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By J. F. Butler, H. W. Paxton

The vapor pressures of manganese in equilibrium with several alloys in the iron-manganese-carbon system between 1200° and 1275°K have been measured using the Knudsen effusion technique in conjunction with a vacuum microbalance. The effect of orifice area of the effusion cell upon the measured pressure has been determined. The binary iron-manganese system shows small negative departures from ideality, and the system of mixed carbides, (Fe, Mn)7C3, in equilibrium with graphite behaves ideally. THIS work is a continuation of the investigations in which the Knudsen effusion method has been used to determine thermodynamic activities in systems and at temperatures of interest to metallurgists. In a previous publication,' the free energy of formation of Mn7C3 was determined and some preliminary work on the solution behavior of this carbide with the hypothetical "Fe7C3" was reported. The present work deals with this latter topic and also includes data on the binary ir-on-manganese system. EXPERIMENTAL METHOD The Knudsen effusion method was used to measure the vapor pressure of manganese in both the alloy and carbide sections of this investigation. This dynamic method of vapor pressure measurement presents a problem when studying solid alloy systems in which one of the components has a much larger vapor pressure than the others. Over-all depletion of the alloy in the most volatile component will occur during evaporation so that the pressure of that component will decrease. Even more serious than the over-all concentration change is the surface depletion of volatile component in the alloy brought about by the slow rate of diffusion of this component from the interior to the surface of the solid particle. Since knowledge of this surface composition is necessary in order to relate it to the activity determined through the measurements, changes in surface composition from the analyzed bulk composition are to be avoided in dynamic vapor pressure studies of solid alloys. The system under investigation in this study presents the problem of surface depletion of manganese since its pressure at 1230°K is 105greater than iron and 1020 greater than carbon. Since the existence of a volatile manganese carbide had been ruled out previously,' the high manganese pressure relative to iron and carbon insured that the only species leaving the effusion cell was manganese. Therefore, the effusing species required no analysis so that the manganese pressure was determined directly from the weight loss of the effusion cell. In order to detect small weight losses near the beginning of effusion, a vacuum microbalance was used to weigh the cell continually. These initial weight loss data allowed the rate of manganese effusion to be determined before the surface of the alloy became depleted in manganese. The apparatus used in this investigation is shown in Fig. 1. Temperature was measured using chro-

Jan 1, 1962

By William M. Knuth

The objectives of this study were the evaluation of the technical and economical feasibility of utilizing color and color infrared aerial photography to satisfy some informational needs for pre-mine planning, mine progress monitoring, and reclamation monitoring. Seven aerial data collection missions were conducted within a two year period over strip mine sites in Pennsylvania. Scales of 1:6,000; 1:12,000; 1:24,000; and 1:48,000 were flown on the first aerial mission. The 1:12,000 was chosen as the optimal scale for the remaining six flights. An extensive literature and legislative review and discussions with strip mine operators identified the informational parameters that could possibly be obtained from aerial photography. Interpretability accuracies were evaluated for parameters in the broad categories of land use, soils, water, vegetation, and geology. Seasonal interpretation characteristics were noted for infrared photography. Man hours for photointerpretation and costs of aerial data collection were monitored closely and incorporated into a cost benefit analysis. Those parameters that could be mapped, identified, or measured with accuracies =75 percent were incorporated into a photointerpretation training manual. An additional analysis was performed to determine the applicability of the interpretation methodologies and results developed for Eastern sites to Western surface coal mining sites. In addition, a separate aerial photographic interpretation manual was produced during this contract. It is intended to be utilized by eastern and midwestern surface mine operators and regulatory personnel.

Jan 1, 1978

By V. D. Jalevsky

A new methodology of an experimental-analytical approach has been developed. It is used in building an information geomechanic monitoring system for the modeling of geomechanic processes during coal seam working. The approach synthesizes experimental (in-situ) measurements of rock pressure manifestation in separate points, methods of numerical modeling of processes on rock boundaries with coal, and a seam analytical calculation of rock mass in a spatial strained state. One of the realizations of this approach is the developed theory and calculation method of adjoining rock surface shift (overhang) formation during underground working of sheet deposits and of rock mass geomechanic state determination. There are description algorithms of cavity configurations with broken lengths of faces during underground working of useful mineral sheet deposits. These algorithms have been used in computer modeling of formations of adjoining rock surface overhangs and abutment pressure upon rock mass in the area of coal faces with irrectilinear longwalls. Peculiarities of surfaces shifts and stress allocation are established for different face schemes. The use of theory and methods alloww working out techniques of automatic control to receive processing algorithms of RPM measurement results and calculate geomechanic situations within panels in the process of planning and development as well as during mining, i.e., to carry out long-term prediction, in-line control, and short-term prediction of rock pressure manifestations.

Jan 1, 1996

By Z. Q. Zhou

It is the first worke in design of pile foundation to determine the carring capacity of single pile, and a static loading on site is considered to be the lost derect and reliable way. All values P and settlements S induced can be plotted as a broken-line. Since soil is a kind of elasto-plastic and cohesive material, the increasing of settlements is generally greater than that of loads. Different value Pu nay be given by different tester on his P-S diagram, because of erroys in the test and complicated, characteristics of soil. The analytical method of exponential equation shown in this paper derives a specified solution. After using an exponential curve to regress values of loads P and corresponding settlements S from on-site test, coeficients A and B of exponential equation can be obtained. With this curve an ultimate carrying capacity of single pile can be determined. The resistant forces of pile shaft and pile tip can also be defined by the tangent of the calculated knee point, as it is called (tangent method). At last, an example is given to show how the ultimate carrying capacity of f 500mm bored pile is obtained with this method for a project in Kunming.

Jan 1, 2010

The first principle one usually Learns about blasting is that cunpetence in this field is best gained by experience in making blasts rather than by reading a book or by listening to a lecture. The reason for this is that there are a large number of variables affecting blasting results and not all of these can be accounted for by a few rules or a few sets of equations. Even an experienced blaster when operating in a new area, may have to make one or two shots just to acclimate himself to the new conditions with which he is faced.

Jan 1, 1989

By George W. Maynard

(Pittsburg Meeting, March, 1910.) AT the Pittsburg meeting of the Institute, May, 1879, I made the first announcement in America of the results obtained by Sidney Gilchrist Thomas and Percy C. Gilchrist, ill their efforts to eliminate phosphorus in the manufacture of steel in the Bessemer converter and the open-hearth furnace.1 The first published statement in an American newspaper was a reprint of the first Thomas-Gilchrist paper, 2 which I sent to J. C. Bayles, at that time the editor. At the suggestion of many friends who were present at the Pittsburg meeting, and others who are cognizant of the beginnings of the process in the United States, and for the information of the younger generation of the iron and steel fraternity, I have thought it eminently proper that the history of the process in detail should be given where I made the first announcement and where the process has had its largest development. During my residence in England, from April, 1873, to February, 1879, and as a member of the Iron and Steel Institute since 1874, I was present at many of its meetings during those years. At nearly -every meeting the burden of discussion was the question of the use of pig-iron containing phosphorus in the. manufacture of steel by the Bessemer or the open-hearth process. In my biographical notice of Thomas;3 read at the New York meeting of, the Institute, February, 1885, I show that the working-out of the process was not a hap-hazard or accidental inspiration, but the culmination of many years of investigation of experiments and theories which had been carried on and advanced by chemists and metallurgists at home and abroad. 1 Trans., viii., .5 (1879-80). 2 The Iron Age, vol. 22, No. 17, p. 3 (Oct. 24, 1878). 3 Trans.. xiii., 785 to 791.

Jul 1, 1910

By Rossiter W. Raymond

(Canal Zone Meeting, November, 1910.) THE death of Professor Blake removes the oldest of American economic geologists and mining engineers, and deprives this Institute of one of its, earliest and most illustrious members. To many of us it brings a personal loss also, the loss of a friend. William Phipps Blake was born June 21, 1826, in New York City. -His father, Elihu Blake, was a surgeon-dentist of eminence, a direct descendant of William Blake, who settled in the Massachusetts Bay Colony about 1630. He was prepared for college at private schools in New York, and entered the Sheffield School of Yale, where he was graduated as Ph.B. in the chemical course, class of 1852, the first graduating-class of the institution. In the same year he became chemist and mineralogist of the New Jersey Zinc Co., and chemist of chemical works at Baltimore, Md. In 1853, lie started the Department of Mineralogy of the World's Fair at New York City. In 1854, 1855 and 1856, he was mineralogist and geologist of the United States Pacific Railroad Surveys of Williamson, Pope, and Whipple, and for the War Department at Washington. His writings, during this period comprise reports on the geology and mineralogy of California and other parts of the Southwest, and constitute well nigh the earliest scientific accounts of the regions described. One of them. was a translation of the Resume and Field Notes of Jules Marcou, of Whipple's expedition. From 1856 to 1859, he was engaged in explorations of the geology and mineral deposits of North Carolina, :and other parts of the country. In 1859, he became editor and proprietor of The Mining Magazine. This was a monthly periodical, founded in 1853 by W. J. Tenny, who conducted it until 1858, when it passed into the hands of Thomas McElrath, a New York publisher, and appeared in May of that year as The Mining and Statistic Magazine, with the name of

Sep 1, 1910

By C. P. Haller, S. J. Aresco, R. F. Abernethy

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash- softening temperature of ash, the free-swelling index, and the hardgrove grind- ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instruc- tions issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the con- tractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal. The Government purchased approximately 5-1/4 million tons of coal in fiscal year 1953. In connection with these purchases, the Bureau analyzed 11,435 samples. These are published for the use of Government officials and the public. A series of publications has been completed on coal analyses by States, or, where production is small in any one State, by groups of adjacent States. In addition to analytical data showing composition and quality of coals of the States, the publications con- tain brief descriptions of the geological structure of the coal basins, typical mining conditions in the various districts, the principal economic data of the industry, and the relationship of mine or channel samples to delivered and tipple samples. The present publication covers many States but deals only with the analytical data of the coals. Previous publications in this series are: Bulletin 516, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Years 1948 to 1950 Inclusive); Report of Investigations 4934, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1951); Report of In- vestigations 4972, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1952). Following are the Bureau of Mines technical papers published by States, with their numbers: Alabama, 347; Alaska, 682; Arizona, California, Idaho, Nevada, and Oregon, 696; Arkansas, 416; Colorado, 574; Illinois, 641; Indiana, 417; Iowa, 269 and 706; Kansas, 455; Kentucky, 308 and 652; Maryland, 465; Michigan, North Dakota, South Dakota, and Texas, 700; Missouri, 366; Montana, 529; New Mexico, 569; Ohio 344 (and Bulletin 499); Oklahoma, 411; Pennsylvania Bituminous, 590 (Supplement 645); Pennsylvania Anthracite, 659; Tennessee, 356 and 671; Utah, 345; Virginia, 365 and 656; Washington, 491 (Supplement 618); West Virginia, 405 and 626; and Wyoming, 484.

Jan 1, 1955

By Michael J. Sapko, William D. Monaghan, Michael A. Trevits

Mine seals are used extensively in underground coal mines to segregate mined-out areas and to isolate fire zones or underground areas that are susceptible to spontaneous combustion. Over the years, 30,000 mine seals have been erected in underground coal mines in the United States. Mine seals, along with rock dusting and ventilation, represent the fundamental means of preventing underground coal mine explosions. In this study the National Institute for Occupational Safety and Health (NIOSH) used ground penetrating radar (GPR) technology to determine if each of three test mine seals were uniformly constructed. Three mine seals representing different construction methods and materials (cast-in-place foamed cement; solid block, polyurethane foam and gravel; and wire mesh, rebar and gunite) were erected at the NIOSH Lake Lynn Laboratory’s underground mine as part of an on-going research program. The seals were imaged using GPR with 400-, 500-, 900-, and 1,000-MHz antennas. We found that variations in uniformity existed in the material for the cast-in-place foamed cement seal. Variations in uniformity also existed in the seal made from solid block, polyurethane foam and gravel. The post-processed radar records correlated closely with recovered core samples (areas of gravel and polyurethane foam, and areas containing only polyurethane foam). Finally, the radar records of the seal made of wire mesh, rebar and gunite showed the various components. The results of this work suggest that GPR could be used as a tool to evaluate mine seal characteristics and construction uniformity.

By Francis Chachula, Niel Erasmus

"In 2002, Titanium Corporation Inc. focused its attention on the development of a process for the recovery of valuable heavy minerals, including zircon and titanium bearing minerals from oil sands froth treatment tailings. The development of a process flowsheet to recover the titanium and zircon minerals from the Athabasca oil sand tailings has evolved through many laboratory, bench and pilot scale iterations.Initial development work focused on so-called ‘beach sand’ material, which is tailings material deposited over a period of time close to the tailings pipe discharge. The derived process flowsheet primarily consisted of gravity concentration stages, which is typical of all mineral sands operations. Titanium Corporation’s business plan calls for the utilization of tailings directly from the tailings pipeline – the process developed around the beach material is therefore risky as it differs from the live tailings in a number of aspects, with the effects on the process unknown. Titanium Corporation successfully obtained an intermediate product through a ‘bulk sampling plant’ coupled directly to an Oil Sands operator’s froth treatment tailings pipeline, during the summer of 2005. Subsequent further processing of this material resulted in poor separation or concentration of the heavy minerals due to a number of reasons. A more effective process flowsheet had to be developed.The newly derived process is basically a marriage between mineral sands technology and oil sands technology that can economically concentrate and recover the heavy minerals and entails the incorporation of a flotation process that takes advantage of the entrained bitumen in the feed to separate the heavy mineral fraction from the quartz gangue This paper will describe the newly derived process as well as the successful results of a subsequent on-site concentrator pilot campaign completed during the 3rd Quarter of 2006."

Jan 1, 2008

By Murray Jacobson

Facts obtained by the Bureau of Mines on the dust-explosion hazard in air of materials used in the plastics industry are presented for 313 samples studied in the laboratory. Information is given on ignition temperature of dust clouds and layers, minimum explosive concentration, minimum energy required for ignition, explosion pressure and rates of pressure rise, amount of inert dust required to prevent ignition and flame propagation, and, in some instances, on the limiting oxygen concentration in an atmosphere to prevent ignition by spark and by heated surface. The effects of particle shape, additives, and resin structure on explosibility are discussed. Relative explosibility of the materials is related to the ignition sensitivity and explosion severity and is denoted by an empirical index. Recognition of the degree of hazard will facilitate adoption of adequate measures for preventing ignition and explosion during manufacturing or processing.

Jan 1, 1962

By Herbert H. Einstein

Appendices A through M contain information that is the basis for many developments reported in the main text (Parts I through V); this information is, however, not needed in applying the research results. Specifically the appendices contain: A: Geology of Sampled Sites B: Comparison of Distribution Forms with Observed Trace Length Frequencies C: Joint Attitude Pole Diagrams D: Resistance and Deformability of Rock Discontinuities E: Resistance and Deformability of Joints - Details of Data Recording Procedure F: Documentation and Details for Simplified 2-Joint Wedge Analysis G: Generalization of the Stiffness Approach H: Inadequacy Due to Simplifying Assumptions in Wedge Analysis I: Rock Slope Reliability Analysis: State of the Art J: Resistance Derivations for Mechanical Model K: Supporting Derivations for Analysis Method DAYLITE L: Supporting Derivations for Simplified 2-Plane Reliability Analysis M: Plots of SLOPESIM Runs

Jan 1, 1979

By P. Walford, C. Mealin, D. Good

"The geology of the Ore Fault Ni-Cu deposit has been reinterpreted in the light of recent studies of the geology of the Neoarchean Bird River Sill Complex and the occurrence of economic Ni-Cu and Zn-Cu-Ag mineralization. The Ni-Cu sulfides are hosted by the lower of two parallel NNW-trending and moderately W-dipping mafic-ultramafic intrusions related to the Bird River Sill Complex. The bod¬ies intruded a bimodal volcanic suite consisting of weakly deformed mafic flows and felsic pyroclastic rocks. The mafic volcanic rocks are geochemically related to the MORB-type rocks of the Lamprey Falls Formation, and the felsic volcanic rocks are related to arc-type rocks of the Peterson Creek Formation. The original pyroxene- and olivine-dominated mineralogy of the sills has been replaced by variable ser¬pentine-amphibole-talc-carbonate assemblages.The Ni-Cu sulfide assemblage exhibits textures and geochemical signatures typical of orthomagmatic sulfide mineralization. The sulfide minerals are associated with cumulate layers of magnetic ferrochromite that range in thickness from a few to tens of centimeters. A later event of Zn-Cu-Ag sulfide mineralization associated with quartz veining and garnet-chlorite alteration along a fault that strikes north, dips vertically, and cuts all rock types. The mineralized fault is cut by the NE-trending Peterson Creek shear zone. Where the Ni-Cu and Zn-Cu-Ag mineralized zones intersect, remnant magmatic features such as amphibolite or cumulate ferrochromite bands occur within quartz veins or local chlorite alteration. The mixed zones contain a very unusual polymetallic assemblage of Ni, Cu, Zn, Ag, and platinum group elements (PGE)."

Jan 1, 2009

By M. Jaffe

The data developed in this study establishes the technical and economic feasibility as well as the improved health and safety characteristics of a novel mining concept. The mining concept is a modified longwall technique using prestressed tendons for roof control, longhole blasting for fragmentation, and remote mucking. The technical feasibility was found to be dependent on the state of the art, while economic feasibility was found to be dependent on particular minerals and on supply and demand. Since these two conditions are not necessarily coincident in time the data is presented in the report in a manner that enables the mining engineer to perform a rapid preliminary technical and economic analyses for a specific property.

Jan 1, 1977

By Joseph B. Cummings

"INTRODUCTION The property was first examined by an engineer 3/ of the Bureau of lanes in December 1942 and was later investigated by the sane engineer in January and February 1943. Prominent outcrops and underground exposures of high-grade iron ore, together with mention of sizable intersections of hematite in logs of four widely scattered churn—drill holes, indicated the possible occurrence of a substantial tonnage of iron ore at this old copper producer.From March to May 1943, detailed topographic and geologic mapping of the property was done by the Federal Bureau of Mines, the Federal Geological Survey, and the Arizona Bureau of Mines.Funds were allotted for exploration of the property by churn and diamond drilling. This work was started in December 1943 and completed in June 1944.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Nines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts, developed by each exploratory project as soon as practicable after its conclusion. The Mining Drench, Lowell B. Moon, Chief, conducts preliminary exmination, performs the actual exploratory work, and prepares the final report, The Metallurgical Branch, P. G. Knickerbocker, Chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision Dr. R. S. Dean, Assistant Director."

Dec 1, 1946

By Shaw-Shong Liew

This paper presents the processes of investigation, analysis, design, construction and monitoring of soil nail stabilisation work to facilitate a 14.5 m deep excavation at an uncontrolled fill ground. An extensive instrumentation programme had been implemented to monitor the performance of the stabilisation solution, to provide validation for the designed nail resistance and groundwater variation. From the monitoring results, it was proved that the soil nail stabilisation technique is effective for loose saturated fill provided that substantial care is taken during implementation. Construction difficulties, solutions to overcome the problems and lessons learned will be discussed in the paper.

Jan 1, 2006

By Keith R. Vining

Solid fuel, usually coke or anthracite, is commonly added to ground iron ore fines in the pelletising process to reduce the amount of burner fuel required and the maximum firing temperature, while maintaining pellet strength and the productivity of the pelletising plant. However, the use of coke and coal contribute to the production of greenhouse gases (eg carbon dioxide) and are a source of NOx and SOx emissions. Utilising wood biomass / wood char is one methodology CSIRO Minerals is investigating as an alternative to coke and coal, as it is a renewable energy source that is very reactive, has a low ash content and the potential to reduce emissions of greenhouse gases from the iron and steel-making process. Previous work has established that charcoal can effectively replace coke in the sintering process (Lovel et al, 2005), and the following experimental work aims to demonstrate that it can also provide an adequate replacement for coke and coal in the pelletising process. The paper presents the results of an experimental testwork program comparing the behaviour of fired pellets containing traditional solid fuels and charcoal. The physical properties of the pellets are compared in terms of their compressive strength, tumble and abrasion indices and the reduction properties. A qualitative assessment of the pellet microstructures is also presented.

May 1, 2007

The works of Metal Manufactures Ltd are situated at Port Kemblam NSW, within a few hundred yards of a deep-water harbour. At present they occupy about 26 acres, and ample provision has been made for future extensions. Rail connection exists between various parts of the Works and the main South Coast Railway, the harbour jetties and the adjacent copper refinery of The Electrolytic Refining and Smelting Co Ltd. A plan of the works is shown in Fig 1.The company was incorporated in March 1916, and commenced production of copper wire in June 1918. Early in 1920, tube manufacture was undertaken, followed by telephone cable mnufacture in 1923. Today the Works consist of five principal sections: Founrdy, Tube Factory, Wire Factory, Cable Factory and Case and Drum Factory. Whilst the last four are engaged in producing the finished materials for despatch from the Works, the first-mentioned is engaged in producing copper, brass, and other non-ferrous billets for use in the Tube and Wire factories. In addition, there are Engineering and Metallurgical Departments supporting the manufacturing sections, and in these, as well as in all other sections of the Works, extensions have been carried out from time to time to provide for increased output and new types of products.

Jan 1, 1938

By Chu E. Ho

Field load tests on deep slurry stabilized bored piles have shown that end bearing resistance was unreliable due to soft toe conditions caused by debris accumulation at the bottom of the hole during pile installation. This is true whether bentonite or polymer slurry was used. Skin friction resistance was less affected by the slurry and is more reliable. A design strategy is proposed which ensures that an adequate factor of safety against the ultimate shaft resistance is maintained for any chosen design working load, such that a pile settlement of 12mm would not be exceeded.

Jan 1, 2002

By Omid Lashkari

Keywords: SEED, SSM materials, Microstructural evolution, Rheology, Swirling Speed SEED (Swirled Enthalpy Equilibration Device) is established itself as a new technology amongst the many Semi-Solid Metal (SSM) processes, where swirling of the mush plays an important role in modifying the dendritic structure of as-cast parts. A range of semi solid metal structures, dendritic, rosette and/or globular morphology of primary phase, can be prepared using SEED. The current article reports on the application of rheological tests in characterizing microstructural evolution during SSM processing of 356 Al-Si foundry alloy. A simple parallel plate test machine, designed and constructed at our labs, was used to determine viscosity values for each structure and identify the optimum structure with superior die filling characteristics. Such findings have important technological and economical implications during high pressure die casting of semi- solid metals. The strain-time graphs for 356 Al-Si foundry alloy indicated lower viscosity values for globular microstructure, i.e. improved die filling.

Jan 1, 2005