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By G. Russo

During the construction of the S.Martin La Porte access adit, 9m in diameter, extreme squeezing conditions occurred while crossing Carboniferous schistose formations, with diametric convergence up to 2m. Back-analysis of monitoring results shows that an acceptable simulation of the observed excavation behaviour can be derived using a combined analytical and numerical approach, with simple elasto-plastic laws but a progressive reduction of residual parameters and a relevant increase of dilatancy.

May 1, 2009

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By P. Mattar

The geotechnical importance of studying fluid flow through porous media and soils in particular, becomes evident when dealing with groundwater movement in surficial geomaterials that can be initiated by hydraulic gradients that develop during construction activity, groundwater extraction, impounding of reservoirs and groundwater recharge during adverse climatic events. In a geotechnical context, rocks are regarded as virtually impermeable materials, with comparatively greater resistance to flow of water through their pore structure. The importance of the permeability of rocks comes to the forefront when deep geologic formations are used in geoenvironmental activities for disposal of hazardous and toxic materials. The permeability of the rocks encountered is of critical importance to these geoenvironmental activities since the movement or transport of the hazardous materials during their eventual release will be largely governed by the permeability characteristics of the geologic formation. The estimation of the permeability characteristic of geologic formations is a non-trivial exercise since the measure of permeability can be influenced by the scale at which the measurement is made. Regional-scale and borehole-scale estimates of the permeability can be greatly influenced by the inhomogeneities, including fractures, fissures, solution channels and other anomalies that are present in naturally occurring geologic media. These anomalies are considered to be site specific and can only be determined in a reliable fashion by either conducting tests at the appropriate scale or in the regional-scale through inverse analysis of tracer movement patterns in rock masses. The estimation of the permeability of intact units of a geologic medium has important geoenvironmental applications in connection with storage of wastes since the units in which repositories will be located should be sparsely fractured and the sealing of the fractures and fissures are a prerequisite to developing an efficient solution for storage. The intact permeability of geomaterials is therefore regarded as an important property that influences efficiency and reliability of geoenvironmental solutions for deep geologic disposal. The permeability of geomaterials such as concrete and cementitious grouts are also important to many geoenvironmental and infrastructure applications where durability of structural materials in general and cements used for sealing deep boreholes and other access shafts employed in waste management endeavours is influenced by the permeability characteristics of these materials

May 1, 2009

By M. Nowak

Extreme high grades often exert too much influence on surrounding block estimates, leading to a smearing of high grades that can cause overestimation of mineral resources. This concern underlies the decision to cap high grades, i.e., to lower the highest grades in a drill hole data set to some level deemed to be reasonable for producing reliable resource estimates. The choice of a capping level can, by itself, have a large influence on the analysis of the economic viability of a project. Despite this, it is often a choice that is made arbitrarily, guided more by art and tradition than by sound technical analysis. This paper makes suggestions for good capping practices, using methods and procedures that have been presented elsewhere, in the technical literature and in conference papers. The authors propose to use capping only if absolutely necessary, and review examples of cases where capping may not be necessary, or where capping does not make the estimates more reliable. It addresses two particular instances where capping is recommended: (1) where there is good reason to believe that estimation with uncapped grades will overstate the true underlying average grade, and (2) where there is potential for overly optimistic assessments of local block grades in the vicinity of some very high grade assays. The proposed capping practice is based on adjustments to only a very few high grade assays. The level of this capping can be assessed by bootstrapping and through analysis of the effect of extreme values on summary statistics like the average and the coefficient of variation. The paper recommends that good practice include an examination of the potential for local overestimation in higher grade areas.

Aug 1, 2013

By J. D. Templeton

A petroleum well that is not in use because it has ceased to produce oil/gas economically and dry holes are referred to as abandoned wells. Once a well is abandoned it is plugged with cement and can take anywhere from two days up to a week to cure depending on the number of plugs in the well. Since plugging a well costs capital, most wells are abandoned at the lowest possible cost and with the minimum obligations set by regulation agencies. These wells can present an enduring liability to petroleum companies. However, the depth and abundance of abandoned petroleum wells makes them an economically attractive source of geothermal energy. Geothermal energy harvested from an oil/gas well is a renewable energy source as long as it is extracted in a sustainable manner. The energy can be used to generate electricity, used directly for heating, incorporated into a water desalination process, or used by a heat pump for heating/cooling applications. In this paper we examine the possibility of extracting geothermal energy from abandoned oil/gas wells by studying the heat transfer in underground geothermal heat exchangers installed in these wells. The design configurations for the geothermal heat exchangers embedded inside a petroleum borehole can be a u-tube design or a shell and tube design (i.e. double pipe). Using in-situ gathered information from some representative petroleum boreholes, the effects of key parameters such as geothermal gradient, ground temperature values, and the flow inside of the tubes are evaluated. In order to provide a constant power production the inlet temperature can be adjusted to keep the difference between outlet and inlet temperatures equivalent. Higher differences between inflow and outflow temperatures will result in a less sustainable load put on the in-situ geothermal energy. Adding insulation to certain sections of the designs can minimize the transfer of thermal energy from the fluid to the surroundings. Insulation can also limit the thermal loss between the inflow and outflow tubes in the shell and tube design. Minimizing the energy loss of these designs leads to an increase in the outlet temperature, meaning a higher grade of heat. The sustainability of long term geothermal heat extraction is a balance between the rate at which geothermal energy is extracted and the rate at which the ground formation can replace this heat. Higher outlet temperatures can lead to a larger amount of power generation, and a higher coefficient of performance for heat pump applications.

Aug 1, 2013

By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019

By Maureen A. McGuinness

Kidd Mine, an Xstrata Copper operation in Timmins, Ontario, operates a 400 t/h pastefill plant that provides paste backfill to stopes at the depth of 9000 ft. This paper will cover the operating practices of the pastefill plant both on surface and underground, highlighting tailings excavation, paste mix design and the pipe maintenance program. Kidd Mine, une opération d'Xstrata Copper à Timmins, Ontario, opère une usine de remblai d'une capacité de 400 t/h. Le réseau de distribution permet d'acheminer le remblai en pâte juste qu'à une profondeur de 9000 pi. Cet article couvrira le mode opératoire de l'usine de remblai tant à la surface que sous-terre en mettant l'emphase sur l'extraction des rejets miniers, la recette du remblai en pâte ainsi que le programme d'entretient du réseau de distribution.

Feb 1, 2008

By Ted Nuorivaara

The use of polymer-surfactant mixtures as foam stabilization agents is a topic that has drawn the attention of several fields but has so far not be thoroughly studied in the context of mineral froth flotation. The present work showcases a study on the impact on flotation performance of cellulose surfactant derivatives and their mixtures with commercial frothers. Bubble size and foam property measurements were run in a two-phase system along with laboratory-scale flotation experiments conducted using a porphyry copper ore from a mine in Finland. A comparative analysis on recovery, grade and flotation kinetics is presented on the products obtained using: i) a partially hydroxylated cellulose derivative (i.e. hydroxypropyl methyl cellulose; HPMC), ii) a commercial polyglycol-ester frother (Nasfroth240; NF240), and iii) mixtures of these two. The results show that using frothers with a total concentration of 30 ppm, the HPMC-NF240 mixtures provide advantages in terms of Cu recovery, (i.e., up to 95%), compared to the use of either NF240 (ca. 76%) or HPMC alone (ca. 1%). Interestingly, only a small proportion of HPMC mixed with NF240 was sufficient to produce a measurable increase in recovery. This improved performance was attributed to a synergistic effect of the polymer-surfactant mixture which further reduced the bubble sizes in a two-phase system compared to that of NF240. The present work offers a further step into understanding the phenomena taking place when a short chained surfactant is either substituted or mixed with a cellulose derivative, offering potential ways of exploiting this behavior for the enrichment of minerals. INTRODUCTION Froth flotation has been the predominant technology used to beneficiate sulfidic copper minerals such as chalcopyrite ever since it was invented in the late 19th century. The reason for the domination of flotation technology lies behind its versatility in selective separation as well as relatively cheap operational costs (Wills & Finch 2015). Even though flotation of sulfidic copper minerals is moderately well understood based on the broad research work done around the subject (e.g., Albijanic et al., 2015, Bournival et al., 2017, Wang et al., 2015, Mikhlin et al., 2015, to cite only a few), the modern era presents new challenges to the primary raw material industry, including questions regarding sustainability of mining operations accompanied by a need to improve the process efficiencies due to declining ore grades (Edraki et al., 2014).

Jan 1, 2019

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"This paper briefly summaries the status of a recent program aimed at identifying new chemistry for use as sulfide mineral frothers and collectors. The background motivation and planning behind this work is given along with the general families of chemical structures synthesied and studied in detail followed by typical flotation application results in various laboratory and plant scale tests. Flotation testing to date has been very encouraging with often improved recoveries of certain minerals and improved pyrite selectivity being observed over commercially available reagents. In addition, in some cases, the dosage and lime requirements of these new collectors are significantly less than that associated with standard sulfide mineral collectors. INTRODUCTIONFroth flotation is one of the most widely used and economic means of concentrating metal sulfide ores. There are numerous reference books that have been published on the chemical aspects of flotation [e.g., ref. 1-7] which are based on studying the influence on selected minerals of chemical structures that have been used commercially for many years. In fact, almost 98% of the volume of flotation collector and frother reagents used at the industrial level today were known and manufactured in some form 25 years ago [8]. There are many reasons for this lack of significant new flotation reagent development [9] including the general utility and relative cheapness of existing collectors such as xanthates and existing frothers such as the alcohols and glycol ethers. Another reason is the inherent complexity of the flotation process itself coupled with highly variable and difficult to standardize feed materials. This environment makes reliable reagent comparisons difficult and seriously limits the use of theoretically based chemical structure studies to predict new or optimal reagents. In addition, the higher cost of specialty flotation reagents demands that their performance attributes be significantly greater than that achieved with existing all-purpose commercial reagents - something often difficult to prove in practice."

Jan 1, 1988

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

By R. Saulters, M. Garshasb

The Transportable Moisture Limit (TML) is the copper concentrate moisture content beyond which liquefaction may occur during shipping. This study indicates that TML is a function of mineralogical characteristics of concentrate, which in turn may directly affect moisture retention properties. A comprehensive mineralogical and chemical analysis was conducted to determine the impact of composition and mineral content on concentrate’s TML. The analysis indicates that the high TML value is associated with particular minerals such as gypsum, swelling clay, muscovite and pyrite. Since higher TML values allow higher moisture contents for shipping, this property is desirable for concentrate inventory management and shipping flexibility. Scarcity of minerals that may increase TML contributes to limitations of shippable inventory. INTRODUCTION TML is the maximum moisture content of copper concentrate beyond which liquefaction may occur. Moisture content above the TML is considered a shipping hazard as it may result in loss of lives and cargo. The details of TML testing are given in ISO 12742:2007 (ISO 12742). In principle, TML is 90% of the Flow Moisture Point. The method of testing for Flow Moisture Point and TML is based on procedures that provide pulsations that simulate the cyclic force of ocean waves to determine moisture levels at which the onset of concentrate flow may occur. International Maritime Organization (IMO) provides guidelines for developing and approving TML testing and moisture determination in the context of its Moisture Management Plan (MMP) for shipment of copper concentrate cargoes (IMO 2013). The IMO regulations are specifically provided in MSC.1/Circ. 1454 “Guidelines for developing and approving procedures for sampling, testing and controlling the moisture content for solid bulk cargoes which may liquefy”. Since each port has its own operational characteristics, resource availability, peculiarities of governmental structure, and desired methods of interaction with the authorities, it is necessary to adopt the IMO guidelines to the local requirements. In order to establish a TML and MMP measurement system, it is required to implement and follow proper guidelines for the relevant procedures. For example, sampling procedures are developed in accordance of ISO 12743, “Copper, lead, zinc, and nickel concentrates – Sampling procedures for determination of metal and moisture content”. Moisture content of copper concentrate samples are determined in accordance with ISO 10251, “Copper, lead, zinc, and nickel concentrates – Determination of mass loss of bulk material on drying”. To assure strict adherence to the MMP procedures, the overall system needs to be integrated into the site QA/QC system, which would make them auditable and certified in accordance with standards such as ISO 9001, ISO 17025, and ISO 17020.

Jan 1, 2019

By J. X. Guo, A. Pindred, J. Moore

"Two modified centrifugal flotation cells (CFC), Q2 and Q3 models, have been developed for froth flotation. The operating mechanism of Q2 uses a rotating bowl to create a centrifugal force on the feeding slurry. Froth concentrate is collected on the central top of the cell and tailing is discharged along the top edge of the rotating bowl. The Q3 utilizes a vertical rotating feed pipe to introduce the feed slurry into a stationary flotation column cell. A centrifugal force is also created by a rotating pipe for the feeding slurry. Froth concentrate floats over the cell and tailing discharges through the bottom of the cell. The centrifugal force causes the flotation recovery of fine particles from CFC to be higher than from the conventional cell. The major operating variables of CFC are the rotating speed, air flow rate into feed slurry, and slurry feeding rate etc. Flotation tests have been carried out on synthetic mixtures of galena-silica and chalcopyrite-silica, as well as some natural base metal ore samples. Parallel tests were also conducted on a conventional flotation cell. The comparative test results demonstrated that both Q2 and Q3 have the advantage of higher recovery of finer than 10 µm mineral particles, which are very difficult for the conventional non-centrifugal flotation cell to recover. The grade-recovery curves produced from CFC are equivalent to or better than the conventional flotation cell. There is a potential in the future for the CFC to be employed in slime flotation.1. IntroductionA centrifugal flotation cell (CFC) was originally developed by Clean Earth Technologies [I] to separate oil from water and was subsequently applied in froth flotation. Figure 1 illustrates the design of the original CFC, in which a vertical feeding pipe is attached to the center part of a rotating drum and a stationary shell encloses it to direct the float froth and tailing discharge. The slurry flows down to the bottom of the spinning drum, gets in touch with a screen of air bubbles and then migrates outwards under the effect of centrifugal force. After the mineralized froth enters the rotating cell, it is pushed back to the inner surface. The overflowing froth is collected in the froth launder while the tailing slurry is discharged through orifices along the outer rim of the drum."

Jan 1, 1998

By E. G. C Charlesworth, M. J. Robertson

"Gold mineralization in the Main Reef Complex at Sheba Gold Mine is hosted within shear zones in a sequence of shales and greywackes of the Fig Tree Group. Competency contrasts between these rocks and a steeply dipping chert unit provided a locus for the development of right lateral steeply dipping shear zones. A set of flatter dipping shear fractures crosscut these zones with their intersections defining a system of en échelon ore shoots. Mineralization is both of vein type and disseminated strata-controlled replacement type. The latter occurs mainly within the wall rocks to the shear zones. Arsenopyrite and pyrite are the major sulfides, with arsenopyrite being confirmed largely to greywacke beds and pyrite to the more iron-rich shale units. Gold was introduced, together with minor sphalerite, pyrrhotite, chalcopyrite and early arsenopyrite, toward the end stages of a first pyrite phase. The mineralizing fluids were introduced along dilated cleavage planes and, emanating from these, produced a series of replacement fronts. Mineralization was syntectonic to late tectonic and occurred under conditions of progressive deformation, resulting in sulfides which are concentrated in the hinges of shear-related folds and semimassive sulfides within tension fractures which are folded, attenuated and fractured. An analysis of the structures shows a sequence of events in which an initial ductile simple-shear event with a steep sense of movement was succeeded by a more brittle strike-slip event. Mineralization is temporally related to the latter. This evolution in structural style was probably related to reactivation of the Sheba Fault as a transcurrent fault during emplacement of large granitoid bodies."

Jan 1, 1994

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By A. Probst, N. Moores, J. A. Finch

"In 1994 McGill and INCO (Sudbury operation) initiated transfer of technology originally developed to detect level in flotation columns to thickeners. A conductivity probe was installed in a concentrate thickener to monitor the mud-line and solids load. The probe consisted in a vertical tube with 32 equally-spaced electrode rings connected in pairs to give 31 conductivity cells. Conductivity was measured as a function of depth (so-called conductivity profile) from which the mud line and % solids could be inferred. The probe was installed in October 1994 and has been successfully detecting profiles since then. This communication includes a description of incidents and experiences during this technology transfer process including: probe installation and start-up; software modifications to accommodate operating conditions and operators' needs; calibration procedures to adjust to changes in performance as a consequence of long term use; and preliminary observations on the last stage, still in progress, signal interpretation and use to facilitate operation, particularly by providing early reaction to upstream disturbances.IntroductionThickening is one of the basic unit operations in mineral processing and hydrometallurgy used to separate suspended solid particles from a solid-liquid dispersion by gravity settling. As the dispersion enters the thickener, the solids settle and clarified water overflows the top. A thickener, which may be continuous or batch, is basically a large vertical cylindrical tank provided with devices to feed the dispersion and to remove the settled solids. The tank provides residence time for the particles to settle. The dispersion enters the thickener through the feedwell whose function is to dissipate the momentum of the feed stream and to create relatively quiescent conditions around the entering point. Rotating rake arms move the settled solids towards the discharge point located at the bottom centre of the tank.There are normally three distinct zones in a thickener: a top layer of clear water, a middle layer called a sedimenting zone in which particles are settling, and a bottom layer called a compression zone in which particles are pressed together as a consequence of the weight of accumulated particles. Proper operation of a thickener requires two simultaneous conditions: no solids in the water overflowing the top and the target solids content in the underflow pulp. To achieve these conditions is difficult because sensors for detecting the sediment line (interface between clear water and sedimenting zone) and the solids content in the compression zone are not commercially available."

Jan 1, 1998

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By J. Kuipers, R. W. Lawrence, P. B. Marchant, W. Brooks, J. T. Chapman

"Bioleach testing and piloting was conducted on refractory gold sulphide concentrate from Austin Gold Venture in Nevada during 1988. The objective of the test programme was to determine the technical and commercial viability of bioleaching as a concentrate pretreatment step prior to gold extraction by cyanidation. Baseline CIL cyanidation typically resulted in < 20% gold extraction from the Austin concentrate. Bioleaching enhanced gold extraction up to 95% using conventional CIL techniques. This paper summarizes the bioleach test programme and results, including pilot plant studies onsite, and describes the commercial design details for a possible retrofit of the Austin flotation tailings leach circuit to accommodate 20 tpd and 40 tpd capacity concentrate bioleach facilities.INTRODUCTIONBioleach testing on a refractory carbonaceous sulphide concentrate from Austin Gold Venture (AGV), was initiated in late 1987 as part of an ongoing programme at Austin to investigate alternatives to concentrate smelting. Preliminary batch biooxidation tests at Coastech indicated that over 90% gold extraction by carbon-in-leach (CIL) cyanidation of the bioleach residue could be achieved, compared with less than 20% gold extraction on untreated concentrate by similar CIL processing.Subsequently, a more rigorous laboratory study was undertaken at Coastech to establish continuous biooxidation operating criteria on a bench scale. The objective of continuous testing in the laboratory was to provide confirmation of enhanced CIL response based on continuous bioleach products and to determine key process operating and design parameters for pilot testing. The success of the laboratory test program led to the installation of a mobile pilot plant at Austin Gold Venture. The plant was operated by Coastech and AGV during 1988 to provide scaleup data and design criteria for commercial design and feasibility analysis. Based on pilot plant operating data, a detailed commercial bioleach plant was designed as a possible retrofit to the existing 1000 tpd CIL plant. Capital and operating costs were estimated to provide a commercial feasibility study of bioleaching as an oxidative pretreatment for Austin refractory concentrate."

Jan 1, 1989

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019

By G. A. Highcock

"Operations started at BCL in December 1973J and the smelter is currently in the seventh year of its fifth campaign. The next major shutdown is scheduled for 1995. During the current campaign, a number of major on-line refurbishments have been carried out without any significant disruption to production. These include the complete rebuild of both drying plant electrostatic precipitators, the installation of a new electrostatic precipitator at the flash furnace, the conversion to a distributed control system throughout the smelter, and the installation of a converter air blowing control system.IntroductionBCL Limited operates a nickel-copper mine in northeastern Botswana approximately 100 km southwest of Francistown. Surface operations for the production of high-grade nickel-copper matte at a design capacity of 42 000 metric tonnes per annum, were commissioned in December 1973. Detailed descriptions of the mine and surface facilities have been presented previously(1-3).Over the years, a number of major engineering modifications and metallurgical projects have been carried out to overcome operating difficulties. improve metal recoveries, increase production rates and provide a better working environment.One of the major results of these projects was an increase in the 19805 in flash furnace feed capacity from 70 t/h to 120 t/h of new concentrate with a nominal feed rate of 105 t/h being achieved.(4)Because of the ore characteristics, i.e. a high mass fraction of ore reporting to concentrate, BCL operates one of the highest capacity spray drying plants and flash smelting furnaces in the world(5).A schematic of the BCL smelter is shown in Figure 1. The smelter is now in the seventh year of its fifth campaign, with the next shutdown scheduled for mid-l99S. In this campaign, the following major projects were completed:"

Jan 1, 1995

By Chris J. Pritchard

Pumpable, two-component resins for anchoring rock bolts provides significant advantages over traditional cartridge resin and cement grout systems where fast and easily adaptable support is required for difficult ground conditions. Cartridge resin anchoring with rock bolts is often ineffective in oversized, fractured and washed-out holes. Cement grouting of cable bolts is frequently plagued with QA and QC issues related to the grouting process. Installation of cable bolts with resin injection techniques is routinely completed in cycle allowing blasting immediately after cable bolting. Xstrata Nickel has evaluated the Minova Resin Injection System since 2007. The Nickel Rim Mine and partner Minova have tested and validated the Resin Injection process for bolting procedures including Hollow Fiberglass Bolts, Rebar, Modified Cone Bolts and Cable Bolts. The resin injection process is adaptable to most bolting processes and equipment. Currently, Nickel Rim Mine use 2 resin injection products with different set times to grout deep cable bolts and development support in highly variable ground conditions. The product predictability and adaptability in application along with a high crew acceptance continues to make this support process part of an adaptable ground support system. Product consistency and quality significantly reduce the quality control concerns for ground support in highly variable ground conditions.

May 1, 2011