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By J Poniewierski, Varcos D

Efficient blasting requires constant vigilance with respect to the actual layout being used in the field. Objective measurement techniques are required in laying out a pattern as the 'by eye' or 'thumb suck' methods cannot guarantee consistent results in layout. Erratic blast results are the consequence of such an approach. In a case study at Sons of Gwalia mine, it was demonstrated that incorrect front burdens had a snowballing effect on otherwise carefully laid out blasts, resulting in both excessive amounts of boulders caused by preconditioning of bench fronts and tops, and tight digging. Both problems caused lower excavator productivity and excessive excavator damage, as well as making it difficult to set out subsequent blasts correctly. Several field measurement methods are available to aid in determining correct blast layouts and one is described in this paper.

Jan 1, 1994

By S Wangchai, D B. Hastie, P W. Wypych, A P. Grima

Industries that handle and process ‘dusty’ ores are facing increasingly difficult challenges to ensure sustainable operation and development. Most existing dust-control measures treat only the symptoms of dust generation and do not deal with the root cause/s of the problem. Many of these methods are also relatively inefficient in terms of controlling dust emissions. This paper summarises the various existing options available for dust control and some of their features, advantages and disadvantages. It then describes some of the new technologies that are being researched, developed and employed to minimise dust emissions by addressing dustability or dustiness and the dust generation mechanisms found in industry. Recent research results and case studies are presented to demonstrate some interesting findings obtained from this work. With improved understanding and modelling of dust generation mechanisms and bulk material dustiness, it is possible to achieve a step-change improvement in the design, troubleshooting and application of more efficient dust-control technologies.CITATION:Wypych, P W, Hastie, D B, Wangchai, S and Grima, A P, 2015. Research and application of new dust control technologies for the iron ore industry, in Proceedings Iron Ore 2015, pp 529–536 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By García B., Wolff E.

The pellet qualities primarily depend upon the thermal profile and gaseous environment during induration. During the induration of the pellet, it undergoes physical as well as chemical changes. Physical changes are mostly due to sintering and chemical changes are due to carbon burning inside the pellet. The effect of carbon on sintering is investigated on a single pellet scale using an optical dilatometer. Sintering is a complex process that involves transportation through various mechanisms. Sintering is quantified in terms of sintering ratio and the kinetic parameter, exponent ‘n’, under isothermal conditions is deduced using the power law equation. The value of n can be used to estimate the sintering mechanism at different isothermal temperatures. Also, the activation energy is calculated using the empirical Arrhenius equation. The activation energy of 0 per cent coke and 1 per cent coke-containing pellets are 531.0 kJ/mole and 552.6 kJ/mole respectively. The order of magnitude of activation energy suggests the same mechanism in both cases. Although the mechanism of sintering is the same, 1 per cent coke-containing pellet sinters more at any isothermal temperature.

Jun 17, 2024

By E Kabwe, E Chanda, M Karakus, S Akdag

The Convergence Confinement Method (CCM) is one of the frequently used methods that considers the ground response to the advancing tunnel face. The CCM analytical solutions represent stress relaxation on circular tunnel walls in a rock/soil media. The CCM analytical solutions is based on circular tunnel geometry and consider a hydrostatic stress field in a homogeneous isotropic rock mass condition. However, noncircular tunnel geometries, non-hydrostatic stress field, staged excavation process in a discontinuous anisotropic non-linear rock mass conditions are usually ignored in these analytical solutions. In this paper, we investigate the performance of the existing CCM analytical solutions developed for elastic and elastoplastic ground behaviour for circular tunnels. For this purpose, a finite difference analysis is conducted to compare the analytical results with the results obtained from Finite Difference Method (FDM) for a chosen rock mass condition. Results obtained from the investigation shows that floor, crown and wall displacement are 30%, 10% and 23% more, respectively, in a horse-shoe relative to a circular tunnel. This indicates that the application of analytical formulation tailored for circular tunnels would lead to inaccurate quantification of wall convergence in horseshoe-shaped tunnels. CITATION:Kabwe, E, Karakus, M, Chanda, E and Akdag, S, 2018. Investigating the tunnel closure using convergence confinement method and 2D plane strain finite difference analysis, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 152–159 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

Many block caving operations experience difficulties during undercutting, resulting in draw horizon damage, production loss and extensive drift repairs for the life of the block cave. This paper deals specifically with block cave undercut aims strategies, methodologies and management to avoid the problems indicated above.

Jan 1, 2000

By A B. Christie, R Barker

Recent studies carried out to support the development of a strategy for the New Zealand mineral industry by the NZ Minerals Industry Association have included investigations of mineral potential, and the development of scenarios for realising this countryÆs mineral potential by 2010. New economic research is applying a general equilibrium model to quantify the opportunity cost of this potential. The model analyses separately four categories of land (private land and three categories of Crown land) and identifies four distinct mineral classes û precious metals, industrial minerals, coal and aggregate. It investigates the economic effect of the increased availability of mineral resources on the mining industry itself, on other industry sectors and on the NZ economy generally, including its impact on unemployment, GDP and household welfare.The analyses suggest that increases in the level of GDP of between 1.9 per cent and 3.4 per cent may be obtained by utilising New ZealandÆs mineral wealth to varying degrees. The mineral industry sectors are significant beneficiaries under all scenarios; mineral output increases by between two and five times its current level. However, the flow-on effects to the rest of the economy, and to households, are also significant. The analyses show that household income, adjusted for changes in consumer prices, can be expected to increase by between 1.6 per cent and 2.7 per cent. This results largely from increased employment.

Jan 1, 2002

By Bidwell TJ, Servant S

Paste back-fill technology is gaining rapid acceptance in the Canadian mining industry. The authors were able to work on four different mining sites employing paste technology in their operation. In each site the paste hackfll is prepared with very fine tailings containing significant amounts of sulphur minerals. The research program involved laboratory testing on samples prepared in the laboratory, on control samples obtained at the hackfilll plant during pouring into the stopes and on core samples obtained from drilling in backfilled stopes. The laboratory testing provided detailed knowledge of the mechanical behavior of the paste backfill. The need for a means of measuring the in-situ mechanical properties of the backfill became clear. A review of various trials published in literature and an evaluation of available technology suggested the Cambridge Self-boring Pressuremeter. A first field campaign confirmed the efficiency and dependability of this instrument leading to the conclusion that it offers a very good method for the in-situ measurement of paste backfill properties.

Jan 1, 1998

A brief history of the significant haulage truck feature changes and the factors that influenced those changes during the 60's and 70's provide a basis for forecasting the changes that can be expected in the 1980's. A review of the impact factors and changing requirements that currently exist that will create changes. Define the critical requirements of a successful haulage truck design and discuss the availability of bigger engines and better electric drive componetry to provide deeper pit capability and improve reliability. The Unit Rig Trolley Assist System to provide improved productivity and diesel fuel savings and an economic analysis to evaluate the Trolley System is covered. The Unit Rig Automatic Truck System for a driverless truck is covered in concept and discussed from the point of view of the experience in a test in a New Mexico mine. INTRODUCTION A good basis for trying to forecast what is going to happen in the future is to go back a little bit in history, to see what the influencing elements were in different periods of time as a foundation for the forecast. INFLUENTIAL FACTORS IN THE 1960'S If you look at the truck development that occurred in the 1960's, there were some identifiable factors that give us insight. (See Fig. 1) Several things happened at the beginning of the 1960's. Mechanical drive haulage trucks were introduced that were

Jan 1, 1982

By R G. Reddy, A Yahya

The sulfur distribution ratio (Ls) is an expression of the amount of sulfur in slag to the amount of sulfur in molten metal. The sulfide capacities calculated from Reddy-Blander (RB) model were used to calculate the sulfur distribution ratio (Ls). A new Reddy model for sulfur distribution ratio (Ls) was developed for modelling Ls for ironmaking, steelmaking, and secondary steelmaking conditions. Besides calcium oxide, the major component in the ladle furnace (LF) slags is alumina. The Ls was calculated for typical LF slags as a function of temperature and composition. The model calculated Ls values are in good agreement with the experimental and industrial slags data. The extremely low oxygen potential in these furnaces after fully-killed steel is favourable for desulfurisation. For any given slag’s composition and temperature, its sulfide capacity can be calculated a priori. The equilibrium sulfur distribution ratio between this slag and liquid metal in a particular vessel can also be calculated a priori. The Ls for ladle furnace (LF) slags is about twice those for blast furnaces (BF) slags and ten times those of basic oxygen furnace (BOF) slags. The desulfurisation of pig iron in BF and desulfurisation of steel in LF during secondary steelmaking are recommended. Steel desulfurisation in steelmaking furnaces is not effective. Since the model used to calculate the sulfur distribution ratio (Ls) is a priori, it is a useful tool for the iron and steel makers in improving the product quality and optimisation of the industrial furnace operations.

Aug 21, 2024

By L M. Zhang, X Y. Li

Surface displacements are routinely monitored at multiple points during slope excavation. The monitoring data reveals the safety status of the slope under current loading conditions. They can be used to enhance the prediction of the future performance of the slope by reducing the uncertainties of the prediction model and its model parameters. In a multistage excavation, the observed displacements in the current stage can be used to update the prediction of the displacements in subsequent stages. Besides, due to the spatial correlation of the slope parameters, the prediction of the displacement at one location can also be updated using the monitored displacements at adjacent locations. This study aims to develop a multistep updating method to enhance the prediction of the future performance of the slope using time-series monitoring data at multiple points. This method integrates the theoretical computational model with observational evidence. It considers the inherent uncertainty of the slope, model uncertainty and measurement uncertainty. With more monitoring information being incorporated, the prediction becomes closer to the actual performance of the slope. A case study of a multistage excavation of an extremely high rock slope in south-west China is presented for illustration.CITATION:Li, X Y and Zhang, L M, 2014. Better prediction of performance of a slope using time-series monitoring data at multiple points in a multistep excavation, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By J Rayner, R P. Langmead, J A. R Coote

Gosowong is situated within the Neogene magmatic arc of Halmahera island in the Maluku province of eastern Indonesia. It was discovered as the result of a rigorous ground reconnaissance program in an area with no previous mining activity. The broad structural setting in the Gosowong District comprises an elongate dome formed by the forceful upward intrusion of magma along a deep-seated structure, resulting in associated tensional fracturing trending parallel to the long axis of the dome. Four copper-gold porphyries and numerous low-grade epithermal veins occur within this mineralised corridor, with the Gosowong Deposit being the only economic occurrence discovered to-date. Gold mineralisation is hosted within multiphase epithermal quartz-adularia and quartz-chlorite fissure veins, breccias, and stockworks. High-grade gold mineralisation is emplaced in two gently south-plunging ore shoots along a 400 m section of the north-striking, east-dipping, Gosowong Fault, the primary control on mineralisation. The Gosowong Fault is believed to be a tensional fracture associated with uplift of the dome. Lithological variation and structural intersections play a large role in grade distribution within the vein zone. Host rocks comprise a wide range of shallow marine, intermediate-basic volcanic and volcaniclastic rocks of ?late Miocene age. The Gosowong gold deposit is a classic example of a low-sulphidation epithermal gold deposit, based on the abundance of adularia and illite in the alteration assemblage, and low base-metal sulphide content within quartz-adularia veins. The indicated resource is estimated at 0.99 Mt at 27 g/t Au and 38 g/t Ag for a total of 870 000 ounces Au, using a cut-off grade of 2 g/t Au.

Jan 1, 1999

By P J. Terbrugge

The concept of vertical pit mining has been developed as an alternative mining method for the exploitation from surface of small, vertical or near-vertical, massive orebodies down to depths of some 200 m, where ore extraction from conventional open pit excavations is rendered uneconomic due to high associated waste:ore mining ratio. Systematic lateral support maintains vertical pit sides, thereby minimising waste mining volumes. Stability analysis techniques have been developed for design of this lateral support, with the support quantum, primarily comprising long cable anchors, dependent upon country rock strength characteristics and pit configuration. Where the cost of support is less than the cost of the comparable conventional pit waste excavation, vertical pit mining becomes an economically viable alternative, additionally providing the benefit of reduced environmental impact and rehabilitation requirements for the mining area. The technique has been successfully applied for the mining of a chrome deposit in Zimbabwe to an 80 m depth, believed to be unique in the world, and a full feasibilty study for a 3000 m2 diamond pipe has been carried out for mining to 200 m depth.

Jan 1, 2000

By J Thoma, W Skinner, W Stewart, R Smart

The acid neutralisation capacity (ANC) of rock sample containing significant iron carbonates and/or reactive framboidal pyrite can be a difficult parameter to determine. Results indicated that negative ANC results can occur if reactive sulfide minerals are present; and an over-estimation of ANC will result if significant Fe rich carbonate minerals are present during industry standard ANC tests. In this paper we investigate these problems. Results showed that a significant lag period may be needed (up to 432 hours) after standard Sobek ANC type tests of siderite for the complete hydrolysis of iron released from this mineral. This even occurred with standard industry modifications that included the addition of two drops of hydrogen peroxide. In this work we use a modified Sobek test that included filtering, and thence continued hydrogen peroxide addition until there was no subsequent pH drop, followed by back titration to pH 7.0. Results indicated that the ANC for the siderite (after zero hours) was immediately comparable to the ANC determined after 432 hours lag by standard Sobek type tests; and a calculated theoretical carbonate ANC. Investigations of coal waste samples containing significant framboidal pyrite indicated that standard Sobek ANC type tests can result in negative ANC values due to the oxidation of this reactive pyrite. Because sulfide acidity is already addressed by the MPA calculation, the inclusion of sulfide acidity as part of the ANC determination is effectively biased towards acid generation and thus positive NAPP values. Negative ANC values cannot be ignored or assumed to be zero as this masks any actual ANC available within the sample, which may possibly affect AMD categorisation. This sulfide acidity can be factored out using the quantity of S in the ANC digestion liquor and knowing the non-acid generating sulfate content of the sample prior to ANC testing. Results indicated that incomplete iron hydrolysis at the completion of the Modified Sobek ANC test is not only a function of iron carbonate dissolution, but is also related to the dissolution of Fe-sulfate salts, and the oxidation of reactive sulfides such as framboidal pyrite.

Jan 1, 2003

By D Matthews

Increases in mining and production capacities can have a major impact on the productivity of a mining and production facility during the construction and commissioning period. With minimised production loss in mind, a multi-phase modular plant design was implemented on the Khumani Mine in the Northern Cape, South Africa. The first phase involved a run-of-mine (ROM) crushing facility and the subsequent modular processing facility with capacity for 8.4 million tons per annum (Mt/a) product. An interim phase comprising modular additions to the processing facility increased capacity to 10 Mt/a product, with tie-ins occurring during maintenance periods. The second phase involves a second ROM crushing facility and modular additions to the processing facility, increasing capacity to 16 Mt/a product. This paper outlines the design considerations and limitations with modular design that need to be considered and shows how effectively construction and commissioning were implemented within shut-down and maintenance periods.

Jul 11, 2011

By J E. Everett

Maximising ore tonnage at a selected target grade requires that appropriate ore identification criteria be established. Iron ore mining block models may consist of many millions of estimated blocks, each block corresponding to the selective mining unit (SMU), with grade interpolated from drill hole data. Each block can be considered as a potential ore candidate. Analysis of such a huge database can require large computational resources, especially for sensitivity analysis requiring multiple computations. However, an alternative streamlined approach is possible, where the data are compressed to an appropriately smaller and representative subset. The consequent data reduction not only makes it feasible to consider the simultaneous analysis of multiple pits but also considerably speeds up computation, enabling sensitivity analysis of the potential ore tonnage as a function of the required grade. Ore identification criteria can be successfully established using appropriately chosen reduced data comprising less than one per cent of the blocks. The ore identified is virtually indistinguishable in tonnage and grade from the ore that would be selected using the entire block model.Two methods of data reduction are tested: sampling (using a proportion of unaltered blocks) and binning (consolidating groups of blocks to a single average grade). The source blocks are first sorted (such as by location, analyte grade, principal component score, random order or value) before sampling or binning. In this study, the sorting options considered were by location and Fe grade. The effectiveness of each method was evaluated using the block model subsets to select the maximum tonnage of ore at a specified target grade. Block model data from an anonymous Pilbara iron ore project with about one million blocks averaging 1.132 kt were used. The blocks are from multiple resource models, to be blended to a single product. Sampling is shown to be superior to binning because sampling preserves the full variability while binning, although matching the mean block grades reduces their variability.It was found that the appropriately sampled data sets (sorted by location) gave results virtually identical to the results for the full data set, even when the samples comprised less than one per cent of the original blocks. The reduction in computer time to identify maximum tonnage at a specified grade was approximately proportional to the sample percentage. The increase in computation speed greatly facilitated sensitivity analysis. A sampled data set of one-eighth the total block model was used to investigate the effects of changing each of the component grades around the original grade specification. The results of this sensitivity analysis are discussed, and illustrate the potential benefit of carrying out sensitivity analysis in determining feasible and marketable product grades.CITATION:Everett, J E, 2015. Block model data reduction and sensitivity analysis, in Proceedings Iron Ore 2015, pp 263–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By D R Quick

The Goodall gold mine is located 30 km east of Adelaide River, within the Pine Creek 1:250 000 map sheet, at 8 525 000 mN: 750 000 mE, on the AMG grid. The first gold was poured in April 1988 and the mine closed in September 1993, having produced 228 400 ounces of gold from 4.095 million tons of ore, at a head grade of 1.99 g/t. Oxide and primary ore was mined from one large open cut and low grade oxide ore from three smaller pits. The gold mineralisation was discovered in 1981 by means of a helicopter borne rock chip sampling survey, which delineated 13 discrete anomalies. Systematic grid sampling of rock chips outlined an area of 1300 m by 300 m within the 2.0 g/t contour. Over 7500 m of costeaning was used to delineate the A and B-Pod mineralised areas. Geochemical soil sampling played only a minor role in the discovery and geophysics none at all. By the end of 1984, 40 diamond drill holes had been completed and a resource of 3.63 million tonnes at 3.0 g/t calculated. In January 1985, Western Mining Corporation Ltd became a joint venture partner and funded exploration to cam a 60 per cent interest. Additional drilling led to a feasibility study in 1987, based on a Measured and Indicated resource of 4.25 million tonnes at a grade of 2.35 g/t. The host rocks are quartzo-feldspathic wacke and interbedded phyllitic siltstone, of the Proterozoic Burrell Creek formation. The main zone of gold mineralisation, A-Pod, occurs in a sub-vertical vein array, up to 50 m wide and 800 m in length, of quartz and sulphide veins (5-20 mm wide), It is parallel to and on the east limb of an upright, north plunging anticline. Five types of veining have been recognised, with the bulk of the gold mineralisation associated with quartz-pyrite-arsenopyrite and chlorite-quartz-pyrite veins. The gold occurs as particles, from 1-20 micron, as inclusions and along fractures in pyrite and arsenopyrite and to a limited extent in chlorite. The mineralisation is epigenetic and structurally controlled by fractures developed during an earlier folding event. The gold is assumed to have been derived from the underlying sediments of the Koolpin Formation by hydrothermal fluids emanating from the deep seated northern margin of the Cullen Batholith. Precipitation of gold may have been controlled by variations in temperature and pressure.

Jan 1, 1994

By J Rutter, E Amini, D La Rosa, N Beaton, M Scott, F Faramarz, L Keeney

Anglo American’s Los Bronces copper mine in Chile has been conducting detailed assessments investigating value adding options for their asset. The mine has conducted several detailed Mine-to- Mill and Grade Engineering studies to investigate increased throughput and head grade and to quantifying the impact of these approaches across the life of mine. CRC ORE has two key technologies namely Grade Engineering and the Integrated Extraction Simulator. These two technology suites have been combined to understand the technological landscape and associated value drivers suitable for application at Los Bronces. Detailed ore characterisation test work was conducted to:  measure and spatially model the propensity of ores to naturally deport and  develop customised blast models for Mine-to-Mill and Grade Engineering evaluation The outputs of this work were utilised to develop a block model populated with a range on new Grade Engineering and blasting parameters suitable for scenario analysis. To facilitate scenario analysis a high-fidelity value chain model of the Los Bronces operation from blasting to concentrate production was built in IES. IES was combined with sophisticated analytical tools such as Neural Networks to develop and reconcile a fully integrated value chain. The value chain model made it possible to simulate in IES all available blocks in the block model to predict throughput and grade changes for different strategic scenarios. The scenario analysis was run across 24 strategic combinations of Mine-to-Mill and Grade Engineering and comprised several million simulations. The scenarios investigated each technology independently and jointly to provide an attributed block model that can feed forward into technoeconomic modelling to determine optimal execution strategies for the mine. This paper presents the first published study combining Grade Engineering and IES to provide mass simulation capability to investigate strategic options for a mining asset.

Nov 10, 2020

By P Corbett, P Sheffield

Springvale Mine is an underground coal mine in the western coalfield of New South Wales which utilises retreat longwall mining technique. The mine encountered significant gateroad floor heave issues during retreat of LW415. Floor heave has subsequently impeded longwall advance as well as longwall bolt up and recovery to some extent during the extraction of the next five longwalls. Floor heave at Springvale Mine develops throughout the lifecycle of the mine roadways, and is most prevalent in longwall gateroads. Floor heave has been measured as early as 2 weeks after roadway development and continues to develop through the post-development phase, with a rapid increase in close proximity to the longwall face. This paper presents a case study of the evolution of understanding of floor heave behaviour at Springvale Mine based on geotechnical characterisation, an intensive convergence monitoring program (roof and floor movement) and spatial correlation of monitored locations with longwall face position. The analysis considers previously known factors contributing to floor heave including mining depth, geological and physical properties of the rock mass and mine design geometry. Investigation results indicate a strong correlation between floor heave magnitude and roof dilation magnitude, geophysically inferred faulting in underlying strata, areas of localised stress concentration and mine roadway dimensions. This paper also discusses the predictive model which was developed as a result of the study, which is now the basis of the floor heave removal program used to manage roadway convergence at the mine. Floor heave monitoring, prediction and management strategies (including floor reinforcement and removal) are also discussed. CITATION:Sheffield, P and Corbett, P, 2018. Managing floor heave in an underground longwall coal mine, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 78–94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By C Beal

Proper understanding and management of production drilling in sublevel cave (SLC) mines is essential for meeting production targets and for avoiding inefficiencies that could lead to costly bottlenecks. In many SLC mine management models drilling is considered a derivative activity of firing and bogging. Its scheduling is considered to be implied in a firing schedule and given an arbitrary target completion, ‘several weeks’ or ‘a month’, ahead of production firing. Like development, drilling activities are most efficient when conducted separately from other production activities. Unlike development, however, it is not apparent during planning and feasibility how far in advance of firing drilling activities ought to be conducted. This paper presents a method of defining a minimum threshold of drilled stocks above which drilling, firing and bogging operations occur most efficiently. As an example, the drilling activities, procedures, and maintenance at Glencore Xstrata’s Ernest Henry Mine are presented, and the larger scale consequences of improvements to these areas are presented to illustrate their importance in the operation of an SLC mine.CITATION:Beal, C, 2014. Understanding the role of production drilling and drilled stocks in efficient operation of a sublevel cave mine, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 235–242 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By K Saito, M Hasegawa

Removing sulfur and phosphorus from molten iron can be expressed by the following reactions, respectively. [S]Fe + (O2-)slag = (S2-)slag + [O]Fe [P]Fe + (3/2) (O2-)slag + (5/2) (FeO)slag = (PO43-)slag + (5/2) Fe(liquid) These equations indicate that desulfurisation and dephosphorisation have opposite oxygen potential conditions. If a small amount of desulfurisation slag not removed is carried over to dephosphorisation process, the reaction of sulfur mentioned above proceeds toward left hand resulting in increasing sulfur content in molten iron. For better understanding of such re-sulfurisation reaction in hot metal pre-treatments, the present study aimed at evaluating the effect of iron oxide on the sulfur distribution ratio between slag and hot metal. To measure sulfide capacities and FeO activities simultaneously at temperatures below the melting point of pure iron, CaO-SiO2-FeO and CaO-Al2O3-FeO ternary molten slags were brought into equilibria with copper-iron-sulfur liquid alloys, and the equilibrium oxygen partial pressures were determined with an electrochemical technique involving the stabilised zirconia solid electrolyte. The experimental results showed that the sulfide capacity increased with an increase in FeO content, and this trend was consistent with the fact that FeO was basic. Although the addition of FeO raised the FeO activity and oxygen potential, the calculated value for sulfur distribution ratio between slag and hot metal increased with increasing FeO content.

Jun 19, 2024