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By D. R. Mathews

The solubility of carbon in electrorefined vanadium was determined to be approximately 0.27 wt pct at the eutectic temperature 1,650° C and 0.03 wt pct at 700° C. The tensile strength and hardness of vanadium increased with car-bon content to the solubility limit, but this effect was small, probably because of the narrow solubility range. Between the solubility limit and 0.3 weight-percent carbon, the second phase had essentially no strengthening effect in vanadium. The second phase, observed metallographically at the grain boundaries and within the grains, was shown by autoradiography to contain high-carbon concentrations. This second phase was identified as VgC by X-ray analysis. The VgC in the grain boundaries contributed largely to the poor cold-and-hot workability of vanadium-carbon alloys. Increased concentrations of V2C occurred at the grain boundaries of the high-carbon alloy ingots as a result of homogenization at 1,600° C for 1 hour. Alloy ingots containing more than 0.36 wt pet carbon (a calculated 2.9 wt pct VaC) following homogenization, cracked severely and failed by intergranular fracture upon swaging at 900° C.

Jan 1, 1965

By Raghoottma S. Pandurangi, Mohindar S. Seehra, Pedro Bolsait, Bronwyn L. Razzaboni

"Surface IR (infrared) modes of crystalline and fumed (amorphous) silica particles, calcined at temperatures up to 1095°C, have been studied by Fourier transform infrared spectroscopy. The ability of these same particles to lyse cells has been measured by a hemolysis protocol. The untreated crystalline and amorphous materials differ by a factor of 40 in specific surface area, and the intensity per unit mass of the sharp surface silanol band near 3745 cm-1 in the amorphous material is an order of magnitude larger than in the crystalline material. A similar difference is observed in the lysing potential of the two materials. The intensity of the silanol band increases after calcination for both materials, reaching peak values near 500°C, followed by a dramatic drop at higher calcination temperatures, and reaching negligible values for materials calcined near 1100°C. The lysing potential data follow essentially the same pattern for both crystalline and fumed silica. These results are consistent with the hypothesis that the surface silanol groups are involved in cell lysis. Further experiments are suggested to evaluate the relationship between the surface structure of ailica particles and their potential cytotoxicity. IntroductionThe characterization of the surface structure of various allotropic forms of silica is of interest because the cytotoxicity of silica particles of respirable size has been commonly related to the chemical interaction of functional groups on the surface of such particles with the lipoproteins contained in cell membranes (1-3). It has been found that the cytotoxic potential of silica particles varies greatly with their crystalline structure (4,5), particle size (6-8), surface composition (9), and molecular surface configuration (1,10). Studies of the infrared (IR) modes of various forms of silica have been reported by a number of researchers (3 ,11-19). Several books and reviews (20-24) have dealt with the identification of functional groups on silica surfaces and the effect of heat treatment on the surface structure. The nature of the surface is said to be critical in determining the biological activity of silica dusts (3).Fourier transform infrared (FTIR) spectroscopy is a highly sensitive ·technique for identifying IR surface modes of tine particulates, and it was deemed of interest to examine the surface structure and its relation to lysing potential of two widely different types of respirable silica dust. The lysing potential of respirable dust particles has been considered a first-level test for potential cytotoxicity."

Jan 1, 1990

By R. L. Solmer

During 1959-61, the Bureau of Mines investigated the strain and deformation induced in rock and concrete linings around mine openings by retreat panel caving at the Climax Molybdenum mine. Two concrete-lined slusher drifts on the Phillipson level of the mine were instrumented with both electrical strain gages and extensometers. Changes in strain and deformation were recorded over an 18-month period during the undercutting and caving of the mining panel. General agreement was found between the strain and deformation measurements and the hypothesis that the vertical component of the stress field on the openings is almost completely removed by undercutting. This phenomenon is a possible explanation for the structural failures that occur in the slusher drifts during the undercutting cycle.

Jan 1, 1965

By J. William Ganser

This paper is one of a series being prepared by the U. S. Bureau of Mines describing mining and milling methods and costs at cement-plant quarries throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might in many instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically palled to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of Fred Burkett, civil engineer, and F. O. Londrey, chief clerk, of the Trinity Portland Cement Co., for assistance in preparation of this paper, "The Geology of Dallas County. 1918," Bulletin 1818, Texas Geological Survey, Austin, Tex., by E. W. Shuler, was also freely consulted.

Jan 1, 1931

By D. J. Stoops, H. Kato, M. D. Carver

The effects of impurity elements silicon , aluminum, copper , nitrogen , and manganese , at 50 to 300 ppm, on properties of the zirconium alloy Zircaloy 2 were investigated . Variations in microstructure , mechanical properties , and corrosion behavior in some inorganic acid and salt solutions were observed with variations in level of impurity element . Corrodents were solutions of sulfuric acid , phosphoric acid , copper chloride , and iron chloride . Silicon was found to modify annealed microstructures by spheroidizing and dispersion of secondphase material throughout grains . Silicon or manganese improved ultimate and yield strength of the alloy without loss in ductility . All five elements affected corrosion rates of the alloy , the effect being generally different for each element .

Jan 1, 1964

By Robert L. Lappi

Eight interburden handling concepts are developed for multiple seam area mine stripping operations in central and western United States. They are based on data gathered and analyzed during field surveys, literature reviews and visits to state regulatory agencies in five states. It is concluded that improvement of reclamation practices through selective interburden handling techniques is possible at lower operating costs than currently incurred. Specific multiple seam mining systems are discussed in this report.

Jan 1, 1980

By Byron A. Baker

The Bureau of Mines used a windowed cell to measure the phase-boundary pressures of two related series of gas-condensate fluid mixtures. Normal butane was added to the mixtures incrementally to determine its effectiveness for lowering phase-boundary pressure. All the experimental data were correlated, so that the pressure required to maintain light oils mixed with natural gas in the single phase may be computed for secondary recovery applications. The heavy hydrocarbon parts of the mixtures were distillation fractions of a Gulf Coast condensate. Intermediate normal hydrocarbons in the butane-heptane range and natural gas were added to the fractions in selected proportions, so that phase-diagram pressures of 26 fluids were actually studied. The experimental range of temperatures was 50° to 280° F. Two correlations were developed to represent phase-boundary pressures by means of a polynomial. Independent variables represent natural gas content, disparity of properties of components comprising the mixtures, and temperature. A fourth variable, for one correlation only, was the quantity of normal butane added to the original mixtures. The latter correlation with four independent variables contains 15 coefficients and is estimated to be accurate to 135 psi.

Jan 1, 1973

By E. S. Shedd

Misch metal was electrowon from a treated bastnasite concentrate in a REF3-LiF-BaF2 electrolyte at 950° C. The metal was prepared and tapped from a 1,000-ampere cell, and nearly 100-percent utilization of the rare-earth oxide was achieved. Prolonged operation in a smaller cell (40 amperes) indicated that the composition of the misch metal product was reasonably constant, and no significant increase of impurities, with the exception of carbon, was noted.

Jan 1, 1970

By J. Drew Potts

The U.S. Bureau of Mines identified respirable dust sources and controls on four continuous auger mining sections, two with relatively low dust levels and two with high levels. Factors adversely affecting dust levels included auger equipment design, continuous haulage, and low seam height. Dust controls included ventilation practices and spray systems. Maximizing airflow seemed to reduce dust levels most. Air leakage and shock loss can be reduced by constructing stoppings with brushed-on mortar containing fiberglass and by keeping areas between curtains and ribs free from obstructions and storing equipment not essential for face activities in outby crosscuts. Curtain configuration, setback distance, and installation can also affect dust levels. Use of both blowing and exhausting curtains is the most effective configuration. Setbacks from the face should not exceed 15 ft. Installing brattice curtains at least 5.5 ft from ribs, when entries are 26 ft wide, minimizes velocity head. Installing curtains tightly against the mine roof and floor helps maintain a forward airflow movement in the center of the mine heading; curtain overlap can create a tighter seal. The wet-auger spray system also effectively controls dust, provided the mine is already exercising good ventilation practices.

Jan 1, 1989

By Bertrand L. Johnson

Fertilizers are indispensable to national preparedness and defense. Production of adequate supplies of nourishing food for sustaining life in the United States is absolutely dependent in many parts of the country on the use of artificial fertilizers of various types. Only by using fertilizers can we maintain our present volume of production without great additional expense. Otherwise we would have to increase crop areas constantly to compensate for declining yields, we would have to lower the quality of food marketed, and standards of farm living and rural civilization would decline. About 60 million of the 360 million acres of crops grown annually in the United States Vow require fertilizing each year, and between 7 and 9 million tons of commercial fertilizers are consumed annually for this purpose.

Jan 1, 1941

By George H. Holmes

Beryllium deposits in the northern Virgin Mountains , Clark County , Nev . , and Mohave County , Ariz . , about 70 miles northeast of Las Vegas , were investigated by the Bureau of Mines . The investigation indicated a widespread occurrence of beryllium- bearing pegmatites within an extensive belt of mica - schist . Several deposits with significant beryllium mineral concentrations were encountered . Only a few of the samples analyzed contained more than 1 percent beryllium oxide ( BeO ) ; in many of the samples , no beryllium was reported . The average tenor of samples from the more important occurrences was 0.25 percent BeO . Chrysoberyl is the predominant beryllium mineral in the pegmatite sills ; beryl predominates in the more massive bodies . Minute quantities of cesium and lithium minerals also occur , but no columbium , tantalum , or other rare minerals were found . Ore dressing tests on a composite sample containing 0.28 percent BeO which was representative of the pegmatite sills , indicated an 85 percent recovery of the chrysoberyl ( 70 percent recovery of total BeO ) by gravity concentration in a concentrate containing 17.6 percent BeO .

Jan 1, 1964

By D. E. Sullivan

The Minerals Availability Program of the Bureau of Mines conducts cost evaluations of current and potential mineral operations in the United States and foreign countries. The International Mining Cost Indexation System (IMCI) allows data of different time periods within a country to be updated to a common base year for analytical purposes. The IMCI comprises 12 factor cost indexes and an exchange rate series for 96 market economy countries, denominated in both local and U.S. currency. The IMCI for each country contains 12 time series indexes that measure the average annual rate of change in the cost of factor inputs to the mining industry within that country. Mining industry factor cost indexes include wages, plant and equipment, construction and mining materials, power and transportation, and other measures considered to comprise the majority of capital and operating costs. Cost data or proxies are collected in local currency. Index series within each country are constructed separately and indexed on a 1975 base year. The local currency index is converted to a U.S.-dollar-based currency index using an exchange ratio.

Jan 1, 1987

By R. H. Jefferson

An electrochemical method to selectively determine sulfur dioxide in the presence of sulfur trioxide was investigated. A hydrophobic gas-permeable membrane separates the gas sample solution from an internal filling solution containing a fixed quantity of chloride ion and a sufficiently large excess of sodium bisulfite so that its concentration may be considered constant. Sulfur dioxide diffuses through the membrane to dissolve in the internal filling solution and liberates an equivalent quantity of hydrogen ions. The electromotive force between a precision-ground, flat-ended pH electrode, which acts as the sensing element, and a chloride sensing electrode, which acts as the reference element, gives a direct measure of S02 in the gas sample solution. Calibration curves in water, tetrachloromercurate (TCM) , and citrate buffer absorption solutions were closely parallel with slopes in their linear segments, ranging from 57 to 52 mv/decade of S02 concentration. The slopes compare reasonably well with the theoretically expected slope of 58 millivolts at 21° C. The water standard curve was linear with respect to the logarithm of S02 concentration from 1 to 1,000 ppm S02; the TCM standard curve was linear from 10 to 2,000 ppm S02; and the citrate standard curve was linear from 30 to 5,000 ppm S02' The high efficiency and nontoxicity of citrate favor it as a substitute for the conventionally used TCM in the absorption solution.

Jan 1, 1976

By Thomas Fraser

About 24 per cent of our total production of bituminous coal is used in industrial power plants. As regards fuel conservation, therefore, the recovery of unburned fuel from furnace refuse presents interesting possibilities. Considerable attention has been given to this problem in the past, but because of the comparatively low initial cost of power plant fuel in the pre-war period little progress, has been made in this direction in the United States. Because of the higher price of coal in Europe more attention has there been given to the problem. In Germany a process has been developed for separating unburned coal in refuse by using an electromagnetic separator In the United States the use of mechanical stokers enabled low-priced screenings of high ash content to be used, so that even with relatively high percentages of combustible material remaining in the refuse, the loss in money is not excessive. If the price of screenings returns to the pre-war level around $1.00 per ton the process proposed here will probably not be especially interesting, except where the freight charges are very high. However, if the price of delivered coal continues high, such a process should result in considerable saving. The cost of continuous operation of such a refuse treating plant should not exceed 75 cents per ton of fuel recovered.

Jan 1, 1921

By John E. Miller

A high accuracy Burnett apparatus for use at 12,000 psi and 0° to 65° C has been constructed at the Bureau of Mines Helium Research Center. The apparatus is patterned after Burnett's original apparatus, but the working pressure is much higher and elastic distortion can be essentially eliminated. An operating procedure to permit faster experimental measurements is suggested.

Jan 1, 1967

The purpose of this study is to develop designs to facilitate and accelerate auger rotation stoppage (and auger rotation start up so as to promote auger disengagement during auger miner repositioning) and to provide a time delay and warning signal prior to auger start up to permit any miner s near the augers to get away from the augers before they start rotating. In the underground coal mines in the U.S., there are four auger miners that are currently in use. They are the Jeffrey 100L (see Figure 1-1) and 100M (see Figure 1-2), and the Wilcox WCM and the MK20A (see Figure 1-3).

Jan 1, 1974

By John P. McDonnell

Coal mine bounces and bursts are major problems facing U.S. mine operators. Bounces and bursts have the potential to inflict severe injury on mining personnel, damage equipment, and cause mine closures. High- stress conditions, at or near the working face, are the common denominator in the burst problem, If mine operators can locate high-stress and potentially burst-prone zones, they can then use stress-relief methods to control the burst condition. One method of locating the high-stress zone is the probe-hole-drilling or drilling-yield method. Probe-hole drilling is used frequently in Europe, the U.S.S.R., and Japan as a means for locating potential burst zones. Consequently, the Bureau of Nines performed tests in the laboratory and in a deep, burst-prone western mine to analyze probe-hole drilling. The in-mine method, very simply, involves drilling a hole into the coal seam and measuring the volume of cuttings obtained. A certain volume of cuttings can be expected from a certain diameter and length drill hole. A significant increase in the volume of cuttings means the zone around that particular hole is highly stressed. In-mine use of the drilling yield method has shown it to be a useful tool for locating highly stressed and potential burst zones. Results from laboratory testing confirm that high stress applied tri-axially to a cube specimen will cause a significant increase in the volume of cuttings from a small-diameter drill hole in the specimen.

Jan 1, 1988

By R. L. Benner

A compound stability diagram was constructed by the Bureau of Mines for the Zn-Fe-S-O system to show the phases that should be thermodynamically stable at various temperatures, oxygen pressures, and SO2 pressures. The diagram was demonstrated to have good qualitative value for predicting stable phases that may, in turn, be related to the recovery of zinc in the leaching phase of the electrolytic zinc process. The study showed that roasting temperature is the most Significant variable in preventing roaster formation of zinc ferrite, which is directly related to subsequent extraction of zinc in the leaching step.

Jan 1, 1966

By Marvin L. Whisman

Several parameters controlling the reproducibility of tritium determina¬tion in organic compounds by liquid scintillation counting were evaluated by the Federal Bureau of Mines. These included optimum volume of scintillator solution for maximum counting efficiency, reproducibility of counting a sealed commercial standard and comparison with duplicate counts on laboratory-prepared samples. The error introduced by using microliter pipets, optical differences in counting vials, reproducibility of counting organic samples where quenching is a factor, reproducibility of counting laboratory-prepared samples with an added internal standard, optimum ratio of internal standard activity to sample activity, effect of sample volume upon counting efficiency, count rate at which coincidence losses become apparent, and reproducibility of organic compound radioassay by the standard addition technique are outlined. From the evaluation of these parameters, a technique that can be applied routinely to organic compounds containing tritium has been established, and details are included in this report.

Jan 1, 1961

By G. Asai

The Bureau of Mines has been engaged in a program to increase the utilization of chromium by providing samples to individuals and institutions requesting chromium for research investigations. This report consists of a tabulation of the disposition of chromium samples distributed from July 1953 through June 1961; 109 requests for chromium were answered by providing chromium as electrolytic plate, powder, or wrought forms. The demand for samples reached a peak in fiscal year 1959 and declined to a relatively low level in fiscal year 1961. The largest number of requests came from individuals engaged in mechanical property studies; there were also many requests from those concerned with vaporized metal and physical properties studies. Most noteworthy application for chromium was the experimental use of the radioactive form, Cr61 in radiotherapy of cancer.

Jan 1, 1964