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By Louis H. Berkelhamer

"INTRODUCTION The method of differential thermal analysis suggested by Le Chatelier (1)1 in 1887 has recently emerged as an outstanding means of studying the constitution of various substances, particularly clays, soils, and miscellaneous hydrous materials (2). The literature ably discusses the applications and results obtained but has paid too little attention to specific details of construction of the apparatus. Knowledge of the apparatus is of importance to the experienced research man as is extremely useful to the novice v ho ventures into this field of analysis. Further, it is generally acknowledged that the variations in design and conditions of operation are one of the essential causes for differences in characteristic temperatures as reported by various investigators. A step forward in the elimination of such differences is the publication of the details of construction and operation of a simple and inexpensive apparatus that has proved useful at the southern Experiment station of the Bureau of Mines, where it was used in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jul 1, 1944

By T. D. Hackett

Multislice mining methods were analyzed by the U.S. Bureau of Mines to determine their application to western United States thick coal seams; ground control, geology, and costs were considered. Multislice mining is used in widely varying seam conditions worldwide, including flat seams too thick to mine in a single pass, pitching thick seams, and seams containing a rock parting. Longwall multislice methods predominate, but room-and-pillar variants also exist. The initial use of the method in western seams is planned at a deep Colorado mine where a rock parting will be used to separate two slices mined by longwall. Ground control and spontaneous combustion are major hazards associated with multislice mining. A well-consolidated upper slice gob can reduce ground control problems and provide a seal against spontaneous combustion. Geologic analysis indicates that the consolidation of the gob depends on the composition of the upper slice roof, the presence of water, and sufficient overburden pressure. A geologically competent intermediate rock parting can also reduce ground control problems and seal against spontaneous combustion. To compete in western coal markets, the cost of multislice mining must be within the range of normal longwall costs. Analysis indicates that multislice operating costs should be within this range, and that multislice mining costs decrease as panel width increases. Relatively wide (600 to 800 ft) panels also provide increased coal recovery.

Jan 1, 1990

By T. E. Gray, A. W. Deurbrouck

This report describes the preparation characteristics of significant coalbeds in Kanawha County , W. Va . It is one in a series of Federal Bureau of Mines reports planned to determine coals suitable for producing metallurgical coke , either as mined or after beneficiation . Almost 9.4 million tons of coal was produced in Kanawha County , W. Va . , in 1959 , of which about 67 percent was cleaned mechanically in 10 cleaning plants . It has been estimated that more than 5,505 million tons remain in the county . Samples were collected from Pittsburgh , Stockton - Lewiston , Winifrede , Cedar Grove , Peerless , Upper Kittanning , Coalburg , Powellton , Eagle A , No. 2 Gas , and the Lower Kittanning beds . These beds were selected by the Bureau based on current production rates and estimated minable reserves . Float - and - sink tests of the samples collected from Eagle A , Peerless , Cedar Grove , Winifrede , and No. 2 Gas beds show that these coals at one location each are suitable for metallurgical use without washing . Lower Kittanning bed at four locations ; Pittsburgh , Stockton - Lewiston , and No. 2 Gas beds at two locations each ; and Coalburg , Powellton , Winifrede , Peerless , Upper Kittanning , and Cedar Grove beds at one location each can be upgraded to metallurgical quality by mechanical cleaning . Crushing the samples to 3/ 8- inch top size increased yields substantially at 1.30 specific gravity of Pittsburgh ( 17.5 percentage points ) and Upper Kittanning ( 13.0 percentage points ) beds and increased yield for the other beds sampled to a lesser amount . At this specific gravity , finer crushing caused In the 1.58 specific gravity float a general decrease in ash and sulfur . fractions of the other samples tested , most of the yields , and ash and sulfur contents , were lowered slightly by finer crushing .

Jan 1, 1963

By Wilder D. Foster

In the method used in the Health Branch of the Bureau of Mines for petro-graphic identification of the minerals in a rock, the sample is crushed, ground to a fine powder in a mortar, the powder is put on a slide, a drop of index oil and a cover slip are added, and the slide is ready for examination. The rock should be ground fine enough so that most of the particles consist of only one mineral, otherwise identification is difficult. Finally, the amounts of the minerals present in the sample are estimated to the nearest 5 or 10 percent. When quartz grains are mixed with some claylike minerals) of which by far the most common example is quartz and kaolinite in a shale, grinding in a mortar does not always separate the quartz from the kaolinite; instead, the quartz grains become coated with the kaolinite and are not visible, even after careful search. Talc acts Similarly, but muscovite and pyrophyllite do not. In evaluating the possible silicosis hazard of breathing dust from a shale, it is essential to be able to see and identify all of the quartz grains, as the other minerals present are relatively innocuous.

Jan 1, 1949

By D. J. MacDonald

This U.S. Bureau of Mines report reviews published information on synthetic berlinite (AlP04) and suggests experimental conditions requisite for its production. Berlinite is a piezoelectric material with potential use as a substitute for quartz in the crystal oscillators, which are components of electronic and electroacoustic equipment. Information gathered here (mostly from published sources) includes historical background, physical properties, end-use applications, criteria of quality, and physio-chemical factors involved in berlinite crystal growth. It is concluded that growing large high-quality berlinite crystal would require high-purity starting materials in an autoclave equipped with a noncorrodible liner and operated with temperature control of ±O.OO5 ac over a range of 250 to 350 ac.

Jan 1, 1995

By F. P. Haver

The Bureau of Mines has investigated the electrochemical reduction of lead chloride as a method for producing lead without the pollution problems associated with smelting. It was determined that high-purity metal (>99.9 pct Pb) could be obtained, using PbC12 prepared by ferric chloride leaching of galena concentrate: PbS + 2FeCl3?PbCl2 + 2FeC12 + S°. Optimum results in small-scale electrolytic tests were achieved with a bath consisting of 40 to 70 wt-pct PbCl2 dissolved in KC1-LiCl eutectic, an operating temperature of 450° C, a current density of 2.5 amp/in2, and an electrode spacing of 0.5 inch. In large-scale tests made to develop a cell design for commercial application, the optimum electrode arrangement proved to be a bipolar configuration with horizontal plates. This gave a current efficiency of 86 pct with an energy requirement of 0.52 kwhr/lb lead. To determine the effect of impurity buildup in the bath, 1,200 lb of PbC12 prepared by ferric chloride leaching of galena concentrate was electrolyzed over a period of 2 months. Little deterioration of the metal quality occurred in that time; all of the lead produced had a purity equal to or better than corroding grade (>99.94 pct Pb).

Jan 1, 1976

By Jos. R. Guiteras

This is one of a series of information circulars describing mining and milling methods being published by the Bureau of Mines. The Summitville Consolidated Mines, Inc., is the only company now active at Summitville. Since the holdings of the company include those of most of the former producers of the camp, the paper virtually becomes a description of the Summitville district. The field data were collected from August 23 to 28, 1937. ACKNOWLEDGMENTS The writer gratefully acknowledges his indebtedness to H. F. Detrick, president, and Edward Thornton, general manager of the company for their cooperation in making this paper possible. Most of the information on underground operations was given by Roy Jellison, mine superintendent; the metallurgical data were supplied by Art Carl son, metallurgist, and W. L. Anderson, mill superintendent; much general and technical information was supplied by J. H. Hannan, engineer.

Jan 1, 1938

By Robert F. Chaiken

The U.S. Bureau of Mines conducted an experimental and theoretical study of coupled chemical kinetic and mass transport processes during leaching of pyrite from coal in a counterflow, "trickle-bed" column reactor. Spatial and temporal data on reactant and product concentrations were used as solutions to appropriate continuity equations, which in turn define chemical kinetic reaction rates. Data from four 180-by 30-cm column leaching experiments using coal, coal waste, and air-water and air-FeC13 lixiviants have been analyzed. The rate of leaching was found to be diffusion limited (probably by Fe3+) and not controlled by bacterial action. Rates of pyrite oxidation were found to vary with elapsed time (80 to 225 days) and followed a bell-shaped curve, sometimes with a delay before start of reaction. Maximum rates of reaction ranged from 3 to 10 (mmol/d)/L (column) for coal waste and 0.4 (mmol/d)/L (column) for coal. Reaction was 30 to SO pct complete, probably due to precipitation of product salts (e.g., jarosites), which impede transport of oxidant through the coal. An absorption-desorption model of solids leaching, which considers the role of heterogeneous porosity in solids leaching, was used to describe time-dependent leaching rates.

Jan 1, 2010

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By H. W. Sheffer

Technical and economic aspects of community refuse disposal systems and their effects on the environment are identified and described. Seven landfills and two incineration systems, located throughout the United States, are reviewed.

Jan 1, 1971

By W. P. Yant, H. C. Fowler

"INTRODUCTIONHydrogen sulphide is probably the most toxic gas associated with crude oil. Hydrocarbon (petroleum) vapors themselves are harmful to the human system, but hydrogen sulphide, when present, is usually more important from the standpoint of health and safety. These conclusions were reached in an investigation of the toxic gases encountered in the transportation end refining of high-sulphur petroleum. The results of that investigation are presented in Bureau of Mines Bulletin 23l. although the writers of Bulletin 231 paid no direct attention to the production of oil in the field, they attributed to hydrogen sulphide reports of accidents caused by gas in the oil fields of Mexico.During the development of oil fields in Texas, a ""poison gas"" was encountered that constituted a decided health and safety hazard. The present report discusses an investigation of this gas made in July, 1926.The major portion of the investigation was conducted in the Panhandle field of Texas, but the study also includes the Big Lake and McCamey fields.Scope of WorkThe work undertaken in each field included:Examination of the gas-coming from representative wells at various locations in the field; also analyses of the gas-air mixtures to which the workmen were or might be exposed.Observation of symptoms of poisoning and severity of these symptoms."

Oct 1, 1926

By Lucien Eaton

This paper describing the mining practices at Mine No. 1, Menominee Range, Mich., is one of a. series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. It is felt that the publication of this information will be of interest and value to the mining industry at large and especially to operators whose mining conditions are similar to those described. ACKNOWLEDGMENTS The author is indebted to the superintendent, engineer, and mining captain of Mine No. 1 for much of the information presented.

Jan 1, 1929

By Heine Kenworthy

"INTRODUCTION In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral content of this ore was considerably higher than in, the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently, tailing losses, especially with respect to lead, were high. A few years later, in order to study the possibilities of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill, feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Sta¬tion for testing-. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values was present.A résumé of the ore-dressing treatment used in the Shenandoah-Dives mill follows. After crushing, the ore passes through a ball mill, the minus 5-mesh discharge of which is distributed to three tables. A finished lead concentrate is made on the tables, and the table tailing goes to the classifier which is in closed circuit with the ball mill. The classifier overflow is treated -by flotation to obtain a bulk sulfide concentrate at a relatively coarse size. The bulk concentrate is thickened and reground to about 95 percent minus 325-mesh before flotation treatment to separate a lead-copper and a zinc concentrate. A typical monthly average showed that the table concentrate contained about 45 percent lead, 1 percent copper, 4 percent zinc, 12 ounces of gold, and 40 ounces of silver; that the lead flotation concentrate contained '35 percent load, 6 percent copper, 7 percent zinc, 3.5 ounces of gold, and 50 ounces of silver; and that the zinc flotation concentrate contained 2 percent lead, 0.5 percent copper, 60 percent zinc, 0.15 ounces of gold, and 4 ounces of silver. Recoveries in salable products were roughly b5 percent of the lead, 70 percent of the copper, 45 percent of the zinc, 85 percent of the gold, and b5 percent of the silver."

May 1, 1948

By John Furness Park

This paper, which describes the mining methods and practices at the Jarbidge mines of the Elkoro Mines Co., is one of a series of papers being issued by the United States Bureau of Mines on mining methods and costs in various districts throughout the United States. LOCATION AND HISTORY The Elkoro Mines Co.'s property is located at Jarbidge in the northeast corner of the State of Nevada (fig. 1). The camp is 9 miles south of the Idaho line; the nearest railroad point is 70 miles to the northeast at Rogerson, Idaho. A road leading to the south and connecting with Deeth, Nev., is passable during the summer months; the heavy snowfall which generally takes place early in the winter usually closes the road until the first of July.

Jan 1, 1931

By Robert L. Davidoff

Growing domestic and global demands for mineral resources have established an imperative need for developing comprehensive, versatile mineral supply analysis evaluation tools. The Minerals Availability System (MAS) of the Bureau of Mines is meeting this need with its computerized Supply Analysis Model (SAM). This paper describes the SAM system and the quantitative methods used by the MAS for mineral supply analyses. The MAS evaluating process consists of deposit identification, tonnage and grade determinations, engineering and cost evaluations, financial analyses, and supply curve generation. MAS has developed this computerized system primarily to facilitate the maintenance of data information for the constructing of commodity supply curves. The SAM system presently has the analytical capabilities of simultaneously (I) evaluating many mineral deposits, (2) updating mineral supply information to reflect inflationary changes in costs and prices, and (3) conducting sensitivity analysis to determine impacts on mineral supply under various conditions. Many potential users in both government and industry will find the SAM system a valuable tool for policy analysis, forecasting, and planning. The SAM system has been constructed so that any types of information that are similar to the data elements in the MAS data base may be used to perform supply studies. The storage space needed for the SAM system?s programs, files, and output data is approximately 14 million characters.

Jan 1, 1980

By J. R. Hauger, P. A. Romans, W. J. Niebuhr

With suitable instrumentation and techniques it is possible to determine the presence of tantalum in columbium to 20 ppm . This paper discusses the selection of X- ray spectrographic instrumentation and describes a technique for accomplishing the low level determination of tantalum . An ion- exchange method of separating tantalum from columbium is also described .

Jan 1, 1964

By H. N. Smith

IN 1944 the Congress passed the Synthetic Liquid Fuels Act that authorized the Secretary of the Interior, acting through the Federal Bureau of Mines, to conduct basic research and construct and operate demonstration plants to produce synthetic liquid fuels from coal, oil shale, and other substances. As a basis for the oil shale investigations to be undertaken in this country, the progress of foreign countries in developing and using oil shale as a source of liquid fuels was studied by the technical missions of the Federal Bureau of Mines. Oil shale mines, retorting plants, and refineries were visited; geological information on the nature and occurrence of the foreign oil shales was obtained; and samples of the oil shales were collected where possible. Samples collected by these missions or acquired by other means came from Australia, Brazil, Canada, France, Manchuria (China) , New Zealand, Scot-land, Spain, Sweden, Thailand, and Union of South Africa. These countries represent a large part of the locations where oil shale developments have taken place. The major omissions are the Estonian, German, and Russian developments.

Jan 1, 1959

By N. S. Petersen

As part of the Demand Evaluation Program of the Bureau of Mines to determine future needs for minerals, a study was instituted to develop and describe a methodology for approaching the problem of substitution between mineral commodities and between mineral commodities and other materials. The report comprises three sections: A review of general factors relative to substitution, a case study of the effect of substitution on zinc die-casting markets in recent years, and a general methodology for reviewing materials substitution with specific emphasis derived from reviewing substitution in the domestic zinc die-casting markets.

Jan 1, 1971

By George L. Gates

The Bureau of Mines developed a rapid instrumental method of analyzing oil well scales containing primarily barium sulfate. After removal of oil and water by carbon disulfide) the scale was dissolved in strong hydrochloric acid. The cations, barium, calcium, strontium, magnesium, and iron, were determined with the flame photometer using the method of additions. Sulfate was deter-mined colorimetrically after separation by selective adsorption on an alumina column. Phosphate was determined colorimetrically and carbonate titrimetrically. The method was reasonably accurate, although iron and magnesium were found to have mutual interference.

Jan 1, 1965

By R. W. Stahl

Gas accumulation and dust suspension are the major safety hazards in coal stockpiling and reclaiming operations. This report presents a schedule of safety precautions and plant design features devised by the Bureau of Mines to reduce danger from these and other sources.

Jan 1, 1965