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By Seth T. Reese

THE INJURY DATA and experience at coke ovens in the United States for 1952 are presented in this bulletin under the following general sections: (A) General injury experience: Tables 1 to 9: Contain current and comparable data on operating statistics, number and classification of injuries, frequency rates, and accident agencies involved in causing injuries. Data are given for the industry as a whole, for each type of oven, and for the States in which coke is manufactured. (B) Selected injury experience: Tables 10 to 15: Contain comparable injury data in the coking industry covering 5- and 10-year periods on the number of injuries, accident agencies, and severity of injuries. (C) Historic injury experience: Tables 16 to 19: Contain data on the number of injuries, frequency rates, and employment at coke ovens from the earliest records through 1952, Operating statistics from 1929 through 1952 are given in table 19.

Jan 1, 1955

By Robert L. Rough

This report presents the results of an investigation by Federal Bureau of Mines engineers of water-injection projects in the northwestern Pennsylvania and southwestern New York area, where oil-producing wells have been converted from pumping to flowing. Data from 24 leases converted to flowing were collected and examined. Only 10 leases had information of significant scope for inclusion in the final analysis. The projects were classified in one of two categories. Group I consisted of leases operated to permit an evaluation of operational changes in terms of existing pressure differentials between injection and producing wells. Group II included remaining properties, for which enough information was available to justify an economic analysis but which did not have sufficient production data to support an engineering study because of radical changes in operational techniques. Variations in production and costs resulting from conversion to flowing were examined for production methods, well-spacing and completion techniques, and reservoir characteristics. Where water-injection rates were constant, oil production usually decreased rapidly at the time of conversion; production then increased slightly for 6 to 8 months before resuming a normal decline rate considerably below the estimated pumping rate. The abrupt decrease in production after conversion is indicative of lower pressure differentials between injection and producing wells, caused by the increased hydrostatic head in the producing wells.

Jan 1, 1960

By H. N. Dunning

A comprehensive research program designed to aid development of new and improved methods for more complete production of petroleum from partly depleted reservoirs is being conducted at the Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla. Water flooding has accounted for much of the petroleum produced by secondary-recovery methods; however, a considerable portion of the crude oil commonly remains in place after water flooding has been terminated. In recent years the possibility of increasing the efficiency of water flooding by using surface-active additives has received wide attention. In general, the results of laboratory research have shown that use of detergents as water-flooding additives will reduce the residual petroleum in porous media (1).3/ Some less extensive field tests have supported this conclusion but have not been entirely conclusive (2). Later studies (3, 4) have given conflicting evidence as to the relative worth of detergent additives for water floods in water-wet (hydrophilic) or oil-wet (hydrophobic or lipophilic) reservoir materials. The results of these studies emphasize the need for a more complete understanding of the fundamental principles involved in displacing petroleum from reservoir surfaces by injected fluids. Accordingly, a comprehensive research program was initiated to investigate the practical and fundamental aspects of detergency in petroleum production.

Jan 1, 1953

By Terry J. Close

A mineral resource survey of the 236-mil (611-km2) Hyalite-Porcupine-Buffalo Horn wilderness study area (RARE 11 Areas No. 1-155 G, Gallatin Divide; and H, Hyalite) between the Gallatin and Yellowstone rivers in Montana, indicates there are phosphate rock and petrified wood resources (fig. 1). The area also has some potential for oil, gas, and geothermal resources. Stone and alluvium are abundant but appear to have little potential for development because other sources are available nearer to markets.

Jan 1, 1981

By Linneas W. Laage

MFIRE is a computer simulation program that performs normal ventilation network planning calculations, and dynamic transient state simulation of ventilation networks under a variety of conditions. The program is useful for the analysis of ventilation networks under thermal and mechanical influence. MFIRE simulates a mine's ventilation system and its response to altered ventilation parameters, external influences such as temperatures, and internal influences such as fires. Extensive output enables detailed quantitative analysis of the effects of the proposed alteration to the ventilation system Network simulation using digital computers has become widespread throughout the mining industry in recent years. However, as the sophistication of the simulator increases (MFIRE, for example), the complexity of input data requirements and interpretations of results requires more skill and knowledge from the users. Perhaps the most difficult part of using MFIRE is to construct the data set describing the mine's physical layout and its ventilation properties. The initial attempts to get the data set running often reveal unknown or ignored aspects of the mine's ventilation.

Jan 1, 1995

MFIRE is a computer simulation program that performs normal ventilation network planning calculations, and dynamic transient state simulation of ventilation networks under a variety of conditions. The program is useful for the analysis of ventilation networks under thermal and mechanical influence. MFIRE simulates a mine's ventilation system and its response to altered ventilation parameters, external influences such as temperatures, and internal influences such as fires. Extensive output enables detailed quantitative analysis of the effects of the proposed alteration to the ventilation system Network simulation using digital computers has become widespread throughout the mining industry in recent years. However, as the sophistication of the simulator increases (MFIRE, for example), the complexity of input data requirements and interpretations of results requires more skill and knowledge from the users. Perhaps the most difficult part of using MFIRE is to construct the data set describing the mine's physical layout and its ventilation properties. The initial attempts to get the data set running often reveal unknown or ignored aspects of the mine's ventilation. MFIRE was written in Fortran 77 and compiled with Microway1 Fortran for the Intel 80386 based computers with a 80387 math co-processor. The source code is portable and available for users who wish to modify the source code to operate on other computers. This user manual describes the development of MFIRE, the input format and requirements, the output, common errors, fire parameters, and examples MFIRE application. Valuable reference material is included in the appendices. Knowledgeable users may skip directly to the PROGRAM INSTALLATION AND OPERATION section to begin using MFIRE immediately.

Jan 1, 1995

By Robert C. Gabler

Three filter cloth fabrics commonly used in drains for coal waste embankments were tested by the Bureau of Mines for clogging behavior and deterioration under simulated field conditions. The objective was to provide guidelines for the mining industry for the proper selection and use of filter cloths to assure safer embankments at mine waste disposal sites. The filter cloths were tested with three coal waste samples in stand-pipes used to simulate coal mine waste disposal environments. Two of the cloths showed a tendency to become clogged with fines from the wastes. One waste caused clogging by precipitating an iron-silicon compound on the test cloths. No apparent cloth deterioration resulted from exposures to the simulated coal waste environments. (The exposures ranged from 2 to 12 months.) In other tests, exposures to waters in the pH range of 2 to 12 and to reagents used in coal-preparation plants resulted in insignificant or no deterioration, as measured by tensile strength. However, long exposures to sunlight (ranging from 4.6 to 6 months) caused major deterioration in two of the cloths (86-and 98-pct losses in tensile strength) and slight deterioration in the third cloth (9-pct loss in strength).

Jan 1, 1984

By Ann G. Kim

Fires that occur in abandoned coal mines, waste banks, and in coal outcrops constitute a serious health, safety, and environmental hazard. Toxic fumes, the deterioration of air quality, and subsidence constitute the greatest hazards from these fires. Although tires on abandoned mined land (AML) occur in every coal-producing state, the severity of the problem varies. Methods to extinguish or control AML fires, including excavation, fire barriers, and sealing, are generally expensive and have a relatively low probability of success This U.S. Bureau of Mines report includes information from a variety of sources, i.e., agencies of the Federal Government, State agencies, research reports, conference proceedings, product information, and technical literature. This information has been collated into a comprehensive discussion of AML fire problems. Data on past fire control projects and on the estimated extent of the current problem have been compiled. Factors affecting the occurrence, propagation, and extinguishment of AML fires are discussed. Conventional fire control methods are described, and their probable effectiveness is evaluated. Information on the hazards of AML fires and safety considerations is included. The status of current technology, recent improvements in fire control methods, and areas of current research are discussed.

Jan 1, 1993

By D. A. Larson

This is the second in a series of Bureau of Mines reports which de-scribe experiments designed to devise an efficient, economic mechanical fragmentation technique for hard rock. The previous study described the development of the ripper cutting technique to successfully cut hard rock with 3-to 6-in-wide drag cutters. This study was conducted to test the ripper cutting technique at full scale using 9-in-wide drag cutters. The experiments were conducted with a special test device that cut shallow, 6-by 6-ft openings in 9,200-lbf/in2 compressive-strength concrete blocks. The tests showed that ripper cutting can excavate large-scale openings of the type required by the mining industry at a production rate that outperforms the conventional drill-blast technique. Moreover, the system can produce openings of various sizes and shapes, is simple to oper-ate and maintain, and produces very little dust or noise during operation. The system appears to meet all of the criteria for a successful hard-rock mining machine.

Jan 1, 1987

By J. Pasini

The Bureau of Mines has investigated novel methods of stimulating petroleum production from reservoirs in the Appalachian Region. An important consideration in applying stimulative production methods is the control and removal of solid precipitates from the boreholes of production wells. Where paraffin-base crude oils are produced, as in the Appalachian Region, the accumulation of paraffin may be particularly troublesome. Paraffin deposition is a major production problem that has confronted the petroleum industry for many years. Although considerable effort has been expended by industry and government, a suitable solution has not been found because of the individuality and complex nature of the deposits. Remedial methods used to prevent or remove paraffin fall generally into four classes: (1) Chemical, (2) physical, (3) operative, and (4) combination. Each class has many subclasses that apply to particular problems in different oil- producing areas. Recently, chemical inhibitors and the sonic pump have assisted operators in preventing and removing paraffin deposits. Because these methods are relatively new, their degree of application has not been completely evaluated.

Jan 1, 1963

By Robert L. Skaggs

Sixteen nonaqueous techniques conceived to replace the current aqueous scheme for separating hafnium and zirconium tetrachlorides were re- viewed and evaluated by the Bureau of Mines. The methods are divided into two classes: separation by fractional volatilization of the tetrachlorides, which takes advantage of the higher volatility of hafnium tetrachloride; and separation by chemical techniques, based on differences in chemical behavior of the two tetrachlorides. The criteria used to evaluate separation methods were temperature, pressure, separation factor per equilibrium stage, complexity, compatibility with existing technology, and potential for continuous operation. Three processes were selected as being most promising: (1) high-pressure distillation, (2) extractive distillation from a molten salt, and (3) preferential reduction of gaseous ZrC14. Any of the proposed nonaqueous Hf-Zr separation schemes must be supplemented with additional purification to remove trace impurities.

Jan 1, 1984

By Paul M. Tyler

Calcium chloride is a conspicuous example of a former waste product that has found a place for itself in the onward march of civilization. Formerly considered a troublesome constituent of the effluent sewage of many chemical manufacturing plants and salt works, it has now become a commercial product of substantial importance, with sales aggregating almost six million dollars in 1929. The point has not yet been reached where it would seem profitable to undertake large-scale production of calcium chloride as a main product, but as a byproduct it has become an item that warrants serious consideration by all who are in a position to recover it at sufficiently low cost. The largely increased demand for bromine and for certain magnesium salts, which are likewise potential byproducts associated with calcium chloride in most salt-works bitterns (and brines generally), adds further impetus to commercial research directed toward the fuller utilization of the natural saline resources of the United States.

Jan 1, 1934

By C. M. Paiencia

The Bureau of Mines studied the potential availability of primary antimony (Sb) from demonstrated resources in 21 mines and deposits in market economy countries (MEC's). Twelve of these properties were evaluated as producers and nine as non- producers. The 21 studied properties contain 499,600 mt Sb as demonstrated resources, of which 304,000 mt is recoverable as antimony metal; another 973,500 mt Sb is contained in inferred resources. Recoverable antimony from demonstrated U.S. deposits is only 10,700 mt, just 3.5 pct of the MEC total. Domestic production of primary antimony from operating mines has averaged only 561 mt/yr over the 10-yr period 1975-84. This represents just over 5 pct of total U.S. consumption of primary antimony, which averaged 11,081 mt/yr during the same period. The United States will thus continue to rely on imported ores andlor concentrates, antimony oxides, and metal to satisfy domestic industrial requirements. At production costs up to $1.15/lb Sb, 110,000 mt of refined antimony is potentially available from 10 of the 21 studied properties. At $2/lb, 294,000 mt Sb is available, and at $3/lb, the total rises to 304,000 mt Sb available from all evaluated producers of refined antimony.

Jan 1, 1986

By Frank L. Hess

"New England" and "granite" if not synonymous are at least associated terms. Where there are granites that are not deeply eroded there are usually pegmatites, the most erratic of rocks, and of them New England has a full portion. Many of the New England pegmatites contain the rare alkalis - lithium, rubidium, and cesium. however, the same in homogeneity of the earth's crust that has made the New England pegmatites unusual, in that so many of them contain the rare alkalis, has likewise made the distribution of the rare-alkali minerals sporadic even in those pegmatites, and most contain only enough to furnish collectors with more or less ornamental and uncommon minerals. New England has long had numberless collectors of minerals, and the mineralogists of its various schools have published many papers on the pegmatitic minerals, including those of the rare alkalis, but none of the papers have dealt with estimates of quantities. In this paper we have tried to place the emphasis on quantity rather than on mineralogy.

Jan 1, 1943

By Pamela J. Watson

A novel technique has been employed by the U.S. Bureau of Mines to determine the zeta potential of particles for a far-reaching series of material types in a wide variety of baseline waters, both alone and with many different chemical additives. The materials tested ranged from naturally occurring Sioux Quartzite and Tennessee marble to commercially produced magnesium oxide bricks. The waters tested ranged from ultrapure distilled, deionized water to municipal tap water and mine-site water. The chemical solutions tested included inorganic additives, such as aluminum chloride (AICI3) and sodium chloride (NaCl); organic additives, such as dodecyltrimethyl ammonium bromide (DTAB); and nonionic polymers, such as polyethylene oxide (PEO). The results of precise zeta potential determinations have application in a large number of laboratory studies as well as in various mining and processing operations.

Jan 1, 1989

By John R. Bradley

The object of this paper is to survey and analyze the bearing of economic nationalism, competitive sources of energy, and technologic developments on international trade in coal with especial reference to the competitive position of the leading coal-exporting countries in the Italian market, the largest in the Mediterranean region, and the Brazilian market, the second largest in Latin America. The political, economic, and financial disturbances caused mainly by the World War have resulted in an amazing situation. Especially since 1930 have conditions been complicated.

Jan 1, 1936

By J. P. Walsted

Offgrade chromite concentrate, with a Cr-Fe ratio of 1.3 to 1.4 has been successfully smelted to produce useful ferroalloys. The Cr-Fe ratio is not improved, but the alloys can be used without a too drastic change in normal steel-mill practice. The ordinary high-carbon ferrochrome has been successfully produced by smelting under highly acid smelting conditions. An alloy containing 50 percent chromium was produced at a power consumption of 4,490 kw.-hr. per ton of alloy. Alloys containing 20 percent silicon were made by direct smelting chromite concentrate and silica.

Jan 1, 1956

By R. C. Anderberg, F. J. Caervenyak, F. J. Frattali, H. J. Kandiner, R. A. Brown

"INTRODUCTION Considerable interest was shown .prior to and during World War II in the winning of metallurgical-grade alumina from anorthosite, kaolin, siliceous bauxites, diasporic clays, and other aluminum-bearing ores. Laboratory and pilot-plant investigations were made on many of these ores by the Bureau of Mines, and a series of reports on them is being prepared. This report covers the tests made on the application of the lime-soda-sinter process to anorthosite, which is a mixture of albite, NaAlS1308, and anorthite, CaAl2Si208. Extensive deposits of anorthosite occur in the Laramie Range in Wyoming and extend into Colorado; other deposits are found in New York, with outcroppings appearing in Vermont, Maine, and Labrador.Anorthosito can not be treated by the Bayer process for the production of metallurgical-grade alumina, because excessive losses of soda and alumina occur from the formation of sodium-aluminum silicate due to the large amount (50 percent) of silica in the ore.RESULTS OF INVESTIGATIONSSmall-scale laboratory tests supplemented by pilot-plant runs have demonstrated that the alunina and soda occurring in the Wyoming anorthosite from the Laramie Range can be extracted and recovered satisfactorily by the lime-soda process. It has been shown that liquors containing approximately 95 gram of A1203 per liter can be consistently produced at Na20:A1203 ratios from 1.75 to 2.27, and that these liquors can readily be desilicated and carbonated to yield high-grade alumina trihydrate of quality comparable to that essential for cell-grade alumina. The optimum results were obtained with Na20:A1203 mol ratio of 1.03 and Ca0:Si02 ratio of 2.14 in the sinter when calcined at an average temperature of 2,444ºF. for 25 minutes."

Nov 1, 1947

By V. R. Miller

The Bureau of Mines has developed a technique to separate and recover the three major components, Pb, Zn, and Cd, from lead smelter flue dust. This research was conducted as part of the Bureau's effort to reduce environmental conflicts and occupational hazards associated with mineral-processing operations and to recover valuable constituents in emissions and effluents. The laboratory process utilizes sulfation roasting of the flue dust followed by water leaching to extract over 95 pct of the cadmium and zinc. Ninety-nine percent of the cadmium was recovered from solution by cementing with zinc dust, and zinc was electrowon from the resulting solution after purification. Zinc electrolysis was carried out in a 1-liter cell at 35° C with a cathode-current density of 8 A/dm2 in a solution containing 65 g/l Zn++ and 180 g/l H2S04, Current efficiencies of 80 pct were obtained. The leached residue consisted largely of PbS04, which was converted to PbC03 and leached with H2SiF6 to produce PbSiF6 electrolyte. Ninety-five percent of the lead contained in the residue was converted to electrolyte. Lead was electrowon from solutions containing 70 gil Pb++ and 90 g/l H2SiF6 using a lead cathode, Pb02-coated titanium anodes at 28° C, and a current density of 1.6 A/dm2. Current efficiencies approaching 92 pct were obtained. Accessory minerals such as cobalt and nickel were separated into purification residues and liquor.

Jan 1, 1982

By Martin D. Conyac

A mineral resource survey of rock types and geologic structures indicates that the Mt. Henry RARE II area has low potential for the discovery of metallic minerals. Potential for coal and geothermal resources is negligible. Essentially, the Mt. Henry RARE II area has had no claim-staking activity, nor has any mine been developed in it. SETTING Size and Location The 23,000-acre (9,308 ha) "1t. Henry RARE II area (No. 1-666) lies within the Kootenai National Forest approximately 36 mi (58 km) north of Libby, Montana, in the Purcell Mountain; of Lincoln County. Irregularly shaped, the area measures roughly 5-1/2 mi (8.9 km) north-south by 8 mi (12.9 km) Past-west, and lies about 1-1/2 mi (7.2 km) south of the Canadian border.

Jan 1, 1982