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By P. Van Marcke, X. Sillen, G. J. Chen, I. Troullinos, A. Dizier, J. Leysens, X. L. Li, J. Verstricht

"In Belgium, Boom Clay is considered as one of the potential host formations for the disposal of the High Level radioactive Waste (HLW). The URL HADES at 223 m depth at Mol site was constructed in order to study the feasibility of HLW disposal in Boom Clay. Since 1995, the URL R&D programme has focused on large scale demonstration tests like the PRACLAY experiment.The PRACLAY in-situ experiments include a set of three tests: The gallery and crossing test, PRACLAY Heater test and PRACLAY seal test. The main aim of the Heater test is to study at a large scale the thermal impact of a HLW repository on the host rock. The test is housed in the PRACLAY gallery. A hydraulic seal, made of compacted swelling and low permeable bentonite annular ring was installed at the intersection between the heated and the non-heated part of the gallery. The primary objective of the seal is to provide undrained hydraulic boundary conditions for the Heater Test.The PRACLAY gallery was constructed in 2007 and the hydraulic seal was installed in 2010. The bentonite is hydrated by natural and artificial process. The swelling, total pressure and pore pressure of the bentonite are continuously measured and analysed by numerical simulations to get a better understanding of this hydration processes. The performance of the seal is tested systematically by means of gas injection breakthrough tests and permeability tests at interface bentonite / Boom Clay and in the Boom Clay around the seal.The PRACLAY Heater will be turned on at the end of Oct. 2014, since a sufficient seal swelling has been attained to fulfill its role for the PRACLAY Heater test. This paper will focus on the PRACLAY Seal test: How we understand the process behind the hydration of the bentonite and how we test the performance of the bentonite seal."

Jan 1, 2015

By D. L. Cramp

The Direct-Connected Electric Hoist In the latter part of 1931 a new electric hoist was installed at the Lake Shore mine. A number of interesting features were incorporated in this machine, which is the first direct-connected, direct-current-operated hoist to be placed in service in the Kirkland Lake district. Many factors requiring care and study enter into the selection of hoisting-engine drive. In this instance, conditions warranted the selection of the generator voltage control system (Ward-Leonard), utilizing a direct-current driving motor and a separate motor generator unit. It was further deter-mined that additional economies could be secured by the selection of a motor generator unit with a flywheel, and consequently the Ilgner-Ward Leonard flywheel set was adopted. Some of the advantages of this system are: 1) Greater accuracy of control, resulting in increased flexibility in hand-ling with increased precision and safety; especially desirable in large, important installations where the rope-speed is high or where frequent shifting is necessary. (2) Reduced energy consumption. (3) Feasibility of load equalization, without which, in some cases, the power system would be unable to carry the fluctuating load imposed on it by the operation of the hoist. ( 4) Elimination of reduction gearing in the construction of the hoist. The hoist is located on the surface and is used for skip operation at the main shaft, hoisting ore from a present maximum depth of 4,200 feet.

Jan 1, 1933

By David Penswick

Despite anecdotal evidence to the contrary, the mining industry is not in decline. Rather, the world?s largest mining companies are among the most consistently profitable companies in any industry. In many cases, profitable mining companies have been built around a few large scale, long life mines. These criteria for success ? size and long life ? have led to the current preference for deposits that can be exploited using open pit methods. However, developments in the science of block caving have resulted in this mining method achieving costs and productivities that are competitive with the largest open pits, while achieving widespread applicability. One implication of the low costs and widespread applicability of block caving is that some current open pits are possibly too deep.

May 1, 2003

By Euler De Souza, J. Daniel Stinnette, Julian Varaschin

"This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and of electric equipment and examines how they can be applied in determining reasonable ventilation rates for Tier IV compliant diesel equipment and for electric equipment operating in mining environments. Airflow calculations for modern diesel-powered equipment and for electric equipment are more complex and must be based on a combination of factors that are unique to each mine. Methodologies for ventilation rate determinations for each case are proposed in this paper.INTRODUCTIONTraditionally, airflow requirements for production and support equipment operating in underground mines have been determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations or determined empirically from known quantities. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is still a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. The question remains, what ventilation rates should the ventilation system designer apply for modern diesel equipment?Also, given the ongoing development of grid/battery-electric equipment and active construction of fully electric mines, it has become critical to determine adequate airflow rates per brake kilowatt of electric engine power. One of the most important criteria for determining ventilation rates for electric equipment is the amount of heat they generate, as this is the most significant emission produced by electric equipment (which do not produce exhaust gases or particulates). Therefore, ventilation rates required to dissipate heat from electric equipment must be suitably determined for all electric vehicle fleets operating in underground mines."

Jan 1, 2019

By B. Hart, D. J. Miller, J. T. Francis, M. C. Biesinger, Smart. R. St. C.

Diagnosis of the surface chemical factors playing a part in flotation separation of a valuable sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Time of flight secondary ion mass spectrometry (ToF-SIMS) can be used to identify sufficient particles of a specific mineral phase for reliable statistics determining a mean value for each species with 95% confidence intervals (1). Using the region of interest (ROI) facility in the Tof-SIMS software, a mass spectrum from each particle, at 1-2 monolayer sensitivity, is recorded and stored. This analysis is reported for a chalcopyrite / pyrite / sphalerite mineral mixture conditioned at pH 9 for 20 minutes in order to study transfer of copper from chalcopyrite via solution to the other two mineral surfaces since this mechanism can be responsible for their inadvertent flotation in copper recovery. Analysis from mineral selection based on specific ToF-SIMS signals (eg. Pb, Zn, Cu, Fe, Fe/Cu) indicated no statistical difference in the copper intensities on pyrite and sphalerite after this conditioning. Principal component analysis (PCA) of the ToF-SIMS imaging data identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from mass spectra recorded at each of 256x256 pixels in a selected area of particles. PCA is a better method of selecting minerals due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The method has been extended to samples from an operating plant again with excellent phase recognition and diagnostic surface chemistry.

Jan 1, 2004

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By H. A. Pearse

Introduction This paper may be regarded as another instalment of the story of the Britannia milling operation. From time to time in the past, articles (1) have been prepared by various members of the staff, giving details of crushing, grinding, and flotation treatment for the normal Britannia ore. It is not, therefore, the purpose of the present paper further to discuss what may be termed the standard milling operation, but rather to describe a flotation practice which has been evolved directly as a result of the general depression. The normal Britannia ore mixture contains chalcopyrite and pyrite as the main sulphide minerals, together with minor gold and silver values. The standard milling practice, evolved during several years of experimentation, provided for bulk flotation of the two sulphides after primary grinding to only approximately 35-mesh, followed by regrinding of the bulk concentrate, with subsequent separation of the chalcopyrite and pyrite to make a marketable concentrate of each mineral. However, in the face of a constantly increasing surplus of copper on the world markets and a steadily falling price during 1930 and 1931, it was obviously undesirable to continue producing large quantities of this metal at a loss. On the other hand, Company officials were very reluctant to add to unemployment by closing down entirely, provided operations could be continued without excessive losses. Fortunately, the existence was known of a fair sized body of ore, quite low in copper and relatively high in zinc content, with also a very considerably higher gold value than that prevailing in other sections of the mine.

Jan 1, 1934

By Michel Ruel, Ali Soltanzadeh, Benjamin Légaré

High fidelity commercial process simulation packages can be used at different stages of a greenfield project, from initial plant design to operator training in the later stages. However, there are several factors that make the software less attractive for small and medium size brownfield projects, such as the licensing cost and the fact-finding manpower required for model design and simulator maintenance. In this paper a different approach is described. The knowledge gathered from operating personnel was used to implement higher level models based on plant data, operating heuristics, and experience rather than detailed component-level models. The computing platform used was a low-cost, well-established, control system vendor-independent software. Throughout this paper we demonstrate the success of implementing this model-based approach using two industrial examples. The first example is a simulation of the carbon monoxide (CO) distribution system at a metallurgical complex. The purpose of this simulator was to test new control strategies and PLC programs prior to implementation. CO being a toxic combustible gas, validation of the suggested control system changes was necessary for plant safety. Simulation of specific operating conditions helped alleviate concerns and improved plant-wide acceptability of the new operating philosophy. The second example is a boiler simulator at a petrochemical plant. The operator training simulator (OTS) was designed as a platform for experienced operators to practice handling rare or abnormal conditions. A customized medium-fidelity model was developed for this targeted application where the cost of a full scale high-fidelity model could not be justified.

Jan 1, 2016

By G. W. H. Norman

"During the past few years emphasis has been placed on the importance of major faults, fault zones, and associated structures in localizing ore deposition. This interest has developed partly through experience in mining camps in other parts of the world, and partly by the discovery of such structures associated with ore deposits in the Abitibi region, northwestern Quebec. The recognition of these structures has been brought about chiefly by detailed mapping that has been gradually extended along most of the southern gold belt of Quebec and across adjacent parts of Ontario. In the Chibougamau region of northern Abitibi, progress has been made in mapping major faults by using aeroplane photographs with a scale of about 1,000 feet to 1 inch for field mapping. These studies have shown that many large faults occur in the Abitibi region; also that there is a relationship, direct or indirect, between faults and mineral deposition. The faults are, however, of more than one type and age, and this should be clearly appreciated in any planned programme for prospecting this great region adequately.Geology of the Abitibi RegionGeneral GeologyFaults of more than one age and type occur in the Abitibi region. In order to appreciate some of the age relationships of the faults, a brief summary of the historical aspects and major structural features of the geology (fig. 1) is necessary. These historical aspects may be briefly summarized in chronological order as follows:(1) Accumulation of Archæan lavas and associated pyroclastic rocks, either alternating with, or essentially followed by, deposition of sedimentary rocks, and interrupted at least once by local and perhaps regional folding and erosion."

Jan 1, 1954

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract - MEGATEMII airborne electromagnetic data collected over the Iso and New Insco massive sulfide deposits have been modeled using three modeling packages. The EMQ package is a quick inversion tool which indicates that the Iso body is a dipping, plate-like body. The New Insco body is inferred to have a geometry somewhere between a dipping plate and a sphere. The Maxwell package was used to refine the properties of the plate-like body at Iso. The EMIGMA package was able to identify which parts of the New Insco orebody were more conductive. It was observed that the most conductive parts correspond to copper-rich zones and the next most conductive to pyrite-rich zones. The EMIGMA package was also used to show that a thick-prism model might be more appropriate for the New Insco orebody. Gravity modeling constrained by the known geology was successful in identifying the denser sulfide zones. The densest zones appear to be pyrite rich. Magnetic modeling identified diabase dikes. Over New Insco, a small magnetic anomaly was attributed to pyrrhotite-rich sulfides. There was only a weak magnetic anomaly over the Iso body, consistent with the nonmagnetic sulfides logged in the holes drilled at that location. Sommaire - Les données MEGATEMII recueillies au-dessus des dépôts d’Iso et de New Insco ont été interprétées en utilisant trois outils de modélisation différents. L’outil EMQ a été utilisé comme un outil d’inversion rapide suggérant que le dépôt Iso peut être considéré comme une plaque inclinée, et que le dépôt de New Insco se situe quelque part entre une plaque et une sphère. L’outil Maxwell a été utilisé pour raffiner les propriétés du dépôt Iso. L’outil EMIGMA nous a permis d’identifier les différences de conductivité à l’intérieur du dépôt Iso. Il a été observé que la partie la plus conductrice correspond à la zone riche en cuivre, suivie par la zone riche en pyrite. L’outil EMIGMA a aussi permis de montrer qu’un modèle de prisme épais pourrait être plus approprié pour décrire le dépôt New Insco. La modélisation des données gravimétriques, contrainte par la géologie connue, définit bien la zone de sulfures massifs. La zone de pyrite semble être la plus dense. La modélisation des données magnétiques identifie bien les dykes de diabase. Au-dessus du dépôt New Insco, on observe une faible anomalie magnétique correspondant aux sulfures non magnétiques observés dans les carottes de forages à cet endroit."

Jan 1, 2006

By Mohamed Sassi, I. Kolo, R. L. Sousa, R. K. Abu Al-Rub, Manhal Sirat

"Fractures induced by folds are pivotal in hydrocarbon exploration, ground water transport and harnessing of geothermal energy. This is because of the need to predict and understand fracture propagation in reservoirs which have folded rock formations. Despite its prominence, there is a lack of reliable numerical models for simulating fractures resulting from rock folding. This is partially due to the difficulty involved in fracture modelling. As a contribution to fold-fracture modelling, this work applies a coupled plasticity-damage model to rock fracturing and anticlinal folds. Parametric studies on a single folded layer give insight into the fold formation and behaviour. The anisotropic continuum damage model which considers both tension and compression is formulated using the power damage evolution law. For ease in formulation, strain equivalence hypothesis is adopted whereby the strain is the same for both damaged and undamaged configurations. Lubliner plasticity yield criterion is adopted for plastic deformation. The model is coded in Abaqus user subroutine UMAT and is applicable to quasi-brittle materials.INTRODUCTIONThe understanding of fractures in the earth’s crust helps in the prediction, evaluation and characterization of fractured reservoirs, whether they are petroleum, geothermal or underground water reservoirs. This is partly because reservoir permeability and stability are dependent on fracture properties (Nelson, 2001). To achieve this, various approaches have been developed to analyze reservoir rock fractures. These could be grouped into (a) discrete approaches – where the rock mass is represented by a finite number of well-defined components and (b) continuum approaches – where the mathematical assumption of an infinitesimal element is made (Jing, 2003). Ivanova (Ivanova, 1998) comprehensively studied fracture systems in nature and highlighted folds as one of the major geologic settings that produce fractures. Naturally occurring folds in reservoirs sometimes compound fracture analysis. It might not be clear whether the fractures formed before, during or after rock folding. Fractures formed during the folding process are expected to show stress orientations related to folding and are thus of primary concern in rock folding simulation. It could be argued that there are no numerical models that as"

Jan 1, 2015

By Reginals W. Burroughs

Diatomaceous or infusorial earth, also called diatomite; fossil meal, or kieselguhr, is derived from the lowest form of vegetable life, the unicellular alga:. It consists of the siliceous remains of extremely minute aquatic plants, which exist in both salt and fresh water. Light i~ a prerequisite to their development. These very small particles secrete silica in much the same way that molluscs secrete lime to form their shells. The diatoms at death sink to the bottom of the body of water in which they lived, and the organic matter gradually decays and is washed away, leaving the skeletons. Thousands of years are required by this means to develop bed5 of sufficient thickness to be of commercial value. The siliceous remains vary in size according to the species, but all are very minute and, as a general rule, they can be identified only under a high-power microscope. Over one thousand types have been distinguished and named. They are all composed of a hydrous or opalescent form of silica, with silica content ranging from seventy to ninety-five per cent. Magnified, they present an attractive sight, a very fragile structure with many interstitial openings known as cells. Many of them consist of two parts, defined as valves, held together by means of a girdle. Certain species, belonging to the Pinnularia family appear as a long comb, in half longitudinal section. The spaces between the teeth are the cells. This particular genus is very common in Nova Scotian deposits.

Jan 1, 1928

By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By A. Hutwalker, T. Plett

"Blast fumes are one of the major sources for NOx in underground mines. In 2016, the Occupational Exposure Limits for NOx in Germany were reduced by 90%. The task is to keep re-entry times after blasting at the present level and thereby ensure an economic operation of the mine. Measurements show that using ventilation solely is not sufficient. A new approach to reduce NOx from blast fumes is described. Laboratory experiments were performed and a reduction of NOx was observed. Measurements were conducted at an explosive factory’s testing facility and in an underground mine at blasting operations. INTRODUCTION Whether for production of ore or for drift development, the processes in an underground mine are always the same: 1) fracturing the rock, 2) loading the pile, 3) support the resulting cavity. The fracturing of the rock can be done mechanically, by cutting, for example by using continuous miners or tunnel boring machines, or by drilling and blasting. Drilling and blasting is more flexible than mechanical driving, as it can be used independently of the rock strength. Furthermore, this driving method allows a more flexible reaction to changes in geological and/or operational conditions. Thus, underground mining and blasting are almost inextricably linked with each other, and regardless of the size and level of technology of the mine, blasting is hardly avoidable. Depending on the mining method chosen and the existing framework conditions, such as the mechanical properties of the rock or the availability of machinery, blasting is an integral part of daily operations. Even in mines where blasting is not part of regular operations, it cannot be completely avoided. The blast fumes generated by the explosions are, in addition to diesel engine emissions, one of the two main sources of emissions of nitrous gases underground. Up to now, state of the art for dealing with blast fumes is ventilation. The fumes are diluted with fresh air and ventilated out of the mine. This treatment of blast fumes is more than sufficient with the former German Occupational Exposure Limits (OEL). The adaption of the OEL in Germany to the recommendations of the Committee on Occupational Exposure Limits (SCOEL), a committee of the European Commission, leads to big challenges for the mining industry in reducing the concentrations of these gases at the workplaces underground. On its meeting on May 2nd and 3rd 2016, the Committee on Hazardous Substances (Ausschuss für Gefahrstoffe, AGS), an advisory body of the German Federal Ministry of Labour and Social Affairs (BMAS), advised the BMAS to copy the OEL, as recommended by the SCOEL, to the Technical Rules for Hazardous Substances (TRGS 900). BMAS followed this advice, consequently the new OEL where published on November 4th 2016 and became part of the TRGS 900. Table 1 shows the former and new OEL for Germany. These new OEL became law after publishing, but two exceptions were made: For tunneling operations, they became law on October 31st 2017, for mining operations they will become law on October 31st 2021 (BAuA, 2004, 2016, 2017)."

Jan 1, 2019

By S. Fabich

Since the very beginning of Polish copper mining, special consideration of sink shaft techniques through highly saturated Cenozoic rocks was required. Shaft freezing has been chosen as a method to consolidate these rocks. Due to the rock mass structure and water inflow potential, shaft sinking without freezing was considered dangerous. In the course of time, rock mass freezing technology and experience were evolved and this technology became safer and more reliable. New techniques appeared not only in the technical method of freezing, but also in the matter of designing. Computer aided techniques allow engineers to make a detailed analysis and view of freeze wall development. Nevertheless it is important to determine basic thermal rock properties. In this paper, the evolution of knowledge and engineering experience taken in Polish copper mines and current knowledge level in that matter were shown.

Aug 1, 2013

By W. G. McBride

The mining industry has already become highly technical in all its branches and this has brought about specialization in mining engineering. Increasing demand for mineral products, exhaustion of high-grade or easily worked deposits, and narrowing of the fields for exploration and development, are forcing mines to greater depth and to working material of lower grade and more complex composition. The Robinson Deep at its Turf shaft has reached a depth of 7,640 feet and expects to go to 8,500 feet; Miami Copper, under normal market conditions, profitably mines ore running only 16 pounds of copper to the ton; Alaska Juneau is making a profit on ore running about $1.15 per ton in gold; and many mines are handling ores of an extremely complex nature. In each case, the success of these operations has depended upon the application of sound scientific principles and good business methods to the problems involved. It may be safely assumed that mining at great depth and the exploitation of low-grade, or complex, ores will become more and more important as time goes on, and this means that greater and greater demands will be made upon the technical skill and business ability of the mining engineer. To meet this condition, the more or less haphazard methods of training the young engineer that have prevailed in the past will have to be replaced by a careful and well-ordered system of engineer-training. Upon the industry and the older mining engineer falls the duty of providing means to assist the deserving student to prepare himself properly to meet the increased demands that are falling upon his profession. Consideration of the training of the mining engineer involves a decision as to what constitutes his field of usefulness. Technical control of methods and processes obviously falls upon the engineer, but there are still many who doubt his usefulness in the executive field, particularly in positions involving close contact with the men and work. Many engineers have failed as shift-boss or foreman, but this has been generally due to fault in the management in using men who were temperamentally unfit to lead others or who lacked the necessary preliminary training.

Jan 1, 1932

By Ashley Tews

In 2005, we automated a forklift-based Hot Metal Carrier to be capable of typical metal transfer operations around a smelter. The project was highly successful and the vehicle has demonstrated hundreds of hours of live autonomous operations to thousands of people from industry and the public. As a result of the exposure and success of the project, we have expanded its focus to demonstrate how various technology components can be utilised to gain benefits in other areas of industrial operations. These include asset tracking, vehicle usage analysis, pedestrian detection and infrastructure profiling. Each of these components was derived from the core autonomous vehicle technology suite and has shown a high potential for improving safety and efficiency of vehicle-related operations, and improved diagnostic processes for measuring deformations of bakes and furnaces. The autonomous vehicle project and its extended technologies are described in this paper.

Aug 1, 2013

By K. E. Waters, J. E. Nesset, F. Rosenblum, J. A. Finch, S. Moon

"Some materials when exposed to various conditions can exhibit a rise in temperature without requiring an external heat source. Generally referred to as pyrophoric or self-heating substances, they challenge the safety of materials handling, storage and transportation. Reliably assessing the self-heating potential of materials is thus essential. Over the years a number of test protocols have been developed. A widely accepted method is that recommended by the United Nations to certify the safety of shipping pyrophoric goods. Our test work on sulphide materials has shown that the U.N. test can give false negatives if the sample oxidation history is not considered. Depending on the degree of oxidation (“weathering”), the same sulphide material can exhibit self-heating ranging from safe to hazardous. For concentrates, oxidation can occur during storage and transport making the sample weathering history an important consideration in the test work. To make the U.N. test, and other single-stage self-heating procedures, more reliable in assessing self-heating potential when testing sulphide materials, it is suggested that a weathering step be incorporated in the test protocol. This test work for two sulphide samples, an ore and a concentrate, demonstrates the impact of incorporating a weathering stage in the test protocol. INTRODUCTIONSelf-heating occurs when exothermic reactions produce heat faster than can be dissipated to the surroundings. Numerous substances self-heat, ranging from wood chips and powdered milk to coal and sulphide minerals (Beever & Crowhurst, 1989; Hudak, 2002). Mixtures of sulphide minerals, most notably those containing the iron sulphide pyrrhotite (Fe(1-x)S), commonly encountered in the extraction of base metals (e.g., copper, zinc, lead, and nickel), are particularly prone to self-heating (Rosenblum, Nesset, & Spira, 2001; Payant, Rosenblum, Nesset, & Finch, 2012). In the mining and subsequent processing stages, the minerals are progressively liberated and finely ground, then separated, usually by flotation, with the resulting concentrates stored and transported to smelters for metal extraction. At most of these stages the sulphides are exposed to both moisture and oxygen, conditions that promote partial sulphide oxidation and the formation of elemental sulphur. Studies have shown that pyrrhotite, in particular, readily oxidizes to form elemental sulphur (Bernier & Li, 2003; Belzile, Chen, Cai, & Li, 2004; Somot & Finch, 2010). The elemental sulphur becomes fuel for further self-heating as the temperature of the mineral mixture increases above 100 oC (Rosenblum & Spira, 1995; Somot & Finch, 2010). It is believed the propensity of pyrrhotite to self-heat is a result of its iron-deficient, and hence somewhat unstable structure. It is worth noting that pure metal sulphides (with the exception of pyrrhotite) do not exhibit appreciable self-heating. A mixture of minerals sufficiently different in their electrochemical rest potential is required to initiate self-heating at ambient temperatures (Payant et al., 2012)."

Jan 1, 2016

By Rodrigo Serna-Guerrero, Ted Nuorivaara

"As the demand of raw materials increases in a global scale due to demographic and economical changes, it is necessary to find technological solutions that improve current production processes in an efficient and sustainable manner. The main objective of this preliminary study is to evaluate the properties of foam produced with a cellulose-based molecule as an alterative to commercial frothing agents in flotation operations. There are two potential advantages identified with the use of cellulose-based additives for the proposed application: i) these chemicals can be produced from sustainable sources (i.e., non-edible crops), and ii) cellulose can be functionalized with chemical groups, in order to rationally modify its behaviour. In previous studies dealing with foam stabilization, it has been proposed that some functionalized cellulose species present a self-assembly mechanism at gas-liquid interfaces. Unlike typical surfactant-based frothers, cellulose molecules form networks around the bubbles that act as protective layers to the mechanical stress and to the occurrence of ionic species. This work studied the properties of foams produced in the presence of a partially hydroxylated cellulose molecule (i.e., hydroxypropyl methyl cellulose; HPMC) under various concentrations in a laboratory-scale column. A comparison with a commercial surfactant frother (i.e., Nasfroth 240) is presented, and a rationalization of the behaviour of HPMC in terms of foam properties (i.e., surface tension, bubble size, foam depth) is proposed. INTRODUCTIONThe search for green alternatives to chemicals produced from non-renewable sources has become a topic of major relevance in industry (Choi et al., 2015). As a chemical consuming industry, the mining sector faces now the challenge of adopting new processing technologies and strategies in order to achieve the future demands of sustainability. Evidently, a move towards green chemistry can only take place by identifying substitute molecules offering potential advantages in terms of recovery and grade."

Jan 1, 2016

By N. Birbilis, S. Kairy, C. R. Hutchinson, D. Jiang, D. R. Feenstra, O. Gharbi

"Recent developments in metal-based additive manufacturing (AM) technology have generated considerable interest in multiple industries, owing to flexibility in design and the ability to produce final components in their net shape. The AM of high-strength aluminium alloys has not been widely explored, due to findings of undesirable microstructures leading to short fatigue life and poor fracture toughness; restricting the application of AM to lower strength aluminium alloys (with cast-like Al-alloy compositions) to date. Herein, aluminium alloy AA2024 (Al-3.6Cu-1.2Mg) was additively manufactured via selective laser melting (SLM), with the resultant microstructures and corrosion properties characterised and compared to wrought AA2024-T3. Microstructural characterisation was carried out using transmission electron microscopy (TEM), revealing SLM produced AA2024 included a population of ?-phase (Al2Cu) in preference to S-phase (Al2CuMg) typical of wrought AA2024. Additionally, the corrosion properties were investigated by potentiodynamic polarisation in a range of NaCl concentrations, whilst elemental corrosion rates were also determined (including for open circuit exposure conditions) and quantified in situ with an inductively coupled plasma mass spectrometer coupled with an electrochemical flow cell. Results revealed a significant improvement in the corrosion resistance, and elemental dissolution of AM prepared 2024 relative to wrought AA2024-T3.INTRODUCTION Aluminium alloys remain the preferred candidate materials in applications requiring a balance of low density and strength. The ability to produce net shape components from aluminium alloys has accelerated due to recent developments in metal-based additive manufacturing (AM) technology, including selective laser melting (SLM) and powder bed 3D printing. The AM of Al-alloys, including Al-Si-Mg (namely AlSi10Mg), has become widespread commercially in recent years. Alloys including AlSi10Mg offer reliable and reproducible production by AM, however such alloys (and variants thereof) are not high strength alloys. The pursuit of higher strength AM Al-alloys presents significant merit to multiple industries; however, such higher strength AM Al-alloys have not been widely studied to date. The solidification of high strength Al-alloys during conventional (casting) operations needs to be executed in a manner that avoids so-called =hot-tearing‘, which can arise as a result of the solute type and loading. A report on the solidification of a high strength Al-alloy prepared by AM, along with factors related to solidification, was recently covered by Pollock and co-workers (Martin et al., 2017). It was reported that AM of high-strength aluminium alloys (which have to date been principally based on the compositions of wrought high strength Al-alloys) may lead to undesirable microstructures that reduce fatigue life and result in poor fracture toughness; presently limiting the application of AM to lower strength aluminium alloys (with cast-like Al-alloy compositions) to date."

Jan 1, 2018