thick or even thinner. Splittings, however, are produced in large quantities only in British India, where labor costs very little. Even there the work is done mostly by children, who not only work cheaper but have a delicacy of touch that enables them to do the splitting faster and better. No mechanical process yet devised will permit ordinary splittings to be made economically in the United States.

Jan 1, 1938

By Charles L. Kimbell

In 1988, the aggregate value of total world international export trade in mineral commodities was estimated at nearly $542 billion in current (1988) dollars, which was about 8.6% above the 1987 level, but still 23.7% below the record high set in 1980. Comparable comprehensive data for 1989 were not available in time for inclusion in this chapter, but 1989 returns for developed market economy countries only were 1 1.8% above those for 1988. These countries accounted for about 50% of the total mineral commodity export trade in 1988. It would be unsound to utilize the overall 11.8% growth rate for mineral commodity export trade for these countries to extrapolate the growth in total world mineral commodity trade because these developed market economy countries account for substantially different shares of the five major mineral commodity groups listed in table 2. Specifically, developed market economy countries in 1988 accounted for 56% of world export of ore, concentrate, and scrap, 74.7% of world exports of iron and steel, 71.7% of world exports of nonferrous metals, and 57.8% of all exports of crude nonmetals, but only 26.6% of world exports of mineral fuels. Moreover, even within each of these groups, the actual product mix included in developed market economy country aggregates differ from that in developing market economy country aggregates and in centrally planned economy country aggregates. Nonetheless, an increase of 9% to 12% in the value of world mineral commodity export trade seems indicated by available returns.

Jan 1, 1992

By Miro Mihelich

The mines and prospects in the vicinity of Landlocked Bay, 25 miles southwest of Valdez, Alaska (fig. 1), were examined, mapped, and sampled in July and August 1955 as part of a comprehensive investigation by the Bureau of Mines of ore deposits adjacent to Prince William Sound. The purpose of the investigation is to establish and record the location, nature, extent, and metallurgical characteristics of copper and associated metallization in the Prince William Sound district and to indicate, if possible, those areas in which additional exploration and development may be justified. Of particular interest are the possibly numerous deposits of massive iron sulfides that were neglected during early mining operations. These deposits may constitute important reserves of sulfur and iron. At Landlocked Bay deposits of copper-bearing iron sulfide minerals have been mined or partly explored through mine workings, which are in a zone about 1 mile wide along the western side of a large overthrust fault known as the Landlock Overthrust. Eight of the principal mines along this zone were examined end sampled. Although only three of the mines have a recorded production of shipping-grade copper ore, all have deposits of copper-bearing iron sulfide minerals that are similar in occurrence. The deposits occur as lenticular masses and disseminations of chalcopyrite, pyrite, and pyrrhotite which replace crushed rock or fill cavities along shear zones in greenstones and in sedimentary rocks that are exposed between sea level and an altitude of 2,500 feet. These lenticular masses of sulfide minerals range in size from small pods to ore bodies that have been stoped to maximum widths of 9 feet, strike lengths up to 70 feet, and dip lengths as much as 350 feet. Where accessible for sampling,, the copper content of the deposits ranged from a few hundredths of a percent to over S percent; zinc, gold, and silver are present in negligible amounts. Flotation tests of a sample composited to represent typical mine-run ore indicate that 81 percent of the copper is recoverable in a product assaying 28 percent copper at a concentration ratio of 17.5 : 1. INTRODUCTION Statistical records indicate that approximately 110,000 tons of metallic copper (about 16 percent of total Alaskan production) was produced from mines adjacent to Prince William Sound during the 40-year period ended in 1938. Although the principal production was from a large-scale mining and milling operation on Latouche Island (Kennecott Copper Corp., Beatson mine), a substantial amount of the total copper was derived from direct-shipping ores selectively mined or hand-sorted from numerous other deposits in the district. No production has been made since 1938; many of the claims have long been abandoned, and mine workings are either caved or deteriorating rapidly.

Jan 1, 1957

By G. Richards Gwinn

The mineral olivine, though known to mineralogists for many years, was of little commercial value in the United States before 1933. It was first described in 1790 by Johann Gottlieb Werner, who named it "olivine in allusion to its olive-green color. Commercial olivine first attracted attention because of its refractory properties. Further research has developed methods of extracting the magnesia content for the production of various magnesium compounds. Experimental and pilot-plant work also are in progress to make olivine available as a low-cost raw material for the production of magnesium metal.

Jan 1, 1943

By Dorothy M. Richardson

The Bureau of Mines has participated in the American Petroleum Institute Research Project 48A (API-RP48A) program on the Separation and Identification of Sulfur Compounds in Crude Petroleum. The lack of reference compounds or infrared spectral data has made difficult the identification of individual sulfur compounds boiling above 140° C. The recent acquisition of 24 alkylthiophnnes has made possible a limited study of this important class of sulfur compounds. The infrared spectra of 2-monoalkylthiophenes and 2,5-dialkylthiophenes for the 2 to 15p range are reported. Correlations for determining the 2-alkyl and 2,5-dialkyl substituted thiophenes are derived from this information. The 2-alkylthiophenes show a unique pattern in the 5.50 to 6.54 region, while the 2,5-dialkylthiophenes show a distinctive pattern in the 5.6µ to 6.7µ region. A skeletal vibration occurs in the 9.5 to 10.0µ region for all of the thiophenes investigated. These data will aid the infrared spectroscopist in the identification of compounds of the type reported.

Jan 1, 1961

By C. A. Frenzel

Extensive spectroscopic data are needed in making reliable vibrational assignments for use in calculating thermodynamic functions of polyatomic molecules. The fundamental vibrations of organic molecules may be observed at any wavelength from 2.5 to 200 microns (micron = µ = 10-4 centimeters), but most often in the region from 3µ to 50µ. Raman spectra generally cover the range in which fundamental vibrations occur, but equally important infrared spectra usually are not measured at wavelengths longer than 25µ. This limitation results because most infrared spectra are determined for analytical purposes, which seldom require information outside the region 2µ to 25µ. Measurements of infrared spectra in the range 15µ to 35µ recently were begun by the Bureau of Mines to obtain data needed in making vibrational assignments. This report presents the spectra of the following thirteen compounds: Tetrahydrofuran, 1-methylpyrrole, piperidine, 2-methylpyridine, 3-miuthylpyridine, 2-propanethiol, cyclopentanethiol, 2-methyl-2-butanethiol, 3,3-dimethyl-2-thiabutane, cyclohexanethiol, cyclopentyl-l-thiaethane, 2,4-dimethyl-3-thiapentane, and hexamethyldisiloxane.

Jan 1, 1960

By R. C. Hickman

"INTRODUCTION The largest known deposits of ilmenite and rutile in Virginia are in Amherst and Nelson Counties. Other deposits occur in the State, but their extent is not known. One of the most promising of the latter is the deposit in Roanoke County on the T. M. Bush and the H. L. Hutchins property near Roanoke. A geophysical survey was made of the deposit, followed by core drilling. In April and May 1946, four holes were drilled, totaling 822 linear feet.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.The project was under the immediate supervision of Mitchell H. Kline, chief, Raleigh Division, Mining Branch,. Bureau of Mines."

Aug 1, 1947

By M. H. Kline

The Scarlet mine, in Randolph County, N. C., was operated on a small scale at intervals from 1899 to 1915, but no records of the quantity of ore produced are available. J. I. Moore unwatered the mine in March 1948, and Bureau of Mines' engineers examined the underground workings. Several assays checked previous sampling of the mine and indicated a small but comparatively high-grade copper-zinc deposit. The high metal content of the veins and the possibility of developing additional reserves prompted the Bureau of-Mines to drill three holes, totaling 530 feet, at the deposit during March and April 1948. Drilling disclosed that the mineralized vein did not extend over 300 feet along the strike and is probably limited in depth to the contact with the granite mylonite.

Jan 1, 1949

By W. M. Myers

[The principle of the application of electrolytes for deflocculation of fine materials in order that impurities may settle out, and the subsequent flocculation of the suspended particles by a different reagent, is well known and has been applied successfully to clays. Flocculation is also applied with success to ore slimes. Thus certain electrolytes, particularly alkalies added to a suspension of colloidal particles cause deflocculation so that, suspension may be-maintained indefinitely. The addition of bother electrolytes particularly acids, on the contrary produce's flocculation and the articles produce's are rapidly precipitated from suspension leaving a clear liquid above: the precipitated mass. Salts of trivalent elements such as aluminum act similarly. Due to its cheapness the double sulphate of aluminum and potassium, ordinary alum, has been used extensively for treating clays. These properties of electrolytes. and. their utilization in the commercial: preparation of clays have been described in publications of the Bureau of Mines.2]

Jan 1, 1927