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By C. H. Fisher, Abner Eisner

"INTRODUCTION Sulphuric acid of various concentrations has long been used as a reagent in the determination of olefins and aromatics in hydrocarbon oils 4 such as gasoline, kerosene, and neutral oils from coal—tar distillates. Despite its long use, however, there is no general agreement as to optimum conditions and concentration of acid, and numerous methods and modifications have been recommended. In most cases, treatment of the neutral oil with 60 to 90 percent sulphuric acid, followed by distillation to the original endpoint to remove olefin polymers, is recommended for the estimation of unsaturated hydrocarbons. The distillate thus obtained is taken as olefin—free oil and used in later stages of the anlysis. Aromatic hydrocarbons generally are determined in the olefin—free oil by suphonation with more concentrated acid (96 to 100 percent and fuming sulphuric acid are recommended), the hydrocarbons not attacked and removed as water—soluble sulphonic acids being considered as saturated hydrocarbons. In some cases the saturates are examined further by differentiatingbetween cyclic (naphthenes) and acyclic hydrocarbons (paraffins). Generally this is achieved by physical methods, although strong sulphuric acid is known to react preferentially with some types of saturated hydrocarbons,It was the purpose of the present work to make a general study of this type of analysis and to investigate the reactions of hydrocarbons under conditions often used in analyses that employ sulphuric acid reagents. Since previous work is not in good agreement, the optimum concentrations of acid for the different stages of the analysis were determined. Several sulphuric acid methods previously recommended and new modifications were compared, two synthetic solutions being used as the reference oil. The results obtained are presented below under separate headings."

Dec 1, 1937

By I. G. Gonçalves

For most industrial minerals, the color is directly associated with economic value. In terms of physics, the principal property that defines the term ?color? is the intensity of light reflected (or transmitted) by an object over the visible band, comprehended between 400 and 700 nm. This reflectance spectrum serves as the starting point for a variety of color-describing factors, the most common in the mineral industry being the brightness (TAPPI, 1977 and 1986) and the L*a*b* system (HunterLab, 2008). Quality specifications for mineral products are usually based on these colorimetric parameters. This market is becoming increasingly more selective and demanding over the quality of raw materials and alongside the traditionally controlled characteristics, such as particle size distribution and chemical composition, a trend exists towards the establishment of increasingly more strict specifications for the optical properties of these materials. This is due to the fact that most plants consuming these industrial minerals incorporate them into products in which the visual appearance is controlled. For these plants, most of them being the manufacturers of plastics, paper, paints, and ceramics, variations in the color of mineral materials result in difficulties to achieve the right color in the final product. Therefore, these plants set strict specifications for colorimetric parameters such as whiteness and yellowness, as well as colorimetric coordinates like L*, a*, and b*. For the manufacturer of industrial minerals, this translates into difficulties simply because many of these parameters are usually alien to the tradition of the mining industry. The main quality parameter in the kaolin industry is brightness, which is a weighted average of reflectance values over the range of 400-510 nm (TAPPI, 1977). Due to the lack of a better property, producers tend to use brightness to also assess the quality of the in situ ore and along the processing operations. However, the unprocessed kaolin is often accompanied by ?contaminant? minerals. For Brazilian kaolins, which are the object of this study, the most important contaminants are hematite (Fe2O3), goethite (FeOOH), and anatase (TiO2). Each of these contaminant minerals has a distinct color and behaves differently during the processing of the kaolin ore. Hematite and goethite in particular are particularly strong pigmenting agents and at concentrations as low as 100 ppm they can make the difference between a high-quality white pigment product for paper coating and waste material. As each Fe-bearing contaminant has a different color and responds differently to processing operations (for example, magnetic separation, chemical bleaching, selective flocculation, and/or flotation in the case of kaolin), the in situ brightness tends to show a poor correlation with the brightness of the final product. Brightness measurements are sometimes complemented with X-Ray Fluorescence (XRF) analysis of Fe and Ti, but the total oxide content provided by XRF is also poorly correlated with product quality because Fe may be in the form of goethite, hematite, or inside the crystalline structure of kaolinite. Thus, a more robust technique capable of distinguishing each mineral phase is desirable. Diffuse reflectance spectroscopy has been used to analyze iron oxide/hydroxide content both qualitatively (Torrent and Barrón, 2003; Liu et al., 2011) and quantitatively (Jiet al., 2002 and 2006). These authors correlate slopes and inflection points at characteristic absorption bands with oxide/hydroxide content in natural soils. The approach presented here involves the extensive use of the Kubelka-Munk (K-M) theory, which has been used for color matching (Schabbachet al., 2009 and 2011) and particle size determination (Otsuka, 2004) in a simplified version. Unfortunately, the scattering constant S is very difficult to measure for dry powders, because the equations require a thin layer of material. Attempts have been made (Gonçalves and Petter, 2007, and Gonçalves, 2009) but the experimental errors tend to be high. Thus, this paper aims to develop a tool for the quantification of contaminant minerals in kaolin based on the K-M theory without resorting to measurements over thin layers. This tool is based on a new two-constant approach, which takes into account differences in scattering between materials over the whole measured spectrum. The experimental dataset consists of the reflectance spectra of mixtures between a bleached kaolin and synthetic Fe pigments.

Feb 27, 2013

By J. D. Stone

This paper briefly reviews the adequacy of existing management theories and practices and the managerial proficiency or competency in the South African mining industry. The investigation revealed that existing management practices are totally inadequate to enable all employees on all the levels of the mining industry to achieve the results required from them, in all aspects, at all times. As a result, the South African mining industry is gradually losing its long standing reputation as a relative cheap, competitive, and reliable supplier of minerals to the local and global markets. According to some prominent management authors and theorists, an all-inclusive unified management theory does not exist at present. In this paper the authors summarize the main aspects of a newly developed comprehensive, practical, and integrated management method. It is believed that the application of this method would significantly improve the future performance and competitiveness of the South African mining industry

Jan 1, 2010

By Gao Dazhao

This paper presents some research results of pile foundation performance. Measurements on the bearing behaviour and driving effects of piles have been carried out during pile testing and pile driving. It has been found that the ratio of end resistance to the ultimate load depends on the pile length, and the ratio in general is less than 40% for single piles. However for pile group, the end resistance seems to be greater than skin friction. The characteristic curves of skin friction and end re­sistance appear as interaction between soils and pile. The contribution of skin friction to the pile bearing capacity not only depends on soil properties but also on the relative position of the soil layer. The pore pressure and the lateral pressure in ground have been observed during the stage of driving piles. Based on the available data, the radius of plastic region and the coefficient of pore pressure A can be found analytically. The pore pressure time process curves which may be used for practice have been predicted by means of numerical method.

Jan 1, 1991

By Fred P. Giese

Southeastern reserves of titanium ores are large, widespread, and ample for anticipated demand. The leading titanium industries are mining and beneficiating sand deposits, principally in Florida, and manufacturing titanium pigments. Most of the mineral output is consumed by the producers themselves. In 1962, 20 percent of the national pigment capacity was in the Southeast.

Jan 1, 1964

By T. L. Owen

Since 1993 Cyprus Amax has brought $2.5 billion dollars of greenfield and expansion projects into production, taking it from a mid-sized domestic minerals company into a major international minerals organization. The near simultaneous development of these multiple mineral projects in different locations around the world provided the opportunity for Cyprus Amax to develop a formal project management approach based, in large part, on an outsourcing philosophy. This formal project management system along with its outsourcing philosophy has served the growth agenda of Cyprus Amax extremely well. These preceding factors, coupled with the in-house retention of a core project group that fully understands the breadth of skills and abilities needed to undertake development of multiple large projects successfully, have been the cornerstone of Cyprus Amax’s project development success.

Jan 1, 2000

By E. Northcott, I. M. LeBaron

Before describing the electrostatic processing of feldspar, it might be well to review some of the basic definitions and terminology of feldspars. The feldspar minerals constitute a group of alumino-silicates of potassium, sodium, and calcium. Barium feldspar sometimes occurs naturally but is very rare. Hardness varies between 6 and 6.5 and specific gravity between 2.5 and 2.8. Color is generally white or pale shades of red, yellow, or green. The approximate chemical composition of the principal feldspars is given in Table I. The albite (sodium aluminum silicate) and an-

Jan 1, 1959

The method of investigation was to study the distribution of ore in great detail, to make a thorough structural study of the lode and the mine area, and then to compare the results of the two studies. Such a comparison usually reveals a very close relationship between geological structure and ore distribution, and can often lead to important conclusions which would not be reached in the ordinary working of a mine.The Triton mine lies 30 miles E.N.E. of Cue, or 380 miles N.W. of Kalgoorlie, in typical pre-Cambrian rocks, consisting of gTeenstone lavas and tuft's, interbedded with slates and some sediments, and intruded by granite and porphyry. Fig. 1 (at end of paper) is a longitudinal section of the mine and shows that the workings consist of the main North Emu and the smaller South Emu, separated by a distance of about 1 of a mile. Both orebodies occur on the same lode, which strikes north and south and dips practically vertically. On the same line, and of 1/2 a mile and a mile respectively to the north of the North Emu, are the small Rand and North Rand workings, where a big width of lode material has proved to be very low grade. In the North Emu the lode width averages 12 to 15 feet; it is seldom less than 5 feet and in places reaches 30 feet. In the South Emu the lode is wide, but only portion of it is payable.The lode is a mineralised bed occurring between massive lava flows on the east and a mixed series of tuft's and thin lava flows on the west. The lode material is hard, fine grained, and dark coloured, and generally has a faint banding which is believed to indicate a tuft'aceous origin of the original lode rock. Microscopic examination shows that the original lode rock has undergone considerable albitisation;' there has also been considerable formation of biotite which gives the lode material a characteristic sheen. The mineralisation consists of abundant fine pyrite, which is auriferous, and a lesser development of pyrrhotite which is, however, barren of gold.THE OREBODIES AND THEIR CHARACTERISTICSThe distribution of ore is best studied from gold contours, as these reveal features that cannot be detected in an ordinary assay section. Gold contours (see Fig. 3) are developed' by plotting the width and grade of all development and stoping assays throughout the mine on a longitudinal projection, representing each sample by a coloured dot according to a suitably chosen range of assay values, and then outlining areas of similarly coloured dots (see H. J. C. Conolly, Econ. Geol., April, 1936). Both width and grade must be taken into account and the simplest method of gold contouring is to use dwt.lft. values, but difficulties arise here with big widths of low grade and small widths of high grade ore. To choose an extreme case, 30 ft. of 2 dwts. and 2 ft. of 30 dwts. both equal 60 dwts.lft., and would therefore be given the same value in dwt.lft. contouring...

Jan 1, 1943

By H. H. Schrenk, W. P. Yant, F. A. Patty

"INTRODUCTION In accordance with the outline of investigation described in a previous report 5 of the Bureau of Mines dealing with the use of acrolein for detecting leakage of methyl chloride from unit--type refrigerating systems, the work has been extended to include an investigation of its use in a multiple system, This report gives the results of analysis of samples of the gas from representative units of a multiple system charged with methyl chloride containing approximately 0.9 per cent acrolein by volume, The results furnish a basis for estimating the Warning that would be given in event of leakage. The properties and warning intensity of acrolein have been described in a previous report. 5 ACKNOWLEDGMENTSThis investigation was made at the combined request-of Several Inc., Manufacturers of refrigerating, appliances, and the Roeasler Hasslacher Chemical Co., manufacturers of methyl chloride. Acknowledgment is given to R. M. Major, ,chief chemist of the former firm for arranging the experimental site and equipment; to Arthur O. Haseeneall, owner of the apartment building where the investigation was conducted, for his courtesy in permitting the investigation; and to R. R. Sayers, chief surgeon, Bureau of Mines, and surgeon., U. S. Public Health Service, for suggestions and advice."

Sep 1, 1930

By R. Bruce Patterson

The New Tacoma Narrows Bridge is a classic suspension bridge founded on concrete caissons. Caisson construction was complicated by the proximity of the existing bridge piers, only sixty feet away. High capacity plate anchors were used successfully to moor the new caissons in currents as strong as seven knots during construction.

Jan 1, 2004

By Piyush K. Dutta

This report describes the design, development and manufacture of a prototype quiet hard rock stoper drill and results of its field tests. It is shown that the stoper drill noise level can be reduced from 118 dBA to below 100 dBA by using this design. The design concept of this drill is based on a valveless independent rotation system, use of an integral muffler and pivot mount. The drill was manufactured in a standard commercial drill manufacturing setup and organization. The design and production technology proved that commercially viable quiet drills can be made available for mine use.

Jan 1, 1985

By Randy Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Occasionally mine operators are unaware of the presence of free gold particles in their ores because they have not seen free gold hand specimens or at the working face of the mine.Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment. The trapping and subsequent release of gold particles can frustrate attempts to calculate accurate metallurgical balances.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1997, 1998, 1999 and Walsh, 1986, 1992). In 1995, the author used radiotracers to locate and eliminate gold traps at La Mine Doyon (Clarkson, 1997). In 1998 and 2001, the author also salted mineral processing circuits at Royal Oak's Pamour Mine in Timmins (Clarkson, 1999) and at Gold Corp’s Red Lake Mine in Ontario with radioactive gold particles.The gamma and X-ray radiation from gold's nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment with scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps, improving security, determining the recovery efficiency of Knelson gold concentrators and estimating retention times of gold particles in various processes."

Jan 1, 2003

By John C. Edwards

The Bureau of Mines developed a mathematical model to predict the oxygen requirements for a miner evacuating a mine. The model accounts for variations in the miner's escape speed with mine airway height, and for the empirically determined expressions for the weight-specific oxygen uptake rate for upright walking, stooped walking (duck-walking), and crawling. A Fortran computer program that is user oriented was prepared based upon the model's constitutive equations. Specific instructions for utilizing the program, as well as applications to miner evacuation from a mine, are presented.

Jan 1, 1986

By R. Marrill

Mining is a complex and intensive industry. Extracting raw material with different shapes, sizes, chemistry from the earth?s crust and transform them into a standardized and high quality final product is a big processing challenge - which involves energy and control on large scales. Not only is the physical work challenging, the mining industry today is facing unprecedented challenges: Decline of mineral grade and reserves, cost escalation for new developments and modernization, regulations, safety, lack of skilled people, and market uncertainty are the new constant. It is clear that process control and management of electrical power will be of increasing importance to the recovery rates the mine will achieve. The objective of this paper is to provide a quick vision about future trends and evolutions in technology related to these fields and their impact on Electrical Safety and Control of the mineral recovery. The paper will cover trends in safety, energy management and efficiency, communications of data, control room evolutions, plant integration, other control technologies, and we will examine how these technologies provide information and the benefits of aligned reporting systems to address current industry challenges. More than just the trends or breakthrough concepts, current technologies are available today that can be applied in the mineral recovery operations now to help overcome anticipated future challenges will be presented later in this document. Finally, a brief discussion to look at some real tools to help make real time changes to the process while maximizing recovery and optimizing cost.

Feb 27, 2013

By Robert S. Hedin

Passive methods of treating mine water use chemical and biological processes that decrease metal concentrations and neutralize acidity. Compared with conventional chemical treatment, passive methods generally require more land area, but use less costly reagents and require less operational attention and maintenance. Currently, three types of passive technologies exist: aerobic wetlands, organic substrate wetlands, and anoxic limestone drains. Aerobic wetlands promote mixed oxidation and hydrolysis reactions, and are most effective when the raw mine water is net alkaline. Organic substrate wetlands promote anaerobic bacterial activity that results in the precipitation of metal sulfides and the generation of bicarbonate alkalinity. Anoxic limestone drains generate bicarbonate alkalinity and can be useful for the pretreatment of mine water before it flows into a wetland. Rates of metal and acidity removal for passive systems have been developed empirically by the U.S. Bureau of Mines. Aerobic wetlands remove Fe and Mn from alkaline water at rates of 10-20 and 0.5- 1.0 g. m-2? d-1, respectively. Wetlands with a composted organic substrate remove acidity from mine water at rates of 3-9 g. m-2? d-1?. A model for the design and sizing of passive treatment systems is presented in this report.

Jan 1, 1994

By J. G. Kirby

The number of petroleum refineries in the United States continued to decline during 1954, and according to the Bureau of Mines annual survey there were 326 refineries with a total daily throughput capacity of 8,420,630 barrels, as of January 1, 1955. The increase in capacity for the year was 413,733 barrels daily, while the number of refineries declined 11. The capacity of the average refinery to process crude oil increased during 1954 from 23,759 barrels daily to 25,830. Breaking down the crude-oil capacity increase, by refining districts; 32 percent was installed at refin¬eries located in the Texas Gulf Coast district, 25 percent in the East Coast district, and 13 percent in both the Louisiana Gulf Coast and the California districts. The Appalachian No. 1, Texas Inland, and New Mexico refining districts reported declines in capacity during the year. Additional crude-oil capacity under construction, January 1, 1955, totaled 146,800 barrels daily. Included in this total are 4 new refineries, 1 each in California, Minnesota, New Mexico, and Washington. In addition to the' new facilities, equipment producing 1.49,550 barrels daily is being replaced.

Jan 1, 1955

By Russell J. Miller

A high-pressure intensifier system was designed, constructed and field tested as part of a program to determining the feasibility of applying high-pressure water jets on conventional mechanical rock excavation equipment to increase advance rates. Also developed were a high-volume swivel, capable of transferring the high-pressure water to a rotating cutterhead and manifold system for locating and protecting the jets on the cutterhead. Field tests were conducted in a granite quarry near Skykomish, WA, approximately 90 miles east of Seattle. The concept of improving excavation rates by using water jets to assist mechanical cutting was proven to be successful, with an average increase in excavation mete of 50 to 60%. For some tests, the excavation rate was more than doubled. Machine torque requirements were reduced approximately 25% when the water jets were used. It was suggested this was due to reduced cutterhead friction in the presence of the water jets. A comprehensive economic analysis was undertaken as part of a concurrent study to determine the degree of cost benefits attainable from increased advance rates. Very significant savings were seen to be possible. It was concluded that the basic concept of combining a water jet capability with a mechanical excavating machine is definitely possible.

Jan 1, 1976

By W. D. Mcmillan

During the fall of 1943 the Bureau of Mines put down four churn-drill holes totaling 435 feet of bore at the McGregor zinc lead mine near Potosi, Washington County, Mo., after the property had been examined by John Soule, an engineer of the Bureau, in the fall of 1942. A small production of lead and barite ore had been maintained at this property for many Years from shallow deposits in residual clays. A few shafts had penetrated the underlying dolomites and exposed a network of narrow fractures containing galena, sphalerite, barite, and marcasite. The drilling by the Bureau tested conditions at depths ranging from 80 to 130 feet. This report sets forth the data resulting from the work.

Jan 1, 1948

By R. G. Horvath

In the Hamilton area, and in many other areas of Ontario and around the world, large diameter drilled pier (caisson) foundations are frequently selected as the most appropriate foundation system for heavily loaded structures. Locally, these drilled piers are typically founded in competent glacial till or in the underlying shale bedrock depending on the anticipated design loads. Drilled pier foundations socketed into shale bedrock were selected for the Hamilton General Hospital Addition. The structural loads applied to socketed pier foundations are supported through shaft resistance, which is the shearing resistance developed along the vertical pier-rock interface, and by end-bearing resistance. The factors which control the load-displacement-time behaviour of socketed pier foundations are the strength and deformation characteristics of: a) the concrete pier, b) the rock mass, and c) the interface between the concrete pier and the rock.

Jan 1, 1987

By L. Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pinpoint the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable temperature readings and gas analyses could have verified satisfactory activity. Hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: good record keeping is a necessity for collection of representative catalyst samples; reliable operating data is an inevitable starting point for all analysis; and trending of operating data is a must for plant optimization and troubleshooting. In addition, these catalyst management tools will give continuous updated knowledge of the catalyst status in each bed, providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking operating data, temperature optimization and good record keeping.

Jan 1, 2009