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By M. Tanaka, H. Narita, T. Fuchikami, K. Morisaku, K. Nagao, T. Yoshida, K. Kuroda

The effect of various N-substituents on the performance of amide-containing tertiary amine compounds in the extraction of Rh(III) from HCl solutions was investigated to optimize the structure of these compounds for industrial use. It was found that N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine and tris(N-di-2-ethylhexyl-ethylamide)amine, which have long, branched alkyl chains, were suitable for Rh extraction, because they were soluble in a practical diluent (80 vol% n-dodecane?20 vol% 2-ethylhexanol) and stable against highly concentrated HCl/Rh solutions, and showed high selectivity for Rh(III) over Pd(II) and Pt(IV).

Jan 1, 2014

By B. Z. Wu

The ore dressing of tin-polymetallic lean ores is a difficult problem and the research emphasis in domestic nonferrous metals mining field. Through research and tackle key problem,and in order to supply reference in dealing with the same types ores, this paper expatiates the exploiture and appli-cation of six item new technology and technics in ore dressing of tin-polymetallic lean ores. It include the technics of multi-step compounding disposing tailings, grinding step by step, grinding and processing circularly technology, high thickness without circle flotation technology, dispersedly flotation tin step by step technology, exceed fine lean plumbum stibium zinc flocculation flotation technology, the synthetically recovery of waste water after ore dressing technology.

Jan 1, 2014

By T. Nomura, N. Saitoh, K. Tamaoki, Y. Konishi

We have developed new recycling technologies, based upon an eco-friendly biotechnology, in order to extract precious and rare metals sourced from end-of-life products and electronics. We have been focusing on the metal ion-reducing bacteria, Shewanella algae and Shewanella oneidensis, that are able to reduce and deposit gold ions (Au(III)) or PGMs ions (Pd(II), Pt(IV) and Rh(III)) into metal nanoparticles at room temperature within 120 min. When processing the aqua regia leachate of printed circuit boards, Shewanella bacteria were able to rapidly and selectively collect gold ions under acidic conditions in the presence of heavy metal ions, proposing a new bio-recovery system for gold. This biotechnological procedure also has the potential to allow the recovery of PGMs from the leachate of automotive catalysts. Shewanella bacteria were also able to successfully perform the complete reduction and deposition of the PGM ions. The ability to collect the PGM ions suggests that this represents a new process for the biorecovery of PGMs from used automotive catalysts. Our proposed biological method enables the rapid and highly efficient recovery of precious and rare metals via separation and concentration utilizing microbial reactions at room temperature.

Jan 1, 2014

By Steve Kral

"The mining industry is a tough business. The obstacles faced in attempting to run a mine - much less build a new one - go beyond an orebody’s geology. There was a time when commodity prices dictated whether or not to build or expand a mine. Today, though, the challenges faced by miners include social responsibility, environmental regulations and a myriad of needed permits on several governmental levels that every miner knows will be challenged by opponents every step of the way. With all of those challenges, and others not mentioned here, it’s a wonder anyone would stay in the industry. But they do. In fact, more than 2,100 mining professionals from around the world gathered in Reno, NV last December for the American Exploration and Mining Association’s (AEMA) annual conference. That is an impressive number, considering that commodity prices remain in the doldrums, preventing companies from building many new mines and limiting expansions at existing ones. Even so, attending such a conference allows these mining industry pros to learn new and more efficient ways to operate their mines and plants through the dozens of technical presentations the conference offered. And mingling with their peers provided another avenue for learning. The AEMA conference also attracted many of the industry’s leading equipment and service providers (228 exhibitors in 246 booths). Technical presentationsThe AMEA meeting is known for its variety of high quality technical presentations and the 2014 conference was no exception. Some of the topics include new technologies in surface and underground mining, explorers and emerging producers, mine closure and remediation, regulations and reserves reporting, hydrology and new innovations in mining. Here is a sample of some of the presentations."

Jan 1, 2014

By David Verrelli, Melissa Kistner, Leanne Smith, Chris Aldrich, Lidia Auret, Warren Bruckard

In this investigation, different mixtures of realgar and orpiment particles were floated in a laboratory batch flotation cell and multivariate image analysis was used to estimate the arsenic content in the froths. The analysis was based on the froth colour, as well as extraction of three groups of textural features, namely those based on grey level co-occurrence matrices (GLCMs), wavelets and local binary patterns (LBPs). Collectively, these features provided better information on the arsenic content of the froths than any one of the individual groups of features. Partial least squares models could explain approximately 78% of the variance in the arsenic by using all the features combined. The colour content, particularly the green component in the red-green-blue (RGB) features, provided almost as much information as each of the three sets of texture-base features individually.

Jan 1, 2014

By Y. F. Li

Fengning ilmenite ore is a magnetic deposit in gabbro containing high phosphorus and low titanium, the main minerals in which are ilmenite, magnetite and apatite. The dissemination size of magnetite is so fine that even the percentage of -0.010mm level is up to 36.50%. The fine and vein magnetite are distributed in gangue and ilmenite, so the majority of the magnetite is difficult to be separated from the gangue. Ilmenite is difficult to be recovered by low-intensity magnetic separation even through fine grinding. In high-intensity magnetic separation of ilmenite, the gangue inter-growth with the magnetite and the Fe-containing silicates may be enriched in the concentrate, and the ilmenite of the concentrate will be reduced. Based on the processing mineralogy research, combined gravity-flotation process is suggested to recover the ilmenite. The method is also good to reduce phosphorus in the ilmenite concentrate.

Jan 1, 2014

By Samira Rashidi, Robert Dunne, Raj Rajamani

"High Pressure Grinding Rolls (HPGR) are known for more energy saving, better particle weakening and higher tonnage compared to semi-autogenous/ball mill circuits. These machines are scaled up based on the roll diameter. Therefore, studies in lab-scale HPGRs are always preferred because less weight of feed sample is required to run batch tests. The 50-hp laboratory-scale machine at the University of Utah is the first-ever lab-scale machine designed by late Prof Schönert, the inventor of HPGR. This 200x100 mm [DxL] HPGR is equipped with a robust data acquisition system, which enables running steady state tests using a feed sample as small as 6 kg to 12 kg. This paper presents the HPGR grinding study on two different categories of ores, one hard ore and the other soft. A test series has been performed to evaluate the energy consumption and the relation with size reduction on open multi-pass and locked-cycle HPGR circuits. The effect of feed size distribution and operating conditions has been investigated. Locked-cycle tests result in higher reduction ratio and higher rate of fines (100 mesh, 48 mesh and 28 mesh) generation when compared to open multi-pass tests. Data shows that scale-up trend lines stay consistent even when the circuit configuration and operating conditions are varied."

Jan 1, 2014

By B. A. Zaharov, J. M. Shneerson, L. V. Chugaev, M. T. Zhunusov, A. M. Markelov, S. V. Drozdov

The main direction of research was the application of autoclave technology for the flotation concentrates or biooxidation feedstocks. The industry modernization also expects the possibility of increasing the yield of the flotation concentrate, to allow an increase in gold extraction in flotation circuit. This paper provides brief description of results obtained for concentrates with the yield of 4 and 8%, as well as corresponding biooxidation feedstocks. Technological efficiency of autoclave oxidation is shown for both concentrates and biooxidation feedstocks. The process has been evaluated on a laboratory and a continuous pilot plant scale. Gold extractions from POX discharge are ranging from 94-97% for each product, with only 5-7 kg/t cyanide consumed.

Jan 1, 2014

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014

By Sachihiko Tokunaga, Hirofumi Taguchi, Kenji Maruyama, Hidenori Takahashi, Yoshiyuki Morikawa

"Abstract The present study proposed a new liquefaction countermeasure to improve sandy ground and conducted a trial execution. The new method is a floating-type and lattice-shaped cement treatment method, where cement-treated soil is not fixed to a non-liquefiable stratum. A fixed structure such as treated soil should be formed at the side of the floating-type treated soil to reduce its lateral displacement. In the study, one-dimensional dynamic response analyses were first conducted to confirm the mechanism of the new method. Then, a series of centrifuge model tests were performed to demonstrate the effect under a stress condition at the prototype scale. The analyses and model tests confirmed the effect of the liquefaction countermeasure. Finally, trial executions were carried out to confirm high-quality vertical execution.INTRODUCTIONLiquefaction induced by an earthquake generates sand boiling and ground settlement. Other problems have also been reported, including a decrease in bearing capacity and an increase in the horizontal earth pressure against retaining walls. To prevent these problems caused by liquefaction of the ground, various countermeasures have been proposed, such as cement deep mixing and high-pressure jet mixing methods. These methods have the big advantage of being applicable to ground that contains soil with a fine-grain fraction. Furthermore, the unnecessary displacement caused by the construction can be reduced. In Japan, a lattice-shaped cement-treatment method has frequently been used at many construction sites to prevent liquefaction, where cement-treated piles are intersected to form a lattice, as shown in Fig. 1. The lattice-shaped walls can reduce the shear stress generated by an earthquake, restricting the liquefaction at that location. However, the construction cost of the cement treatment is relatively high compared to other methods such as the sand compaction pile (SCP) method, and needs to be reduced. In particular, the cost of the high-pressure jet mixing method, which can be applied to the liquefiable ground under existing structures, is significantly high. Therefore, decreasing the total volume of the cement treatment is necessary to reduce the construction cost."

Jan 1, 2014

By Olga D. Khmelnitskaya

The paper presents the results of research on the development of gold recovery technology from oxidized gold-copper ore of one of deposits in Russian Federation. Gold and copper grades in the ore are 9.5 g/t and 0.4%, respectively. Various options of flowsheets, such as direct cyanidation, thiourea leaching, flotation and gravity concentration followed by subsequent cyanidation of con-centration products, were tested. It was established that gravity-cyanidation technology with filtra-tion leaching tails and the use of solutions in the recirculation is the optimal option for ore treatment. The proposed flowsheet provides gold recovery for 91.0% at NaCN consumption 2.5 kg/t ac-cording to the results of pilot testing. Ammonia-cyanide gold leaching was also examined. In comparison with cyanidation, gold leaching solution in system NaCN-NH4OH-(NH4)2CO3 allows NaCN consumption to be reduced three times from 4.5 kg to 1.5 kg per 1 ton of the ore and provides the same gold recovery. Based on the laboratory and pilot plant tests results of gravity-cyanidation technology of gold dissolution, process design criteria were developed.

Jan 1, 2014

By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

To extract the gold from refractory gold concentrate with high sulfur and arsenic, the gold concentrate was catalytically oxidized to expose the gold for cyanide leaching. The effects of reaction temperature, initial nitric acid concentration, reaction time and initial gold concentrate concentration on the conversion rate were studied. The results show that the appropriate conditions for the catalytical oxidation of this gold concentrate are: reaction temperature of 65 oC; initial nitric acid concentration of 25% (wt.); reaction time of 1.5 hours; initial gold concentrate concentration of 10% (wt.). Under such conditions, the conversion rate of gold concentrate is 92%. The solution can be used to prepare nano-iron oxide red pigment. Gases released in the process can be recycled and reused by oxidation absorption. A chemical background of catalytic oxidation is proposed.

Jan 1, 2014

By H. Gumede

The challenges of noise emission in the mining industry are well known. These challenges are exacerbated by the increasing trend towards mechanized mining, and there is general consensus that an effective industry-wide Buy Quiet initiative (BQI) will significantly assist in reducing noise-induced hearing loss by minimizing noise at its source. In its endeavours to improve the health of workers, the MOSH Noise Team has facilitated development of a proposed strategy and structure for a BQI. Extensive consultation with stakeholders resulted in support for the initiative. The MOSH Noise Team was advised to solicit the contributions of consulting mechanical and electrical engineers (CM&EEs), whose support is viewed as critical for realization of the initiative, since elimination of noise at source is an engineering challenge, and most procurement standards and specifications are set and managed by engineers. A workshop with CM&EEs and their representatives, as well as group environmental engineers (GEEs), confirmed the urgent need for the initiative and provided valuable insights. The workshop used obstacle based planning techniques to identify the factors on which the success of this BQI will depend. Most potential obstacles to the implementation revolved around proper scoping, leadership commitment, and companies? adherence to the initiative. Lack of involvement by the relevant stakeholders and economic issues were also identified as potential obstacles. Delegates at the workshop felt that the successful implementation of the industry-wide BQI, will depend on the mining industry addressing the specific obstacles. The most critical and urgent issue was identified as the formation of a properly constituted industry-wide BQI task team that includes representatives from critical stakeholder groups and which is mandated and empowered to drive the initiative.

Jan 1, 2014

The major components of sylvinite ores, sylvite (KCl) and halite (NaCl), are separated by flotation. Since both these minerals are water-soluble, the process is carried out in a saturated brine, 6~7 mol/L aqueous solution of NaCl and KCl. C16~C22 primary amines, utilized as a collector, are practically insoluble in water. In commercial potash ore flotation operations these amines are melted by heating up to 70~90°C. They are then neutralized with hydrochloric or acetic acids, and such a hot emulsion/dispersion is introduced to the flotation pulp (which is at room temperature). This is immediately accompanied by the appearance of a white precipitate in the system. As our measurements indicate, the Krafft point of dodecylammonium chloride in concentrated electrolyte solutions is much higher than 80°C, and the Krafft point of C16~C22 amines is substantially higher than that. Introduction of a hot amine emulsion into a pulp, at temperature much lower than the Krafft point for the utilized amines, must cause precipitation of the amines. Some of these species are obviously flotation-active. It is interesting to observe that in summertime, when temperatures are high-er, longer chain amines perform better. It demonstrates that the colloidal amine species that precipitate serve as active species in the potash flotation. Therefore, at higher pulp temperatures, when the temperature difference between the pulp temperature and the Krafft temperature of the utilized amine is not sufficiently large, a longer chain amine, the amine with a higher Krafft point, is more efficient. The results reveal that premixing of an alcohol such as MIBC (common frother) with the amine significantly improves flotation performance of the amine. In the presence of such an alcohol the amine disperse system becomes less turbid, and the rheology of the system less non-Newtonian. All this indicates that MIBC, which does not operate as a frother in a potash flotation system, when used as a co-surfactant, enhances the dispersion of the amine colloidal system. The appearing colloidal species perform as an active form of the collector.

Jan 1, 2014

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By Ljubisa Obradovic, Baisui Han, Batnasan Altansukh, Zoran Stevanovic, Atsushi Shibayama, Jonovic Radojka, Daizo Ishiyama, Kazutoshi Hag, Radmila Markovic, Ljiljana Avramovic

This paper discussed a combined froth flotation and high pressure leaching (HPL) process to recover copper from mine tailings. At first, froth flotation were carried out using the mine tailings sample under various conditions in the presence of different pH (3.5-10) and sulfurizing reagent value (0-1000 g/t), respectively. As a result, optimum condition (sulfurizing reagent of 1000 g/t, pH of 10, PAX (collector) of 100 g/t and MIBC (frother) of 200 g/t) was found for froth flotation of copper. The effects of sulphuric acid concentration, leaching temperature, total pressure (steam pressure plus oxygen pressure) on high pressure leaching (HPL) of mine tailing were investigated using sulphuric acid solution in the presence of oxygen. The best conditions for HPL were obtained to be sulphuric acid concentration: 0 mol/L (water), leaching temperature: 170 ?, total pressure: 2 MPa, leaching time: 1 hr and pulp density: 100 g/L. The leaching rate of copper reached nearly 99 % and the concentration of copper in pregnant leach solution (PLS) was 0.24 g/L. Finally, copper in the mine tailing was recovered using froth flotation followed by HPL. As a result of a combined froth flotation and HPL, the vast majority of copper (99 %) from the mine tailings was extracted.

Jan 1, 2014

By Khoi Nguyen, Keeney. Luke

An outcome of geometallurgical mapping and modeling is the generation of continuous down hole profiles of quantitative geometallurgical attributes at assay scale. These attributes vary from traditional routine data collection methods such as assays and geotechnical logging (e.g. RQD, Fracture Frequency), to new measurements including petrophysical attributes, EQUOtip hardness data and modelled estimates of metallurgical performance indices (e.g. A*b, BMWi). Highly variable continuous geometallurgical data with high spatial resolution can make it difficult to identify spatially continuous domains. An automated method based on the well known time series analysis technique of cumulative summation (CuSum) has been developed which uses statistical analysis to identify domain boundaries in down hole profiles. A bootstrap analysis automatically identifies potential domain boundary locations with associated confidence levels and a series of t-tests determine the significance of defined populations. A hierarchical clustering algorithm is applied to results to enable data sensitivity to be taken into account. The method produces statistically significant populations and is suitable for application on either single or multiple drill hole datasets. Domains defined preserve the inherent variability of the continuous down hole data and provide a method for scaling up variability data (i.e. assay interval scale) to mine scale (i.e. bench scale, block model). A major advantage of the method is its ability to provide suitable input parameters for use in spatial modeling of non-additive and non-linear geometallurgical attributes through conditional simulation techniques.

Jan 1, 2014

By B. Csoke

As opposed to large household appliances, in the processing of which dissambling has an important role, this possibility is pushed into the background as the size decreases. The practicable solution is physical liberation of the used small electronic household devices (by comminution) and separation of the liberated components according to their physical properties. In the first phase of the experimental work the structural/material composition of the typical products (mixer, kitchen robot, hair dryer, coffee machine, iron, bread toaster, vacuum cleaner, oil fryer) was determined. In the second phase a physical liberability test for each appliance using a rotary shear/shredder for crushing and a hammer shredder for milling was carried out. In the third phase the experimental separability tests using an air classifier and a shaking air table, as well as an eddy-current and an electrostatic separator were performed. In the present paper the results obtained using the air classifier and the electrostatic separator, are reported. To follow the life of a grain a new methodological procedure was elaborated. The particle size fractions after comminution were sorted into material fractions (copper, aluminium, plastics, etc.), then separated, and finally the recovery of the material components in the products were determined. Furthermore, the joint separability was investigated from two points of view: 1) for grain fractions and 2) for each waste appliance. According to the tests carried out so far, it was established that it is reasonable to form appliance groups by selection (e.g. mixer, iron, bread toaster and similar appliances form the first group, while the sandwich oven,

Jan 1, 2014

By M. Hesham El Naggar, Yasser Abdelghany

"ABSTRACT: The axial and lateral monotonic and cyclic behavior of helical pile foundations was investigated and new innovative helical screw systems suitable for seismic loadings were developed and patented. More than one hundred full scale field load tests were conducted on instrumented helical screw piles installed in cohesive soil. The piles included: plain helical screw piles (P-HSP); grouted (G-HSPs); fiber reinforced polymer FRP-G-HSPs; and reinforced grouted RG-HSPs. The RG-HSP piles axial capacity was more than twice that for P-HSP, with minimal reduction after cyclic loading, and their lateral capacity was more than 3 times the P-HSPs capacity. A 3-D finite element model was established. The results of 3-D finite element modeling were used to establish the load transfer mechanism and a design methodology for the considered piles.INTRODUCTION AND LITERATURE REVIEWHelical (screw) anchors have been utilized in tension loading and have gained popularity for bearing load applications. Helical piles represent an overall cost effective alternative to conventional piles for new construction and repair applications. The helical piles speed and ease of installation, less noise during installation added advantage with regards to their efficiency and reliability for underpinning including re-support and reconstruction of distressed and damaged foundations for either stabilization or rehabilitation. The “square shaft” SS175 pile is a segmented deep foundation system with helical steel bearing plates (helices) welded to a central steel shaft. Load is transferred from the shaft to the surrounding soil through these bearing plates. Segments or sections are joined with bolted couplings. Practically installed depth is limited only by soil resistance and economics. A helical bearing plate or helix is one pitch of a screw thread. All helices regardless of their diameter have a standard 75 mm pitch (Figure.1). The performance of single helical anchors and group action were studied experimentally and theoretically by several researchers, the researches focuses on the installation torque and uplift resistance. Some researches focus on the load carrying capacity with little pile response to cyclic loading effects or to instrumented full scale field testing. Helical piles axial compressive or lateral loading still is not well characterized and needs more analyses and their seismic performance was not investigated. For such this research was initiated to investigate the helical piles monotonic and cyclic performances under axial and lateral loadings to consider their usage in different applications in seismic zones. Among the several researchers, Clemence (1983); Mooney et al. (1985) conducted field and laboratory testing; Hoyt (1989), Hoyt et al. (1995), and Ghaly and Clemence (1998) conducted theoretical and experimental testing, Puri and Vijay (1984), Huang et al. (1995), Perko (2000), and Pack (2000) conducted theoretical analyses. Rao and Prasad (1993), Prasad and Rao (1994), conducted experimental testing; Vickars and Clemence (2000) studied the performance of helical piles with grouted shafts."

Jan 1, 2014