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By L. E. Schultze

The Bureau of Mines devised a technique to recover a Zn-Pb concen-trate from a geothermal brine. More than 99 pct of the Zn and Ph was precipitated by treating the brine with H2S and controlling the pH with lime. Recycle of the sulfide precipitates increased crystal size and resulted in easily filterable products. A typical sulfide precipitate contained 53 pct ZnS, 8 pet PbS, 24 pct MnS, and 15 pct FeS. Addition of sulfide as FeS or CaS was not effective in precipitating Zn and Pb, but Zn in the brine was selectively removed with a strongly basic ion-exchange resin. A proposed flowsheet for metals recovery is discussed.

Jan 1, 1985

By W. A. Stickney, J. W. Town

Batch and continuous - circuit flotation , leaching , precipitation , and electrodeposition studies were made by the Bureau of Mines to determine optimum conditions for treatment of complex mercury - antimony sulfide and mercury- arsenic sulfide ores and concentrates . On the Red Devil ore sample over 95 percent of both the mercury and antimony sulfides were recovered in a flotation concentrate containing 35.6 percent mercury and 21.0 percent antimony . By selective flotation a mercury concentrate containing 71.0 percent mercury and 2.9 percent antimony was obtained with a mercury recovery of 90.4 percent . Leaching results show that , with 150 grams per liter of sodium sulfide and 50 grams per liter of sodium hydroxide , 95 to 99 percent of the mercury , antimony , and arsenic sulfides could be extracted from the concentrates treated . Sodium hydroxide reagent consumption was based on the sulfides generated in the dissolution of the sulfide minerals and on the method of metal recovery used . Selective leaching of the antimony and arsenic sulfides with potassium sulfide dissolved more than 95 percent of either of these two sulfides and 0.5 to 5 percent of the mercury sulfide present . Methods for recovering mercury and antimony from solution were electrodeposition of mercury followed by electrodeposition of antimony , aluminum precipitation of both mercury and antimony , or antimony precipitation of mercury followed by antimony electrodeposition . The method used in recovering the mercury depended on the mercury- antimony content of the solution being treated .Batch and continuous - circuit flotation , leaching , precipitation , and electrodeposition studies were made by the Bureau of Mines to determine optimum conditions for treatment of complex mercury - antimony sulfide and mercury- arsenic sulfide ores and concentrates . On the Red Devil ore sample over 95 percent of both the mercury and antimony sulfides were recovered in a flotation concentrate containing 35.6 percent mercury and 21.0 percent antimony . By selective flotation a mercury concentrate containing 71.0 percent mercury and 2.9 percent antimony was obtained with a mercury recovery of 90.4 percent . Leaching results show that , with 150 grams per liter of sodium sulfide and 50 grams per liter of sodium hydroxide , 95 to 99 percent of the mercury , antimony , and arsenic sulfides could be extracted from the concentrates treated . Sodium hydroxide reagent consumption was based on the sulfides generated in the dissolution of the sulfide minerals and on the method of metal recovery used . Selective leaching of the antimony and arsenic sulfides with potassium sulfide dissolved more than 95 percent of either of these two sulfides and 0.5 to 5 percent of the mercury sulfide present . Methods for recovering mercury and antimony from solution were electrodeposition of mercury followed by electrodeposition of antimony , aluminum precipitation of both mercury and antimony , or antimony precipitation of mercury followed by antimony electrodeposition . The method used in recovering the mercury depended on the mercury- antimony content of the solution being treated .

Jan 1, 1964

By Kenneth L. Bickel

During an underground mine fire, the importance of controlling the spread of smoke and toxic gases with suitable ventilation structures has been proven. However, under certain conditions, control of the propagation of the fire itself may be even more critical in insuring a safe mine evacuation. Fire doors offer the means for accomplishing both objectives. In 1978, the Bureau of Mines initiated research to evaluate the state of fire-door technology and develop and test a fire door suitable for large openings (10 by 12 ft or larger) in noncoal underground mines. This report discusses current fire-door technology in the context of the underground mine environment and the design, fabrication, lab testing, and in-mine field testing of a mineworthy fire door. This door has a 1.5-h fire resistance rating and limits temperature rise across the door to 2500 F during the first 30 min of fire exposure.

Jan 1, 1987

One of the major unknowns in the use of iron and copper is the quantity of various low level impurities, particularly hydrogen, that may be introduced during the deoxidizing process prior to casting. Introduction of hydrogen results in the embrittlement of components made from these metals. In addition, hydrogen bubbles in castings of copper result in the formation of blisters and swelling of the casting. During the last year, a significant effort has been made at the University of Missouri-Rolla to understand the permeation of hydrogen in galvanized automotive steel components and the hydrogen absorption during the electrodeposition of copper. The galvanized steel components consisted of automotive upholstery clips, seat belt holders and brake clips. Although the process of galvanization protects the steel from corrosion the process invariably causes the steel to pick up enough hydrogen to make it susceptible to brittle fracture.

Jan 1, 1992

By D. E. Wolfson

The Bureau of Mines carbonized 35 coal samples from Logan and Mingo Counties) W. Va., at 900° C using the Bureau of Mines-American Gas Association method, and determined yields of products and physical properties of cokes. Twenty samples represented the No.5 Block, Stockton, Chilton, Cedar Grove, Lower Cedar Grove, Alma, No. 2 Gas, and Eagle beds in Logan County, and 15 samples represented the Coalburg, Buffalo Creek, Winifrede, Cedar Grove, Lower Cedar Grove, Alma, and No.2 Gas beds in Mingo County, W. Va, Chemical analyses were determined for all coals. All coals in both counties rank as high-volatile A bituminous. Most of the coals are chemically suitable for metallurgical coals. Coals with accept-able ash and sulfur contents can be used as major constituents in coking blends with higher rank coal to yield coke with satisfactory properties for blast furnace use.

Jan 1, 1967

By J. N. Greaves

Investigations were conducted by the U.S. Bureau of Mines to develop flowsheets for the recovery of tungsten and gold from four Alaskan scheelite-bearing ores. Basic gravity concentration and cyanide leach tests were performed on all samples. About 46 pct of the tungsten and 30 pct of the gold from one sample were recovered in a gravity concentrate containing 24 pet W03 (tungstic oxide) and 119 troy ounces per short ton (tr oz/st) Au. Froth flotation of the gravity concentrate resulted in separate tungsten and gold products with grades of 38 pct W03 and 2,720 tr oz/st Au and recoveries of 60 and 97 pet, respectively. Additional gold was recovered from the gravity and flotation tailings by cyanidation. Overall recoveries of tungsten and gold from this sample were 28 and 94 pet, respeetively. A flowsheet with mill design parameters was developed that consisted of (1) free gold and scheelite recovery by gravity methods and froth flotation and (2) fme-grained gold recovery by cyanide leaching of reground gravity and flotation tailings, followed by a carbon-in-pulp (CIP) circuit. Data were developed from the Bond mill work index, gold and tungsten flotation, conventional and high-rate thickening, cyanide leaching, and CIP adsorption tests.

Jan 1, 1989

By Joan Weinberg

Real gross national product (GNP) grew at a seasonally adjusted annual rate of 2.2% in the third quarter, down from a revised 3.0% in the second quarter, according to preliminary data from the U.S. Department of Commerce (table 1). The slowdown in the rate of growth was attributed to the summer drought, a larger trade deficit, and a decline in Federal spending for defense. Exports slowed from the second quarter, as the dollar, compared with other industrial country currencies, edged up. Imports of both consumer goods and capital goods rose sharply, with consumers buying more foreign cars, computers, and electrical machinery. Although net exports of goods and services deteriorated slightly from the second quarter, the U.S. trade position continues to be much improved from 1987 and first quarter, 1988. Business spending for new plant and equipment rose at a 4.6% pace, well below that recorded earlier in the year. The 3.5% increase in consumer expenditure was accounted for mainly by nondurable goods and services; expenditure for durable goods--those products lasting more than 3 years--rose only 0.4%. Inflation, as measured by the fixed-weighted GNP price index, rose at an annual rate of 4.9% in the third quarter. Prices rose slightly less than they had in the second quarter, when inflation reached a 6-year high. In September, 1988, the President signed a U.S.-Canada free trade agreement (FTA) which will eliminate all tariffs and most nontariff barriers between the two countries by 1999, thereby creating the world's largest open market. In 1987, U.S.-Canadian bilateral trade totaled $161 billion. The expansion of trade is expected to generate 5% higher growth for Canada and up to 1 % higher growth for the United States by the end of the century. The higher growth for the United States translates into an estimated 750,000 jobs, and $2.4 billion in exports. Canadian parliamentary approval of the agreement is still required before the treaty can take effect. The debate in Parliament is continuing, and the issue is not expected to be resolved until after the November 21 election.

Jan 1, 1988

By Richard L. Rains

During this study in 1983, the U.S. Bureau of Mines examined one mine and five prospects in the Greenwater Valley Wilderness Study Area (WSA). No mineral resources were identified within the WSA. Principal mineral commodities in the WSA are gold and silver with minor lead, and zinc. Two properties have significance; sample analyses indicate the Salsberry Prospect may have gold-silver-lead-zinc resources, and the Graham Jem Mine may have gold resources. The likelihood for development is greatest at the Salsberry Prospect, although the only recorded production from the study area was from the Graham Jem Mine; in 1908 less than 1 ton of gold-bearing ore valued at $25,000 per ton was produced. Gold, silver, lead, zinc, and copper minerals in the WSA are associated with rhyolite dikes and quartz veins in Precambrian gneissic rocks, commonly concentrated in sheared zones along the dikes and veins. Although known to contain silver-lead deposits elsewhere, Precambrian Noonday Dolomite sampled inside the WSA contained no significant mineral values. Much of the WSA is covered by relatively unmineralized Tertiary and Quaternary volcanic rocks. The Bureau collected 140 rock samples at four adits, nine shafts, four trenches, and 33 prospect pits in the WSA. In 1983, 14 lone claims and one millsite within the study area were current. No patented claims, placer claims, or coal, mineral, oil and gas, or geothermal leases were in the WSA.

Jan 1, 1985

By F. M. Boler

The U.S. Bureau of Mines has configured a flexible data acquisition and analysis workstation, which incorporates control and analysis software written in-house for use in mining research experiments conducted in the laboratory and in operating underground mines. This data acquisition system combines computer-automated-measurement-and-control (CAMAC) modular instrumentation with a Unix-based graphics workstation. The data acquisition front-end hardware can be interfaced to almost any computer. CAMAC instrumentation modules adhere to mechanical, electrical, and digital interface standards and can be custom designed or purchased off the shelf. Communications along the CAMAC bus are regulated by the crate-controller module, which contains the only hardware link to the computer interface. Software support for the data acquisition and analysis workstation consists of a series of functions and programs written in the "C" programming language designed to provide flexible and fast data acquisition, processing, and analysis. The user can interactively control the digitizers and other CAMAC modules by sending standard CAMAC read, write, and command function codes from a menu-driven program. Automated data collection is achieved through software that responds to hardware interrupts triggered by acoustic emission or microseismic events. Graphics display routines are used to plot part or all of the data and provide the ability to process and store signal information selectively.

Jan 1, 1990

By B. J. Moore

This Bureau of Mines publication reviews U.S. helium resources as of January 1, 1973. These resources, estimated to be 693.7 billion cubic feet, are broken down into four classifications, as follows: helium in storage, 34.9 billion cubic feet; helium in measured helium-rich natural gas reserves, 119.5 billion cubic feet; helium in measured helium-lean natural gas reserves, 62.8 billion cubic feet; and helium in indicated or undiscovered natural gas resources, 476.5 billion cubic feet. The helium in undiscovered natural gas is considered a national resource; however, this gas may not be discovered depending on many factors beyond the scope of this paper, and most of the helium in natural gas will be dissipated as the gas is consumed for fuel and other purposes.

Jan 1, 1976

To provide longwall operators with a method to predict methane emissions from panels with increased face width.

Jan 1, 1997

By R. V. Ramani, P. M. T. White, D. Sutton

1.1 General The examination and evaluation of a mineral deposit to determine whether or not it can be profitably exploited entails many factors unrelated to the physical nature and intrinsic worth of that deposit. Nevertheless, geology and geologically related factors have great bearing on the economic potential of the deposit. This is only natural because the deposit owes its existence to these factors. This is even more so in underground mines where the whole system is a geologically enclosed one. Geology plays a major role in at least four phases of a mineral venture. Firstly, it acts as an indicator of the existence of parti¬cular minerals. For example, it is inconceivable that a sedimentary coal deposit would exist in a granitic batholith or stock, or that a sandstone would host primary copper or nickel sulphides. Further, the positional relationship of different rock types may be significant in locating deposits such as replacement zinc and copper sulphides in limestones which have been intruded by igneous rocks. Thus, geology is important in the exploration phase of a mineral deposit. Secondly, once potentially valuable minerals have been discovered, knowledge of geology plays a significant role in determining the dis¬tribution, grade and extent of the mineralization. Controls on mineralization include one or all of those related to structure, rock type, sedimentary features, post-depositional redistribution, etc. Con¬sequently, in order to effectively evaluate a deposit in terms of

Jan 1, 1974

By Joseph A. DeCarlo

This publication presents statistical data on oven-and beehive-coke plants in the United States. Information on the carbonizing capacity of the coke industry is important because of the close relationship between the coke industry and most of the other basic industries of our country. Coke is an essential-raw material in pig-iron production; also, coal-chemical materials are used to make fertilizers, paints, plastics, synthetic rubber, explosives, detergents, nylon, pharmaceuticals, dyes, and many other useful products necessary to sustain and improve the high standards of living in our country. Oven-coke plants in the United States on December 31, 1958, are tabulated in table 1. This tabular presentation shows the location, classification, number and type of ovens, annual coke capacity, coal chemicals produced, and name and address of parent company for each individual coke plant. About 86 percent of the capacity of slot-type coke ovens in the United States is owned by iron and steel companies. In most of these plants the coke ovens are integrated with the blast furnaces to facilitate transportation of raw materials for steel making. This has resulted in large coke plants, and the average annual coke capacity of "furnace" plants in 1958 was 1.3 million tons. Nonfurnace or "merchant" plants include coke plants associated with chemical operations, gas utilities, as well as coke plants that produce metallurgical, industrial) and residential-heating grades of coke and coal-chemical materials for sale on the open market. These plants ordinarily are not as large as furnace plant~ and annual coke capacity of merchant plants in 1958 averaged only 500 thousand tons. At the end of 1958 there were 55 furnace plants and 22 merchant plants.

Jan 1, 1959

By Jerry W. Ramsey

The Bureau of Mines examined a low-, a medium-, and a high-volatile Pennsylvania anthracite by densimetric methods using four mesh si.s of each anthracite. Using high-pressure mercury the macropore volumes and distributions of these pore volumes determined, densities in mercury were calculated, and specific pore vo1.r. ware obtained from these mercury densities in conjunction with helium densities. The helium densities were also used with the ultimate analyses of these anthracites in calculating structural parameters by statistical densimetric methods. The effect of 106 or 108 rads of gamma irradiation in the presence of air and in vacuum upon the properties studied with two mesh sizes of each anthracite. Results of the statistical densimetric method seem to show some breakdown of condensed ring structural units at the lower irradiation level, with subsequent polymerization at the longer period of gamma irradiation. The structural parameters obtained also indicated that in going from high- to low-volatile anthracite, either the number of condensed rings per structural unit increased, or the degree of polymerization increased.

Jan 1, 1965

By F. E. Cash

Much has been written concerning accidents in coal mines; the fact that accidents cost the employer and employee money is generally well known, but how much accidents actually cost is vague, even in the minds of many operators. Unquestionably there are hazards in coal mining, but many of them can be eliminated; and from the prevention of accidents there can be realized a material saving in dollars and cents as well as in human suffering. In presenting the frequency, severity, and cost of accidents in some Tennessee coal mines, it is hoped that other mines in Tennessee, as well as mines in other States, will by a comparison of the data with their own ex¬ perience be enabled eventually to reduce the number of' their accidents.

Dec 1, 1932

By S. A. N. Sheya

The U.S. Bureau of Mines performed batch equilibrium contact experiments to examine the ability of activated coconut-shell carbon to adsorb various metal cyanide complexes. Tests were also conducted to determine the effect these cyanide complex impurities might have on the adsorption of gold by the activated carbon. Metal cyanide species included in the investigation were antimony, arsenic, cadmium, calcium, cobalt, gold, iron, mercury, nickel, silver, thallium, and zinc. Tests were made over a pH range of 6.4 to 12.5. The carbon exhibited a preference for gold adsorption over other metals present in solution. In the absence of gold, the metal cyanide complexes were adsorbed; adsorption generally decreased with increasing pH. However, calcium and thallium adsorptions increased with increasing pH, while arsenic and iron were not adsorbed at any pH.

Jan 1, 1989

By M. A. Mahtab

This report describes the procedures used by the Bureau of Mines for obtaining attitudes of joints surveyed with a borescope in inclined boreholes. An algorithm for computing the dips and azimuths of the observed joints is presented. The algorithm is used to solve an example problem. A computer program based on the algorithm is listed. It is hoped that the procedures described here will be useful in treating large quantities of data obtained from comprehensive borehole surveys.

Jan 1, 1973

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

APPENDIX E REFUGE CHAMBER LEAKAGE ANALYSIS Variables p 0 = pressure outside of chamber (psi) p = pressure inside of chamber (psi) i q = leakage flow rate (cfm) Q= total leakage (cu ft. ) V = chamber volume (cu. ft. ) t= time (minutes) p= nominal atmospheric reference pressure (14.7 psi) A= chamber leakage coefficient (cfm/psi)

Jan 1, 1976

By S. R. Borrowman

Mill tailings from conventional uranium extraction processes contain nearly all of the radium originally in the ore. Such tailings require controlled storage in perpetuity to safeguard the surrounding environment from radioactive contamination. Alternatives to controlled storage of the tailings are (1) removal of the radium from the tailings for separate storage or use or (2) removal of the radium when processing the uranium ore. In laboratory tests conducted by the Federal Bureau of Mines, radium was leached from tailings using either hydrochloric acid or ethylenediamine tetraacetic acid. A hydrochloric acid leaching method was used to extract both radium and uranium from the ore to yield tailings containing less radium than those produced by either conventional sulfuric acid or alkaline leaching processes. From 77 to 94 percent of the radium in mill tailings was concentrated by sedimentation in slime fractions representing nearly 25 weight-percent of the original sample.

Jan 1, 1975

By Welby Courtney

Because of the inherent safety problem associated with the deposition of airborne respirable dust onto the floor and other airway surfaces, the Bureau of Mines investigated the rate of reduction of airborne respirable dust in an airway due to deposition of the particles onto the surfaces of the airway. The effects of relative humidity and air velocity on the deposition rate were examined. It was found that the deposition rate was comparable in magnitude with the Stokes sedimentation rate and that it was independent of relative humidity. However, near the dust source the deposition rate depended significantly upon the air velocity, with such dependence decreasing with increasing distance from the dust source. In addition, the size distribution of the airborne particles was approximately constant along the first 300 ft of the airway, indicating that it was not merely the larger (heavier) particles that were being deposited. These results suggest that deposition, though comparable with the Stokes sedimentation rate in magnitude, does not follow a simple Stokes-type process, and that the process of deposition remains to be explained.

Jan 1, 1986