Search Documents

By I. D. Shah

Thermal decomposition of copper (II) sulfate (CUS04) and copper (II) oxy-sulfate (CuO?CUS04) are important steps in the overall oxidative roasting of covellite (CuS) and chalcocite (Cu2S). Nonisothermal thermogravimetric techniques were used to investigate the decomposition reactions in flowing Na and air. Thermal decomposition of CUS04 and CuO?CUS04 followed "linear" kinetics with an apparent activation energy of 55±2 and 66±3 kcal per mole decomposed, respectively. These apparent activation energies comply with those previously reported when isothermal kinetic techniques were used. The addition of oxygen decreased the rate of decomposition, while small amounts of iron which were admixed with CuO?CUS04 did not have a significant effect. Neither oxygen nor iron had any appreciable effect on the apparent activation energy of the decomposition reaction.

Jan 1, 1972

Reduce injury to people or damage to equipment when a scheduled production blast is detonated. Approach The essential elements of an effective blast area security system were identified through case studies of five mining operations where the blast area guarding practices were considered to be superior to those generally found in the industry. These elements were used in making recommendations for improved blast area safeguarding practices. Background The blast area security system is a means by which the mine operator prevents injury to people or damage to equipment when blasting is performed. Analysis of blasting accidents showed that most blasting accidents occur during scheduled blasting and are due to inadequate blast-site security. Factors contributing to the system's breakdown are failure to clear the blast zone, inadequate guarding. and failure of personnel to follow instructions, retreat to a safe location, and/or take adequate cover. Mine personnel, visitors and even trespassers can inadvertently wander into a blasting zone unless proper procedures exist to ensure that all personnel are cleared from the blast zone and kept safely away until after blasting IS completed. Statistics show that the blaster is the miner most frequently injured In these accidents.

Jan 1, 1986

By James P. Rider

This U.S. Bureau of Mines report describes a viewing transformation algorithm that generates a perspective view of a three-dimensional scene. This tool may be used by researchers to improve mine safety by assessing the visual capabilities of a mobile equipment operator. Three-dimensional transformations used to build the viewing transformation and techniques used to project the image onto a two-dimensional display screen are defined. The algorithm is written in the C-programming language and designed to stress portability, allowing it to work without significant modifications on numerous computers. A listing of the computer routines along with sample output is included in the report.

Jan 1, 1992

By Barbara J. Halpern

There?s no denying that mining is a male-dominated industry. Yet thanks to technologies developed over the last 20 years, societal changes in sex role stereotyping, individual determi­nation, and the willingness of companies to train women, there are no jobs in mining today where women are not represented. Women are drillers and electricians as well as drivers of heavy equipment and haulpack trucks. They perform jobs ranging from field exploration and metallurgy to clerical and janitorial and warehousing positions, from prospectors and underground blasters to geologists and land reclamation experts, from communicators to legal experts on mining law and more. The Women?s Mining Coalition, founded in 1994 to shepherd responsible legislative mining reform, estimates that 20 percent of the workers in the mining industry are women. Although women are concentrated in clerical and adminis­trative jobs, at least 10 percent are in non-traditional, hardhat jobs, claims the group. There are women in management, but the numbers in senior management remain small, especially in larger companies.

Feb 1, 1998

By John R. M. Hill

The Bureau of Mines performed elastic-plastic, finite-element analyses to investigate the support performance of hydraulic backfill. A mathematical model was developed for two vertically adjacent stopes separated by a sill pillar. An exact duplicate of a working stope was not intended; however, the model did simulate a working stope to the extent that field measurements from an active stope could be used for comparative purposes. Using a predetermined mining sequence, the computer analysis simulated the mining operation as a series of incremental cut-and-fill steps. Computer results included a complete history of stope closure and pillar stresses throughout the mining sequence. With the mining sequence and rock properties held constant, three separate analyses were made using varying backfill properties. These cases included no fill,-low-to-medium-quality fill, and medium-to-high-quality fill. Results of these analyses show decreases in stope closure and pillar stresses as the backfill quality increases, thus reducing the possible occurrence of rock bursts. Predicted stresses within the backfill compare favorably with field measurements. A relationship between maximum stress normal to the stope wall and the ratio of relative fill stiffness to relative rock stiffness was also indicated.

Jan 1, 1974

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989

By Eric Cather

A mineral investigation of prospects in the Sawtooth Mountains B Wilderness Study Area (WSA) by the U. S. Bureau of Mines in 1983 revealed none had mineral production, resources, or development potential. The area is underlain by tonalite and smaller amounts of schist, One developed prospect and one prospect pit are in the WSA. They are in schist similar to host rock which has yielded gold in nearby mining districts, Sand and gravel deposits in the WSA are large but too far from markets to be considered resources. No energy (oil, gas, coal, or geothemal) resources were identified in the USA.

Jan 1, 1984

By W. H. Engelmann

The electrokinetic (zeta) potentials of a charcoal granite in an aluminum chloride (AlCl3) solution and in an oleylanunonium acetate (C18H35NH3+ -OCOCH3) solution have been correlated with the specific damping values as measured by the pendulum sclerometer. This investigation shows that the pendulum specific damping attains a minimum at the isoelectric point for the charcoal granite-aluminum chloride and charcoal granite-oleylammonium acetate systems, and thus indicates that the penetration of the diamond points is a maximum at the isoelectric point.

Jan 1, 1967

By Fred N. Kissell, J. E. Matta, J. C. LaScola

The methane gas emitted from coal samples collected from the conveyor belts dumping into silos was measured by the Bureau of Mines. Approximately 50 pct of the total gas desorbed into a sealed can within 1 week was released during the first 24 hours. No simple correlation between the gassiness of the coal stored and the methane concentration in the silo open space above the coal was found. This was probably because the gassier coals were stored in open-top silos, which were better ventilated. Although the methane concentration in the open space above the coal pile was less than 1 pct for all 34 silos investigated, a methane measurement in the coal pile showed that high methane concentrations can exist. The methane released in the pile appears to accumulate and not liberate freely into the open space above the coal pile. Probably this gas is released during reclaiming operations, but further research is required to substantiate this claim.

Jan 1, 1978

By Donald R. Johnson

Apparatus developed by the Bureau of Mines for thermal analysis of oil shale was used to determine the thermal properties of shortite. Dissociation of shortite near 470° C occurs as an endothermic reaction that could consume significant quantities of heat in the oil-shale retorting process that produces shale oil. The shortite dissociation products undergo other thermal reactions that would not affect the retorting process. These reactions include crystal inversions near 365° C and 425° C and melting and decomposition endotherms above 500° C. Two separate reaction route for fusion and decomposition of the shortite decomposition products are dictated by the presence or absence of CO2 around the sample.

Jan 1, 1974

By Alfred E. Schwaneke

The surface tension from 240° to 844° C and the density from 236° to 583° C of 99.999 percent purity liquid tin has been measured using the maximum-bubble-pressure method. Results for surface tension (y) show y (dynes/em) = 566.84 -4.76 X 10-2 T (° C) with a standard error of 1.9 dynes/cm. Results for density (p) show p (g/cm3) = 7.16 -6.3 X 10-4 T (° C) with a standard error of 0.012 g/cm3. Comparisons with other data found in the literature are discussed. The experimental results are considered to be as good as any data presently available.

Jan 1, 1970

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

By Daniel Edelstein

The supply of arsenic trioxide in 1982 was adequate to meet domestic demand. Allocation of supply by major domestic and foreign producers that began in 1977 ended during the first quarter of 1982. Major demand was about evenly divided between industrial chemicals and agricultural chemicals. Domestic Data Coverage.-Commercial- grade arsenic trioxide and arsenic metal were produced by only one U.S. company. In order to prevent disclosure of proprietary data, arsenic production data have been withheld.

Jan 1, 1983

By W. A. Calhoun

The purpose of this investigation was to develop a procedure for removing excess iron from representative samples of bauxite ore from the Quapaw deposit of American Cyanamid Co., Saline County, Ark., in order to produce a beneficiated ore suitable for use in the alum industry, At the request of the sponsoring company, the samples were reduction-roasted at 800° C. and then magnetically separated. Although some rejection of iron was effected under these conditions, the general results were not satisfactory, A much more successful procedure, from the standpoints of both rejection of iron and recovery of alumina, consisted of a short (l5-minute), low-temperature (400° C.) oxidizing roast, followed by a 2-minute interval in a hydrogen atmosphere, then cooling to room temperature, and, finally, high-intensity magnetic separation to remove the iron.

Jan 1, 1957

By A. Visnapuu

The Bureau of Mines investigated carbonyl processing techniques for the recovery of the critical metals Ni, Co, Mn, and Cr from domestic primary and secondary sources. In most cases, the source materials require reductive precarbonylation treatment to metallize the contained Fe, Ni, and Co compounds to render them reactive with CO. The critical metals were recovered either by direct conversion to the respective carbonyls or as upgraded products by carbonyl removal of an undesirable metal. Best metal-to-metal carbonyl conversion was under CO pressure, from 80 atm upward, and at 1400 C. Carbonylation was accelerated by the addition of HzS in small quantities. CO pressure, temperature, promoter and pretreatment trends, and other factors enhancing metal carbonyl formation are presented.

Jan 1, 1987

By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

By W. Blake, J. Whyatt

Sixty years of rockbursting in the Coeur d’Alene district has taught painful lessons and led to a number of practical advances in controlling rockburst hazards. This paper summarizes those lessons, concentrating on practical measures that have been successfully adopted to reduce hazards. These lessons are explained in the context of district mining history and current understanding of rockburst phenomena. Overall, the paper provides the practicing mine engineer with an appreciation of rockburst hazards and an overview of practical measures that can be used to control these hazards in the context of Coeur d’Alene district experience.

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

To develop an in-mine water treatment system in which bacterial sulfate reduction and limestone dissolution continuously remove metals and acidity from contaminated drainage. Approach A section of mine tunnel was converted into a water treatment bioreactor by constructing cinder block dams and fang the area between them with a porous substrate mixture of limestone gravel and compost. Readily fermentable materials such as dairy whey, spent brewing yeast, or sugar were periodically added to the reactor. Mine drainage was impounded behind one of the dams and continuously percolates through the reactor substrate at a controlled rate. How It Works The reactor substrate soon becomes anaerobic after it is saturated with mine water. Under anaerobic conditions, sulfate-reducing bacteria consume the organic materials that are added to the reactor and generate hydrogen sulfide (HIS) and alkalinity. The H2S reacts with dissolved iron and heavy metals to form metal sulfide precipitates. The alkalinity raises the pH of the water and induces aluminum to hydrolyze and precipitate as aluminum hydroxide [Al(OH)3]. Additional alkalinity is generated by the continuous dissolution of the substrate limestone. Metal sulfide precipitates and Al(OH)3 are retained within the reactor, and the treated water is discharged. The underground location of the system allows year round operation.

Jan 1, 1994

Develop a cost-effective diesel aerosol sampler that can be used by industry and regulatory agencies to determine the diesel exhaust aerosol concentration in mine atmospheres. The sampler must be easy to use, wearable by mine personnel, compatible with current personal sampling protocols, and inexpensive. Approach The University of Minnesota (University) and the U.S. Bureau of Mines (USBM) have developed and tested a prototype diesel exhaust aerosol sampler. The sampler, however, was complicated and expensive to fabricate. Consequently, the USBM redesigned the sampler to simplify both manufacturing and use, and the sampler was evaluated to ensure equivalency with the prototype. Background The National Institute for Occupational Safety and Health (NIOSH) has recommended that "whole diesel exhaust be regarded as a 'potential occupational carcinogen,' as defined in the Cancer Policy of the Occupational Safety and Health Administration." In addition, the U.S. Mina Safety and Health Administration (MSHA) has been directed by an advisory committee to establish a diesel exhaust aerosol standard and regulations to minimize exposure to diesel pollutants in underground coal mines.

Jan 1, 1992