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By J. M. Singer

This study was undertaken to obtain some fundamental information about hazardous mixtures of coal dust and methane (firedamp) likely to occur in mines. Fuel concentration limits for ignition of mixtures of coal dust, methane, and air have been determined by a hot-gas ignition method. The limiting concentration of each of the two fuels was usually less than that corresponding to its lean flammability limit in air. The lean limits of flammability of coal dust vary with the type and size of the dust; in this study coal dust concentrations were less than 80 mg/liter. Ignition jets were turbulent pulses (emerging from a channel of 0.5 cm diam) resulting from explosions of stoichiometric mixtures of methane, oxygen, and nitrogen, Temperatures of the ignition jets were varied by changing the oxygen index (OI) = O2/(02 + Nj2) of the primary methane-oxygen-nitrogen mixture (adiabatic flame temperatures from 2,000° to 3,000° K). The objectives of the study were to establish quantitative relations between concentrations of each fuel at ignition limits of hybrid mixtures and to study the mechanism of ignition of these hybrid mixtures by hot turbulent gases, Empirical equations were fitted to concentrations for four coals, namely) Pittsburgh Seam (sizes A, B, and C), Sewell No.2 Seam, pocahontas No.3 Seam, and anthracite. Equivalences of coal dust to methane were computed from these equations; equivalence being defined as -Ac/Am, where c is the coal dust concentration and m is the methane concentration, each in milligrams per liter of air. It was found that the equivalence increases as the temperature of the hot-gas jet decreases. In general, the equivalence is also an inverse function of volatile content of the coal and a direct function of the particle size, However, volatile con-tent in itself is not a sufficient correlating variable, nor is the specific surface area of the coal dust.

Jan 1, 1967

By Ralph H. Whaite

In undermined urban areas, new solutions to subsidence problems are being sought. The Bureau of Mines is investigating a hydraulic backfilling technique whereby fill material is pumped as a slurry through a closed system and widely distributed in inaccessible mine workings from a single borehole. A full-scale demonstration was completed in 1973 in Scranton, Pa., which is underlain by abandoned anthracite mines in several coalbeds superposed one above another. A 30-acre residential area was stabilized by injecting about 450,000 cubic yards of crushed mine refuse into two coalbeds through five injection boreholes. Nearly 200,000 cubic yards was injected through one borehole from which the material moved into the mine workings on all sides; the injected material reached a maximum lateral distance of 640 feet and filled mine openings from floor to roof. In the gravity-feed method formerly used to backfill inaccessible mine workings, quantities of fill injected per borehole averaged about 300 cubic yards. The gravity-feed method required many closely spaced injection holes and provided incomplete filling. The new method, designed for inundated mines, proved successful also in mine workings about mine-water pool level. Distribution of slurry through a buried pipeline minimized disturbance to the community.

Jan 1, 1975

By John B. Ivey

This is a geologic study of the U.S. Bureau of Mines Oil Shale Tract in the Piceance Creek Basin of Rio Blanco County, Colorado for the preparation of a set of detailed surface geologic maps, measurement and identification of joint attitudes and frequencies, and the classification and mapping of the soils of the area.

Jan 1, 1978

This paper summarizes the progress of geological exploration at North Broken Hill Ltd.The North Mine orebodies occur in knots of minor folds on a simple limb structure which is itself highly folded, giving rise to two distinct orebodies pitching N. at av. 42° down to 2,920-ft. level, where the pitch steepens to near vertical as a result of complementary shear movement on the Globe-Vauxhall Crush Zone.The lack of adequate marker beds and top and bottom relations makes the resolving of the complex structural environment of the orebodies most difficult.To test the deeper ground of each side of the De Bavay Fault on the 2,600-ft. level the footwall drive was extended 3,556 feet and over 20,000 ft. of drilling completed from three transverse fans, only one of which intersected the orebodies due to steepening of pitch.The problem of locating the North Mine orebodies N. of the DeBavay Fault remains speculative because the exact position of them S. of the fault is still unknown. Exploration beyond the fault in the search for ore had two lines of mineralization to consider, an eastern one through Cosgroves-Round Hill, long regarded as the continuation of the main lode, and a western one passing through Silver Hill Silver Peak.From surface 45,000 ft. of drilling was completed in five sections, establishing that the structure was dominantly synclinal with a flatdipping E. limb, the W. limb and adjoining structures being involved in the Globe-Vauxhall Crush Zone. Mineralization, though weak, was remarkably persistent but the economic mineralization exposed at surface has not persisted with any continuity.Deep exploratory drilling below the bottom level (3,370 ft.) has established high-grade ore to a depth of 4,095 ft. and also has proved its existence within the Globe-Vauxhall Crush Zone.INTRODUCTIONThis paper summarizes the progress of geological exploration at North Broken Hill Limited from the inception of the Geological Department in 1941 until the end of 1955. The writer has drawn freely on departmental records for the period prior to 1947.

Jan 1, 1956

By B. A. Eaton

The subject of many discussions and technical papers in the last 20 years has been the prediction of the well-bore pressure gradients that are required to induce or extend fractures in subsurface formations. The subject merits this attention because of the frequently recurring problems that arise from an inability to predict fracture pressure gradients. Encountered in several common types of operations in the oil industry are problems associated with the prediction of formation fracture pressure gradients. When wells are being drilled in both new and old fields, lost circulation is often a very troublesome and expensive problem. Complete loss of circulation has been disastrous in some cases. Many times, such disasters could have been avoided if techniques for calculating fracture pressure gradient had been employed in the well plans, and if casing strings had been set, and mud weight plans had been followed accordingly. In areas of abnormally pressured formations, the prediction of fracture gradients during the well-planning stage is extremely important. In fact, it is as important as the prediction of formation pressure gradients, which has received a great deal of attention in recent years. There are several published methods used to determine fracture pressure gradients. However, none of these methods appears to be general enough to be used with much reliability in all areas. In 1957, Hub-bert and Willis published a classical paper that included the development of an equation used to predict the fracture extension pressure gradient in areas of incipient normal fau1ting.l Overburden stress gradient, formation pore pressure gradient and Poisson's ratio of rocks were the independent variables that were shown to control fracture pressure gradient, the dependent variable. In 1967, Matthews and Kelly published another fracture pressure gradient equation that is different from that of Hubbert and Willis in that a variable "matrix stress coefficient" concept was utilized.3 Later the same year, Costley wrote about a similar idea.5 Goldsmith and Wilson used a least-squares curve-fitting technique and field data from the Gulf Coast area to correlate fracture pressure gradient with formation pore pressure gradient and formation depth.' They noted that the fracture pressure gradient increased with increasing depth while the pore pressure gradient remained constant. In each of these cases, the problem for which a solution was sought was to determine the bottom-hole pressure gradient required to initiate or extend a fracture. Results of the previous work show that fracture pressure gradient is a function primarily of overburden stress gradient, pore pressure gradient, and the ratio of horizontal to vertical stress. There is argument for a fourth variable in that in many cases breakdown fracture pressure gradient is greater than the fracture extension pressure gradient. However, if the fracturing fluid is able to penetrate the formation through the pores or existing cracks, there is very little

Jan 1, 1970

By W. A. Wood, H. M. Bendler

Cylindrical fatigue specimens of OFHC* copper were subjected to alternating torsion while under axial tension. The superimposed tension strongly influenced the fatigue life of the specimens as well as causing characteristic changes in the structure of the fissures that form and develop throughout the life of the specimen. A further effect of the superimposed tension is a continuous extension of the specimen throughout its life in a manner formally similar to creep at elevated temperatures. RECENTLY, studies of the structural changes leading to fracture of metals by fatigue have been made by a technique which reveals, in section, the lattice distortion arising from slip movements inside the metal and the disturbances built up by these slip movements at the metal surface.1'2 According to this approach, fatigue develops as follows: a) fine slip movements concentrate in bands, producing little strain-hardening and thus permitting abnormal totals of plastic strain before fracture and, therefore, abnormal amounts of lattice distortion along each slip band; b) both forward and backward slip movements occur in each band which, according to their distribution across the band, may build up surface disturbances that include sharp notches; c) these notches early in the life of a specimen penetrate the distorted slip zones and transform them into deep, fine fissures; d) the fissures on continued cycling locally saturate the metal and cause local collapse in the form of a microcrack. Thus, the significant consequence of fatigue or cyclic

Jan 1, 1962

By G. W. Murrie

A geologic study of the Mary Lee Group of coalbeds in the Black Warrior coal basin was undertaken to examine coal stratigraphy and determine regional trends and extent of the coalbeds. The area investigated encompasses 835 square miles in Jefferson, Walker, and Tuscaloosa Counties, Ala. More than 700 core logs were used to construct a structure map, coal, interval, and overburden isopachs, and cross sections. There is evidence that structure affected sedimentation. Coalbed isopachs indicate the Mary Lee Group was deposited in fluvial-deltaic and low-lying coastal plain environments. The Mary Lee coalbed is the only coalbed which is continuous throughout the area, commonly with two benches which have a combined thickness of 2 to 12 feet. The Mary Lee coalbed changes rank in the basin from high-through medium-to low-volatile coal. The methane gas potential of the Mary Lee Group coals is estimated to be greater than 1 trillion cubic feet. There is an excellent correlation between the orientation of surface cleats with those measured underground in the Mary Lee coalbed. The face cleats roughly parallel the axes of the area's folds and trend northeast-southwest.

Jan 1, 1976

By Kenneth Eilerts

[The development and operation of ?combination on wells?5/ have created new and unusual problems, many of which cast to solved only if information is available concerning the properties of the fluids produced. Data as to the characteristics of the fluids at the relatively high pressures that exist in the reservoirs are especially important, and there is growing economic concern to know what part, if any, of the liquid recovered at the surface was liquid in the reservoir, As an extension of this problem, it is important to Know whether liquid will be formed in the reservoir it as a result o a isothermal retrograde condensation when the reservoir pressure is reduced. The pressure range of such condensation, if it occurs, is significant in the design of gas-recycling plants for maintaining reservoir pressures. In connection with the operation of such plants, it is particularly important to know how gyres sure and temperature will affect the yield of the liquid phase and the composition of the gas to be returned to the reservoir. It has not been possible to predict the behavior of these fluids that have high ratios of gas to liquid by comparing them with the behavior of low gas-liquid ratio fluids at identical pressures and temperatures. Such comparison fails because the proportions in which a component will be distributed between the phases of a system at any given temperature and pressure depend increasingly on the composition of the mixture as the critical temperature and pressure of the oysters are approached. Because many combination wells are producing from reservoirs that have temperatures near the critical point, experimental date on the properties of the fluids under reservoir conditions are particularly important at this time. To rest the immediate requirements of the industry for such experimental information an equilibrium cell has been constructed at the Petroleum Experiment Station of the Bureau of Mines, Bartlesville, Okla. When adequate experimental date, have boon accumulated, it may be possible to mare dependable estimates of the phase relations ft. high gas-liquid ratio fluids at the pre runes and temperatures characteristics of ?combination-well? reservoirs.]

Jan 1, 1940

By R. A. Hill, J. D. Pitts

"Long distance slurry pipeline systems have been successfully trans-porting steam coal, iron concentrates, copper concentrates and limestone for an aggregate of nearly 60 years and nearly three billion ton-miles annually. A phosphate concentrate pipeline is nearing start-up and systems for coking coal, lead/zinc concentrates and fly ash are planned. The solids pipeline concept, first patented in the early 1900's and commercialized in the 1950's, is now a proven technology providing an economic, environmentally pleasing and safe method for long distance bulk transport.The challenge for larger tonnage and longer distance movements of solids, for traversing increasingly rugged terrain in grass roots mineral developments, for transporting untried materials and for shipping more economic forms of proven materials still remains. This has necessitated continued refinements and optimization of the technology. The economic and environmental incentives for slurry pipelines when compared to other transport alternatives has justified substantial activity in this area. The scope of planned systems in coal, iron and other minerals is indicative of the firm place slurry pipelines will have in worldwide mineral development.In this presentation, the state-of-the-art in long distance slurry pipelines is reviewed with a focus on major systems of interest to the mineral processing industry. An overview of new developments in the application of this concept is presented, and finally, a projection of the future of pipelines in mineral development both worldwide and in Canada is discussed."

Jan 1, 1978

By John E. Kelley

A method for measuring the spark-shower radiance of metals when abraded on a grinding wheel was developed by the Bureau of Mines for evaluating the sparking tendency of metals. The radiance was measured in units of emissive power per solid angle per area of the detector. Over 100 metals were tested and rated relative to commercially pure iron. The metals tested included elemental metals, iron binary and ternary alloys, iron-carbon ternary alloys, commercial steels, nonferrous alloys, and a few hard-metal compounds. Some alloys were synthesized; others were obtained commercially. Alloys that possessed good strength properties were emphasized for selection. The results indicate that the spark-shower radiance of plain carbon steels and carbon alloy steels was greater than that of pure iron. Certain elements, particularly vanadium and chromium, reduced the sparking tendency of iron. Stainless steels and particularly nickel alloys displayed low spark-shower radiance. Some metallic elements had much lower radiance than iron; others, much greater. Plain carbon steels, heat treated to a variety of hardnesses, gave radiance values that generally increased with increasing hardness. The effect on sparking tendency of an increase in hardness of an alloy steel was studied. The sparking tendency increased with an increase in hardness to a maximum, then decreased with a further increase in hardness.

Jan 1, 1974

By W. L. Falke

The Bureau of Mines has developed a system that permits the "soft" soldering of aluminum and aluminum alloys with standard tin-lead solders. The method employs application of a thin nickel-copper-alloy coating to the substrate, which enables the tin-lead solders to wet readily and spread over the areas to be joined. With conventional technology, aluminum and aluminum alloys are extremely difficult to solder because tenacious surface oxide films prevent wetting. With the Bureau-developed method, the aluminum substrate is mechanically or chemically cleaned to facilitate bonding to a minute layer of zinc that is subsequently applied with an electroless zincate solution. The nickel-copper-alloy (30 to 70 pct Ni) coating is then applied electrolytically over the zinc, using immersion cell or brush-coating techniques. Development of acetate electrolytes has permitted deposition of the proper alloy coatings. The coated areas can then be readily joined with conventional tin-lead solders and fluxes. The joints so formed are ductile, strong, and relatively corrosion resistant, and exhibit strengths equivalent to those formed on copper and brass when the same solders and fluxes are used. The method has also been employed to soft-solder magnesium alloys.

Jan 1, 1983

By Steven W. Schmauch

A mineral survey by the U.S. Bureau of Mines and U.S. Geological Survey indicate the Blanco Mountain RARE II area has low potential. Lode deposits consist of small, mineralized quartz or quartz-gossan veins. The veins are sparse and widely separated and lead, silver and gold content is restricted in amount and concentration. No gold or other potentially economic minerals were found in a placer deposit. There is no evidence of industrial mineral, geothermal, or energy resource potential in the study area. INTRODUCTION A mineral resource survey of the Blanco Mountain RARE II area (No. 5059), Inyo and Mono Counties, California was conducted in July 1981. This report summarizes the results and interpretations of the Bureau of Mines investigation.

Jan 1, 1982

By A. E. Raddatz

The Bureau of Mines is investigating methods for recovering tungsten from domestic resources. A calcine-quench-leach (CQL) technique was developed for the extraction of tungsten from the Golconda, Nev., hot springs ores. The deposit contains disseminated tungsten that cannot be beneficiated by conventional techniques and must be treated by hydro-metallurgical methods. The CQL procedure consists of calcining the ore at 900° C for 3 hours, quenching in a solution containing 1.5 parts of Na2C03 and 1.5 parts of NaOH per part of WO3 in the ore and at a solution-to-ore ratio of 3 to 1, leaching at 200° C and at 250 psig for 3 hours, and filtering and washing the residue. A series of closed-circuit batch tests showed that 92 pct of the tungsten was extracted from a sample containing 2.32 wt-pct W03. The pregnant solution contained 11 g/l W03.

Jan 1, 1982

By W. J. Kingwell

Where the equipment, technique and materials are available for the construction of large diameter rock socketted piles, this is frequently the most economical and environmentally acceptable method of supporting very large concentrated foundation loads in geoglogically appropriate areas. This paper outlines the current approaches in Australia to design and installation of large diameter rock socketted piles. The equipment and procedures described generally reflect those developed or used by Vibro-Pile (Aust.), a company which, while installing the usual range of driven and bored piles, specializes in the design and construction of large diameter rock socketted piles and possesses special expertise in drilling in high strength rock. A high capacity crane attached drill for large diameter drilling in rock is briefly described. Discussed in detail are the construction techniques employed and structural and geomechanical design methods adopted.

Jan 1, 1989

By D. A. Elkins

This report is the second of a series of three that will evaluate, in order, the metallothermic, carbothermic, and electrolytic methods of magnesium production. The historical development of the carbothermic process is outlined. Production costs varying from 38.9 to 21.8 cents per pound of magnesium are estimated for different versions of the process. Additional suggested process modifications are listed. The technical and economic potential of the different versions are compared. Areas deemed most promising for future research on the process are delineated.

Jan 1, 1967

By Hamid Maleki

Roof falls are one of the leading ground control problems that adversely influence productivity and worker safety in underground mines, construction sites, and nuclear waste repositories. To control roof stability problems, the operator needs to have practical methods for measuring changes in strata conditions and criteria for defining the timing of secondary support installation. The objective of this study was to develop measurement techniques and criteria for assessing roof conditions at the mining face. An integrated rock deformation and tomographic imaging method was developed and applied at two sites in a western U.S. trona mine. It was shown that rock damage occurred at a deformation of 30 to 60 mm (1.2 to 2.4 in) (2 to 4 pct strain) and was associated with a significant (16 pct) reduction in wave velocity. Thus, supplementary support may be installed when there is a measured change in wave velocity of at least 16 pct. Tomographic measurements can be obtained in rocks rapidly, thus providing a powerful tool for analyzing growth of failure and for installing supplementary support systems in a timely manner.

Jan 1, 1996

By D. J. Young

Alloys used at high temperature must resist both creep and corrosion. Design for corrosion resistance is based on the formation of a slow-growing, protective oxide scale by selective oxidation of an appropriate alloy component, usually chromium or aluminium. A successful scale will exclude other corrodents, notably carbon, which can otherwise cause extremely rapid corrosion at high temperatures. Selective oxidation of an alloy component necessarily lowers the concentration of that metal in the alloy subsurface region. Under thermal cycling conditions, mechanical damage to the scale leads to renewed oxide growth and accelerated alloy depletion. Eventually, a point is reached where diffusion of a corrodent into the alloy becomes competitive with the outward diffusion of alloy metal to repair the protective scale. Two examples of alloy failure by carbon attack are considered. In the steam cracking (pyrolysis) process, centrifugally cast tubes of heat-resisting alloy are exposed to a gas stream of hydrocarbon and steam, at a carbon activity of unity. Formation and repair of the surface chromia scale causes alloy depletion, Kirkendall void formation, and subsequent internal precipitation of chromium-rich carbides. Their formation makes chromia scale formation much more difficult, and generates internal stress. Eventually, the tubes fail by creep rupture. In other processes (e.g. steam reforming, heat treatment), synthesis gases are supersaturated with carbon at intermediate temperatures. Once the alloy's protective scale is breached, carbon attacks the depleted substrate. In the case of ferritic alloys, it forms a surface scale of Fe3C. As this scale thickens, the supersaturated carbon precipitates as graphite within its outer regions. The resulting volume expansion causes disintegration of the cementite in a process known as metal dusting. In the case of austenitic alloys, no metal carbide is formed. Instead, carbon dissolves in the depleted metal to diffuse inward and precipitate as graphite within the metal matrix. Again, volume expansion causes disintegration of the alloy, and metal dusting results. Dusting occurs at an extraordinarily rapid rate, and leads to failure by section loss or even penetration.

Jan 1, 2013

Geologists in some underground gold mines collect grab samples from broken ore piles or trucks as a method of grade control. It is often known as muck sampling. Generally, the goal of grab sampling is to try and reconcile the mined grade at the ore source to the predicted grade and/or predict the mill feed grade. The mass of the sample collected is limited by health and safety issues, as well as by the capacity of the laboratory to process the samples within a given time frame. In general terms, grab sampling is known to be problematic because samplers tend to oversample the fines, and/or pick out high-grade fragments; surface sampling of piles does not test material within the pile; muck piles in development drives/faces are likely to be zoned due to the blasting sequence; high or low-grade material may preferentially segregate in the pile during mucking; the five per cent mass reject size of the material in muck piles is very large from underground blasting; some correlation usually exists whereby the larger fragments are enriched or depleted in the critical component of value; and the average error made in estimating the true stockpile grade is likely to be high. The method is prone to chronic fundamental sampling, grouping and segregation, delimitation, and extraction errors. Substantial warnings must be given about the use of grab sampling for grade control in gold mines. The method may appear to work sometimes, which can be attributed to a fine gold particle sizing and more disseminated distribution. As with all sampling methods, its appropriateness must be determined by ore characterization and heterogeneity testing to ensure the method suits the ore type.

Jan 1, 2010

By George Rice

Foreword Following the explosion in the Hillcrest mine, which occurred in the evening of Sunday, September 19th, 1926, and in which two men lost their lives, the writer was invited by the Hon. J.E. Brownlee, Premier of Alberta, to conduct an investigation into the causes of the disaster, and to make such recommendations as seemed advisable with a view to minimizing as far as possible the chance of future explosions in this and similar Alberta coal mines. Accordingly, the mine was visited, and extensive investigations were made underground on October 21st, 2.2.nd, and 25th, in company with Mr. John T. Stirling, Chief Inspector of Mines for Alberta, Mr. Moses Johnson, District Inspector for the Crowsnest Pass District, Mr. J as. A. Richards, Inspector of Mines, Edmonton, and also Mr. Thomas Davies, manager, and other officials of the Hillcrest mine. Hearings of the coroner's inquest were also attended on October 20th and 23rd, when testimony regarding the explosion was given by various witnesses. The following paper summarizes my general observations in tracing the place of origin of the explosion, and my efforts to determine the cause of ignition. Certain recommendations arc also made, and the writer invites discussion on these and the other matters dealt with in the paper.

Jan 1, 1928

By M Stevens, M P. Simpson, J L. Mauk

The Karangahake deposit was the second largest producer of gold-silver bullion in the Hauraki Goldfield, New Zealand. New mapping of a 2 + 3 km (6 km2) area demonstrates that hydrothermal alteration surrounds productive veins. Wallrocks proximal to veins are intensely altered and alteration decreases toward the margin of the system.   At Karangahake, distinct zonation of adularia, calcite, epidote, illite and illite-smectite surrounds gold-bearing lodes with unaltered rocks containing magnetite and plagioclase occurring on the margins. Adularia, illite, illite-smectite, and calcite zonation defines hydrothermal alteration extending 2 km to the east of productive lodes. Epidote and adularia zonation occurs proximal to veins. The adularia zone compares well to potassium/thorium studies conducted in the area. Illite zonation is well developed to the east of the veins grading into interstratified illite-smectite containing 5 to 40 per cent smectite 1.5 km from the Maria Lode. Calcite is restricted to the east of the study area occurring in 18 per cent off surface samples. Less altered rocks containing plagioclase and magnetite occur distal to veins. The magnetite occurrence compares well to aeromagnetic studies conducted in the area.   Adularia and coexisting adularia and albite indicate the host rocks were highly permeable. Epidote, illite, illite-smectite and previous fluid inclusion evidence implies temperatures graded from >240¦C in the core of the system to approximately 150¦C on the periphery. The alteration association of quartz, adularia, calcite, pyrite, chlorite, illite and illite-smectite reflects a near-neutral to weakly alkaline water. Calcite occurrence and the absence of zeolite imply the fluid contained significant dissolved CO2.

Jan 1, 2005