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By Henry Brehaut

"It is difficult to know how much environmental information is absorbed by those in a position to put it to use. The following information may seem like ""old stuff"" to those whose companies are taking steps to improve their environmental performance. This paper is directed in particular to those people who are interested in determining what further changes are required to make improvements as concerned environment citizens.IntroductionUntil recently, the author was comfortable with the fact that none of the operations for which he was responsible had any environmental charges against them. It was not until one of his operations was charged with non-compliance that the author discovered due diligence as a way to avoid a second charge, and when an unfortunate spill occurred at another operation, the meaning of risk prevention was learned. Knowledge was gained step by step to the point where finally environmental information is being heeded, rather than waiting to learn from sad experience. With the appreciation of what it takes to do a good environmental job, comes an understanding of the challenge that lies ahead, and the fact that there is a lot to learn.At a recent environmental gathering, comments from the participants varied considerably. Some just didn't understand why government was being so unreasonable, while at the other end of the spectrum one individual whose company was well along the path to becoming a good environmental citizen remarked that it was all very basic. What was immediately understandable to one went right over the heads of others, indicating the different stages that have been attained in the acceptance of environmental responsibilities."

Jan 1, 1991

By Raja V. Ramani, Sukumar Bandopadhyay

"The dispersion of diesel contaminants into the mine atmosphere is a variant of general class of diffusion-dilution problems relevant to underground mining practice. The equipment operations in underground mining are characterized by different activities with different time duration s, i.e. varying duty cycles. Therefore the volume and quality of diesel emissions and consequently, instantaneous concentrations are quite variable. Design of mine ventilation systems under these conditions becomes complex. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport in the design of ventilation system are discussed.IntroductionThe turbulent diffusion of suspended matter in an atmosphere is not only a topic of considerable intrinsic interest to the mathematical physicist and meteorologist, but also a problem of great practical interest. Release of particulate matter into the atmosphere at large has created o ne of the acute problems of the present day. Pollution of environment by industrial and domestic smoke, fumes and grit is widespread and has necessitated extensive studies in order to determine the concentration and distribution of pollutants in various areas. Pollutants discharge from stacks, whether chemical or radioactive, give rise to similar, but more localized, problems. The laws which govern turbulent diffusion in the atmosphere are also applicable to the study of the diffusion of toxic gases and the deposition of radioactive dust from nuclear explosion.The dispersion of diesel contaminants into the mine atmosphere is but a variant of a general class of diffusion-dilution problems relevant to underground mining practice. Most of the mine air pollutants, such as respirable dust, methane, diesel exhaust, and blasting fumes are produced in the face areas and haulage ways. Understanding of their dispersion in the mine airways is important to calculate their concentrations. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport are discussed. The over-all objective of this research effort is to evaluate the impacts of dieselization on production and ventilation systems and to aid in mine planning and design, as shown in the flow model in Figure I."

Jan 1, 1983

By G. J. Desroches

"In order to improve zinc plant productivity, areas of low efficiency were identified. As a result, solution purification was improved, additional dust precipitator capacity was made available and a new zinc casting plant was installed. The effects of these and other changes are discussed and the expenditure and benefits reviewed. HistoryThe operation of the Flin Flon metallurgical complex including an electrolytic zinc plant commenced in October 1930. The design of the zinc plant was based on that of the Commonwealth Mining and Smelting Company at Trail, British Columbia, the Anaconda Great Falls Montana Plant and the Electrolytic Zinc Company plant at Risdon, Tasmania.The plant began with a design capacity of 60 tons per day and currently produces 255 tons per day. Since plant start-up, approximately 3.5 million ton s of zinc metal have been produced, most of it exceeding special high-grade specifications.IntroductionThe facility incorporates the basic process steps of roasting, leaching, purification, electrowinning and casting. Figure I details the flowsheet. During the late 1970s, management recognized that in order for the zinc plant to continue operating, it was necessary to introduce cost-effective practices.Study groups, consisting of design engineers and operations personnel, were formed to investigate the details of plant revisions.The objectives were to improve productivity by reducing manual labour, reducing energy usage, increasing zinc recovery, increasing metal output and reducing costs.This paper details the changes made during the period 1979to 1986 and shows how these changes have affected the productivity and economics of the zinc plant operation."

Jan 1, 1988

By P. Venkatasubramanian

"In recent years, computer based ""expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts requiring empirical knowledge, judgment, experience, developing a ""best solution "" by the use of plausible reasoning. Mining method selection is an appropriate area for the application of an expert system because extensive and detailed knowledge is required to make a ""best"" interpretaion of frequently ambiguous geological information. The expert system model presented here would enable users to apply expert knowledge to the evaluation of methods for coal deposits mineable by underground methods. IntroductionIn an increasingly complex and specialized world, human expertise spanning scientific, economic, social and political issues plays an increasingly important role in all branches of engineering. This is especially true of mining engineering. The number of scientific and professional disciplines involved in mine planning and evaluation, illustrates the problem. A conservative list includes geology, geophysics, geotechnics, hydrology, mining, environment, and economics.Engineers are almost obliged to be experts in at least one of the above disciplines if they are to handle the volume of information required in the planning process. Although computers have become indispensable tools in many endeavours, there is continued reliance on the human expert's ability to identify and synthesize these diverse factors, to form judgments, evaluate alternatives , and make decisions . This is especially true with regard to problems that are not easily amenable to precise formulations.The precious resource of human expert is also fragile and transient. The departure of a crucial expert from an organization ma y cause serious dislocations. Senior experienced people impart their knowledge of younger colleagues, but the demand for their talent may not leave sufficient time for such educational efforts. In recent years, computer based "" expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts, requiring empirical knowledge, judgment , experience, developing a ""best solution"" by the use of plausible reasoning."

Jan 1, 1988

By S. K. Paul

"This paper briefly describes the underground crushing and conveying system at Sherritt Gordon Mines' Ruttan Mine. A series of three steel-cord belted conveyors, with a total length of 2J55 metres and a total vertical lift of 407 metres, convey the muck from the underground crushing station to the mill at the surface. The maximum size of the crushed rock is 6 in. All the conveyors are provided with numerous safety and fire suppression devices. IntroductionThe Ruttan Mine of Sherritt Gordon Mines Limited is located 20 km east of the town of Leaf Rapids, 760 km north of Winnipeg. The orebody is multilensed, with lens width varying from 6 to 45 m. Ore production started in 1973 with the opening of a 10,000-tpd open-pit mine. Initial development of the underground mine was started in 1972 with the driving of parallel conveyor and access declines at minus-2507o gradient to the I 220-m level, and then the access ramp was further extended to the 1160-m level. Exploration drifting was done on the 1280-m and 1160-m levels from the access ramp. The final development plan for the underground project was approved in January 1977, and full-scale development and constructionwere resumed.At present, Ruttan Mine is in a period of transition from open-pit to underground mining. Ore production is now coming from both operations. By mid-1980, open-pit production will cease and all production will come from the undergroundmine.The underground mining method at the Ruttan Mine is sublevel open stoping with delayed backfilling. The orebody is divided along strike into a series of 27-m-long stopes and 15-m pillars, both 60 m high."

Jan 1, 1980

By O. Garg

This paper summarizes the computer applications in open-pit mine planning at the Iron Ore Company of Canada (IOC). A brief history of the use of computers at IOC is given, and a description of the existing facilities is outlined. The following systems are discussed: storage and retrieval of geological data; geotechnical data analysis; long-term grade and tonnage forecasting; ore grading; and open-pit mine design. Justification for using computers in open-pit mine planning is given, and possible future areas of application are considered.

Jan 1, 1979

By D. Pearcey, S. T. Vessey, V. Hegde, J. Staples

"Pellet quality has taken on a new dimension during the last ten years. Quality in the seventies was generally defined as adherence to certain physical and chemical specifications. Today, the talk is in terms of how the business is managed, how customer's expectations can be exceeded, not only in product quality, but in service responsiveness.Coke breeze and flux additions, lower silica levels, and improved furnace control practices have all contributed to the improvement of pellet physical and metallurgical properties. Statistical process control has provided additional insight into the parameters that affect pellet quality.Increased customer contact and product quality surveys have heightened our awareness of customer needs and also provide direction for quality improvement test work. Current work is focussed on improving reducibility and understanding the relationship between tumble, fired compression and metallurgical properties.This paper will review the Iron Ore Company of Canada's efforts during the past decade and describe some of its initiatives for the future.IntroductionThe Carol Pellet PlantThe Iron Ore Company of Canada's Carol Project is located in Labrador City in the southwestern portion of Newfoundland and Labrador , approximately 965 Ian northeast of Montreal. The project consists of mining facilities, beneficiation complex and a pellet plant, which began operations in 1962. The pellet plant consists of six Dravo-Lurgi straight grate machines, regrinding, filtering and balling facilities. The current capacity of the Carol pellet plant is approximately 10.5 million tonnes , while the concentrator has the capacity to produce about 18 million tonnes of concentrate.The orebody consists of specular hematite, magnetite and small quantities of limonite and goethite. The average grade of the orebody is approximately 39% iron."

Jan 1, 1991

By Grant L. Anderson, Richard C. Rice, Richard L. Jentgen

"Data for underground mine-hoist ropes determined in the Ontario Special Rope Tests were obtained, encoded and analyzed statistically. Prior 10 refined statistical analyses, these data were subjected la characterization studies and preliminary analyses to allow trends to emerge that could be used to guide and facilitate the refined analysis. The data were characterized by determining distribution s for a wide range of variables including remaining strength, service life in terms of lime and hoisting cycles, outer-wire torsion values, elongation during tensile testing, diameter reduction, location of strength loss and the strength lasses associated with corrosion rating and lubrication rating , This paper describes the more important relationships between remaining strength (or, conversely, strength loss) as the dependent variable and some of the principal independent variables mentioned above.IntroductionBoth productivity and safety in underground mines could be improved if mine-heist rope Iife and reliability could be predicted more accurately . As a result, hoist-rope failure processes and their effects on rope life and remaining strength need to be quantified and related in such a way that improved retirement criteria can be developed. This is true whether the failure is incipient or actual or whether the failure mode is by corrosion , wear, fatigue or a combination of these factors."

Jan 1, 1984

By M. W. Mikhail, R. J. Mikula

"Funding has been made available through the National Energy Program to build a mobile fine coal treatment plant. The plant is intended f or field application and also to upgrade the existing pilot plant facilities.Western Canadian coals with high proportions of fines (due 10 their friability) cause high losses of fine coal to the reject and in turn reduce the over-all recovery of saleable coal. Eastern Canadian coals with high amounts of sulphur of ten require crushing to fin e sizes to liberate pyrite and therefore need effective and efficient separation of these fine sulphur particles. The difficulties involved in solving these problems are two-fold. One is the reluctance to experiment in an operating wash plant and the other is that laboratory scale testing often cannot be extrapolated to the plant environment. The mobile fine cleaning plant with its ability to operate at existing coal preparation plants across Canada and with its flexibility in implementing flowsheet option s and close monitoring of fine coal circuit variables, is ideally suited to solve these fine coal cleaning problems. The mobile plant objectives are to design and optimize flowsheets, evaluate and improve fine cleaning circuit operations and 10 lest new process monitoring and control equipment.The schedule for construction and the required resources will be outlined along with flowsheet options and the general R&D philosophy of the mobile plant.IntroductionIn relation to coal preparation technology, Canadian coal s can be grouped as Eastern coal, Rocky Mountain metallurgical coal and Foothills high volatile bituminous coal. The eastern coals have high sulphur contents and in some cases require crushing or even grinding to liberate the fine pyrite . Rocky Mountain metallurgical coals often occur in highly sheared seams which have been subjected to rapid coalification. The high friability of these coals means that degradation during mining, handling and processing is extensive and results in large amounts of fine s ranging between 20 and 60% by mass of the wash plant feed. The widely varying geo logical structure and exposure to the elements results in partially oxidized coals which perform inconsistently in the traditional method of fine cleaning by flotation . Foothills high volatile bituminous coals for thermal use are frequently interbedded with soft shales and bentonitic clays. These clays disintegrate during washing and swell, producing large volumes of tailings. The presence of clays in plant circuits, particularly fine circuits, tends to increase the viscosity and may cause deterioration of the fines density separation and increase magnetite losses. In view of the fact that fine coal cleaning is the most difficult aspect of coal preparation , a research program is being established to study the factors involved and to offer some solutions.A recent performance evaluation of Canadian washeries showed that yield losses in the minus 2 mm coal circuits were approximately ten times those occurring in the coarse coal circuits(1). Because 2 mm x 0 coal represents 30 to 70 per cent of the raw coal, these losses can be considerable . The operating and capital costs of beneficiating minus 6 mm coal are about four to five times higher than for plus 6 mm coal. In the case o f minus 2 mm coal the costs are even higher. The economic importance of the fine coal cleaning cannot be over emphasized and as a result, the CANMET R&D program is geared for fine coal beneficiation."

Jan 1, 1984

?NWCC has the highest number of Aboriginal students of any post secondary institution in BC and the region served includes 25 bands ? Chair of the Board of Governors is Irene Seguin (Hagwiloo K?am Saxwhl Giis) from Gitwinksihlkw ? FN council ? 39 First Nations Members * focus is to develop policy recommendations to increase student success rates

May 1, 2009

By P. J. Urso

"This paper discusses the mining problems encountered at the Fording River coal mine to date, and how they have been solved. All of the production now comes from surface mining, but underground hydraulic mining is planned and briefly described. Other facets of the operation, including markets, equipment and personnel, are covered. IntroductionFording Coal Limited was formed in 1968 to mine and market metallurgical coal resources held by the company in the East Kootenay region of southeastern British Columbia. The company, at its Fording River operations, holds approximately 48,000 acres of coal lands, having an estimated 2.0 to 3.0 billion long tons of metallurgical coal in place. (Although not a point for further discuss ion in this paper, the company also holds approximately 1.0 million acres of mineral rights. These consist primarily of coal in Alberta, potash and coal in Saskatchewan, and minor industrial mineral holdings of limestone, salt and bentonite in the three western provinces.)Fording Coal is owned 60% by Canadian Pacific Investments Ltd. and 40% by Cominco Ltd. Inasmuch as Cominco itself is owned approximately 54% by CPI, it is seen that the effective CPI ownership of Fording is about 82%. The company, originally staffed and managed by Cominco, has been independent since January, 1978, with its own board of directors, management, staff and employees.The company's head office is in Calgary, Alberta. The Fording River operations are located approximately 45 miles north of the Crowsnest Pass, near the Alberta/British Columbia boundary, only 95 air miles and 200 road miles from Calgary.A contract was signed in 1969 with the Japanese steel mills to provide 45 million long tons of metallurgical coal over IS years, commencing in 1972 at an annual rate of 3 million long tons per year. Despite some start- up difficulties, the mine and plant facilities achieved their rated capacities in 1975, producing and shipping at the 3-million-Iong-ton level. The coal specifications are shown in Table I."

Jan 1, 1980

By Yu. V. Ponomarenko, A. I. Meka, P. A. Witherspoon, Yu. I. Volkov, J. E. Gale

"The mining of iron ore in the Kursk Magnetic Anomaly (KMA) region of the U.S.S.R. is done mostly by the open-cut method. An assembly of open pits capable of producing about 100 million tons of ore per year makes KMA the largest iron ore field in the world. Three gigantic open pits are currently in operation: Lebedinsky, Mikhailovsky and Stoilensky. These pits are as large as 13 km2 on the surface and as deep as 230 m. The mining operations are constantly faced with the problem of flooding from aquifers that overlie the orebodies; the magnitude of the problem is evident from the fact that the present groundwater inflow to these three pits is about 110 million mt /yr.Under such conditions, safe operations and pit wall stability are of great importance, and this has been accomplished very effectively by the appropriate use of seepage barriers and drainage systems. At KMA, the most important items used in the system of groundwater control are standard pumping wells, raise wells that drain into a 20 km to 30 km long underground drift located just outside the perimeter of the pit, horizontal wells driven through the pit walls, and horizontal drains. This paper describes the mining and engineering technology that have been developed at KMA to control the groundwater systems and protect the mines from flooding."

Jan 1, 1992

By Rae Simpson

"This paper provides insight into the elements of computerized maintenance systems and identifies some of the factors which influence their effectiveness. The paper describes what to expect in terms of benefits and problems, the nature of effective computerized maintenance systems, some of the systems available and a process for selecting a system for your organization.The paper will be of interest to mining company executives and maintenance or computer personnel who are involved with, or contemplating, the introduction of computerized maintenance systems.IntroductionIn the drive to improve profits in an increasingly competitive world, mining companies are now using some of the most sophisticated equipment available. The introduction of large and complex equipment such as drag lines, haul trucks, and high-capacity milling equipment has resulted in order-of magnitude improvements in productivity. However, this productivity is now, more than ever, dependent on the continued operation of the equipment. A prolonged breakdown of a critical component can have a significant effect on companies' bottom-line results. As more technologically sophisticated equipment is introduced, maintenance costs become an increasingly important factor for mining companies.Fortunately, sound modern management principles are being used more often in maintenance departments. Progressive maintenance managers are turning to computers to help manage the myriad of details associated with running a maintenance organization.Some maintenance departments in larger mining operations would find it difficult, if not impossible, to operate at current productivity levels without their computer systems. Unfortunately, some other companies gain very little from their computerized systems and would probably be better off without them.How can you be sure that computerized maintenance will improve the maintenance picture for your company? What benefits can you expect to achieve? How do you go about selecting a maintenance system for your organization? These are some of the questions facing industry managers and executives today. In the following sections, we will provide some guidelines and insights to help address these challenges."

Jan 1, 1988

By Ray Collier

MINING TODAY l EXTENSIVE AND EXPENSIVE PERMITTING PROCESSES WITH UNKNOWN RESULTS l GENERAL AND IMPASSIONED RESISTANCE TO RESOURCE BASED INDUSTRY l SOPHISTICATED, ORGANISED, AND WELL FUNDED OPPOSITION l MOST LOCAL GOVERNMENT DOESN?T WANT MINING TODAY?S TALK l FOUR SPECIFIC OPERATIONS ON WHICH OUR EXPERIENCE IS BASED ? SECHELT ? CADMAN ? GRANVILLE ISLAND ? LEHIGH CEMENT DELTA PLANT l OUR APPROACH TO COMMUNITY RELATIONS

May 1, 2002

By K. B. Chaudhuri, I. D. Webb, F. E. Rachor, F. A. Sauert

"A characteristic of all methods of copper concentrate smelting is that slags with a high copper content are produced at some phase of the operation. Recirculation to the smelting unit, electric furnace reduction or flotation are at present used on an industrial scale to recover the copper from these slags. This paper describes the application of the top-blowing technique, originally developed by KHD Humboldt- Wedag AG for refining of metallic copper, for the treatment of copper-containing slags. By this method, a mixture of a reducing gas and commercial oxygen is blown onto the melt at velocities which can be supersonic from the tip of a water cooled lance. The impingement of the reaction gas mixture on the surface of the slag forms a depression in the molten phase and a deflection of the jet which brings the slag into a rotating motion. This causes high rates of heat and mass transfer. Results of pilot-plant tests for batch and continuous treatment of slags are presented, and the potential applications of top blowing for industrial-scale operation are indicated. In combination with the cyclone as a smelting unit, this process appears to be economic for smelters of very low capacity."

Jan 1, 1980

By Takahiko Okura, Chiharu Tokoro, Shunta Shibuya

Copper concentrates bearing arsenic as enargite (Cu3AsS4) or tennantite (Cu12As4S13) have disadvantage on copper smelting environmentally and economically, so those concentrates should be treated decently. In this paper, some experiments of arsenic removal from several kinds of copper concentrates by heat treatment in an inert atmosphere were discussed. In this study, several samples in which arsenic contents varied 0.18 to 8.3 wt % were heated to the temperature range of 400 °C to 700 °C under argon gas flow during 1 hour. The heat residues and volatilized materials (V.M.) were analyzed by XRD, XRF, ICP-AES, XAFS and MLA to analyze residual concentration of arsenic and residual mineral composition. Experimental results showed that arsenic removal from copper concentrates advanced in 2 steps; at the temperature range of 500 ° C to 550 °C and of 550 °C to 650 °C, respectively. MLA analysis showed that a few of arsenic in enargite was removed by 550 °C heating and a majority of it was still combined with copper and sulfur as tennantite. On the other hand, arsenic in tennantite was removed almost completely by 650 °C heating. Furthermore, a particular type of arsenic mineral, such as Cobaltite (CoAsS) still remained after heating at 700 °C.

Jan 1, 2014

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By A. L. Holloway, N. M. Soonawala, L. S. Collett

"Since the late 1970s, a major R&D program has been under way in Canada to assess the concept of disposing of nuclear fuel wastes in deep plutonic rock. Atomic Energy of Canada Ltd . (AECL), a federally-owned corporation, has been given the responsibility of directing this research (Rummery et al., 1983).The Underground Research Laboratory (URL), constructed in a granite pluton 15 km east of Lac du Bonnet, Manitoba (Fig. 1) is a major component of the Canadian Nuclear Fuel Waste Management Program. A diverse geotechnical experimental program is being carried out during both the construction and operating phases of the URL. This program involves detailed geological mapping, rock mechanics and hydrogeology studies, and geophysical surveying, to characterize the rock mass surrounding the shaft, and it has been described by Simmons et al. (1983). As part of the construction-phase program, ground-penetrating radar (GPR) surveys are being carried out during excavation, in an attempt to delineate fractures both ahead of the excavation and behind the walls of the excavation. This paper presents the results of surveys performed during shaft excavation and describes a procedure for plotting the data.Ulricksen (1982) cites examples of radar surveys to evaluate surficial deposits, such as peat, sands and gravels, and cavity detection in subsurface hard rock. Fowler (1981) used radar for fracture and clay vein detection in coal seams.In Canada, pioneering work in GPR has been done by Annan and Davis since the mid-seventies (Annan and Davies, 1976). Their work concentrated on problems relating to permafrost in the Arctic ."

Jan 1, 1986

By D. W. Morgan, K. W. Downes

"OVER half a million tons of chromite ore is used annually on the North American continent, all of which is imported from overseas. Chromite is essential in the manufacture of stainless steel, armour plate, and tool steel, to mention only three important uses. It is, therefore, a strategic mineral, and every effort should be made to discover a means of utilizing our domestic supplies.Both Canada and the United States possess deposits of chromite, but they are low grade with respect both to their chromium content and to the ratio of chromium to iron. Mechanical concentration can improve the chromium content •by rejecting gangue, but chromium concentrate produced is still lower in chromium than imported chromite and, more important, the ratio of chromium to iron is only about half that in the imported material. At present, a chromium to iron ratio •of 3:1 is desired by industry. To obtain this .ratio in the case of domestic ores, a chemical attack on the chromi'e is necessary."

Jan 1, 1952

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988