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By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014

By G. Zeng

Although the solubility of oxygen in zinc electrolyte is less than 9 mg/L, the effect on deposit stability and zinc-dust consumption can be significant. Sodium sulfite is used to deoxygenate the electrolyte. The effect of the sodium-sulfite concentration on cobalt removal is investigated. The results show the reduction of sulfite to elemental sulfur that adhered to the zinc dust surface forming a passivating layer, and small amounts of sodium sulfite have no effect on cobalt removal. The optimum amount of sodium sulfite is 100 mg/L. It is an important consideration in purification circuits to use sodium sulfite as an additive to cobalt cementation.

Jan 1, 2005

By A. N. May

"This paper describes the present approach of the Mines Branch to the problem of measuring the stress condition in the interior of rocks surrounding underground openings. An instrument, which will be referred to as a stressmeter, has been developed at the Mines Branch to measure un-directional stress changes in absolute units. There are two modes of operation of this stressmeter. It can be regarded as a fixed instrument, in which case it is installed at the end of a diamond drill hole and left in position to record any subsequent stress changes taking place. Alternatively, three of the stressmeters can be used in conjunction with a trepanning opera-tion to allow the existing stress condition to be determined. The initial laboratory work and subsequent experiences in the field with the stressmeter are described. All the field development work on the stressmeter was made possible through the co-operation of Canadian Refractories Limited, Kilmar, Quebec."

Jan 1, 1960

By K. L. C. Gonçalves, V. K. Alves

"CVRD’s Department of Development and Technology – GETEK has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. This methodology has been applied in several prospective CVRD mining projects. It encompasses a procedure for variability analysis based on bench scale tests, pilot scale grinding and flotation tests and modeling and simulation for scaling up the industrial flowsheet.The bench scale tests include the determination of the Work Index, simplified DWT tests, rougher flotation and locked-cycle tests with samples that are representative of the ore body variability. After completion of these studies, continuous, pilot-scale flotation tests are carried out at a Mini Pilot Plant with drill core samples representative of different stages of the mine life. Finally, studies are carried out with large volume samples using a conventional grinding and flotation pilot plant. This sample is also used for liberation characterization, grinding kinetics, flotation kinetics and industrial circuit scale up. This methodology has been successfully employed in the development of CVRD’s new mining projectINTRODUCTIONCVRD has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. The definition of the processing route and the sizing and scale up of the processing system are some of the products generated during the pre-feasibility of a greenfield project. This paper is focused on the scale up of grinding and flotation circuits, operations known to be of the most importance in a mineral processing plant.The methodology for the definition of the flotation and grinding circuits is divided in the following stages: bench scale ore variability studies, pilot plant operation and modeling followed by simulation. The product of this work is a calibrated simulator that can be utilized for plant operation as well as mine planning, looking to achieve optimal operational conditions.The current models used for scale up of the grinding circuits are aimed at the generating information about the size distribution of the circuit product. However, it is well known that the liberation state of these products may be of critical importance for the performance of the concentration processes downstream. Nevertheless, CVRD has been developing a methodology for liberation kinetics during grinding, aimed at optimizing grinding circuit throughput together with downstream flotation recovery."

Jan 1, 2006

By A. Gronningsater

Introduction As is well known, the fight between the blast furnace and the reverberatory furnace in copper smelting during the second decade of the century ended with a victory for the latter, a result which must largely be attributed to the introduction of flotation methods. To my knowledge, no new blast furnace has been blown-in at any American copper smelter since the War. As the metallurgy of nickel, up to and including matte smelting, is generally considered a close parallel to that of copper, the introduction of reverberatory smelting in the big new smelter of the International Nickel Company at Copper Cliff, built in 1928-30, seemed a logical adherence to a well established trend. In view of these facts, considerable comment was made when Falconbridge Nickel Mines decided to retain the blast furnace in their smelter built about the same time, in 1929. A presentation of the reasons governing this choice should therefore be of interest. The basic principles underlying the Falconbridge practice, and the considerations guiding the successive steps in the operations, will be discussed in the following. To understand the problems involved, the character and mode of occurrence of Sudbury ore must be kept in mind. Large amounts of disseminated ore are generally present. Although the gangue usually runs only about 50 per cent Si02, the ore hoisted as a rule contains more silica than needed in the smelting operation; until recently this excess was removed entirely by hand picking (in later years supplemented by magnetic sorting methods), a difficult and not very satisfactory method, in which 'the border line between ore and waste is entirely arbitrary, and therefore too much depends on the judgment of the picker.

Jan 1, 1934

By André van Wageningen

Long-term mine scheduling is one of the most difficult optimization problems. The problem is said to be NP-complete in that the best possible solution cannot be found any quicker than checking all possible permutations and combinations. Although a number of techniques have been used in the past, many include significant simplifications or fail to produce acceptable results within the required timeframe. Genetic Algorithms (GAs) are among the most promising optimisation techniques within operations research. They are based on natural selection and evolution of solutions to complex problems. They have been known to quickly converge within a few percent of the optimal solution by examining only a fraction of the solution search space. The GA itself contains very little problem specific information and as such, has been linked to a discrete-event simulation (DES). The DES feeds information regarding the feasibility and quality of the solutions back to the GA during the optimisation process. In this paper, GAs and DES are described and the coupling of the two methods is outlined. The GA coupled DES is then used to ?optimise? a problem and the results are discussed.

May 1, 2004

By Sherwin F. Kelly

"THE TITLE I have chosen is certainly not one of those self-explanatory ones. I shall endeavour to make its significance clear during my remarks but, in the hope of minimizing that inevitable exodus which follows a good lunch such as this, I am going to withhold the final key to its meaning until the very last sentence of this talk.Some explanation is due at the beginning, however, so for those of you unfamiliar with Spanish I will explain that casa means house, or home. The casa about which I am going to talk necessitates a wide .and generous interpretation of the word, because I am using it to indicate principally that portion of the North American continent which is the home, in the western hemisphere, of British and American ideals of justice and freedom, the dignity of the individual and his right to exercise private initiative .and engage in private enterprise. In a wider sense, I am including the entire western hemisphere, which may yet stand as the last bulwark of political and industrial democracy.As for the treasures of which I am about to speak, may I remind you that there are no• material treasures but those derived from the earth, and they are derived by one of two processes, -mining and farming. These two fundamental industries are the basis, and the sole material basis, of our welfare, our wealth, our very existence. From farming, whether it be farming of the land. or farming of the sea, we obtain the food to keep us alive, healthy and able to work."

Jan 1, 1955

By G. C. Mackenzie

At the last Annual Meeting of the Institute, Dr. C. V. Corless sketched the potential mineral wealth of Canada so clearly, graphically and with-all so entertainingly that one's imagination was fired with the promise held out to future generations for the tremendous expansion of the mining industry in the Dominion. Posterity will undoubtedly witness the fruit of much of the geographical search and survey that is now carried on by our government mining departments. Year after year the work advances, slowly but surely, new areas are . explored, older areas are surveyed in detail, the information being compiled in maps and reports of incalculable value to the prospector, the engineer and the general public. The immensity of the task of exploring, geologically, the outlying portions of the country, with the ultimate view of making valuable mineral discoveries, may be visualized from a study of Dr. Corless' paper and the subsequent discussion which took place and one becomes impressed with the fact that three-quarters or more of the problem can be included under the word "transportation". For instance Dr. Corless said, "The few geological explorers who have penetrated to these remoter regions . . . . . . have as a rule been compelled to stick closely to canoe routes,"; Dr. Goodwin remarked, "This barren Laurentian granite, which is put down on the maps as covering the greater part of this area, is the best guess the geologist could make from travelling along watercourses Within the next few years . . . . . . the Timiskaming and Northern Ontario railway will undoubtedly be extended to James Bay . . . . . . In order that we may be prepared for the probable influx of prospectors when transportation facilities to tidewater are provided, I think all available information on this district should be gathered together in handy form." All three-Corless, Goodwin and Cole-emphasize the well-known fact that explorers, geologists and prospectors working in new country must stick to the watercourses and that transportation by rail, road or water has always been the all-important deciding factor in facilitating the exploration and development of remote districts. Dr. Corless did, however, suggest other means of transportation in stating, "The aeroplane will be of assistance in future study of some parts of these remote areas."

Jan 1, 1924

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006

By Polysius AG

"The Lone Tree demonstration was an important milestone in bringing High Pressure Grinding Roll (HPGR) technology into hard rock applications in the mining industry. HPGRs have become standard equipment in the cement, iron ore, and diamond industries over the past fifteen years, but their use in severe duties found in the hard rock mining sector has been restricted due to high roll wear and subsequent low availability. HPGR availability has historically been limited because of frequent downtime for edge weld rebuilding as the rolls wore and short tyre life from high roll surface wear rates.Recent advancements in HPGR wear protection are now being evaluated for commercial applications in the gold and copper mining industry where this technology may offer benefits in comminuting hard and/or abrasive ores and in improving metal recovery in heap leaching applications.Proving the feasibility of HPGRs for processing competent, abrasive gold ore, Newmont Mining Corporation, the world's largest gold producer, operated an HPGR demonstration plant employing a POLYSIUS (POLYCOM) HPGR incorporating some unique wear protection, at their Lone Tree gold mine near Winnemucca, Nevada. Results of the successful demonstration are presented and evaluated in this paper.The Lone Tree HPGR demonstration plant operated for three months, from April through June 2003. The HPGR operated for 1626 hours and processed 141,000 tons of ore. This technology demonstration focused on measuring operating performance, wear characteristics, and availability of today's HPGR technology.Polysius' innovative roll surface wear protection system eliminated edge-welding downtime. Improved surface wear protection extended tyre life to predicted durations acceptable for very abrasive service. The POLYCOM HPGR is now deemed suitable for selected hard rock applications."

Jan 1, 2005

By H. E. Grier, H. H. Aronson, H. F. Coffer

"Nuclear explosions are currently being planned for use in oil and gas production, the recovery of oil from oil shale, gas storage and copper leaching. The current status of each of these projects is discussed, with emphasis on the economics of each application. The first commercial application of nuclear explosives will be in gas stimulation. Project Gasbuggy will be rapidly followed by two additional shots, also related to gas production. These three events, each in a different formation, will be described in this paper with a discussion on their significance to the world's oil and gas industry. The use of nuclear explosives in oil and gas stimulation should be a standard accepted practice within a few years. Calculations based on explosions in media such as tuff, alluvium, granite and dolomite predict large increases in productivity when nuclear devices are used in tight, thick formations. The broken-up rock resulting from the explosion becomes the new well bore, with a production rate of six to twelve times that of a normally completed well.Also included in the paper is a discussion of the real or possible problems associated with nuclear explosive engineering. The only major foreseeable problem is the seismic shock wave. This limits the size of explosive which can be used near important surface structures. A discussion is included on the radiation problem, which we believe to be largely psychological in the case of contained explosions."

Jan 1, 1968

By J. C. Kingston

Introduction The sliding-form method of erecting concrete structures was first devised and used in the early part of this century by the Sante Fe Railroad Company for the erection of a grain elevator at Santa Fe, New Mexico. A somewhat related principle has been employed for a number of years in shaft lining work and, to our knowledge, was perfected in Butte, Montana, but until the building of the concrete headframe at the Jeffrey mine of the Canadian Johns-Manville Company, Ltd., at Asbestos, Que., the method, as applied to surface structures, was quite foreign to the mining industry in Canada. The current shortage and cost of structural steel shapes has no doubt contributed more than any other single factor to the investigations that have led to the use of reinforced concrete as a headframe building material. Mining men in western Quebec and northern Ontario have shown a great deal of interest in the design and construction of the headframe at the East Sullivan mine in Bourlamaque township, Que., and we have had many queries regarding the methods used and, in particular, for an explanation of the sliding-form principle. This article is written in an attempt to set forth the conditions which were to be met; to explain the construction methods used, and to discuss the economy of concrete headframes as compared with the conventional steel structures with which the mining fraternity is familiar.

Jan 1, 1949

By W. A. Lang

"I.-IntroductionAn attempt bas been made in this paper to provide a basis for appraisal of the future of the coal briquetting industry in Alberta by outlining the processes used for briquetting various ranks of coal, by specifying the requirements of a briquetted fuel, by indicating .the status of the industry in the United States, by giving developments in Western Canada, by assessing costs of processing, and by discussing briquetting researches in progress. Much of .the detail bas been omitted since this might mask, rather than reveal, the more important phases of the problem. Reference will be made when possible to published articles where many of the details can be obtained.It should be stated at the outset that, in the writer’s opinion, there are three possible developments in Alberta as regards briquetting: (a) an expansion of the briquetting of the fines of • non-coking and coking coals of semi-anthracite, and of low and medium volatile bituminous rank; (b) the processing of the fines of high-volatile C bituminous coals; and (c) the upgrading of the lower rank high-moisture sub-bituminous coals. Details of the chemical and physical properties of these coals can be obtained in publications of the Research Council of Alberta (1, 2), and of the Fuel Research Station, Bureau of Mines, Ottawa (3).Semi-anthracite and low and medium volatile bituminons coals occur in the mountain areas of Alberta, where, during the upthrust of the Rocky mountains, the coal beds served as the sliding surface. This resulted in the coals being; crushed and consequently they contain a h1gh percentage of fines. In some cases they are high in mineral matter and require to be cleaned before being processed. However, the cleaning of fine coal is both difficult and costly. Both the amount of fines present in the mine-run coal and the amount of mineral matter associated with the coal have increased through the introduction of mechanized mining and through the recovery of coal by stripping operations."

Jan 1, 1950

By P. G. Claridge, G. P. Holmes, M. A. Redfearn

"IntroductionThe purpose of this chapter is to describe current practices in operation and maintenance of flotation circuits in Canadian mineral processing plants. The chapter consists of five sections covering description of equipment, typical flow diagrams, operating practice, instrumentation and maintenance. The approach to this subject matter is intended to be practical in nature, hence no deeply technical treatment of flotation theory will be included.Flotation is an extremely common method of beneficiation of ores. Reasons are the relatively low cost of flotation compared to many other processes, the wide range of minerals to which flotation may be applied and the high efficiency of separation which can usually be achieved. The flotation process as we know it today has been developed within this century and it has had a major impact on the mining industry. While flotation is commonly considered to be important because it provides a relatively simple method of separating minerals in complex ores, the availability of flotation has also made a multitude of mineral deposits in Canada into economically viable mining operations because it allowed production of a concentrate of valuable minerals from the ore. These concentrates could then be transported from geographically remote locations to centraHzed plants for further processing, although the existence of the remote and perhaps small ore body alone would not have justified installation of metallurgical processing plants on site and the grade of ore would not have justified direct shipment of ore.Some of the more common minerals concentrated by flotation are sulphides of copper, nickel, cobalt, iron, zinc, molybdenum, lead and arsenic, as well as non-sulphides such as sodium chloride, potassium chloride, phosphates, silicates, chromite, fluorite, limestone and coal. Precious metals are also recovered by flotation, generally in association with another sulphide mineral."

Jan 1, 1989

By Andy Fortin, André Vien, Christophe Bouché, Jeff McKay

"The technology and equipment design of the Twenty-first Century permit us to exploit low-grade ore bodies with milled tonnages reaching 300,000 tpd. Because of their substantial operational costs (energy, wear parts, etc) and precarious economic situations, the operations of today must maximize their metallurgical performance.The implementation of an Expert System becomes a logical avenue to pursue in view of increasing plant performance.Many operations, following the implementation of an Expert System, meet the objectives they determined before its integration; such as increased tonnage, stability, decreased costs, etc. However, they often cannot develop the full potential of the system due to certain factors that have been neglected or omitted during the implementation of the system.Three main elements have been identified during the implementation phase at INMET Mining Troilus Concentrator: 1- Instrumentation & Control 2- Software 3- Integration. Even though they have been clearly identified, these elements are often neglected due to lack of resources or lack of comprehension on the part of the operations personnel. This document will demonstrate, based upon our experience at Troilus and that of Metso Minerals, that we can identify and handle many factors which influence the profitability of the Expert System, for both short and long-term process control improvements.INTRODUCTIONThe Inmet Troilus Mine is an open pit mine, situated 175 km north of Chibougamau in the province of Québec, Canada. The mill, which started production in November of 1996, was originally designed to treat a gold – copper ore at a rate of 10,000 tpd.In early 1998, the mine plan called for a pit pushback and decreasing head grades for the following two years. With the price of gold nearing decade lows, the Troilus project was facing a major economical setback. There was a sense of urgency to reduce operating costs below the market price of gold. The mill team presented a project to management calling for an increase in mill throughput while minimizing capital expenditures and operating costs. This idea was supported by the existing mine plan, which called for a mine cut-off of 0.7 g/t Au and stockpiling low grade 0.5 g/t material for future milling."

Jan 1, 2003

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed. The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grad~, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the fmal cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure 1."

Jan 1, 2003

By M. Pourkani, M. Karga, Samid Banis, Andre Laplante, G. Langari-Zadeh

"The Sarcheshmeh mine processes 40,000 t/d of ore grading 0.9% Cu and 0.035% Mo. Grinding is effected in single stage ball mills using 80 mm forged steel balls, with an average consumption of 850 g/t. One of its 5 m diameter, 8 m length ball mills was emptied to measure the ball size distribution. The broken balls were first separated from the total charge, and the remaining balls classified into five size intervals of +7O mm, -70 +60 mm, -60+50 mm, -50+40 mm, -40 mm.The charge was composed of 280,534 balls (excluding broken balls) with a total mass of 305,180 kg. It was found that 4.0 % of the balls were broken; the size distribution of the charge was also markedly different from the desired one, in particular for the small-sized balls. For instance, 9% of the balls were expected to measure 2.54 to 3.18 cm in diameter, but none was found. On the other hand, the amount of top size balls was 30% higher than expected. The radial hardness of balls, which was determined by cutting the balls in halves, showed that the hardness sharply drops when the balls become smaller than 65 mm. The unexpected ball size distribution was attributed to the rapid change in the balls radial hardness. Based on the measured ball size distribution, a new ball make-up charge which uses 80% of 80 mm and 20% of 60 mm balls instead of 100% of 80 mm was proposed and implemented. The effect of the new ball make-up procedure in terms of ball consumption and grinding efficiency is being investigated."

Jan 1, 1999

By Marc D. Melker, Geoffrey R. Lane, Michael Jahraus

"The Cresson gold deposit is located in the Cripple Creek district of Colorado. The deposit is composed of volcanic intrusive rocks and volcanogenic sediments where gold mineralization is associated with veins and cavities within a diatremal breccia.The purpose of the current study was to:1. Determine the penetration potential of the Cripple Creek Breccia.2. Assess the relationship between penetration and gold recovery within the Breccia.Two methods were applied using a cyanide solution containing ultraviolet sensitive dye to elucidate pathways of penetration within the rock. The first involved stagnant soaking of twoinch square pieces within the solution. The second method involved column leaching of ~100kg of Breccia crushed to P80 12.7 mm (0.5 inch). Samples were selected at specified intervals to capture the penetration progress of the solution. Photomicrographs and image analysis were utilized to illustrate and quantify the degree of penetration.Results indicated that the maximum penetration for the Cripple Creek Breccia (85 to 97%) due to a porous and permeable groundmass, containing large non-porous lapilli fragments. In addition, ~90% of leachable gold was recovered with only ~50% rock penetration.INTRODUCTIONDye penetration studies were first developed at SGS-Lakefield Research for the purpose of determining the fluid penetration amenability of differing rock types. The method was to place a large rock or drill core in a pan with 1 to 2 inches of a pre-mixed, water based fluorescent dye. The sample was sequentially cut after prescribed time periods to reveal a fresh surface. The cut surface was photographed under long wave ultraviolet light, and the same piece returned to the dye and allowed to sit until the next prescribed cutting."

Jan 1, 2006

By V. S. Papezik

Pyrophyllite, an AI silicate used in the production of ceramic materials, is formed mainly by alteration of felsic to intermediate volcanic rocks, either directly (at temperatures of 250-300°C and pressures of 1-2 kbar) or by subsequent low-grade metamorphism of aluminous protoliths produced by thermal fluids or even by prolonged weathering. Most pyrophyllite deposits in North America are concentrated in a belt of Late Precambrian volcanic and sedimentary rocks, the "Avalon Zone ", which extends along the eastern flank of the Appalachian mountain system from Newfoundland to the southeastern U.S.A. The only producing pyrophyllite mine in Canada is an open pit located near the settlement of Foxtrap on the Avalon Peninsula of Newfoundland. It lies in a belt of rhyolitic flows and pyroclastics intruded by a granitoid pluton. The rocks have been leached along a shear- or fracture zone, depleted in silica, alkalies, Ca, Mg and Fe by the action of hydrothermal fluids, and recrystallized to a very fine-grained massive assemblage of pyrophyllite, muscovite ("sericite") and quartz. High-grade pyrophyllite lenses contain small nodules of diaspore with minor barite; rutile is present in trace amounts. The close proximity of all pyrophyllitized zones on the peninsula to the granite contact suggests that the alteration was produced by thermal fluids genetically connected with the granitoid pluton. The fine-grained pyrophyllite-bearing rocks, with their simple mineralogy, are suitable for quantitative modal analysis by X-ray diffraction. Chemically analyzed samples from the alteration zone were used for the construction of working curves by plotting calculated mineral content against the intensity of selected diffraction peaks. The accuracy of the resulting curves is ±4.5% for quartz, ±3.6% for pyrophyllite and ±2.7% for muscovite. Pelletized samples give best results. The XRD method is suitable for a rapid analysis of a large number of grab or core samples to outline higher-grade areas for more detailed sampling.

Jan 1, 1978

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017