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By Jehan Rondot, Raymond Marleau

"Des quartzites trés pars ont été découverts au cours de la cartographie de la region du lac des Martres, étape de l'étude géologique de la region de Charlevoix.On distingue quatre groupes métasédimentaires, tons con tenant des niveaux de quartzite dans an mains deux domaines géologique différents, c'est à l'ouest, clans le do¬maine gneisso-charnockitique que se situent les quartzites du groupe des Martres. Quartzite et gneiss à, grenat et sillimanite, en banes épais, constituent la formation de La Galette. A Pest, dans un environnement gneisso-granitique, les deux groupes métasédimentaires de Saint-Siméon, et de La Malbaie comprennent, par contraste, des bancs pen épais et de compositions variées. Les niveaux de quartzite dépassent rarement 50 m d'épaisseur. L'autre groupe métasédimentaires, celui de Saint-Tite des Caps, recoupé de nombreuses intrusions charnockitiques et granitiques, ne possède que de minces niveaux de quartzite.La pureté et la grande épaisseur des quartzites de La Galette suppose une histoire complexe qui se termine par des depots continentaux de climat aride, par opposition aux depots marins des autres groupes. D'autre part, la presence de ces quartzites an sein de roches Presque anhy¬dres et de haute temperature que sont les charnockites leur confére des caractéristiques de fusion sans decrepitation.Parmi la multitude de depots de quartzite qui existe clans le monde, peu sont de qualité supérieure. Or, de par sa composition chimique, le quartzite de La Galette se compare avantageusement à ceux des meilleurs gisements des Etats-Unis, de l'Europe de l'Ouest et de l'Afrique du Sud. D'accès facile pour l'exploitation, les gisements ne sont qu'à une trentaine de milles de Baie Saint-Paul ou de La Malbaie, sur le Saint-Laurent.L'utilisation en metallurgic prévue pour le quartzite de La Galette comprend la production de silicium, de ferro¬silicium et d'autres alliages de silicium. La composition du quartzite est en outre appropriée pour la production de carbure de silicium et de silicate de sodium. Les fines peuvent être utilisées pour la fabrication du verre et comme matiere de charge"

Jan 1, 1977

By J. Buckle

"Recognition of the diamond potential of the Wawa subprovince was initially determined from regional data using a kimberlite model. The world’s largest stable Precambrian craton, the Superior Province, is considered to be favourable for the emplacement of diamondiferous kimberlite. The Wawa area is located near the intersection of intra-craton structures visible in the regional magnetic data.The Enigma project is located north of the town of Wawa in northern Ontario. From field evidence and background research, it became obvious that in the Wawa area there were at least two potentially diamond-hosting events, Archean lamprophyric volcaniclastics and Proterozoic kimberlites. The host lamprophyric rock does not contain the classical KIM signatures. However, to complicate the Enigma, stream sediment samples within 200 m of the diamond-bearing lamprophyre produced a typical suite of kimberlite indicator minerals.The micro- and macro-diamond content of the Wawa lamprophyric volcaniclastic rocks is typically 0.2 ct/t to 1 ct/t, although it can be higher locally. The economic diamond potential of these Archean dykes, sills and irregular lamprophyre bodies is still under-explored (Kaminsky, 2002, unpubl.). Oasis Diamond Exploration is currently exploring the area using geophysical, geochemical, and geological data."

Jan 1, 2002

By M. D. Everell

Le Centre de Recherches minérales (CRM), qui est un organisme de recherche appliquée du ministère de l'Energie et des Ressources du Québec, a été créé en 1969, dans le but de procurer un support scientifique et technique à l'industrie dans le domaine des mines et de la métallurgie. Pour atteindre ses objectifs, le CRM met à la disposition de l'industrie un personnel spécialisé et compétent dont une quarantaine d'ingénieurs et de scientifiques. Etant donné la nature même de l'industrie minérale, ce personnel est très versé dans l'étude des problèmes diversifiés des domaines de la technologie minière, du traitement des minerais, de la métallurgie extractive et de l'analyse minérale. Ce Centre de recherches met également à la disposition de l'industrie une usine-pilote permettant de reproduire les résultats du laboratoire au moyen d'un appareillage de type industriel, d'obtenir des échantillons en quantité suffisante pour une exploration du marché et de familiariser du personnel avec les opérations normales de l'industrie. Certaines de ses contributions récentes au développement de l'industrie minérale du Québec seront présentées.

Jan 1, 1985

"Many underground mines are achieving extended life and optimizing existing facilities by mining at greater depths. The challenges to do this require a sound engineering approach to mine design and mine services, as well as ingenuity in safety design. The social consequence is full utilization of existing infrastructure.Accessing ores at depths of 2000 m to 3000 m requires exceptional hoisting design. May’s theme issue includes a paper that examines a case study of one such hoisting plant, with emphasis on the hoist rope selection at Agnico-Eagle’s Penna shaft. The paper also describes the process whereby consultation with provincial safety authorities resulted in a revised safety factor suited to the hoist. Another paper examines the challenges of ventilating mechanized mines to 3000 m, including air cooling and dilution of diesel exhaust emissions. Vent system designs are discussed, using sound engineering design, and proven technology that minimizes emissions to achieve cost efficiencies. The paper suggests design based on process and ventilation simulators to obtain realistic economic data at the design stage. Increased ground pressures present unique challenges for production and safety. While this is not confined to deep mining, one paper examines rock pressures and seismic events at the Brunswick mine, for which experience may be applied at depth. It describes seismic monitoring as a predictive tool in a real mine situation, and how it is used to improve overall recoveries and maintain worker safety."

Jan 1, 2004

By G. J. S. Govett

World mineral production is dominated by six countries - the U.S., the U.S.S.R , Canada, South Africa, Australia and China - which also hold most of the reserves of the world?s minerals. For the developed and centrally planned countries, there is a strong positive correlation between the mineral production of a country and its land area: there is no correlation between mineral production and land area for the less developed countries. These facts imply that, after taking due account of geological controlling factors, a country may expect to produce minerals in approximate proportion to its land are a provided that political, economic, and historical factors are conducive to mineral exploration and mining. Contrary to popular political belief in many parts of the world, the developed countries are the major source of mineral imports for the industrialized countries. Moreover, exports of ores and minerals account for a relatively small par t of world trade, and are an important factor in the export picture of only a few of the less-developed countries. The looming resource confrontation between the developed and the less-developed countries is based largely on the false premise that the industrialized countries of the world are minerals-poor and owe their wealth to cheap minerals from the less-developed countries. The data presented refute this. Geological controls are relatively minor in the present distribution of world mineral production; political and economic factors are dominant. It is argued that an expansion of world trade in minerals - based on increased exploration and new forms of finance for mining ventures - rather than cartels, price-fixing and trade restrictions is by far the preferable solution to the problem of redressing the legitimate grievances of the poor countries of the world.

Jan 1, 1977

By K. E. Barnes

"The IsaMill was developed for fine-grained ores that required at least double the grinding efficiency of ball or tower milling to be economic. This was achieved, but in practice, the benefits of using inert media (eg sand, slag, ore, ceramic) have proven to be at least as important as the higher grinding efficiency. Flotation selectivity and rate was improved for all particles, particularly fines. This allowed a dramatic simplification of the Mount Isa lead zinc flotation circuit – adding 6 MW of ultrafine grinding power reduced reagent addition and flotation volume and increased plant energy efficiency. This was quite unexpected.This paper examines four orebodies that were enabled by inert grinding – McArthur River, George Fisher and Black Star Open Cut Mines (complex fine-grained lead zinc orebodies in Australia), and the Western Limb Tailings Retreatment plant (a PGM operation in South Africa). In a unique case history, the operating performance of the Mt Isa lead zinc concentrator is explained by size-by-size mineralogical data collected over 25 years, systematically explaining the impact of declining ore quality, and the effects of additional conventional grinding, inert grinding, and circuit and reagent redesign.The mineralogical case histories are so compelling that it is argued that the advantages of inert grinding should not be confined to difficult, fine-grained orebodies. The availability of largescale efficient inert grinding mills could have profound impact on circuit design for many orebodies.INTRODUCTIONThe IsaMill was developed by MIM (now Xstrata) to enable the development of the McArthur River Orebody in the Northern Territory of Australia. This ultra-fine grained ore needed a grind size of 80% passing 7 microns to produce a saleable concentrate. Such a fine grind was not economic with conventional ball or tower milling. Below about 25 microns the low energy efficiency and high media consumption of these mills is prohibitive. Critically, the high steel consumption and associated change in pulp and surface chemistry also seriously affects flotation metallurgy."

Jan 1, 2006

By J. Moyes

The Intec Process is a generic process for the production of pure base metals and precious metals from sulphides concentrates derived from copper, nickel, zinc and lead ores. The development program for the Intec Process initially focussed on the treatment of copper concentrates, (the ?Intec Copper Process?), and more recently of zinc concentrates, (?the Intec Zinc Process?). Developed and proven in Sydney, Australia at a cost of US$15m over the last ten years, the Intec Copper Process is now ready for commercial application. The knowledge gained during the development of the Intec Copper Process has been applied to the Intec Zinc Process, which utilises the same basic chemistry to produce high purity zinc ingot from metallurgically complex zinc sulphide concentrates containing lead, copper, iron, silver and gold. The demonstrated ability of the Intec Zinc Process to treat low grade mixed zinc/lead/copper concentrates, including those with high iron and manganese levels, holds out the real prospect of overcoming major metallurgical hurdles that have long affected the zinc industry. The Intec Zinc Process consists of the three consecutive circuits of leaching, purification and electrowinning. The leach circuit is of single stage configuration with a series of reactors to which concentrate and lixiviant are fed. Purification consists of cementation and precipitation by pH adjustment. Electrowinning employs an electrolytic cell very similar in design to that of the Intec Copper Process, but differs in that a conventional plate cathode is produced. During electrowinning, the same mixed halide species (BrCl2 -, HalexTM) that is integral to the Intec Copper Process is generated in solution at the anode and exhibits powerful leaching characteristics capable of directly leaching the sulphide concentrate feed. The need to roast the concentrate prior to leaching, as is practised in the conventional Roast/Leach/Electrowin (RLE) process, is thus eliminated whilst a range of by-products (notably lead, copper and precious metals) can be extracted in the simple, single-stage leach. This paper describes the Intec Zinc Process; the technology, predicted economics and its environmental aspects.

May 1, 2002

By Helen Francis

Over the last decade, lower ore grades and deeper mine environments have demanded that mining companies develop new technologies (tools and processes) to ensure a mine?s economic sustainability. At Inco Ltd., this demand has lead to the focus of technological development within the area of automation. Delineation (Drilling and Interpretation) is a key step in the determination of ore grade and location and therefore was chosen as a priority area for enhancement through automation. Focusing on the tools (the diamond drill) automation, significant benefits have been consistently achieved in terms of productivity, process efficiency, operational safety, cost reduction, component life cycles and machine reliability. It is suggested that optimum benefits have yet to be achieved, and will not be achieved until the human aspects of automation have been properly addressed. Since project inception, the human aspects of automation were recognized as critical to the success of the diamond drill automation project. However, it was only upon the installation of the Automated Diamond Drill in the field and its continued use on a daily basis that this issue received due attention. The human aspects of automation can be broadly addressed as economic, physical and psychological. This paper, with examples from the field, will discuss the human aspects of automation in each of these areas. The paper will draw from observations and experiences acquired throughout this project and recommend implementation strategies that should be utilized in future automation projects to enhance both the acceptance of automation and the success of the automated process itself.

May 1, 2002

By R. H. O. Wagner

"This paper describes the bench testing, pilot plant studies of alternative flowsheets, to determine the feasibility of gold recovery, by carbon in pulp extraction, in the Schumacher Mill gold flotation tailings. The economics were calculated based on pilot plant recoveries and actual industry operating costs.The economics of the carbon in pulp treatment of the gold flotation tailings were not justifiable. The economics of desliming the gold flotation tailings followed by carbon in pulp treatment were marginal, but favourable. INTRODUCTIONPamour Porcupine Mines, Limited is a gold, silver and copper producer located in Timmins, Ontario. In 1983 the head grade of Pamour's gold ores averaged nine one hundredths of a troy ounce of gold per short ton.Pamour operates two area mills to concentrate the gold ores. Free milling gold ores are processed at the Pamour One Mine mill, whereas the refractory carbonaceous gold ores, and complex gold, silver, and copper sulphide ores, are processed through the Schumacher Mine mill.The complex Schumacher mill feed ores do not all react favourably to flotation methods, consequently this study was commissioned to investigate the feasibility of the carbon in pulp cyanidation of the Schumacher mill gold flotation tailings. These tailings contain ten to fifteen percent of the gold in the mill feed. During the study period, the average grade of the Schumacher mill flotation tailings was nine one thousandths of a troy ounce of gold per ton, or one quarter of a gram of gold per metric tonne."

Jan 1, 1984

By S. W. Stogran

"A brief summary of the environmental testing and analyses required to ensure and maintain compliance of mining properties will be discussed. Programs for new and existing properties and for properties which may be purchased will be outlined and potential solutions to problems will be discussed. In addition to the compliance aspects of operations, due diligence will be discussed.1.0 INTRODUCTIONThe impact of mining projects on the environment is an area of major concern to the public, governmental agencies and mining companies. Due to the ever increasing pressure on the government by special interest groups and the public, governments have implemented legislation to control potential environmental impact of mining, from the exploration phase through to close-out. By not planning for environmental issues during all phases of a mining operation, unavoidable delays and retrofitted environmental programmes will be expensive and cause projects to be delayed, which, ultimately, may cause the abandonment of a mining prospect. Most jurisdictions require at least one full year of background environmental data. Therefore, many thousands of dollars are wasted as construction is interfered with or held up due to data collection. This may be avoided by a thousand dollars worth of sample being collected and analyzed early in the project."

Jan 1, 1992

By Dave Bulled, Chris Bennett, Glenn Kosick, Glenn Dobby

"Mining companies around the world are embracing geometallurgical modeling at a rapid rate, as senior executives realize that inputs must be properly measured if the output is to be managed effectively. Geometallurgical modeling is used to scientifically manage risk in project evaluation, for plant design and production forecasting, and optimization of production planning and mineral processing/metallurgical unit operations. The technology also provides a solid foundation for implementing broad corporate strategies with respect to intelligent asset utilization and metal sales. Over the past five years, MinnovEX Technologies Inc. has been actively engaged in developing, promoting and applying geometallurgical modeling technology for major mining companies around the world. This paper describes the methodology for successfully applying the technology for the unit operations of comminution and flotation in the mining industry.INTRODUCTIONGeometallurgical modeling (referred hereon as geomet modeling), in theory, can be applied to its full potential on all unit operations in mineral processing; however, this paper will concentrate on two of the largest unit operations, namely comminution and flotation, where the technology is actually being practiced by many large mining companies. For concept studies and prefeasibility studies, aspects of geometallurgical technology are regularly applied but in a less rigorous manner than for final feasibility studies where justification for funds is sought. This paper will focus on the final feasibility stage of a project and on existing operations or planned expansions, where the full power of geometallurgical technology is brought to bear in a cost effective manner.One of the unique aspects of geomet modeling, when used to its potential, is the ability to design plants, and forecast and plan production with a quantifiable degree of precision, something that was unattainable in the past. This means that when new comminution and flotation plants are designed, the mining companies and financial institutions involved in the project can measure the precision of the design and therefore better understand and manage project risk. It means that for existing and new operations, metal sales personnel can carry out their sales strategies with a much better understanding of the degree of error associated with production forecasts of concentrate/metal and quality of concentrates. For mine and mill managers, geomet modeling allows the effect of the mine plan on the downstream processes to be quantified; thereby allowing the mine plan to be recast in a more optimized manner. Finally, existing concentrator personnel can optimize their unit operations based on a more definitive understanding"

Jan 1, 2004

By A. P. Schissler

Mining has several characteristics, uncommon in other business sectors, which pose additional challenges to the implementation or design of IT and management systems that use the information. Understanding these characteristics would improve the chances of successfully importing new information technology and management techniques to mineral producers. The most important characteristics that should be understood are workplace issues, the industry’s dual nature of being a continuous construction project using cyclical factory processes, labour challenges, workplace culture, information availability, integrative data elements, and the current technical education of mining engineers. These characteristics were taken into account in two applications of information technology and systems design at operating companies. The research and consulting projects focused on the development of an IT-enabled performance management system at several underground metal mines in Canada and an integrated data warehouse for surface mines spread throughout the United States and Latin America.

Jan 1, 2006

By John G. Henning

The Porcupine Joint Venture operates the Dome Mine in South Porcupine, Ontario. Dome underground began production in 1910. It is the longest continuous operating gold mine in Canada, producing in excess of 15 M ounces. More than 900 underground stopes have been mined and hundreds of miles of drifts, sublevels and raises developed. Underground mining methods included shrinkage, cut and fill and longhole. Not all stopes were backfilled upon completion, particularly the longhole stopes. The Dome open pit was designed above the underground mine workings such that, as the pit is excavated, it intersects underground drifts and stopes. Potential operational problems associated with the interactions between the stopes and the pit walls may occur, necessitating pit wall redesign, ground support installation and operational rescheduling. Each intersection of the pit with the underground mine workings is closely evaluated to maintain a safe working environment and wall stability. This paper discussed how risks to pit wall stability are assessed, mitigated and monitored.

May 1, 2004

By David R. Skuse, Jacek A. Kostuch, Steven M. Fortier

"Particulate ground calcium carbonate (GCC) is used as a filler and coating pigment in a wide range of applications including papers, paints, plastics and films. In this paper we will overview the requirements for GCC used in both filling and coating applications in the paper industry and highlight the processes used in the production of these materials.INTRODUCTIONCalcium carbonate is both abundant and very widely distributed occurring most commonly as limestone, marble and chalk (Harben 2002). Given, the high purity, whiteness and relative inertness of these materials it is not surprising that they are heavily utilised in a range of industrial applications. Worldwide ground calcium carbonate (GCC) capacity is estimated at 50.5 million tonnes per year (Roskill, 2002). This usage is divided between relatively coarse materials that are used in applications such as landscaping, cultured marble and carpet backing and finer grades that find application in plastics, rubbers, inks, paints and paper. Given the usage of calcium carbonate products across a very wide range of consumer products, the outlook for GCC is very promising with growth expected in many markets. Growth is anticipated across many applications in the emerging nations and more specifically in paper applications on a global basis.Over the last several decades the GCC processing industry has evolved to be well adapted to both the cost effective production and delivery of standard products and the production of high performance speciality products. Many of the standard unit operations found in the metaliferous raw material processing industry are also used, albeit in some cases in modified form, in the processing of GCC. Coarse products (diameter > 3 - 10 µm) are typically produced by dry processing routes. Whereas, the finer products are typically produced by a combination of wet and dry processing."

Jan 1, 2004

By M. Kinne

Catalyst preparation/ characterization Slightly modified DP (~Schumacher et al. Catal. Lett. 89, 109, 2003) CeO2 HAS 15 from Rhodia calcined in air for~ 2h BET: ~188m2/g, particles size: 5.7nm (TEM, XRD) + HAuCl4 at pH of 6.5-7, (>95% of the Au was deposited) ? Au/CeO2 (2.6wt% Au, ICP-AES) A new conditioning procedure was applied, including heating at low temperature in N2 and H2/N2 mixtures) Patent DE 10205873A1. Very small Au particles <2nm, for CO oxidation catalyst as Au/TiO2, Au/Fe2O3, and Au/Co2O3 Here Au particles size <3.5nm (XRD) Summary ? CO is nearly exclusively adsorbed on the Au particles ? Positive reaction orders of 0.5 are found for CO and H2O ? Ea= 40kJ/mol ? The catalyst is very active and stable ? During WGS reaction huge amounts of formates are formed and cover the surface ? The activity of the catalyst seems to be correlated with the formate species.

Oct 1, 2003

By F. Hassani, D. O’Donnell, M. Momayez, P. Guevremont

Shotcrete is a practical and economical support system in many Canadian underground mines. Although shotcrete technology has gained acceptance in the mining industry, there are some problems that have emerged with respect to quality assessment and thickness measurement of the liner. This paper presents recent tests performed with miniature seismic reflection technology (MSR) developed and patented at McGill University primarily for thickness measurement of this heterogeneous liner. MSR is also capable of providing information regarding the quality of shotcrete in terms of its mechanical properties such as modulus of elasticity and Poisson’s ratio. Work was performed on site in an underground mine in Ontario, Canada. This paper also presents the results from laboratory tests performed on fiber-reinforced and non-reinforced shotcrete panels that were used to assess the P-wave velocity in both materials. The results of these tests were used in a second site investigation. The NDT thickness measurements showed good agreement with direct thickness measurement such as coring. In addition, the MSR technology has the advantage of being more accurate and more affordable compared to other non-destructive testing (NDT) systems in the market.

Jan 1, 2002

By T. A. Grammatikopoulos, B. Vasily, A. H. Clark

"The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoeshaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York, no carbonate protolith is preserved, and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560°C, or, alternatively, 550 MPa and ca. 630°C.Several high-grade zones, averaging >40% but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 cm to 5 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates.St. Lawrence compares favourably to other known prospects and operating wollastonite deposits: having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production."

Jan 1, 2003

By M. Mirnezami, D. Lascelles, J. A. Finch, E. El-Ammouri

"Aggregation, i.e., the tendency of particles to cluster, can be expected to influence flotation selectivity. In this paper, a method of measuring aggregation is introduced and used to conduct plant surveys.Aggregation is measured using settling rate and turbidity converted to an aggregation index (AI) where 0 corresponds to most dispersed and 1 to most aggregated over the range of conditions tested, normally pH. Surveys of Cu and Zn flotation stages at four concentrators showed the AI increased significantly above pH 9. The metal ions identified in the process waters, principally Ca and Mg, were tested to determine which might be responsible. The presence of Mg was found to be the most important. In doping tests, Mg was shown to cause significant variation in AI over the pH range of 9 to 12.The impact of Mg was restricted to pH > 9. Over this pH range, Mg forms a range of hydroxy species, including Mg(OH)2 precipitates. An aggregation mechanism associated with these precipitates, electrostatic bridging, is suggested. Possible problems and opportunities in flotation practice arising from the findings are discussed."

Jan 1, 2002

By A. P. Bois, K. Saleh, A. Ghorbal, V. Hajiabdolmajid, G. Ballivy

"The knowledge of the initial stress field is not always sufficient to ensure the stability of mining stopes due to the high-stress variations generated by mining. Monitoring of these openings is then necessary and can provide quantitative information (deformations and stress variations) as well as qualitative information (state of stability).An applied technique for following the variations of stress and deformation in static and dynamic conditions, in relation to the evaluation of the stability of underground openings known as “Cylindre Instrumenté de l’Université de Sherbrooke” (CIUS) is discussed in this paper. In addition, a data acquisition system combined with a rock failure warning system has been developed to be connected to the CIUS for detecting the instabilities, which can endanger the stability of underground openings. Also, the installation of six CIUS and a data acquisition system as well as the selected procedure of programming in a warning system are briefly described."

Jan 1, 2003

By R. A. Bergman, C. A. Pickles, J. M. Toguri

"Black calcium cyanide is utilized mainly as a reagent for gold extraction. It is produced by reacting calcium cyanamide, sodium chloride and calcium carbide at temperatures in the range of 1200°C to 1400°C in a smothered arc furnace. The equivalent sodium cyanide content of the product is in the range of 45% to 50% and the calcium cyanamide conversion efficiency is in the range of 90% to 95%. Since black cyanide contains impurities such as salt and lime and also because the conversion efficiencies are below 100%, the product contains unwanted materials which significantly increase the shipping costs.The impurity content of the raw materials can not be lowered without increasing their cost and/or the processes to produce them, and therefore the present research was focussed on studying those factors which affect the cyanide grade. The major variables investigated were: the heating rate, the reaction temperature, the salt to cyanamide ratio, the nitrogen content of the calcium cyanamide, moisture additions and calcium carbide additions. It was found that each of these variables had a significant effect on the product grade. The highest cyanide content of the product was obtained for salt to cyanamide mass ratios of 0.55 to 0.60. The salt reduces the decomposition rate of the cyanide and, therefore, at low salt to cyanamide ratios and at higher temperatures, the product grade is decreased. It is likely that the salt evaporates at the higher reaction temperatures and this decreases the cyanide capacity of the melt. High heating rates minimize the residence time and thus salt evaporation is reduced and higher grades can be obtained. As expected, the cyanide content increased with the nitrogen content of the cyanamide. Calcium carbide additions resulted in an increase in the product grade. The presence of small amounts of moisture in the charge caused a significant decrease in the cyanide content of the black cyanide. An equilibrium reaction is postulated in order to explain the black cyanide process and in particular the effect of calcium carbide on the product grade."

Jan 1, 2002