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By F. R. Cattoir, R. E. Cumings

Columbium metal was electrorefined in a fused - salt electrolyte . Excellent results were obtained in lowering the impurity content in a 94 - percent columbium anode feed material to produce a 99.8- percent - pure metal . The reductions of the major impurities follow : Oxygen from 19,800 to 500 ppm , carbon from 9,700 to 25 ppm , iron from 9,200 to 630 ppm , nitrogen from 2,100 to 90 ppm , and silicon from 750 ppm to not detected . Columbium with a purity of 99.9 percent was produced from 99.5- and 99.8 - percent grades of columbium. The investigation was devoted to the evaluation of a fused - fluoride - salt electrolyte ( KF - NaF- K₂ CbF, ) for electrorefining columbium. The effects of the columbium concentration and the voltage upon the product's purity were investigated . The effect on the cathode current efficiency of ampere - hours of deposition and the formation of a dual valence state of the columbium was also investigated .

Jan 1, 1964

By H. W. Sheffer

Technical and economic aspects of community refuse disposal systems and their effects on the environment are identified and described. Seven landfills and two incineration systems, located throughout the United States, are reviewed.

Jan 1, 1971

By B. G. H. Thomas, W. P. Yant, A. C. Fieldner, R. R. Sayers, W. J. McConnell

"One of the outstanding problems confronting automotive engineers in attempting to construct motors of greater economy is that of eliminating the ""knock"" from the operation of the engine. Recent investigations of this detonation or knock in internal-combustion engines, especially of the high-compression type, have demonstrated that it can be eliminated or reduced by decreasing the reaction velocity of combustion by adding small quantities of certain compounds to the gasoline, This makes it possible to use engines of a higher compression ratio, thereby greatly increasing the mileage per gallon of gasoline consumed. The savings in fuel reserves from increasing the proportion of crude oil marketable as motor fuel and in permitting the designing of more efficient engines are obvious.Ethyl gasoline, one of the widely used anti-knock fuels, is ordinary motor gasoline to which has been added 3 c.c. of tetraethyl lead and 2 c.c. of a halogen carrier, as ethylene dibromide or trichiorethylene, or approximately 0.06 per cent of the lead compound and 0.04 per cent of ethylene dibromide by volume. Ethyl gasoline should not be confused with ethyl fluid, which is a mixture of concentrated tetraethyl lead and ethylene dibromide in the prowler proportions for mixing with gasoline, but is not a motor fuel and is not sold to the public. Also tetraethyl lead is not a motor fuel, and likewise is act sold to the public."

Dec 1, 1924

By Susan E. Brink

The first step in determining whether Mn can be recovered by in situ leaching is to develop and test a selective lixiviant. Two column leach tests and one core leach test Were conducted by the U.S. Bureau of Mines on Mn oxide ore using aqueous sulfur dioxide (SO2) as the lixiviant. The column tests showed that aqueous S02 could selectively dissolve available Mn oxides from calcite-rich ore in a heap leach system. However, the core test showed that calcite gangue side reactions can have pronounced negative effects on the likelihood of successful in situ leaching of a calcite-rich ore with aqueous S02. Petrographic and geochemical analyses showed that both Mn (IV, III) oxides and calcite were dissolved. The abundance of dissolved Ca caused precipitation of gypsum. Acid consumption by calcite dissolution caused a rise in pH that caused the SO/S species to shift to S032-(sulfIte), which hindered reductive dissolution of Mn oxide. Gypsum precipitation did not affect complete leaching of the rock fragments in the column tests; however, it plugged the natural permeability in the core. Manganese recoveries were high for the column tests and low for the core test.

Jan 1, 2010

By A. G. Loomis

METHODS for measuring relative permeability as a valid function of saturation were compared by the. Bureau of Mines, using core samples from representative oil-productive California formations, from the Bartlesville sand in Oklahoma, and from synthetic samples. Measurements for gas-oil systems were made by steady-state dynamic, unsteady-state displacement and two stationary-phase methods. Measurements for water-oil systems were made by the unsteady-state displacement method. As the ratio rather than individual relative permeabilities is measured by the last method, three methods for calculating individual relative permeabilites from their measured ratio were compared for gas-oil systems and two methods for water-oil systems. Errors arising from capillary discontinuities, such as the end effect and stabilized-zone flow, are discussed and evaluated; possible errors rocs arising from turbulant flow are also examined. The inapplicability of non-steady-state methods for water-oil systems that are not definitely oil-wet is discussed in detail. Measurements of relative permeability to both gas and oil can be made quickly and accurately by the steady-state dynamic method when rates of flow of the two phases are sufficient to minimize the capillary discontinuity at the outflow end of the sample. At such rates relative permeability-saturation measurements are essentially independent of the rate of flow. The steady-state method wits modified by a dispersion section at the inflow end of the sample acid designated tie dispersed-feed method.

Jan 1, 1962

By T. C. Wesson

The need for elemental-analysis information on coal mine dust for use in health and safety research prompted this study by the Bureau of Mines. Neutron-activation and X-ray fluorescent techniques were used to obtain five-element analysis (silicon, aluminum, iron, calcium, and magnesium) on 444 samples from 68 coal mines in 10 States. From these analyses, the average composition of the dust in coal mines was determined. The contribution of the primary dusting material (limestone dust) to the makeup of coal mines was shown. Regional differences in mine-dust composition were indicated.

Jan 1, 1974

By L. D. Patts, J. D. Noll, S. E. Mischler, G. H. Schnakenberg

In this study, we evaluated the ambient diesel particulate matter (DPM) concentrations (at the intakes and exhausts of the mine) as the entire vehicle fleet of a stone mine switched from using 35% biodiesel to using a water emulsified fuel (PuriNOx). Elemental carbon (EC) was reduced by 45% when a PuriNOx blend containing 10% water replaced 35% biodiesel and by 57% when a PuriNOx blend containing 20% water was used. Other factors such as engine duty cycle and production changes could potentially cause some day-to-day EC fluctuations, and no direct comparison to commonly used dieselfuels (No. 1 or No. 2) was achieved. Therefore, a second study was performed in a controlled “isolatedzone” environment to fametal mine, comparing PuriNOxto No.1 diesel fuel in a load haul dump vehicle. The EC fraction of the DPM was reduced by about 71% when the PuriNOx blend containing 10% water was used and by about 85% when the PuriNOx blend containing 20% water was employed. This study did not determine how the water emulsified fuel would affect the engine or power.

By D. A. Reynolds, R. G. Travis, James J. Dowd, R. F. Abernethy

"1. Reserve estimates have been made for eight coal beds in Monongalia County, W.Va., but only the Pittsburgh, Sewickley, and Upper Freeport beds are important at this time. The Pittsburgh, Sewickley, Waynesburg, and Upper Freeport beds contain the largest recoverable reserves.2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 3,526 million tons as of January 1, 1954. Of this total, 3,294 mil¬lion tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.3. Recoverable reserves of coal have been estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Monongalia County, as determined by this investigation, is 47.9 percent. This percentage is based on the total thickness of coal (less partings three-eighths inch thick or more) in the bed rather than on the thickness of the coal mined. Based on the weighted average percentage of recovery for all beds in Monongalia County, the recoverable reserves are estimated at 1,577 million tons as of January 1, 1954.4. Monongalia County coals of the major producing beds are of high-volatile a bituminous rank.5. The Pittsburgh and Lower Freeport beds in this county yield coal that can be used as metallurgical coal, especially when blended with low-volatile coals. The Lower Freeport coal is coked singly and in beehive ovens, and makes good metallurgical coke.INTRODUCTIONThe investigation to evaluate the reserves of coking coal was planned to cover three phases: (1) Estimation of known measured and indicated recoverable reserves of all coking coal; (2) study of methods of upgrading marginal coals through effective preparation; and (3) study of carbonizing properties of coals and coal blends not now widely used for metallurgical coke making."

Jun 1, 1956

By L. P. Larson

In this Bureau of Mines evaluation of the domestic supply position of tungsten, certain tungsten resources in the United States are estimated as to quantity and grade and then are systematically costed in detail (excluding exploration costs). A supply curve is developed which depicts the quantity of tungsten (WO3) up to about 15.5 million short ton units that is producible at calculated price levels ranging from about $13 to $125 per short ton unit. About 10.4 million short ton units are available at a calculated price that is less than the present market price ($40). Total known resources amount to about 40.2 million short ton units. A very large portion of that quantity was not costed due to inadequate information on either resources or processing methods. Further exploration and research would have a significant effect on the availability of tungsten in the United States.

Jan 1, 1971

By S. Harteis, D. Dolinar

Many mining operations rely on bulkheads to provide a barrier between impounded water or slurry and active mine workings. However, bulkhead failures could cause and have caused catastrophic flooding that puts the underground workforce at risk. The National Institute for Occupational Safety and Health1 (NIOSH) in collaboration with the Mine Safety and Health Administration (MSHA) is conducting research to evaluate the adequacy of existing design practices for water and slurry bulkheads. A key component of this research effort is documentation of the performance history and design parameters for bulkheads installed in underground coal mines during the last 20+ years. This research is part of a larger effort to develop general design guidelines and procedures for constructing and maintaining bulkheads that will help to ensure their long-term structural integrity, while significantly reducing the inundation risk for miners. This paper presents the results of NIOSH’s research to identify state-of-the-art bulkhead designs, including design criteria, leakage monitoring systems, and emergency warning systems. Underground observations and evaluations of existing bulkheads suggest that the most important design factors influencing their performance are the interface of the bulkhead with the surrounding strata and the potential magnitude of the hydraulic pressure to which they may be subjected. When a bulkhead has failed, leakage has generally been through the surrounding strata or along the bulkhead/strata interface, with the failure potential along the interface increasing with hydraulic head. It was also determined that development of a monitoring program to ensure the long term structural integrity of bulkheads is an important safety consideration. Current monitoring procedures range from weekly visual inspections to constant monitoring via pressure transducers and fluid level indicators. Where possible, these devices are used in conjunction with a computer based mine monitoring system to alert mine personnel when an emergency condition exists at the bulkhead installation.

By Robert J. Hundhausen

During the early part of World War II , it appeared likely that supplies of chromite for United States industry might become critically short . As a part of the ensuing search for new sources of domestic chromite supply , the chromite - bearing black sands along the coast of southern Oregon were hurriedly investigated by State and federal agencies and by private interests , These investigations led to a decision to begin exploitation of the deposits immediately . A government stock- piling program was put into effect , a concentrator was financed by the Defense Plant Corporation , two privately controlled companies were encouraged to start mining operations , and the Bureau of Mines and the Geological Survey were authorized to search. for additional reserves of minable ore .

Feb 1, 1947

By Frank E. Williams

This Bureau of Mines report describes 147 known fluorspar deposits in New Mexico and briefly mentions 54 miscellaneous occurrences for which little or no information was obtained. Most miscellaneous occurrences are minor and too poorly exposed to be considered more than prospects. History and production of fluorspar in New Mexico, type of deposition, mineralogy, uses, and grade specifications are discussed. Total mine production of fluorspar in New Mexico is nearly 641,000 tons of various grades of crude ore and hand-sorted material. Fluorspar deposits occur in 13 of the state's 32 counties. Grant, Valencia, and Luna Counties account for 86.4 percent of the total production. During the investigation, 141 deposits were visited. A total of 72 character samples was collected for assay, and 3 larger samples were collected for bench-scale metallurgical tests. Results of these metallurgical tests indicate that an acid-grade product can be obtained with 95 percent recovery of the CaF2 content of the crude ore.

Jan 1, 1966

By Frank E. Williams

This Bureau of Mines report describes 147 known fluorspar deposits in New Mexico and briefly mentions 54 miscellaneous occurrences for which little or no information was obtained. Most miscellaneous occurrences are minor and too poorly exposed to be considered more than prospects. History and production of fluorspar in New Mexico, type of deposition, mineralogy, uses, and grade specifications are discussed. Total mine production of fluorspar in New Mexico is nearly 641,000 tons of various grades of crude ore and hand-sorted material. Fluorspar deposits occur in 13 of the State's 32 counties. Grant, Valencia, and Luna Counties account for 86.4 percent of the total production. During the investigation, 141 deposits were visited. A total of 72 character samples was collected for assay, and 3 larger samples were collected for bench-scale metallurgical tests. Results of these metallurgical tests indicate that an acid-grade product can be obtained with 95 percent recovery of the CaF2 content of the crude ore.

Jan 1, 1966

By Staff

This U.S. Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles.

Jan 1, 1989

By D. K. Steele

The domestic primary copper industry generates in excess of 600 million t of mining and mineral-processing waste annually. Most of the waste poses negligible environmental threat, but a small fraction, because of toxic or corrosive characteristics, may be subject to regulation under Subtitle C of the Resource Conservation and Recovery Act (RCRA) or other pertinent regulations. Among the wastes generated by various copper producers are flue dusts, slags, refinery-bleed solutions, and. acid-plant wastes. The U.S. Bureau of Mines (USBM) has researched methods to mitigate the environmental threat posed by copper-processing wastes while recovering valuable metals from these materials. Acid-leach processing of flue dusts has been demonstrated feasible along with sulfide treatment of liquid refinery wastes and acid-plant-bleed and gas-cleaning solutions to precipitate dissolved metals. In, addition, the feasibility of removing copper and molybdenum from slag, as well as stabilization of precipitated sulfide wastes by vitrification, have been investigated.

Jan 1, 2010

By J. Douglas Causey

A U.S. Bureau of Mines study indicates over 200 million yd3 (153 million m3) of cinder resources occur in the Mount Washington Wilderness. No future demand for the deposits is anticipated. Based upon the geologic environment, the area is considered favorable for discovery of geothermal resources. INTRODUCTION The Mount Washington Wilderness, located about 32 mi (51 km) west of Bend, Oregon, contains 46,655 acres (18,881 ha) (fig. 1). A 6,300-acre (2,550-ha) addition on the northeast and east boundaries has been proposed by the Forest Service under RARE II. The U.S. Geological Survey made regional geological, geophysical, and geochemical surveys, and the U.S. Bureau of Mines examined, analyzed, and evaluated the economic potential of prospects and commercially important mineral resources.

Jan 1, 1982

By Alan A. Campoli

The U.S. Bureau of Mines conducted research to characterize longwall gob loading under bump-prone geologic conditions. Bureau-designed stress meters were installed in the floor rock beneath two longwall panels and coal pillars in the gate road between them. Gob and gate road pillar stress was monitored continuously by a state-of-the-art data acquisition system. The timing of the final destruction of the abutment pillar's load-bearing core was optimal, since the pillar is located between two gob areas and no longer of significant importance for ground control. Maximum stress was observed immediately in front of the longwall face, and this pressure quickly dropped as the face moved past the instruments. The center of the longwall panels regained significant overburden load, while the instruments located less than 100 ft from the edge of the panel showed little or no increase in pressure due to gob reloading.

Jan 1, 2010

By Arno C. Fieldner

In view of the widespread interest in the production of synthetic liquid fuels from solid and gaseous fuels to supplement declining reserves of petroleum, and the many requests that are now being received for information on the subject, this bibliography of Bureau of Mines contributions has been compiled. In addition to the publications issued by the Government in printed or mimeographed form, references are included to articles written by the Bureau staff for the technical press and to cooperative reports of work done jointly with States, colleges, and industries. References are given under each section in chronological order. Bureau of Mines bulletins, technical papers, and Minerals Yearbooks are printed and are obtainable at the prices indicated from the Superintendent of Documents, Government Printing Office, Washington 25, D. C. If no price is given, the publication is out of print. The price of entire volumes of the Minerals Yearbook or of reprints of certain chanters may be obtained upon request. Any orders or remittances in payment for these publications should be cent directly to the Superintendent of Documents and not

Jan 1, 1945

By H. F. Feldmann

This work was done to provide thermodynamic, electrical, physical, and compositional data on the seeded combustion plasmas of seven coals for the design of MHD generators. The systems were assumed to be at equilibrium, and the design data were generated by solving for the composition of both gas and liquid phases with a digital computer. The coals reported in this study include a western subbituminous, a Pennsylvania anthracite, and five representative bituminous coals. The data include dewpoint temperatures of both slag and seed. A Mollier diagram for each coal is given to allow graphical generator calculations.

Jan 1, 1970

By M. J. Beus

The Bureau of Mines, under a cooperative agreement with Hecla Mining Co., is conducting a rock mechanics study of the 6,200-ft-deep circu-lar, concrete-lined Silver Shaft in northern Idaho. The objective of the project was to instrument and evaluate lining behavior and rock de-formation when a deep shaft is constructed in a high in situ stress field and anisotropic rock mass. Rock mass displacements were moni-tored with multiple-position borehole extensometers. Liner stress and strain were measured with concrete pressure cells and embedment strain gauges. Field data from the 5,955-ft test level show that rock displacement is controlled by rock mass anisotropy. Liner stress and strain levels reflect the high in situ stress field as well as nearby station and raise construction. Maximum stresses measured in the lining, as a result of shaft excavation, are about one-third of its compressive strength. Subsequent loading pocket excavation resulted in signifi-cantly increased stress and strain levels in the liner. Continued monitoring and preliminary analysis of the data indicate that concrete-lined, circular shafts are stable for the high, unequal horizontal stress fields and rock anisotropy encountered in deep-level mining. Adjacent development work can be expected to significantly alter the initial stress and displacement conditions.

Jan 1, 1984