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By S. M. Bradshaw, R. Smith, J. H. van Vreden, C. A. Snyders

"The re-treatment of gold tailing heaps has shown to be a potentially significant revenue stream for both large and small scale gold companies. Limited access to capital and lack of skilled labour remain restrictive especially when dealing with a refractory ore and/or where limited amount of material are available. Alternative techniques such as low temperature pre-leaching options to unlock value are therefore in demand. Several low temperature pre-leaching experiments in acidic and alkaline solutions, followed by cyanidation were performed which ultimately led to the further investigation of a caustic pre-leaching step. It was found that the Au recovery from a refractory ore tailings heap could be significantly improved from ˜ 15 to 20% to greater than 60% with a simple atmospheric NaOH pre-leaching step. It was further considered, that since the NaOH pre-leach liberate the Au associated with refractory sulphide minerals, the overall process may benefit by the inclusion of a froth flotation step to separate refractory sulphides from the free milling ore. Froth flotation on weathered tailing heaps are, however, known to be difficult, ultimately resulting in poor recoveries. A process flow sheet, incorporating a caustic pre-leaching step and a process which includes flotation and caustic pre-leaching of the concentrate, are technically evaluated and ultimately compared to simple cyanide re-processing. INTRODUCTION South Africa consists of a large number of gold tailings dumps. Janse van Rensburg (2016) estimated that there was about 517 dumps in the Gauteng area, covering approximately 320 000 ha of surface area. Recovering value from the dumps has received a great deal of interest but can be problematic due to the dumps often being refractory, preg-robbing and weathered. High recovery of valuable metals (Au and Ag) are possible (Fleming and Brown, 2010) but would most likely require pressure oxidation and subsequent neutralisation which can be very capital intensive demanding a high skill set to operate and maintain. In addition, these flowsheets target high processing tonnages due to the economy of scales at the lower grade feed materials, further increasing the capital requirement."

Jan 1, 2018

By S. Carsten, S. Subramanian, R. Vasant Kumar, S. Vimalnath

"The effect of EPS components namely protein, polysaccharide and biosurfactant purified from Pseudomonas fluorescens was investigated for the bioremediation of Pb(II) ions in aqueous solution. Two parameters, namely the amount of EPS component and the concentration of Pb(II) ions were optimized for maximum Pb(II) ions uptake. The EPS components interacted with Pb(II) ions were characterized using energy dispersive X-ray analysis (EDAX) to ascertain the presence of Pb and by attenuated total reflection-Fourier transform infrared spectroscopy (ATR–FTIR) to reveal the functional groups involved in Pb(II) binding. The maximum Pb(II) binding capacities of protein, polysaccharide and biosurfactant were found to be 11.4, 0.55 and 0.11 mg mg-1 respectively. The biosorption processes followed the Langmuir model. The Gibbs free energy (?G0) values of -23.6, -20.9 and -23.2 kJ mol-1 for Pb(II) biosorption by protein, polysaccharide and biosurfactant respectively, attested to spontaneous, chemisorption processes. The ATR–FTIR results revealed the presence and involvement of amino, hydroxyl, carboxyl, phosphate, and methyl functional groups in Pb(II) binding and EDAX analysis confirmed the interaction of Pb with EPS components. The Pb(II) binding mechanisms of EPS have been discussed. The results demonstrate the potential of the purified EPS components of P. fluorescens for removal of Pb(II) ions from aqueous solution INTRODUCTION Waste water containing toxic metals from various industries pose a serious threat to human health and ecosystem. For treating such waste water, conventional methods like chemical precipitation, coagulation, evaporative recovery, electrodialysis, floatation, flocculation, ion exchange, reverse osmosis, nanofiltration, ultrafiltration are used (Lakherwal et al., 2014). These methods have some disadvantages like toxic sludge generation, incomplete metal removal and high cost (Singh and Gadi, 2012), necessitating the search for cheaper and efficient alternative methods. Bioremediation is one of the emerging alternatives where bacteria, fungi, yeast, algae and other biological substances are used as sorbents to remove toxic heavy metals (Vijayaraghavan, et al., 2015). Recently, the bioremediation potential of extracellular polymeric substances (EPS) of microbial origin has attracted attention. However, for Pb(II) removal, there is a paucity of literature focusing on EPS."

Jan 1, 2018

By I. D. Ustinov, V. A. Arsentyev, A. O. Mezenin, A. M. Gerasimov

"The solid mineral raw materials of the sediment deposits containing the argillaceous variations such as the coal and the potash ores are the most multi-tonnage solid minerals mined and processed in the territory of the Russian Federation. Both types of the deposits have relatively simple geology aspects with large and medium-sized solids and as a rule, the most often, with the regular bedding which are characterized by the fitchery thickness and the internal structure. Such deposits are very difficult for mining and processing. The thermal modification of this of ores allows changing the physico-chemical properties of its components in such a way that their further processing - grinding, separation, transportation and storage can be carried out without the use of process water or significantly reduces its consumption. The purpose of the present study is to increase the efficiency of the mineral processing containing the layered aluminum silicate by reducing their negative impact on the basic dressing processes, the separation of suspended matters and the storage of waste. INTRODUCTION Many deposits of minerals are associated with the presence of layered silicates such as the argil, mudstones, argillaceous slate - highly hydrophilic mineral varieties which have the ability to swell in the water. This ability to self-disperse creates the great difficulties both for the extraction and the processing of such ores. Since the dressing of most minerals is associated with the use of wet processes, where in contact with water the swelling layered silicates are dispersed to a particle size of less than 50 µm, but due to their high hydrophylic property they form bonds that promote the formation of so-called structured suspensions having increased viscosity. In this case the structured suspensions make it difficult to perform the separation operations as the classification, the gravity and magnetic separation, the flotation and thickening and filtration operations."

Jan 1, 2018

By V. F. Petrov

Cyanide is widely used gold lixiviant for hydrometallurgical processes. The resulting tails contain complex toxic compounds. With reference to this, the protection of the environment should be the major issue. A complete detoxification of cyanides before disposal, a partial detoxification to the allowable concentrations and a disposal of tails at a polygon followed by the detoxification of excess water into the environment are offered as an environmentally friendly way of disposal. However, a complete detoxification of the cyanidation tails does not give the required results due to the presence of toxic compounds, cyanides and thiocyanates in tailings ponds. This is due to adsorption-desorption process occurring between solid and liquid phases. A partial detoxification is used to down cyanide to the allowable concentrations, which are safe to the environment. The storage of tails without detoxification is mainly used at low concentrations of toxic compounds in the disposed tails. With reference to this, water recycling is practiced by Russian plants in order to reduce as much as possible or almost eliminate toxic effluents into the environment. Fresh water is applied if necessary and to make up for water losses, with 8-12% of total water supply. This allows for the stability of water balance and the decrease of consumption of the reagents applied. The conditioning technologies of water recycling followed by regeneration of free cyanide and metals recovery as saleable concentrates are specially developed due to adverse impact of water recycling on gold recovery processes due to high concentration of base metals (copper). These technologies are also profitable. In order to detoxify cyanide in the tails for tailings dam, effective and inexpensive technologies involving a seasonal use of detoxified reagents were developed. For example, a technology with aldehydes use which is applied by a series of operations. Effluents disposed to the environment are detoxified using chlorination followed by almost a complete destruction of toxic cyanides and thiocyanates. Before disposal, chlorinated water is settled to precipitate the resulting hydroxides of metals and complete chemical reactions such as a full decomposition of hypochlorite ions. In order to protect ground water, watertight screens from local water-resistant materials are used. The samples of these materials were previously tested and chosen according to their maximum ability to adsorb toxic compounds in the tailings pond. If local water-resistant materials are not available, whole welded impermeable polymer screens are used. The options mentioned allow the storage of cyanidation tails in accordance with national ecological standards. Keywords: cyaninides, thiocyanates, wastes, environmental safety, recycled water-supply, detoxification, storage

Sep 1, 2012

By Qiuyang Hong, Bo Li, Dongyun Liang

"A weathering-crust niobium-rare earth-bearing deposit is formed by the weathering alterationof alkaline granite, which is refractory due to its low grade and complex properties. The mineralogicalcomposition of ore, the grain size of majorminerals as well as the occurrence of Nb and REE are studied in this paper using MLA combined with traditional methods. According to the results, a wide range of Nb-Ti-REE compound minerals including titanoniobite, uranpyrochlore, chlopinite, samarskite and ilmenorutile areformed for the extensive isomorphous substitution among the elements of Nb, Ta, REE, Fe, Ti, U and Th. The occurrence of REE is extremely complex. First, the REEexistingas rare earth minerals including monazite, xenotime, bastnaesite,etcaccount for 21%. Second, the REEexist in the lattice of Nb and Zr minerals as isomorphous additions, which account for 18%. Third, the REE exist as colloidal rare earthdeposit,which account for 35%. Last, the REEexistingas ion-adsorption-type rare earth,which are adsorbedon the kaolinite in the form of hydrated hydroxyl ions, account for 26%.Based on the results of mineralogy, the combined technology process "mineral processing- hydrometallurgical separation" is needed to deal with the ore. The mineral processing tests show that, for the feed ore containing Nb2O5 0.065%, REO 0.13%, an Nb-REE concentrate containing Nb2O5 1.38%, REO 1.98% can be gained by "high intensity magnetic separation-regrinding-gravity separation by shaking tables". The recovery of Nb2O5 and REO is 62.42% and 44.78% respectively. The Nb-REE concentrate is dealt by the metallurgy process "direct reduction- acid leaching & acidulating- neutralization & precipitation- chlorination & distillation" and the rare earth oxide of 92.34% REO as well as the Nb-Zr oxide of 24.62% Nb2O5 can be obtained with the recovery of REO and Nb2O5 being 76.83% and 59.37% respectively."

Jan 1, 2014

By Sarra Scherbakova, Alexander Kurkov, Andrey Egorov

"Deep concentration of iron ores involves extraction, in addition to magnetite concentrate, of hematite and martite concentrates and recovery of other valuable components. A flotation technology was designed specifically for finely disseminated hematite ore, allowing producing saleable hematite concentrate containing 64-66% Fe. The main process challenge is caused by the presence of other ferruginous minerals such as carbonates, silicates, and phosphates, and fine hematite and martite mostly concentrated in the -0.044 mm fraction. Main operations of the processing circuit are removal of slime, flotation to remove impurities (carbonates, phosphates etc.) with an anionic phosphorous collector in an alkaline environment, hematite and martite flotation using same collector in a slightly acidic environment to produce commercial iron concentrate. Tailings of wet magnetic separation of magnetite containing 24.5% Fe and finely disseminated hematite ore containing 51% Fe were processed to produce iron concentrates with a yield of 15% and 50%, respectively, containing approximately 65% Fe and 5% of silica. Hematite flotation tailings had the highest content of gold (up to 0.09 - 0.11 g/t), while in other products it never exceeded 0.02 g/t. Using a Knelson concentrator was able to recover 40 to 45% of the gold into 3.31 g/t Au gravity concentrate. The success of gravity concentration is due to high gravitational contrast of gold to mostly quartz and aluminosilicates in the hematite flotation tailings. In general, the proposed process can be used as a solution to the challenge of selective concentration of finely disseminated iron minerals."

Jan 1, 2014

By Ela Mielczarski, Jerzy A. Mielczarski

"The adsorption of xanthate takes place at a different potential on each major sulfide mineral, hence, as it was demonstrated in the past, each mineral component can be selectively separated from ore under well controlled potential conditions. In real flotation this concept never works out for two reasons: the potential of single mineral particle results from complex surface reactions controlled by solution chemistry, and there is a galvanic interaction between different mineral particles present in the flotation pulp.In this study the formation of amyl xanthate hydrophobic products on pyrite, galena and chalcopyrite has been spectroscopically investigated in the presence of combinations of these minerals. The type of the adsorbed species and their amount were determined directly on mineral surfaces by infrared external reflection technique. Galvanic contact between grains of two different minerals has tremendous consequence on the adsorption of collector on both minerals. The detected changes are dramatic, from no adsorption to a coverage formation of a few monolayers. The results obtained indicate clearly that the observations and conclusions about the collector adsorption, hence also the surface hydrophobization, made for a single mineral system does not describe the real situation in a multi-component mineral system such as flotation pulp."

Jan 1, 2003

By Cheng Xiang, Nan Ye, Xinyuan Ke, Yang. Jiakuan, Huabin Wang

Bayer red mud is a highly alkaline residue produced by the alumina industry through the Bayer process. Its disposal is a worldwide problem. The high alkali content and poor pozzolanic activity is aconstraint for its utilization on construction materials. In this study, the red mud was activated through an alkali-thermal method to improve its activity so that it can be utilized in geopolymerization. The red mud was mixed with different amounts of sodium hydroxide, and calcined under 800 °C to produce geopolymer precursors, and then mixed with water directly to prepare one-part geopolymer. X-ray diffraction was conducted to study the phase transformation of red mud and the mechanism of its geopolymerization. Nitrogen Isothermal Adsorption tests were conducted to analyze the pore structure of the geopolymer binders. The results show that calcinations with alkali would promote the Al in red mud transforming into glassy SiO2 to form the N-A-S phase which is soluble in water. When the red mud was calcined at 800 °C with a Na2O addition more than 10%, the dissolving of Si and Al from red mud was greatly improved. The thermal-alkali activated red mud with 10% Na2O obtaining a compressive strength of 9.77 MPa after it reacted with water and cured for 7 days at 20 °C and 95% RH. But the strength decreased as the curing time extended to 28 days. The reason is suggested to be that the polymerization of Al-O and Si-O is unstable due to the low Si/Al ratio of red mud. The alkali in the structure dissolves again into the pore water and corrupts the pore structure. Therefore, the thermal-alkali red mud should be combined with other reactive aluminosilicate materials such as granulated blast furnace slag to absorb the alkali released by the thermal-alkali red mud at the latter curing days.

Jan 1, 2014

By A. O. Gapchich, T. N. Matveeva, N. K. Gromova

"Tin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. The aim of the work is an experimental study of the modification of the surface of sulfide minerals and cassiterite by stable metal-collector complexes to increase extraction of fine tin, silver, copper and other metals from complex tin ores. Triamide cyanuric acid (TCA) was studied as a thin silver flotation modifier. Thermophilic polymer with a functional group of phenylphosphine TMPPh was used as a selective flocculant. For experimental studies of the physical and chemical effects of collecting agents on the surface of minerals the following analytical techniques were used - the analytical scanning electron emission ASEM (LEO 1420VP INCA OXFORD ENERGY 350) and laser (KEYENCE VK-9700) microscopy, measurements of electrode potentials of mineral anthills by potentiometric titration, monomineral and pulp flotation. New data on formation of the adsorbed layer of DBDTC on the surface of chalcopyrite, galena and arsenopyrite were obtained, and the dimensions of the reagent films and the strength of their adsorption. The indiscriminateness of cassiterite to DBDTC ensures its selective separation into a chamber product during the flotation of sulfides. It is shown, that modification of the sulfide surface by stable complexes Me-DBDTC and Ag-TCA-TMPPh will increase the recovery of non-ferrous metals and silver into a collective sulfide concentrate and will provide a high-quality tin concentrate for flotation of tin sulfide ores.The studies were perfomed with the aid of the Russian Science Foundation (Project No. 17-17-01292).INTRODUCTIONTin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. In this regard, it seems advisable to use new varieties of flotation reagents in order to increase extraction of finely dispersed tin, silver, copper and other non-ferrous and precious metals from multi-metal tin ores (Bocharov and Ignatkina, 2007; Khanchuk etal., 2012; Wu and Zhu, 2006; Yusupov etal., 2016)."

Jan 1, 2018

By Luo Chuansheng, Rao Jinshan, He Xiaojuan, Qiu Xianyang

The dissemination grain size of chalcopyrite is really fine and refractory grains of -10µm take up 25%. Dissemination relationships among chalcopyrite with pyrrhotite, pyrite, marcasite and gangue minerals are complex. Content of Fe-bearing sulphides and Fe-bearing silicates associated with chalcopyrite reaches to about 60%. It’s hard to liberate and separate chalcopyrite from pyrrhotite. The above four are the main mineral processing difficulties of a copper ore in China. Because of the similar floatability and poor separation effect between chalcopyrite and pyrrhotite, enhanced depressing and collecting method was adopted in Cu-S separation before 2009. Due to the different magnetism among chalcopyrite, pyrrhotite and Fe-bearing silicates, magnetic separation is creatively induced in Cu floatation circuit based on the in-depth study of process mineralogy. High efficiency and new Cu-S separation technology of "Rough concentrate regrinding-pyrrhotite rejecting from middling by magnetic separation" and a highly selective copper minerals collector YL-1 had been developed to solve the difficult problems of refractory Cu-S separation, which are heavy load of middling recirculation,difficulty in upgrading Cu concentrate, unstable locked cycle and low separation indexes. And grade of Cu concentrate has been increased by 3.33%, recovery of Cu and Ag has been increased by 19.32% and 10% respectively.

Jan 1, 2014

By S. Vimalnath

The bioremediation capability of Pseudomonas aeruginosa cells was investigated for the biosorption of lead ions from aqueous solution. The various parameters such as pH, kinetics, biomass loading and concentration of lead affecting the biosorption process were studied. Complete bio removal of lead could be achieved for an initial concentration of 12.4 mg/L at pH 6.2, corresponding to typical industrial effluents. The biosorption isotherm followed Langmuirian behavior and the Gibbs free energy (?G) was determined to be-30.8 kJ/mole, indicative of chemisorption between the functional groups of the bacterial surface and lead. The biosorption kinetics adhered to a pseudo-second order model. The possible mechanisms of interaction of lead with the bacterial cells are discussed. A carbon paste electrode with a coating of biomass was developed for lead ion detection in aqueous solution using cyclic voltammetric technique. Concentrations of lead up to 5x10-5 M could be successfully detected using cyclic voltammetry, which could be improved to a detection limit of 1x10-8 M adopting differential pulse anodic stripping voltammetry (DPASV). Keywords: Pseudomonas aeruginosa, bioremediation, lead, voltammetry

Sep 1, 2012

By Mohammad Noaparast, Hamed Haghi

"In this research work, it was attempted to reduce the iron contents (Fe2O3) in relatively low grade silica sample which was obtained from Shenin silica mine, using magnetic separation. The prepared sample contained 93.75%SiO2, 0.44%Fe2O3, 2.78%Al2O3, and 0.08%TiO2 and the Fe2O3 had to be reduced to less than 0.08%. Mineralogical studies and XRD analysis indicated the presence of Hematite, Pyrite, and Goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections demonstrated that the degree of freedom of silica is more than 80% in -300+212 ?m size fraction. After primary stages including crushing, milling, scrubbing and de-sliming, various methods such as low intensity magnetic separation (LIMS), high gradient magnetic separation (WHGMS) and dry high intensity magnetic separation (DHIMS) were applied to find out that which process would be appropriate for the elimination of iron impurities from this sample. Different experiments were carried out on the product of wet rod mill and scrubber. However the magnetic field intensity of WHGMS was increased down to 2Tesla, and there was not any acceptable result in reduction of Fe2O3 content lower than 0.08%. Thereafter the product of wet rod mill and scrubber were dried and reported to DHIMS. In these experiments, maximum magnetic field intensity was 1.4Tesla. In this case very significant results were achieved, and Fe2O3 content of final product were reduced to less than 0.05% which meets glass manufacturing standards."

Jan 1, 2014

By Y. M. Zhao

Reutilization of waste printed circuit boards (PCB) can not only prevent potential environmental pollution, but also achieve recycling of secondary resources. Study on recycling of discarded PCB belongs to the front edge of environmental pollution prevention and resource recycling. In order to effectively crushing waste PCB, and solve the problem of secondary pollution of fugitive odor and dust during the crushing process, a wet impacting crusher was adopted to achieve comminution liberation of PCB in water medium. 96.79% of the crushed yield was distributed in ?2mm, and metal took 97.18% in this grade of production. Size distribution of PCB particles was characterized double peaks at the sizes of ?1+0.5mm and ?0.074mm. A double Rosin-Rammler function, is called DRR function, is put forward to describe the size distribution of PCB particles. The DRR function of cumulative weight percentage oversize of PCB was non-liner fitted by self-defining DRR function of the Origin 7.0. The evaluation indexes of the fitting results are the correlation coefficients R2 of 0.9994 and residual E of 0.18671, those show that DRR function is perfectly accurate. Based on the research the mechanical separation and material properties of PCB, a wet process of reclaiming metals from PCB using a new style separator ? tapered diameter separation bed (TDSB) in water medium was designed, and the related separation mechanism was studied. The fluid field of the tapered diameter separation equipment was simulated by the Ansys Flotran software, the variation laws of the velocity in each position in the fluid field as well as the equation of axial distribution sectional max velocity were analysed according to the simulation result, the stress change and motion trajectory of the pellet in the certain fluid field were analysed. The results show that the expanding tubular structure of the varied diameter separation bed indicates gradually decreasing velocity of water flow along the axis, assuming a certain angle in the bed, as a result of the gravity?s influence, and there was corresponding change to the distribution of the flow velocity, thus the whole formed a special fluid field where velocity variations exist in different positions. When the material passed through the fluid field along with the water flow, as a result of the difference to the particle density, the granularity and the shape, there would appear the difference to the motion trajectory as well as the movement distance under the action of the fluid: The lower density materials discharge along with water flow, but the higher density materials would be kept in bottom of the bed and discharge through material mouth. Therefore, light and heavy products were separated effectively according to the density. Using tapered diameter separation bed to process the ?1mm size crushed material of waste printed circuit boards, with the discharge of water 5.5m3/h, feed-rate of the material 250g/min and with an obliquity 35°, product with 93.92% in integration efficiency and 93.73% in recovery ratio of the metal were obtained by the primary separation. Compared with other mechanical methods, the range of particle size was broaden using the TDSB to recovery metals from PCB, and lower limit size of separation almost approach to 0. An innovative process of ?wet impact crushing+ classifying+ tapered diameter separation? recycling metals from waste PCB was developed.

Jan 1, 2014

By S. Castro, L. Uribe

Seawater can be considered as a particular process water with a high concentration of NaCl (about 0.5- 0.6 mole/L) and high concentration of hydrolyzing metal cations (mainly, Mg2+ and Ca2+ ions). Micro-flotation tests, induction time measurements, and zeta potential measurements have been used to investigate the effect of these ions on the natural floatability of molybdenite. The results demonstrate that molybdenite is strongly depressed in the alkaline pH range over which hydrolysis products of Mg2+ and Ca2+ ions are formed. At pH 10, colloidal magnesium hydroxide seems to be responsible for molybdenite depression in seawater and in Mg2+ solutions. This is also supported by the measurements of the effect of Mg2+ ions on the zeta potential of molybdenite. The mechanism of depression of molybdenite with Ca2+ ions is different, and depression takes place in the pH range were Ca(OH)+ complexes are formed, below the pH of precipitation of calcium hydroxide. Adsorption of the cationic hydroxy species and/or hetero-coagulation of the positive charged colloidal hydroxide on the negative charged molybdenite particles seem to be the main mechanisms involved.

Jan 1, 2014

By Yuexin Han, Jie Liu, Shuai Yuan, Yanjun Li

"In order to improve recovery efficiency of iron minerals from iron ore tailings and to reduce its connected environmental pollution, this article investigated the reducing roasting of iron ore tailing in a laboratory fluidized magnetization roasting reactor to optimize the roasting method and conditions. The examined parameters included roasting temperature, roasting time and reducing atmosphere. The parameters evaluating magnetizing roast efficiency and theoretical value were determined. X-ray diffraction (XRD) analysis was used to investigate the conversion of iron phase after roasting. The results show that the best magnetizing roast conditions are roasting temperature of 540?, holding time of 15min, and CO concentration of 20%. The magnetization conversion ratio of roasting products is over 80%, under the best magnetic separation condition, the concentrate grade of iron is 65.61 % and the recovery of iron is 83.77 %. The XRD analysis shows that Fe exists in hematite and siderite before roasting and exists in magnetite after roasting. The technique not only recovers the iron minerals from tailings with good economic benefit, but also reduces the environmental pollution of tailings accumulation.INTRODUCTION Iron ore tailings are the solid wastes generated during the beneficiation process of iron ore concentration and are one of the main pollution concerns in the mining industry (Das et al., 1996). Continuous development of the iron and steel industry has led to the increasing amount of iron ore tailings; there are over 300 million tons of iron ore tailings discharged per year (Rao et al., 2016). The huge amount of stockpiled iron ore tailings brings a series of environmental and social problems. Comprehensive utilization of iron ore tailings can not only reduce environmental load but also conserve resources, promoting sustainable development of the society. In recent years, iron ore tailings as secondary resources have received considerable attention in many countries in the word and numbers of studies on utilization of iron ore tailings were carried out, such as recycling the valuable minerals (Datta et al., 1996; Jia et al., 2013; Panda et al., 2018), used in construction material compositions as alternative source of raw materials (Das et al., 2012; Zhou et al., 2012; Luo et al., 2016) and other utilization. The iron minerals were recovery by magnetization roasting (Rao et al., 2016; Yang et al., 2013; Yang et al., 2011) and flotation (Kumar and Mandre, 2016). By comparison the reduction roasting has more advantages, but it was found that the conventional roasting equipment was inefficient, high energy consumption and un-economically applied on an industrial-scale."

Jan 1, 2018

By A. Deepatana

This study compares the use of an aminophosphonate chelating resin Purolite S950 and a sulphonic acid strong cation exchange resin Purolite C160H to recover nickel and cobalt from the synthetic bioleach solutions. Batch adsorption of metal citrate is performed as a function of metal citrate concentration (15~2000 mg/L) and solution pH (0.01M and 0.1M citric acid). The adsorption mechanism as inferred from the fit to Langmuir (LM), Freundlich (FM) and Redlich-Peterson (RP) models demonstrates that nickel citrate adsorbed onto C160H appears monolayer in comparison to that adsorbed onto S950 exists multilayer. In contrast, cobalt citrate adsorption onto both C160H and S950 agrees with the LM model. The results have shown that loading capacities of nickel and cobalt citrate onto C160H are 60 and 65 mg/g whereas those observed onto S950 are 16mg/g and 6 mg/g respectively. These are achieved in metal citrate prepared in 0.1 M citric acid. Resin regeneration is conducted in using 2 M nitric acid solution. The results show high efficiency of nickel and cobalt citrate elution from Purolite C160H. Findings from this study suggest Purolite C160H is a suitable adsorbent for recovering nickel and cobalt from bioleaching solutions.

Jan 1, 2014

By Xiaoming Wang

This paper presents an arcuate magnetic separator to remove the grinding ball fragment directly from the mill discharge, which will cause wear to downstream processing equipment such as pump, hydro cyclones and pebble crusher. Furth more this type separator was applied in Wushan mine under China National Group Corporation in China. After months of operation, the equipment has been a success. It removes majority of ball fragments from mill discharge. Keywords: magnetic separator, sag mill, pebble crusher, grinding ball fragments

Sep 1, 2012

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By Rainer M. Lotzien, Michael J. G. Battersby, Jan Kleefeld, Julian V. Brown, Rainer M. Imhof

"The standard method of separation using flotation is compromised in terms of kinetics and efficiency, because of the generally slow separating differentials of fine bubbles and fine particle suspensions. A new flotation system has been developed that addresses these issues and imparts other benefits. The new technology is based on established pneumatic flotation designs called Imhoflot which use intensive in-line pre-aeration to aerate the flotation pulp prior to its introduction to the separating cell. Consequently the cell is designed only for the separation of the phases and not for bubble-particle contact. In the new system this separation is speeded up dramatically by the introduction of centrifugal motivation in the separating vessel, without the use of internal moving parts. The design focuses on providing increased differential forces on buoyant mineralised bubbles and hydrophilic fines. The observed result of these differential forces is the improvement of concentrate qualities by the reduction of the amount of misplaced material found in the froth. The commercial benefit to industry is much reduced residence time, less than 30 seconds, which offers considerable cost savings in equipment and infrastructure.Prototypes of 0.65m, 1.7m and 2.2m cell diameter size have been constructed for hydrodynamic and industrial scale tests to assess the previously established computational methods for scale up of the process. The 1.7m cell has been installed and operated for cleaning of potash concentrates in Germany, at throughputs of 150 m3/hr, with extremely encouraging results. A 2.2m cell has been installed and operated in plant trials for superfine coal in South Africa. Results are presented that illustrate the effects of differential separations by comparison with conventional pneumatic and mechanical flotation techniques. Predictions of performance are provided in the contexts of the applications tested."

Jan 1, 2003

By L. A. Cisternas, R. I. Jeldres, C. Cruz, P. A. Robles

"Previous studies have shown that the floatability of chalcopyrite in seawater at highly alkaline conditions is significantly affected by the presence of clays. The reason is that the species of calcium and magnesium present in seawater under those conditions may act as a bridge between the surfaces of clay and chalcopyrite, generating massive aggregates that then depress. In this context, the objective of this work is to analyze the impact of pretreated seawater with low amount of calcium and magnesium ions on the recovery of a sulphide copper mineral with high kaolinite content as clay. The seawater pre-treatment is done by the addition of sodium hydroxide in a high carbon dioxide environment. The chemical reactions realized under these conditions lead to the formation and precipitation of calcium and magnesium species that are subsequently removed by vacuum filtration. The pre-treated seawater is then used in flotation tests at pH 11 for copper sulphide, where the mineral is synthetically prepared by mixtures of chalcopyrite, kaolinite, and quartz. When comparing the flotation results for different types of water, including seawater and pre-treated seawater, a significant effect is observed: as the seawater hardness decreases, which comprises the calcium and magnesium ions, the recovery of chalcopyrite is increased. However, the effect is markedly enhanced in the presence of kaolinite. Therefore, the results indicate that sodium hydroxide and carbon dioxide are able to remove different species of calcium and magnesium from seawater and could improve the chalcopyrite recovery with high kaolinite content. INTRODUCTIONIn many cases, mineral deposits are found in arid areas with little access to water resources. Water is a fundamental element to carry out the unit operations that achieved the separation of valuable minerals (especially in concentration operations). Seawater has acquired an interesting role in recent years (Cisternas and Moreno, 2014); in fact, it seems to be one of the few viable options to ensure the sustainability of the mining industry in arid zones. At present, there are numerous experiences of industries that use or have used this resource, either by submitting the seawater to a desalination treatment by reverse osmosis or by applying it directly, without desalting. The latter case may involve significant economic benefits (for example, by avoiding the investment of building a desalination plant) and in some cases some operational benefits. A positive aspect is that in general terms the foaming in the saline medium is much more efficient compared to fresh water (Quinn et al., 2014; Castro et al., 2010). Some reports show that the foaming doses required to achieve a certain quality of bubbles are remarkably reduced, reaching exceptional cases such as Xstrata's Raglan concentrator, where it did not even include foaming to carry out the operation. This fact is quite promising, considering that some researchers have stated that controlling the quality of bubbles and foam could float minerals through coarse particles. This would lead to multiple benefits, such as energy savings by avoiding excessive grinding and a lower presence of fine ore that causes major problems in water recovery operations by gravitation (such as thickening) and in tailings management. However, seawater also causes significant challenges in multiple operations (Jeldres et al., 2017, 2016; Castro et al., 2010), as for example in minerals with high clay content (Uribe et al., 2017). In fresh water, the presence of clays minerals in ores is already a major problem in the flotation stages since the operation becomes difficult to be controlled, and operators are commonly forced to increase the consumption of reagents because the collectors are deposited on the clays' surfaces reducing froth stability (Farrokhpay and Bradshaw, 2012). Sometimes the use of rheology-modifying reagents should also be incorporated since the pulps become more visc"

Jan 1, 2018