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By R. V. Lundquist

Aeration in water slurries and controlled drying of manganous hydroxide produced from dithionate leaching of Artillery Peak manganese ores from Arizona were investigated by the Bureau of Mines at its Electrometallurgical Experiment Station, Boulder City, Nev., to determine whether a simple process could be developed for converting this product into a battery-grade manganese dioxide. The properties of manganese dioxide prepared by the thermal decomposition of manganous nitrate were investigated also. Manganese dioxide suitable for use in batteries was not obtained from the dithionate leach product, but some of the factors controlling its oxidation were isolated. Aging of manganous hydroxide was of major importance in retarding its oxidation by aeration. Sodium hydroxide and sodium silicate promoted oxidation by drying. Optimum quantities were about 0.85 mol of sodium hydroxide and 0.2 mol of sodium silicate per mol of manganese, and drying temperatures of 200° C. produced yields of manganese dioxide up to 90 percent of the manganese present. Higher temperatures and concentrations of reagents carried oxidation of manganese beyond its tetravalent state.

Jan 1, 1957

By V. E. Edlund

This report presents the results obtained in a study of the technical feasibility of recovering a usable pig iron by pyrometallurgical treatment of typical copper reverberatory slags . The iron in the slag was readily reduced with carbon , but the copper and sulfur content of the metal was best controlled by a three - stage procedure comprising ( 1 ) melting the slag with pyrite to remove copper as a low- grade matte , ( 2 ) smelting the partly decopperized slag with fluxes and carbon to reduce the iron , and ( 3 ) refining the impure iron alloy from step 2 with a flush slag to remove sulfur and residual copper . Laboratory - scale tests demonstrated that washing with 8 wt pct of pyrite lowered the copper content of a typical reverberatory slag from 0.58 to 0.12 Subsequent smelting of a mixture composed of 70 pct decopperized slag , 25 pct lime , and 5 pct coke reduced 84 pct of the iron to metal containing 2.27 pct sulfur . This metal then was successfully desulfurized by treatment with a basic flush slag to produce a finished metal that contained , in percent , 93.5 Fe , 0.02 S , 0.26 Cu , and 4.9 C. Overall recovery of iron under the conditions of trial was about 80 pct . This could be increased if higher tolerances for copper could be accepted . Commercial processing would be accomplished in three furnaces with molten materials passing from one to another . Currently produced smelter slag could be treated fairly inexpensively , because the molten product would require only a little additional heat to produce an iron byproduct that undoubtedly would be attractive to local foundries .

Jan 1, 1964

By William W. Aljoe

The hydrologic characteristics of two abandoned underground coal mine sites, near Latrobe, PA, and Uniontown, PA, were investigated by the U.S. Bureau of Mines for possible implementation of alkaline injection into the mine pools as a means of abating their acid discharges. The Latrobe site was chosen for a one-time application of alkaline injection to achieve a partial, short-term neutralization of a limited portion of the mine pool. A quantity of alkaline reagent (sodium hydroxide) sufficient for a one-time neutralization of the water in this portion of the pool was added. Although nearly all of the neutralizing reagent had moved away from the injection wells within 6 weeks, no evidence of neutralization was noted at the mine discharge during the study period. This lack of neutralization probably occurred because the injection wells did not intercept a primary flow path through the mine. Criteria for successful application of alkaline injection at this or other sites include (1) positive identification of the primary flow paths through the mine pool and (2) addition of quantities of alkaline reagent sufficient to neutralize the entire volume of the pool along the primary flow path.

Jan 1, 2010

By Todd M. Ruff

Current methods of inspecting wire rope for broken wires or excessive wear include visual inspection, physical measurements of rope diameter, and electromagnetic nondestructive testing (NDT). Visual inspection and physical measurement arc the least comprehensive methods. Electromagnetic NDT enables a more thorough assessment of the condition of a wire rope, but the repeatability, accuracy, and objectivity of this method can be improved. One means of achieving this goal is to use a computer to analyze the test data and determine the condition of the wire rope, including the presence of broken wires and corrosion, and the amount of wear. An off-the-shelf data acquisition and analysis system was tested in a U.S. Bureau of Mines laboratory using a continuous loop of wire rope containing fabricated flaws. The test rope was run through a commercially available NDT instrument. The output of the instrument, normally connected to a paper strip chart recorder, was digitized and analyzed with a personal computer. These initial tests were successful in showing that the use of a computer can improve current methods of NDT waveform collection and analysis.

Jan 1, 2010

By L. A. Haas

S02 reduction with CO was studied in an integral flow reactor at a nominal flow of 0.5 liter per minute. Reactant gas contained 3 percent SO2, 6 percent CO, and the balance He. SO2 conversion was determined for three different types of catalysts. The first consisted of 16 commercial catalysts used for various chemical syntheses. Only the commercial catalysts which contained transition metals in alumina removed more than 30 percent 80a at temperatures below 510° C. Two other types of catalysts were prepared in the laboratory either by pelletizing equal amounts of powdered alumina and transition metal oxides or by impregnating commercial alumina tablets with transition metal ions. Regardless of preparation techniques, Cr and Fe in alumina were the two best catalysts. The observed results suggest that an intermediate (SCO) is formed by the interaction of surface metal sulfides and carbonyls. Alumina then catalyzes the interaction of SCO with S02 to form the end products (sulfur and carbon dioxide). Over 80 percent S02 was removed at 460° C with 2 grams alumina impregnated with 2.5 percent iron.

Jan 1, 1972

By Charles H. Parr

A testing program was conducted to determine the suitability and reliability of adhesives and polycarbonate lenses for extended use in luminaires in mine environments. Polycarbonates were exposed, for periods up to 36 months, to four environments including ultraviolet light, humidity, intermittent water spray, and heat of either 180°F or 407 in various combinations. Rod impact tests on the exposed lens material indicated, that polycarbonate functions well under all 180°F environments and could be used with confidence for periods exceeding the test period, for as long as ten years, with a suit) able safety factor employed in design. The specimens exposed at 240°F showed decreased toughness after 24 months' exposure. Extrapolation of these data was deemed to be risky. A 462-day compatibility test between polycarbonate and six hydraulic fluids was run on stressed PC beams. One fluid caused beam breakage in less than one day, while three caused breakage at intermediate times. Two fluids exhibited essentially no effect on the PC when compared to a control. Epoxy and silicone adhesives were tested as lens adhesives and sealants. Three epoxy combinations tested showed low and erratic failure stresses. A room-temperature-cure silicone adhesive functioned extremely well for time periods up to 36 months and temperatures u2 to 240°F.

Jan 1, 1985

By P. M. Sullivan

Galvanizers' sal skimmings have been treated by two methods of leaching in attempts to produce preflux solutions suitable for use in galvanizing operations. Both water-leaching and acid-leaching procedures are effective, except in severely exhausted skimmings when water-leaching becomes impractical. A preliminary analysis of the skimmings is not required. Solutions in the recommended concentration range can be produced conveniently by control of pH, specific gravity, and chlorine content. A technician would require only a short period of training to be able to perform the operations described.

Jan 1, 1958

By H. C. Carpenter

Lignite tar made by low-temperature Lurgi-Spülgas carbonization of North Dakota lignite was hydrocracked in single-pass, fixed-bed operation at 3,000 pounds per square inch over cobalt molybdate catalyst to produce gasoline, and at the same pressure, over zinc chromite catalyst to crack the high-boiling phenolic compounds to low-boiling phenolics. Hydrocracking the raw tar or the creosote-oil fraction from the tar over cobalt molybdate removed most of the oxygen, sulfur, and nitrogen in the forms of water, hydrogen sulfide, and ammonia, and produced gasoline yields from 31 to 59 volume-percent. The gasoline fractions contained from 0.1 to 7.7 volume-percent tar acids, but tar-base percentages were too low for reliable measurement; removal of these materials with dilute caustic and acid solutions also reduced the sulfur and nitrogen to 0.01 weight-percent or less.

Jan 1, 1963

By R. J. Pokora

This Bureau of Mines report is an applications manual that can be used by the nonmetallic mining industry for guidance in installing noise control materials into crushing and screening plants. These noise control modifications were installed and successfully tested at three operating quarries. This report identifies the major noise sources that can be encountered in crushing and screening plants, and discusses the applicable noise control materials and techniques that a plant operator can utilize on a retrofit basis to reduce equipment noise.

Jan 1, 1984

By B. C. Parks

This is the first of a series of reports on the relation between microscopic composition and chemical and physical properties of banded bituminous coals. It describes the relation between microscopic composition and behavior during thermal decomposition of a heterogeneous, high-volatile A bituminous coal from the Chilton bed in West Virginia. The standard free-swelling test was used as a simple means of studying the effect of heat on the coal. Although swelling indexes are not precise indicators of coal behavior in the coke oven and have limited value in caking investigations, they are reliable for predicting expansion of coal in a fuel bed and have practical value in the study of fuels. The swelling test also supplements other useful laboratory tests for determining the plastic and expansion properties of coal.

Jan 1, 1957

By R. W. Smith

The Bureau of Mines has been engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies were designed to provide basic thermodynamic information of high accuracy, facilitating the theoretical study of flame and combustion phenomena.4 This report is the fifth of a series5/ presenting results of the study for particular fuel-oxidant systems. These calculations have as their objective the constant pressure flame temperature of acetylene-air for a range of pressures.

Jan 1, 1954

By Thomas J. Peters

The King Mountain study area is centered about 120 air km northwest of Blackfoot, and 30 air km north of Arco, Idaho. The study area makes up the southern one-third of the northwest-trending Lost River Range--the highest mountain range in Idaho. The area is predominantly underlain by Paleozoic-age marine limestone and lesser dolostone, with a relatively small inlier of silica-rich, Ordovician-age quartzite. There are vast, unquantified resources of these industrial minerals present; however, special markets need to be developed for these resources which are near enough for transportation costs to be competitive. Five prospects were found in the study area; however, only one, the Elbow quartz silica prospect, contains resources and current claims. There has been no mineral production in the study area.

Jan 1, 1993

By P. L. Sibrell

The U.S. Bureau of Mines has tested cyanide leaching for recovery of palladium (Pd) from spent petroleum processing catalysts. Three different catalyst samples were supplied by a spent-catalyst processor. These catalysts consisted of a zeolite base and contained 0.4 to 0.7 pct Pd. During alkaline cyanide leaching, the catalysts exhibited ion-exchange properties due to their zeolite matrices. Hydrogen ions were released from the zeolite in exchange for sodium ions in solution, resulting in a significant decrease in solution pH. This could present a safety hazard because of the potential for release of toxic hydrogen cyanide gas. A pretreatment step where the catalysts were contacted with a 1.0M sodium hydroxide solution was found to prevent the pH shift from occurring. Following the sodium hydroxide pretreatment, two stages of leaching at 160 °C with solution containing 1 pct sodium cyanide and 0.1[M] sodium hydroxide gave at least 75 and up to 95 pct Pd recovery. The Pd was quantitatively recovered from the leach solution by thermal decomposition in an autoclave at 250°C for 1 h. The Pd content of the precipitate was over 50 pct. Thermal decomposition also decreased the total cyanide content of the barren solution to less than 0.2 mg/L. The catalyst leach residues passed the Federal Toxicity Characteristic Leaching Procedure and the California Waste Extraction Test, indicating that landfill disposal of the leach residues would be acceptable.

Jan 1, 2010

In 2005, a total of 263 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining commodity sector, comprising 1.8% of all mining operations. ? Gold mines comprised 46.0% (n=121) of all metal mining operations. Other common types of metal mines were iron ore (n=32; 12.2%), copper ore (n=31; 11.8%), and lead and/or zinc ore (n=16; 6.1%). ? Nevada had the largest number of metal mines (n=52; 19.8%), followed by Alaska (n=27; 10.3%).

Sep 1, 2008

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By E. C. Baker

Costs of disposing of steel slag are estimated based on the present method and a proposed alternate method for a steel mill in the Pittsburgh area. Estimated cost data were calculated by the Bureau of Mines and do not reflect the investment and operating costs and credits of a specific steel mill and processing plant. The alternate method of steel slag disposal would result in an appreciable cost savings to the mill and concurrently supply the industrial and commercial markets with low-cost, high-quality construction materials.

Jan 1, 1970

By Floyd G. Anderson

This report reviews and summarizes information on prevention and suppression of dust in mining, tunneling, and quarrying published in the United States from 1961 through 1967. Unpublished pertinent data developed or assembled by the Bureau of Mines during this period also are included.

Jan 1, 1969

By Lowell Stroud

A windowed-cell phase equilibrium apparatus was used to obtain equilibrium vapor- liquid data for a helium-bearing natural gas (Hogback) at temperatures from -100 to -250° F and pressures to 500 psia. Anomalous phase behavior resulting in the formation of two stable liquid phases occurred at tmperatures below -200° F and pressures above 200 psia. A review of the published literature on the occurrence of multiple-liquid phases included in the report indicates that the experimental results with Hogback gas are the first substantiated evidence of a vapor-liquid-liquid equilibria in a helium-containing natural gas.

Jan 1, 1963

By Michael J. Friedel

The integrity of mine structures, such as the roofs, ribs, face and supporting pillars, is difficult to assess beyond the exposed surface. To mitigate potential rockfall hazards, the U.S. Bureau of Mines is assessing the usefulness of Rayleigh wave dispersion analysis to detect damage and stress-relieved zones in mine structures. Classical surface wave dispersion modeling is utilized at both laboratory and field scales in damaged and undamaged material to assess the integrity of a mine pillar and roof. To more fully exploit Rayleigh wave propagation characteristics, derivation of a novel dispersion parameter was conducted using a convolutional model. The development of a suitable Rayleigh wave dispersion system based on insight derived from forward modeling is presented. The application of inverse modeling for damage and stress assessment in the mine environment is also discussed.

Jan 1, 2010

By G. M. Kintz

From 1895 to 1932, inclusive, 1,0163/ men were killed in and about New Mexico coal mines. Of these, 473 (approximately 47 percent) were killed in the 17 explosions listed in this paper. The second largest explosion of record in the United States, in so far as fatalities are concerned, occurred in New Mexico. The data in this circular were taken from publications of the United States Bureau of Mines and published annual reports of the State inspector of coal mines of New Mexico. The tables included are complete only with regard to major disasters. The Bureau of Mines considers as a major disaster one in which 5 or more men are killed. A few minor disasters are included, however.

Jan 1, 1934