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By F. H. Hueston, R. S. Barclay

"Depending on the application, zirconia, fused magnesia and graphite have been found to be the most suitable crucible materials for melting uranium metal and its alloys. Although graphite has been found to be satisfactory for uranium and uranium alloy castings with cross sections of 4 square inches or greater, ceramic-type molds are superior for small sections and those shaped castings which prohibit the economic use of machined graphite molds. Heating cycles, addition mechanisms and furnace conditions for melting are discussed."

Jan 1, 1967

By Alfred Guenkel, Kyle Marte, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985 (Borbely, Devuyst, Ettel, Mosoiu & Schitka, 1985). Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. Though it is possible to supply sulphur dioxide (SO2) in either gas or liquid form, the majority of these SO2/air operations use sulphite-based salts as the ‘SO2’ equivalent reducing agent. This is probably due to the lower capital cost, safety concerns with, and availability of liquid SO2. Sodium metabisulphite (SMBS) is commonly employed, and its cost is an order of magnitude higher than that of sulphur. The increased capital expenditures (CAPEX) for a sulphur-burning SO2 gas plant could have a pay-back of less than two years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas inventory. Furthermore, a SO2 gas plant will not trigger the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and Boleo).This paper discusses the different processes which require SO2 as a reducing agent and compares the capital and operational costs of a SO2 gas plant to conventional process alternatives using sulphite-based salts or liquid SO2.The heart of the SO2 gas plant is the sulphur furnace. The most economical way to produce SO2 is by combustion of sulphur in air producing up to 19.5 vol% SO2. Examples of large and small sulphur furnaces are discussed in terms of design, operation, and impacts on operational costs.The SO2 gas produced in a sulphur-burning plant has to be contacted with the liquor to be reduced. The choice of gas-liquid contacting device is important, and two contacting devices are discussed: 1) Gas sparging into the bottom of leach tanks (high, nearly constant, back pressure due to liquid head) and 2) absorption columns (low gas-side pressure drop)."

Jan 1, 2014

By D Marshall

The sub-level blasthole benching method of mining has been proved to be economical at Willroy Mines. How-ever due to the nature and attitude of the wall rock, this method is susceptible to serious hanging-wall dilution of the ore. Attempts to solve the dilution problem by various means were not satisfactory until long Stressteel bars were employed as rock bolts. The adoption of this de-vice does not require any special skill, and has become routine in the under-ground operation. Since the inception of this method, the dilution of the ore has been greatly reduced and the ov1!r-all costs of controlling this dilution are much lower. INTRODUCTION T HIS is a report describing the successful use of long Stressteel bars as rock bolts in preventing l1anging-wall failure and consequent dilution in open stopes. Willroy Mines Limited is located (Figure 1) near the town of Manitouwadge, Ontario, approximately l1alf-way between Sault Ste. Marie and Port Arthur.

Jan 1, 1963

By F. J. Alcock

IN the summer of 1934, gold was discovered on Lodge bay, on the north shore of lake Athabaska in northern Saskatchewan, about fifty miles east of the Alberta boundary line. The first claims were taken up by the Consolidated Mining and Smelting Company of Canada, Limited, and there was a 'rush' to locate similar showings. Staking continued through the summer and succeeding winter, and in the spring of 1935 the provincial government established a recording office at a convenient point which is central to the more important holdings and where 'planes can land in any weather. During the past summer, the name of this townsite was changed from Beaverlodge to Goldfields, and a post office was established here. The season was one of great activity; a great deal of assessment and development work was carried out and a large amount of further prospecting done. In addition to the work by private companies, geological investigation was carried out in the region by a Federal Geological Survey party under the charge of the writer and a reconnaissance examination was made of an area of some 7,000 square miles surrounding the region of particular interest. Though this was the first discovery of gold in the region it was not the first occasion that prospecting had been carried out along the north side of lake Athabaska. Over twenty years ago, a number of prospectors were at work in the area and a large number of claims were staked, many of which were never recorded. One man by the name of Piché, in the years 1910, 1912, and 1913, took up a considerable number of claims north of Pine Channel narrows, east of Fond du Lac. His discoveries, which consisted of small showings of sulphides in sedimentary gneiss, proved to be of no economic importance. In 1915, a sudden widespread interest was aroused by the report that a sample of ore collected near Fond du Lac had yielded a very high assay in silver. In March and April of that year, prospectors began to rush into the field by dog teams to take up claims, and, as soon as the Athabaska river was free of ice, others started by boat from Athabaska Landing. Some hundreds of claims were staked and recorded in the Dominion Land Office at Edmonton or at Fort Smith. By July, most of the prospectors had? left the region, having failed to find any silver ore. In 1921, considerable prominence was given to the area a few miles east of Goldfields by reports that very large masses of iron ore were available there. Claims were taken up, but the material is much too low grade to be considered commercial ore.

Jan 1, 1936

By R. H. Waddington

Historical The limitations of reverberatory furnace operation have prompted many investigators to consider electric furnaces for melting electrolytically refined cathode copper. In the majority of cases where experimental work was performed, the furnace used was of the granular resistor, induction, or indirect-arc rocking type, and attempts to adapt the three-phase direct-arc furnace to copper melting appear to have been relatively few. In 1935, the International Nickel Company of Canada, Limited, carried to an advanced stage its experimental investigation of continuous melting of copper in the three-phase direct-arc furnace, and demonstrated that this process was technologically and economically practicable. Trial operations were conducted at the Huntington, W.Va. works of the Company, and were followed by the installation at Copper Cliff, Ontario, in 1936, of a full-scale unit for commercial operation. Two years later, a second unit was installed -which raised the electric melting capacity to a point permitting complete replacement of the coal-fired reverberatory furnace operation in the production of refined copper castings.

Jan 1, 1946

By J. L. Bowlby

OWING to the pressure of routine analyses at the laboratory during the past year, work of an investigational nature on water problems has been greatly curtailed. Favourable reports by the boiler inspectors indicate that the operators are giving satisfactory attention to feed-water treatment at the several . power plants. Some of the operators prefer lime and soda, others the phosphate and soda treatment. Springhill is still on the same commercial treatment as they were using last year, and satisfactory results are being obtained. This individual preference for a particular treatment, although it may be different for feed waters of similar nature, indicates that so long as proper conditions of alkalinity and concentration are maintained within the boiler, it is immaterial what chemicals are used in the treatment. This statement refers, of course, to the low-pressure boilers. In high-pressure boilers, a treatment such as lime and soda cannot be satisfactorily employed, on account of the precipitated calcium carbonate unduly increasing the amount of suspended matter. Only one case of impending trouble was reported during the year. That was at Seaboard, shortly after the new unit was placed in operation. Dissolved oxygen, considerably in excess of the permissible 0.030 cubic centimeters per liter, was detected at various points on the feed line. It was suspected that a de-aerating heater was being operated at too low a temperature, and chemical tests, made before and after the necessary adjustments, proved that this was the source of the trouble. While it has been impossible to give mine waters the attention they require, progress can be reported in the work carried out by the Mechanical Department. Past investigation of the action of mine water on various acid-resisting alloys is now bearing fruit, and it can safely be said that repair work on mine pumps has been reduced by nearly one-half.

Jan 1, 1938

By Andrew J. Troop

"VAUGHAN THOMPSON designed the Thompson retrievable diamond drill wedge and reaming assembly in 1948. Since 1950, the Hudson Bay Exploration and Development Company, Limited has used the method extensively. The wedge, setting tool, and reamer have been modified slightly since they were first introduced. In 1951, Mr. Thompson designed the Thompson arc cutter. The purpose of this tool is to decrease effectively the diameter of the arc cut, using standard drilling tools. This directional drilling device is usually employed when a branch hole is desired. The Thompson arc cutter has been used with success at Birch Lake, Saskatchewan, at the property of Cuprus Mines, Limited, Manitoba, and at Thompson Lake, Manitoba.UsesThe Thompson retrievable wedge provides a simple method for:(1) Re-drilling lost core sections(2) Re-sampling sections of old holes(3) By-passing lost tools Correcting the direction of a hole(4) Drilling a branch hole to obtain intersections at a higher elevation than the original holePrevious to the spring of 1951, the wedge was used only for the first four of these purposes. Recently it has been employed extensively for drilling branch holes."

Jan 1, 1953

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By Cristina Echavarría

MAIN POINTS ? The region: opportunities and limitations ? Overview of main issues emerging from MMSD in South America ? Who comprises the local community? ? What are the main challenges? ? Some suggestions for companies to improve their contribution to local sustainable development of mineral rich localities THE REGIONAL CONTEXT 1. The region is a producer of minerals contributing over 20% to world metal production. It consumes only 8% 2. Significant diversity of national contexts-both between countries and within countries 3. Variable but predominant need for strengthening of government and community institutions and governance, especially at the local level 4. Dearth of baseline information for decision making 5. Sustained social spending during early 90?s as a consequence of economic recovery and fiscal policy, produced important advances in education and health 6. Despite government efforts in most countries poverty continues growing 7. Highly inequitable distribution of wealth persists

May 1, 2002

By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012

By B. Courtaud, L. Donati, V. Weigel

As a growing mining company, ERAMET is looking for new positions in the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earths and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by existing practices, from both technical and economic points of view. ERAMET has developed since 2008 an innovative hydrometallurgical process, which has been successfully operated at a pilot plant scale (more than 35 weeks in continuous). The upstream part of the process aims to dissolve valuable elements in sulphuric acid. The first step is dedicated to dissolve the ore matrix, leaving the pyrochlore unleached. The second step consists in chemically breaking down pyrochlores in order to form soluble species of the valuable elements. After dissolution, the valuable elements are separated into different flows: niobium and tantalum are recovered and transformed as commercial ferroniobium on one side, and rare earths and uranium remain in the solution to be recovered in the downstream part of the process. The main goal of this paper is to discuss the upstream part of the process, which has given successful results.

Jan 1, 2014

By D. Moronkeji, R. Maharidge, D. A. Curry, B. J. Davis, U. Prasad, J. Franquet

"Proper shale characterization is crucial in shale gas drilling, exploration, completion and production. Unlike porous sandstone and carbonate reservoirs, the challenge with shales comes from their micro- to nano-darcy permeability ranges and the anisotropy of their mechanical and hydraulic properties. Most porosity-dependent logs are not sensitive enough to capture the true behavior of shales. Consequently, mineralogy and other strength and stiffness-related properties must be determined to characterize magnitudes and variances in shale mechanical and flow properties. In addition, these properties must pass quality assurance/quality control (QA/QC) practices to give confidence in their use in subsequent log calibrations, during geomechanical modeling, or in fracture design models. This paper presents a technique to integrate shale properties that are measured by various methods, and a methodology to perform QA/QC on the data before application.Shale properties originate from various sources, including downhole and laboratory measurements. Physical samples for laboratory testing are usually limited to a few depths. Lab tests are often costly, and replicating in-situ conditions can be difficult or impossible. In addition, results frequently show wide scatter, reflecting inherent depth variability and lateral heterogeneity. Wireline logs provide nearcontinuous data, but rarely yield direct measurements of rock strength properties. Although geomechanical and fracture models use log data, calibrating it with reliable and previously verified lab-measured properties is important. This paper presents a process to perform QA/QC on lab-measured data using various crossplots.Ten mechanical, microstructural and physical properties are graphically displayed to visually characterize shale strength behavior in ambient and in-situ conditions, whether measured or modeled statically or dynamically. These properties are often sourced from different departments. The properties are integrated but are individually subject to the previously mentioned uncertainties. Pairs of property values are crossplotted and compared with correlations from the literature or previously established with qualified data from related formations. Conformance with these correlations gives confidence in the data, whereas outliers are flagged as questionable. Repeating the process with questionable data crossplotted against other parameters for the same depth highlights the property with the greatest uncertainty. The determination of its value is investigated to locate the source of the inconsistency and establish a more reliable value. Where this is not possible, the user has a rational basis for rejecting that property value."

Jan 1, 2015

By F. R. Archibald

MR. A. F. B. Norwood: Having been associated in the past few years with nine different plants roasting aurif erous concentrates in Australia, two of which were new installations for which design and construction were undertaken by the writer, I read Mr. Archibald's paper with very great interest, and I deem it a great privilege, as a member of a sister Institution, to be invited to contribute to the discussion on the paper. I wish to congratulate the author on a very informative and interesting paper, and, although situated many thousands of miles away, I feel I have gathered from it a very close idea of the operating conditions and of the work that has been carried on at the Beattie gold mine. Working along somewhat different lines, it is interesting to note that the conclusions drawn by the author run closely parallel to those accepted in Western Australia, viz., that the object of roasting is to obtain a porous calcine, and that this can best be achieved by roasting first at a temperature below 900 deg. F. to 1,000 deg. F., and then raising the temperature at the finish of the roast. Turning first to the laboratory work, the materials I have studied in Western Australia cover a range from those with little or no arsenic to concentrates carrying as high ?as 20 per cent, i.e., even higher than in the analysis quoted for the eoncentrates from Nepheline Products, Limited. In the ease of arsenic-free pyrite concentrates, the roast is ideally carried out at a temperature ranging from 900 deg. F. to 1,000 ferric oxide is one cause of the refractory gold remaining In deg. F. No improvement in extraction is obtained when the calcines are cyanided by raising the final temperature above this point; nevertheless, in technical practice it is desirable to finish the roast at 1,200 deg. F. in order to decompose basic ferric sulphate and thereby reduce the consumption of chemicals in the subsequent cyanidation step. However, if at any stage of the roast the temperature is raised above 1,200 deg. F., the extraction by cyanidation falls, and continues to do so the higher the maximum temperature that is reached. Line A in the accompanying graph typifies this effect.

Jan 1, 1949

By H. M. Roscoe

Fifty per cent. increased lump coal production and at the same time a reduction of from 20 to 40 per cent. in explosive consumption. These results were achieved by the use of the rock-dust cartridge method of stemming shots in the Ruhr coal mines, as announced by Dr. Alfred Stettbacher in the September 1923 number of the Explosive Engineer. Immediately, the explosive and the coal-mining industries on this continent became intensely interested. Considerable experimental work has been carried on in a number of American and Canadian mines during the past year, by which our engineers have become assured that the use of rock-dust cart-ridges for stemming shots increases the efficiency of explosives and promotes safety in coal mines.

Jan 1, 1924

By M. Zamalloa, P. J. Mackey, P. Coursol, Y. Prévost

"Over the last decade or so, the availability of commercial thermodynamic modelling packages, such as FactSageTM, have been utilized to help the plant optimize slag chemistry and to minimize slag handling issues that can arise, such as those due to a process upset, for example, by undue feed variability. This paper illustrates an extension of the application of this software in examining a large range of NCV operating parameters, such as the %Fe/SiO2 ratio in the slag and the level of minor gangue components in the slag including CaO, Al2O3, ZnO, MgO, and PbO. The conditions influencing the slag liquidus range of NCV slag are discussed with respect to the overall process chemistry.Given that a sufficiently low %Fe/SiO2 ratio is used in NCV slag, most components such as CaO-ZnOPbO- Al2O3-MgO, in small concentration, all contribute to lowering the NCV slag liquidus. Considering the present level of these minor components, the NCV can operate consistently at 1200°C if the %Fe/SiO2 is between 0.6 and 0.8 in the slag. Using the type of phase diagrams presented in this paper, it is possible to develop different Noranda reactor/Noranda converter operating strategies adapted to the feedstocks available at Xstrata mines/plants or from other sources. The NCV is unique in that a fayalite-based slag is employed for high-efficiency continuous converting with excellent operating results."

Jan 1, 2007

By Paul Hammond

Abstract The Allard Lake ilmenite deposits, which are currently being developed on a large scale, occur as a series of dykes or lenticular, flat-lying bodies within the northeastern part of a large, oval shaped anorthosire mass of Precarnbrian age which lies with its long axis paralleling the gulf of St. Lawrence. The Lac Tio deposit, discovered by Kennco Explorations, Limited, in 1946, is the largest body of titanium ore of its type now known in the world. It contains upwards of 112,000,000 short tons of ilmenite ore averaging 32 per cent TiO2 and 36 per cent Fe. The ore is an aggregate of ilmenite with oriented microscopic blades of hematite. The deposits appear to be high temperature, late magmatic injections containing only a small amount of volatiles, and bear a genetic relationship to the anorthosite rocks in which they occur. * * * Introduction Recent developments on the ilmenite deposits in the Allard Lake district of Quebec indicate the probability of a major industry, and one which may make Canada the world's greatest producer of titanium pigments and, ultimately, of titanium metal. The presence of ilmenite in this district was first reported by the Quebec Department of Mines following a reconnaissance shore-line geological survey in the year 1941. The ensuing report by Retty describes the occurrence of a number of small ilmenite lenses about the shore of Allard lake and' along two smaller lakes in the vicinity. These showings were later staked by Toronto and Montreal interests who carried out a certain amount of development work, and were described in more detail by Longley for the Quebec Department of Mines. The claim groups were later optioned by Kennco Explorations, Limited, Canadian subsidiary of Kennecott Copper. None of the deposits in themselves constituted a sufficiently large body of ore to warrant the major construction expenditures necessary for their exploitation on a profitable basis. The surrounding anorthosite areas, however, were considered favourable for the possible occurrence of other ilmenite deposits

Jan 1, 1949

By J. E. Armstrong

"Pinchi Lake and Bralorne Takla mercury mines; Canada's only producing mercury mines during the past war (1939-1945); occur within the Pinchi Lake mercury belt. This belt is in central British Columbia; and is approximately 150 miles long extending from southeast of Fort St. James northwest to the headwaters of Omineca river.During the field season of 1937 cinnabar was discovered by J. G. Gray of the Geological Survey in Permian limestone on the north shore of Pinchi lake, where the main showings of the Pinchi Lake mercury mine were later developed. Following the publication of Gray's report claims were staked in the spring of 1938, and later that year were optioned to the Consolidated Mining and Smelting Company, and in June 1940 a reduction plant with a rated capacity of SO tons a day was brought into operation. In 1943 the plant had a capacity of more than 1,000 tons a day. The grade of ore treated was reported to average S to 10 pounds of mercury a ton, and production during the years 1940 to 1944 exceeded 4,000,000 pounds. The Bralorne Takla mercury mine, which is 90 miles northwest of the Pinchi Lake mercury mine, was brought into production in November 1943 with completion of a 50-ton mill. During the next 10 months more than 100,000 pounds of mercury were recovered, and the grade of the ore was reported to average 15 to 20 pounds of mercury a ton. During the war, production from these two properties was far in excess of Canadian requirements, and Canada was able to supply the United Kingdom and United States with part of their need.s. Both properties ceased operations during 1944, and, due to an excessive supply of mercury, have not yet reopened. The Pinchi Lake mercury belt lies along a northwest-trending major fault zone called the Pinchi fault zone (Fig. 1). This zone is approximately 150 miles long and varies in width from 200 to 1,000 feet . It forms the northeastern edge of a northwest trending fault belt up to 10 miles or more wide in places. In general the northeastern margin of the Pinchi fault zone represents the contact between closely folded, stratified Permian rock:s on the southwest and Mesozoic formations and Omineca intrusions on the northeast. It seems probable that the fault zone marks the site of major thrust faulting from the southwest and that the Permian rocks moved up with respect to the Mesozoic formations. Intense faulting occurs in the Permian rocks within the fault zone. There the more important faults trend north and northwest, dip steeply west and southwest, and may join a major low-angle thrust fault at depth."

Jan 1, 1954

By Somchet Vongpaisal

This paper presents the R&D results on the development of a new knowledge-based system for predicting stope instability and associated unplanned dilution in deep underground mining operations. A new prototype was developed based on databases generated from 3D non-linear elasto-plastic finite element stress analysis, heuristic rules, and case histories. This prototype aims to assist mine operators to make decisions on strategic mine planning and feasibility in a quick and efficient manner thereby minimizing risk on ground failure and optimizing mining costs.

Jun 1, 2012

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016