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By Chen Xia

Iron separation from rare earth elements has always been an essential operation in almost all steps of rare earth element recovery and purification processes. As RE3+ and Fe3+ behave similarly in many operations the separation can sometime be either difficult or cost-inefficient. This article attempts to review the methods and options for removing the iron content within the process, with the focus on the existing or proposed precipitation and solvent extraction technologies. The precipitation of iron from REE solution as iron hydroxide, jarosite, goethite, hematite, or phosphate are briefly introduced. Methods for precipitating REE from solutions leaving iron impurities in the aqueous phase are discussed. Some proposed solvent extraction flow sheets for separating iron from REE are conceptually reviewed in this article.

Jan 1, 2013

By T. Johnson

Hydrometallurgical processes can be exceptionally corrosive. This is particularly true in acid leaching processes for copper, cobalt, nickel and rare earth elements. In the last five years, several large hydromet plants have been built in North America (Vale - Long Harbour, Baja Mining ? El Boleo and MolyCorp - Mountain Pass). Hundreds of storage tanks, extraction vessels and electrowinning cells along with miles of piping were designed and fabricated to withstand the aggressive environments inherent in these processes. One key element all three projects had in common was the extensive use of FRP in equipment design. As a material of construction, FRP provided equal if not improved durability relative to alternative corrosion resistant alloys at a considerably lower cost. This paper will highlight the extensive use of FRP in these three world scale projects and why it was chosen for each process.

Jan 1, 2013

By A. D. Dalvi

With the current economic situation, the demand for nickel and other base metals has fallen significantly. More than 440 kt/yr world nickel capacity has been taken out of production within the last year, or more than 25% of the total [1]. This situation is similar to that at the end of 1970?s and it will take a number of years for the demand to recover to the levels before the economic downturn. In the meantime, the challenges facing the industry have increased due to diminishing ore grades, more inaccessible and complex deposits, mounting capital and operating costs and the various external pressures which include socio-economic, environmental, and energy challenges. All industries will be faced with paying the ?total ownership costs? in the future. This will only increase the burden on the industry. How to cope with this in what Thomas Friedman calls the ?Energy-Climate Era? [2] will be the most pressing challenge for the next generation of metallurgists and managers. It will force us to take a broader view of the problems and the solutions beyond mere technical. The metallurgists, engineers and project managers will have to look at the overall projects and their objectives in designing the solutions, requiring a top-down strategic approach.

Jan 1, 2009

By L. J. Cabri

The metallurgical response of platinum-group element (PGE) ores to conventional grinding and bulk flotation is driven by (a) the distribution of PGE as discrete platinum-group minerals (PGM), (b) the speciation of PGM, and their size range, (c) the deportment of PGE in host sulphides and (d) the degree of alteration of the host rock. Accordingly, characterising such materials is a complex exercise, and a challenge to the applied mineralogist. In a recent case study, we will describe how PGM balancing using gravity pre-concentration and SEM techniques, automated mineralogical analysis of host sulphide and non-sulphide minerals, and analysis of host sulphides using LAM-ICPMS (laser ablation microprobe -inductively coupled mass spectrometry) were integrated to characterise such PGE-bearing materials. We also describe how these data can be used to predict likely metallurgical response.

Jan 1, 2009

By C. Walker

Since the 1950's, production of ferronickel from laterites has predominantly been achieved using the Rotary Kiln -Electric Furnace (RKEF) process. The productivities of kilns and furnaces have increased steadily over the years and metallurgical smelters can now rely on a smaller number of high-powered, reliable units to meet production objectives at much lower capital and operating costs per tonne of production. Modem RKEF plants are characterized by one or more process lines consisting of one large kiln feeding one large furnace. The current benchmark is one RKEF line with a high capacity kiln feeding an 80 MW furnace to process approximately 1.3 million tonnes per year of new laterite ore. It is proposed that a single RKEF line comprising one kiln producing 240 t/h of calcine feeding a 120 MW furnace could process 2 million tonnes per year of dry new ore which, for an ore grade of 2% nickel, is equivalent to 36,000 t/y of nickel per line. The plant could also be twinned to double the capacity to 72,000 t/y of nickel. This paper reviews recent developments in kiln and furnace technology, which enable substantial increase in productivity of an RKEF plant. The reduction in the capital and operating costs of a single-line, 2 million tonne of ore per year nickel laterite facility, and accompanying improvement in energy efficiency and environmental performance compared to existing operations, are also highlighted.

Jan 1, 2009

By D. G. Tisdale

A pilot plant was installed and operated at the Xstrata Nickel Sudbury Smelter 10 demonstrate the CANSOLV SO2 Scrubbing System. A 350 m3/h slipstream (through a 10cm pipe) was drawn from two different industrial gas streams to test the performance and robustness of the scrubbing system. The system achieved high sulphur capture, typically above 99%, and proved tolerant 10 varying gas strength and dust content in the feed gas.

Jan 1, 2009

By Mark Kennedy

New technology projects, particularly those involving first-of-a-kind metallurgical facilities, have a poor track record of achieving their overall financial targets, as they incorporate technological risks in addition to normal project risks. Traditional project management tools focus on risk from concept development through implementation, but typically fail to address the additional risks associated with a new technology project including slow start-up, slow ramp-up, and failure to achieve design performance (quality or throughput). These additional risks affect future cash flows produced by the project and hence its value, typically measured as net present value (NPV) or internal rate of return (IRR). Common accounting practice is to reduce the present value of future cash flows by applying a chosen discount rate, often reflecting the corporation?s cost of capital. This discount rate does not contain an allowance for technological risk, which is often underestimated or misunderstood by both the financial and engineering project managers. This paper will focus on the topic of project risk and new technology, and how these play a role in the probability of achieving the predicted future cash flows. By properly addressing technological risk in the form of risk-weighted returns, marginal projects can be prevented from proceeding, while sound projects can be given the additional time and resources required to achieve the optimal level of front-end-loading (the level which returns the maximum risk-weighted net present value). A simple set of mathematical tools should enable engineers and financial professionals to establish a common level of understanding, thereby leading to a more accurate assessment whether a new technology project is ready to pass through its next level of approvals.

Jan 1, 2013

By Roderick Guthrie

Three regimes of bubble formation in liquid metals, in terms of the mechanisms of bubble formation are reviewed. Towards this, bubble formation for a horizontal nozzle submerged in liquid pig iron was re-examined, for which an empirical correlation had been developed, correlating bubble size with gas flow rate, liquid metal surface tension, nozzle outer diameter and the capacitance number of the gas delivery system. Very good agreement between predicted and measured bubble size was obtained for non-wetting, ceramic-liquid metal systems. However, the question of how to create much smaller bubbles than those generally formed in liquid metals according to that work, is critically important. One method could be to create a submerged gas injection system by passing the gas entering the liquid metal through a narrow slot nozzle and make use of Rayleigh-Taylor instabilities. Ralph Harris has provided us with evidence to suggest that a carefully designed slot nozzle might serve as a candidate to create very small bubbles in liquid metals.

Jan 1, 2013

The NorthMet deposit of PolyMet Mining contains a large reserve of copper-nickel-cobaltprecious metal mineralization. Historically it has been difficult to recover separate copper and nickel concentrates of a quality broadly acceptable to custom smelters using conventional mineral processing techniques. Recently, improved flotation methods have made it possible to produce separate and saleable concentrates which will be produced during initial startup of the NorthMet deposit and construction of the PLATSOL TM hydrometallurgical plant. After the initial transition period, it is planned that production of a bulk flotation concentrate will be followed by PLATSOL TM hydrometallurgical treatment to produce copper, nickel/cobalt and precious metal products. The PLATSOL TM process uses chloride-assisted total pressure oxidation treatment of a bulk concentrate to digest the base and precious metal content of the bulk concentrate into an autoclave solution. Following solid-liquid separation, the solution is then treated sequentially for precious metal recovery by reductive precipitation, copper solvent extraction and electro winning and finally, nickel and cobalt recovery by precipitation. During the pilot plant testing of the PLA TSOUM process for NorthMct bulk concentrate treatment, two variations on nickel and cobalt recovery were tested including mixed hydroxide precipitation with magnesia and separate nickel and cobalt hydroxide precipitation following solvent extraction separation with Cyanex 272. The results of the pilot plant testing of the nickel and cobalt recovery circuits for NorthMet arc presented.

Jan 1, 2009

In view of the increasing environmental regulations that have been promulgated all over the world in the last 30 years, non-ferrous smelters and refineries have learnt and adapted to treat effectively metals'-containing process waste streams that need to be bled from the plant. However, anions such as sulfates, chlorides and fluorides-presently not a major problem ?are coming under increasing scrutiny and need to be addressed in the near future. The current paper reviews options for waste water treatment with reference to: a) types of waste streams processed b) process chemistry c) discharge options d) recovery and reuse of water and e) solids disposal. Methods to obtain zero liquid discharge ?a possible solution to eliminate discharge of above anions and residual heavy metals- are discussed with case studies. The long term goal of any non-ferrous smelter plant should be to have a zero liquid discharge philosophy-an approach that would become an epitome of water reuse and conservation.

Jan 1, 2009