Search Documents

By A. Cummings

This paper reports two aspects of reactivity of complex Ni-Cu sulphide ores: variations that result from stockpiling of a nickel-copper sulphide ore in the Sudbury area and its consequences on flotation behaviour, especially in terms of metal losses to scavenger tails. In relation to the first aspect, self-heating characteristics of the stockpile were carried out by monitoring the internal temperatures of the stockpile. Six heat sensors were installed with respect to external conditions in local weather during a 7-month period. Stockpile temperatures were mainly influenced by ambient temperature with some retardation effects. The maximum temperature recorded in the stockpile was 44 °C. Samples taken at the beginning and at the end of stockpiling were tested to assess variations in behaviour of the rougher-scavenger flotation. Relative to the fresh ore, nickel and copper losses in flotation of the stockpile fines were 5.0 and 3.6 %, respectively. The fresh ore yields concentrates with higher nickel grades due to differential flotation behaviour of pentlandite and pyrrhotite relative to the stockpile fines, which exhibit a truly bulk flotation behaviour at least during the first 3 stages.

Aug 1, 2013

By P. Mišcevic, B. Kavur, I. Vrkljan, N. Štambuk Cvitanovic

It is known from earlier and recent research that mechanical properties of intact rock like uniaxial compressive strength (UCS), Young's modulus (E) and Poisson's ratio (?) are influenced by shape deviations of test specimens as deviations from the ideal cylinder. That impact can be significant at certain level of inaccuracy of specimen preparing, and it should be objectively evaluated and controlled in testing. The effects of intact specimens side straightness, ends flatness, ends parallelism and perpendicularity to the specimen axis, on UCS, E, and ?, measured in several actual ways during laboratory compression tests, were determined by previous research on 90 homogeneous specimens of limestone. In this paper, we subject these new experimental results to Response Surface Methodology (RSM) to model the mentioned dependence, to identify significant connections of variables and to evaluate the conclusions obtained directly from experimental phase. This study indicates how the responses of the model (outputs) – parameters UCS/E/??of limestone rock depend on factors (inputs) – parameters of specimen shape deviations like flatness R, parallelism P and perpendicularity O, assuming modern test machines with spherically seated upper platen. Starting from general RSM model with three factors (R, P, and O), we investigated the multiple linear regression models of specific mechanical property (UCS, E, and ?). Using the NCSS program ("NCSS 2004 and PASS 2005") in several steps, final models with very high coefficients of determination were developed for properties with the most evident effects of specimen shape deviations: nine models for strength UCS and UCS50 (equivalent UCS for specimen with 50 mm diameter), and three models for ?L (Poisson's ratio calculated from axial deformations measured on the entire specimen length). These statistical models with their response surfaces further strengthen and confirm the results and conclusions from the experimental phase. The critical values of R, P, and O are established using an additional statistical analysis to determine the lower and upper engineering limits. These findings set the basis for the new eligibility criteria for specimens of limestone (and similar rock with UCS about 100-150 MPa) in further testing of strength and deformability.

Jan 1, 2015

By J. R. Giegerich

"IntroductionMINING operators in common with other operators are confronted today with two serious problems, shortage of experienced workmen and rising costs. The following review of practices at the Sullivan mine of The Consolidated Mining and Smelting Company of Canada, Limited, outlines certain measures that have been responsible, during recent years, for minimizing the effect of these two problems. The paper is divided into three main sections:( 1) Training programmes and job studies( 2) Improved mechanization and equipment( 3) Large-scale methods of operationTraining Programmes and Job StudiesJob TrainingJob training courses were introduced at Cominco immediately after the last war and proved to be a great benefit to the operations. There were three courses given, Job Instruction Training, Job Safety Training, and .Job Relations Training. These were spread over a period of two years and were taken by all operating supervisors and some key operators.The courses were introduced by a trained instructor from the British Columbia Department of Labour. This man trained twelve of our employees as instructors by giving them an intensive one-week course. Similarity between the three courses was such that the instructors trained in the first one were very readily trained for instruction in the two succeeding courses."

Jan 1, 1952

By J. Jung, W. Keller, A. Zucht

"The agitator design for nickel high pressure acid leach autoclaves (HPAL) is critical with regard to the process result, i.e., the recovery rate. Further considerations during the design phase are the avoidance of acid hot spots which reduce the lifetime, due to corrosion of the wetted parts, including components manufactured from titanium. Besides the process knowledge to design HPAL autoclaves, tools such as, Computational Fluid Dynamics (CFD) supplemented by lab testing allow the design of optimized agitation systems. This paper describes the effect that different feed point locations have on instantaneous blending of the reactants. Furthermore, experiments and CFD show where abrasion issues might occur and how to obtain information about the static and dynamic forces acting on internals. We show how simulations can be validated by lab testing to ensure that the CFD models are applied in an appropriate way.INTRODUCTIONAgitated systems in hydrometallurgical processes have to comply with multiple process tasks and in many cases have to withstand extreme operation conditions such as pressure up to 50 bar, elevated temperatures of up to 250°C and exposure to very acidic or alkaline environments and abrasive ores. The process tasks range from instantaneous mixing of reactants, homogeneous suspensions of up to 65% wt. solids with coarse and heavy particles, enhancing the solid-liquid mass transfer for leaching, dispersing large volumes of reactants (gas-liquid, liquid-liquid mass transfer) and moreover to transport generated heat e.g., from exothermic reactions through the vessel walls or internal heat exchangers if required. For economies of scale, agitator systems have reached sizes of 5000 m³ for large open leach tanks with impeller diameters of approx. 6 m, while autoclaves nowadays have exceeded 5.5 meters in diameter with a power demand for a single compartment drive between 300 - 400 kW. In parallel all process industries require a more efficient use of resources, to generate less by-products and higher yields, while ore-bodies tend to be less qualitative and new process routes (e.g. direct leach) are developed. Besides all these facts the mixing solution must be robust and economic. In this paper we want to address our approach in the development and designing of HPAL agitation equipment."

Jan 1, 2012

By B. Westin, G. Voicu, C. Daoust

Orogenic gold deposits represent a major class of deposits that are found in various rock types of various ages. Those deposits show a strong structural control that usually complicates their interpretation at the regional and deposit scales. The Rosebel Gold district located in Surinam (South America) is hosted in a Paleoproterozoic greenstone belt of the Guiana Shield, and has been recently classified as one of those orogenic gold deposits. The gold district comprises eight distinct deposits located along three different structural trends and within different rock types. The mineralization is undefonned and shows a strong structural control characteristic of orogenic gold deposits. All the deposits of the Rosebel Gold district have been subject to a detailed structural analysis that has led to the elaboration of a new structural model for the whole gold district, which is now differing considerably from the previous models. This characterization had direct implications at three different scales. 1- While the older models were considering some areas of the property as gold-barren, the new structural model has led to recent exploration campaigns which have revealed positive results. 2- At the deposit scale, the comprehension of the various vein systems and of the folding of the host rocks has helped the establishment of optimized drilling campaigns. 3- At the mining scale, the comprehension of the architecture of the veins helps for the elaboration of optimized mining method. This study thus shows that the structural analysis of orogenic gold deposits is critical, and should be a priority for exploration and production in any mine.

Jan 1, 2011

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By Y. Duna

The reliability of mine ventilation systems is critical to normal and safe production in a mine and includes reliability of the following parts: ventilation system branch (or passage), ventilation structures, ventilation network, and the fan. Among these, the reliability of a ventilation branch may be considered the foundation of the whole ventilation system. The branch ventilation flow includes four parameters: air volume; toxic and hazardous gas concentrations; temperature, and dust concentration. The calculation model for the reliability of a branch was established based on the analysis of normal distribution of flows in any one branch. Then, the efficiency of the ventilation structures and fire risk compromising the reliability of branch was studied. The results obtained were as follows: if the air volume, toxic and hazardous gas concentrations, temperature and coal dust concentrations of the branch are within reasonable limits, set at any stable state and at the same time, then this branch is reliable.

Aug 1, 2013

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

By C. Morlot, C. Auvray, E. Fourreau, J. Talandier

"During the excavation of underground galleries in a rock mass, reorganisation of the stress field around the site results in damage to the surrounding material. In the framework of research undertaken at the ANDRA underground laboratory in France, galleries have been excavated in a Callovo-Oxfordian argillite formation. The damage has manifest as a number of fracture systems in the adjacent rock. Observations have shown that fractures generated during excavation and storage exploitation are able to self-seal during re-saturation of the site in the post-closure stage. Although indirect evidence for argillite self-sealing has previously been reported, from experiments performed both in situ and on samples, no direct observations of self-sealing have yet been made.For the present study, we performed a range of self-sealing experiments using a newly-developed triaxial compression cell placed within a nano-CT scanner with a 10 µm resolution. The body of the compression cell is X-ray transparent, allowing sample healing to be monitored directly. The samples contained an artificial fracture that had been generated in the laboratory, into which a fluid was injected. The fractures were orientated either perpendicular or parallel to the plane of anisotropy of the material. Our initial results demonstrate that when fluid is injected perpendicular to the plane of anisotropy, the flow-rate has no apparent influence on the kinetics of fracture closure. Permeability varies significantly, from 2.10-14 to 2.10-18 m2 over 116 hours. Post-test observations of the fracture lips show swelling that appears to be orientated perpendicular to the fracture plane and therefore parallel to the plane of anisotropy. Initial results for an injection parallel to the plane of anisotropy suggest that, in this case, the rate of flow affects the kinetics of fracture closure. For a flow-rate of 0.25 ml/min, closure begins after around one minute. In contrast, for a rate of 0.05 ml/min, it is necessary to wait several minutes before partial sealing of the zone is observed. The reduction in permeability is again significant, from 2.10-15 to 4.10-18 m2 over 96 hours. After completion of the test, swelling was observed in elongated zones that lie parallel to the fracture plane and therefore to the plane of anisotropy."

Jan 1, 2015

By V. G. Papangelakis, I. Guzman, S. J. Thorpe

Pressure oxidation (POX) leaching has been commercially applied to refractory gold ores since the 1980s. In the process, sulphide material is oxidized and dissolved in order to release the gold encapsulated in the sulphide matrix, making the gold available for further recovery. Redox potential is a significant parameter during POX, however it is only measured ex-situ at atmospheric conditions. In-situ redox potential measurement would provide instant information that allowing adjusting the process parameters accordingly. In the present study, redox potential measurements were performed during POX of sulphide material at high temperatures and high pressures. The working electrode was an Ir electrode combined with a flow-through reference electrode in a novel and robust configuration. Experiments were performed in a 2 L titanium autoclave, at 200–220°C, 50–110 psi oxygen overpressure, and 10–30% solids mass fraction. Temperature and oxygen pressure conditions were selected in order to reflect POX of refractory gold ores. Results show that the Ir electrode is consistent with theory and is able to perform well under these conditions, showing promise as a new in-situ sensor.

Jan 1, 2017

By J. Donnelly, A. V. Deev

Substitution of coal and coke by renewable carbon (charcoal) is a low-risk and low-capital path to 50% or more reduction in net CO2 emissions by the steel industry. However, the high cost of charcoal and its low availability in most countries are barriers for the implementation of this approach. Development of an efficient wood carbonisation technology (slow pyrolysis) capable of producing large-volumes of charcoal from low-cost wood feed (e.g. wood wastes or forest residues) is an essential step towards the use of renewable carbon by the iron and steel industry. This paper provides a summary of the progress made over several years of R&D covering: (1) development and piloting of a new energy efficient slow pyrolysis process for production of charcoal from woody biomass at a competitive cost to the PCI coal, (2) techno-economic evaluation of the process. The main feature of the process is that the material undergoing pyrolysis is heated spontaneously without the supply of heat or air to the reactor. This makes it possible to carbonize large volumes of small-sized wood (e.g. wastes and residues) in a single reactor unit and capture high calorific value pyrolysis by-products

Jan 1, 2015

By H. Lazreg

This paper presents an evaluation of surface resistivity techniques as a tool for delineating salt-water intrusion in Shippegan, N.B. The study consisted of resistivity profiling, resistivity soundings and a limited number of induced polarization soundings in selected areas in the Province of New Brunwick. The results from resistivity profiling indicate that when seawater intrusion occurs in a sandstone formation the resistivity contrast is sufficiently large to allow a precise delineation of the intrusion. A formula is then derived to convert resistivity values to chloride concentration in the "cone of intrusion". The results from resistivity soundings showed that shaly formations may have resistivities as low as seawater-contaminated sandstone. An indeterminacy has resulted from this resistivity overlap. A limited number of IP soundings were performed in an effort to resolve it. The results showed that IP can be of appreciable help in resistivity interpretation.

Jan 1, 1972

By Les Philips

National Institute for Safety and Health?s (NIOSH, USA) Office of Mine Safety and Mine Safety and Health (OMSHR) has definitions for: -Proximity Detection as detection of personnel, vehicles and other objects near a machine using some type of sensor technology -Proximity Warning (aka Collision Warning) as detection of personnel, vehicles and other objects near a machine resulting in alarms that ?Warn the operator only ?Warn the operator and nearby personnel (two-way) -Collision Avoidance as the processing of sensor information resulting in control signals or actions that alter machine status/movement to avoid a collision by ?Computer control ?Human control

May 1, 2013

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By P. Tarassoff

Extractive metallurgy is concerned with the winning of metals from their ores and concentrates. It is therefore not unexpected that extractive metallurgy in Canada has always been closely linked with mining. The discovery and exploitation of new orebodies has provided the impetus for the building of many of our smelters and refineries - past and present - and for the development of new metal extraction processes. The purpose of this paper is to provide a brief overview of those early metallurgical developments, and to highlight the continuing expansion and diversification of the Canadian metallurgical industry.

Jan 1, 1999

This paper states how alloy and welding advances have made possible the rapid development of the use of aluminum in the construction of equipment for earth moving and off -highway rock hauling. The main details are given regarding the construction and field testing carried out on an aluminum prototype body. The test results of strain gauge readings are analysed, and a description is given of how these have been applied in subsequent designs. The increase in the number of aluminum units put into the various types of service in Canada, as well as the problems encountered, is described, and the experience gained from five years of field service is discussed in some detail. An assessment is also made of the durability of the e units. The economics of using aluminum, together with the current development position, are reviewed, and predictions are made for considerable future increases in the use of aluminum units in open-pit and off-highway operations.

Jan 1, 1964

By Peter A. Adcock, Rob Fraser

Interest in monitoring nucleation overpotential in electrometallurgical processes dates back some 40 years or more. Conversely, remarkable progress has been made in recent years on describing in detail the processes involved in the formation of thin films by electrodeposition. The newer body of work underscores a need for greater clarity in speaking about the role of nucleation and in the acquisition and interpretation of nucleation overpotential measurements – the aim of this paper. In electrometallurgy, it is generally desirable to form deposits that remain smooth, compact, and relatively fine-grained while the deposit grows to a thickness on the order of 5-10 mm, about 100 times thicker than technological thin films. Hence, we distinguish two kinds of nucleation that can result in formation of new grains:- (1) initial nucleation (onto the substrate surface) of islands that coalesce into growing deposit, and (2) ongoing nucleation of new grains on the deposit surface long after the substrate has been covered and ceases to have a direct influence. Nucleation overpotential of the first type should be measured on an electrode surface truly representative of a real industrial substrate. The second type requires judicious choice of electrode material – an “ideal foreign substrate”. In general neither the industrial substrate nor native metal to be deposited is suitable for measurement of the second type of nucleation overpotential, because of interference by other processes. For the future, clear terminology is needed to distinguish these two types of nucleation potential. The second is the one for which the type of plot dubbed by Moats and Derrick as an “Adcock plot” and by us as a “Kerby-Adcock plot” was first conceived and correlated with relatively thick zinc electrodeposits. The data of Moats and Derrick showing trends for copper electrodeposition on stainless steel and on copper electrodes are interpreted within this framework.

Jan 1, 2016

By Zhiyang Long, Ruiling Xiao

"A mine shaft is one main development method of establishing access in an underground mine. The construction technology of the mine shaft sinking is complicated and large equipment setup on surface and in the mine shaft. The paper briefly reviews a single-line operation method, parallel operation method and mixed operation method as well as the features of the one operation method with the excavation, lining and installation. The special construction technology mainly would include ground freezing methods, full diameter shaft drilling methods, caisson methods, grouting technology and concrete curtain methods as well as other methods. The paper summarizes the shaft sinking numbers and effects by the special construction methods during different periods. The paper states the shaft sinking conditions and the each created record conditions in the coal, metallurgy, non-ferrous metal, hydropower, highway, railway, nonmetallic and other industries. The paper has a prediction on the shaft sinking requirements and development tendency in the future for China.INTRODUCTIONA mine shaft is one main development method of access in an underground mine. In recent years in China the new shaft mines represent 45% of the total number of new mines. With the development of new mining area under construction and the development of deeper mines, the ratio of the mine shaft as access for underground mines will increase. The construction technology of the mine shaft engineering will be complicated, the operation site footprint will be small and the working environment will be more difficult. The mine shaft sinking operation will often be varied by the geological conditions and affected by underground water inflows, seam gas outbursts, geothermal and other natural conditions. The safe construction of the mine shaft sinking will be challenged by all these conditions. Although the mine shaft engineering will only be about 5% of the total mine roadway engineering, the mine shaft construction period often will take over 40% of the total mine construction period. With the progress of modernized mine production technology and the construction of a high production and high efficient mine, the mine transportation roadways mostly would be set in the seam and the engineered amount of the mine rock roadways reduced year by year could cause more prominent long extensions of the mine shaft construction period. Therefore, in order to speed up the construction, to shorten the mine construction period and to realize the investment benefits as early as possible, the technical level of the mine shaft sinking should firstly be improved and the construction speed of the mine shaft engineering and sinking should be speeded up, which would have important significant benefits."

Jan 1, 2019

By M. T. Ho, D. E. Wiley

The iron and steel industry accounts for almost 5 % of the total world CO2 emissions. Optimisation of the steelmaking process has led to significant reductions in the energy intensity to the point where it is now close to the thermodynamic limit. Further reductions are not likely to be achieved with efficiency improvement alone and will require the development of novel or breakthrough technologies. This paper will show the costs of implementing CO2 capture at direct atmospheric emission points for a number of iron and steel production processes. These include a conventional process, top gas recycling processes, the Corex and Hismelt smelt reduction processes and the Midrex direct reduction process. Depending on the point source emission, costs of capture with existing chemical absorption technology at iron and steel plants can be similar to capturing CO2 at pulverised coal fired power plants.

Jan 1, 2015