Search Documents

By J. R. Rodda

Stainless steels are widely used to handle concentrated sulphuric acid (H2SO4) solutions produced in the manufacturing process, The majority of corrosion rate data published for stainless steel in product acid conditions is typically complied in tables or in iso-corrosion diagrams (iso-corrosion rates plotted as a function of temperature and H2SO4 concentration), without any reported consideration as to the accuracy and relevance of the method used to obtain the data, Given the characteristic potential cycling associated with the active-passive corrosion behaviour exhibited by stainless steel in hot, concentrated H2SO4, weight loss is considered to be a more reliable method than electrochemical measurements to measure corrosion rates, Consequently, an effort is made herein to demonstrate the accuracy and relevance of weight loss to determine laboratory corrosion rates in product acid conditions.

Jan 1, 2010

By C. Nikolic

A process utilizing ozone for the precipitation of cobalt from nickel sulphate liquors containing ammonium sulphate has been developed. Best results were obtained using nickel carbonate to maintain solution pH at 5.0 to 5.5. Work was performed both in column and stirred-tank reactors. Variables studied included neutralizer type and concentration, NH4+ concentration, temperature, Ni++ and Co++ concentration, per cent O3 in the O2 carrier gas, O3 input rate and agitation. The over-all rate of cobalt rejection increased sharply with increasing agitation and ozone concentration in the gas phase, reflecting relatively slow transfer of ozone from the gas to the liquid phase.

Jan 1, 1978

By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right 'strength' is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By P. Kostuik

"Recent interest in the pipeline transport of solid mate-als has been sparked by the idea that, in an inflationary onomy, pipeline costs are more stable than the costs of any other transport systems. Pipelines have proved over 1e years to be dependable, records indicate that main-•nance and operating costs are comparatively low, and 1eir amenability to automation is of considerable im->rtance.The concept of hydraulic hoisting of solids from under-round, or cross-country hydraulic transportation of con-~ntrates and ores, is currently of prime interest to the ining industry. In general, this paper deals with a preliminary investi-ation of energy losses incurred while transporting a rela-vely heavy, crushed mine product, namely magnetite, oth vertically and horizontally. The basis and validity of everal equations derived by other experimenters to com-ute these losses is discussed. A theoretical analysis of ydraulic hoi:,,ting is made, and, based upon test results, calculation of horsepower requirements for hoisting an re under a given set of conditions is presented. Results indicate that:n vertical transport, the friction head losses are identical to those of clear water, and the total energy requirement for hydraulic hoisting then becomes a function of height of lift, concentration and specific gravity of the solids being hoisted. .-In horizontal transport, friction head losses can be calculated with reasonable accuracy using Bonning-ton's correlation curve. Losses computed utilizing Durand's correlation (K = 85) result in estimates which are too low by 10 to 30 per cent, an<l those calculated using Newitt's correlation (K = 1,100, K = 66) give friction loss values which are too high by 10 to 30 per cent . . -The theoretical horsepower (RMS-hp.) required for hoisting hydraulically is approximately half of that required for conventional double-drum skip hoisting."

Jan 1, 1966

By M. C. Bétournay

? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough ? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough Disadvantages ? High cost and long time for equipment development ? Hard rock mining condition limitations ? Size of equipment ? Equipment set-up time, down time ? Performance does not meet financial return targets ? Ground control issues ? Drill and blast retains overall advantage

Feb 1, 2008

By Ian Hattie, Mark R. Wilson, T. Kurtis Kyser, Brian W. Janser

Petrographic, chemical and isotopic compo itions of auriferous and non-auriferous quartz vei ns from the Sta r Lake and Flin Flin-Amisk Lake areas of northern Saskatchewan indicate diver e origins fo r the fluids associated with gold mineralization. In the Sta r Lake area, the metavolcanic , Star Lake pl uton, and heared mafic dikes have retained their original igneous 81 80 values. The 81 80 value of quartz from mi neralized veins vary by I per mi! and range from+I0 to+IJ. The only quartz ample having a 81 80 value outside th is range came from a vein not associated wi th a dike or gold mineralization . Quartz from the Star Lake pluton has identical 8180 value to the qua rtz from mi neralized vei ns which suggests that the vei ns and the pluton are related to imilar proces es. The diffe rence in 81 80 values between mi neralized and barren vein may erve a a potential exploration tool in this area. Because o34S val ues of a limi ted number of amples of pyrite from gold-bearing quartz vei ns at Star Lake correlate directly with gold content. the gold may have been syngenetic with the su lphur and the 834 value may be useful for exploration . 8180 values of co-existing quartz, calcite, and amphibole in the veins from Star Lake indicate that isotopic disequilibrium among the minerals is common, but the val ues also record a high temperature of formation (ea . 500°C) involvi ng a component of magmatic fl uid. TheoD value of hydrou mineral from Star Lake retain their original igneous values but whole rock values are generally much lower, an effect attributed to interaction of the minerals with a late meteoric water. In the Fl in Flin-Amisk Lake area, auriferou and barren quartz veins formed from a mixture of hydrothermal and metamorph ic flu id at lower temperatures (ea . 350°C) than those at Sta r Lake. Becau e there i no apparent correlation between 8180 values of the quartz with gold content or relative age of the vein , nor between the 834S val ues of pyrite and gold content, table isotopes appear limited as an exploration tool in the Fl in FlonAmisk Lake areas.

Jan 1, 1986

By E. H. Dudgeon

In order to make increased use of automation in copper smelting, it is evident that a useful first step .world be the accurate determination of the copper end point in the converter operation. After laboratory tests, the copper end points in a copper converter at Gaspe Copper Mmes Ltd. were determined without reference to melt samples or other observations. The results indicated that the rapid measurement of the S02 level in the gas released from the converter has potential as a new and independent method of determining the copper end point in converter operation.

Jan 1, 1966

By Tugba Cebeci, Bahjat Khoshaba, Bern Klein, Libin Tong, Andrew Bamber

"Sensor-based sorting technologies have potential to pre-concentrate low grade subeconomic ores through discarding the barren waste particles. However, the inability of sensors to accurately discriminate ore from waste is a barrier to prevent their wide applications. The present study focuses on the development of more intelligent sensing systems by using correlation and regression analysis of X-ray fluorescence (XRF) sensor responses on the copper ore samples obtained from Chile. The responses obtained through XRF scanning were reported both in the form of counts and the grades of elements. Linear and multiple linear correlation analyses were made between the XRF counts and the copper grades obtained through chemical analysis. Both the heterogeneity of the ore particles and the matrix effect in the XRF measurement are discussed in the study.INTRODUCTIONSorting can not only discard waste rocks away from the concentrator but also recover metal bearing ore particles that would be lost to the waste dump. The benefits of ore sorting include reduced energy consumption, water and reagent usage in the downstream operations (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). X-ray fluorescence belongs to sensor-based sorting technologies and Xrays are a high energy-high frequency form of electromagnetic radiation inhabiting the region between the ultraviolet radiation and gamma rays (Shackley, 2011). Recent XRF sorting studies on low grade copper ores were carried out at MineSense Technologies Ltd. aimed at increasing the capacity related to improving the understanding of ore heterogeneity as the basis for developing semi-bulk or bulk sorting systems (MineSense Technologies Ltd., 2016)."

Jan 1, 2016

By E. Adam, B. Milkereit, M. Salisbury, L. E. Reed, G. Perron

Integrating seismic reflection, borehole geophysical, and physical rock property studies is an effective means of mapping lithological contacts and structures in the crystalline crust. At Les Mines Selbaie in the northern volcanic zone of the Late Archean Abitibi Subprovince, a high-frequency seismic reflection profile has provided the first images of deep crustal structures of this important polymetallic mine site. Physical rock property and borehole geophysical studies confirm that prominent seismic reflections can be caused by lithological contacts, faults and sulphide mineralization. At Les Mines Selbaie, the first two of these are shown by this study. Clearly identifiable reflection images from sulphide mineralization have not been demonstrated in analysis of the profile. The seismic images provide useful information about gross structure in the vicinity of Les Mines Selbaie. They can also place important constraints on the sequence of tectonic events and, therefore, can aid future deep exploration programs.

Jan 1, 1997

By K. G. (Ken) Thomas

"This paper gives an insight into the various processes available to treat gold ores. A brief overview is given of the various types of refractory gold ores. Particular emphasis is given /0 comparing the costs of oxide vs refractory gold ore processes, inclusive of grinding through to dore bar.HistoryThro ugh time gold has been recovered from the earth&apos;s crust by various mean s. Five major historical steps can be identified for metallurgical processing as shown in Table I .Gravity concent ration started with, for example, river bed panning and developed to more sophisticated processes such as the Johnson concentrator, belt concentrator and jigs. The South African gold fields were a major developer of gravity concentration processes during the first half of the twentieth century.As coarse free gold became depleted, stamp milling, in conjunction with amalgamat ion , was developed. Basically, rock was crushed under large mechanical hammers an d the gold collected in mercury . The mercury was then evaporated in a retort to leave sponge gold for further fire refining.As deposits became deeper and gold finer, the gold became more difficult to recover ; fine grinding was required to liberate the gold. In the 18905, MacArthur and the Forrest Brothers of Glasgow, Scotland, introduced the cyanide pro cess for dissolution of gold and its subsequent precipitaiton by means of zinc. This process, in vogue until the early 1970s, was commonly referred to as the Merrill-Crowe process for recovering fine gold .Activated charcoal was used as a means of recovering gold from solution in the 1880s, especially in chlorination plants in Australia( l). Two factors probably retarded the development of carbon instead of zinc-based processes during those year s. First , there was no satisfactory procedure for the elution of carbon to allow its recycling and, second, the development of the Merrill-Crewe process for gold recovery by zinc cementation probably discouraged any further work on the use of carbon"

Jan 1, 1991

By V. S. Sastri, Elboujdaini. M.

"Economics of wear in mining industry and methods by which wear cost may be reduced will be discussed.IntroductionCanada loses more than $5 billion annually due to friction and wear (Table 1). It is estimated that about $1.3 billion, or about 25% of the losses, could be saved through better application of existing technology (Table 2). It should be noted that the costs given in Table 1 and 2 refer to 1986. The losses due to friction and wear and the savings would be much higher in 1996. Tribology combines the many branches and specialties in science and technology concerned with understanding and combatting friction and wear. Specifically, tribology is concerned with the design and manufacture of sliding and rolling bearings, piston rings, gears, cutting tools and other devices in which surfaces interact, in sliding or other relative motion. Tribology is concerned with the correct use of materials for interacting solid surfaces, with the interaction of the surfaces with the lubricants, with the chemistry, physics and use of lubricants. It is concerned with the reduction of friction and wear and the avoidance of associated failures in machinery. Similar tribological components such as bearings are used in different technologies and similar tribological problems such as abrasive wear occur in different industries. Thus, tribology is in itself a generic science and technology, concerned with the generation and dissemination of knowledge on friction, wear and lubrication, and the application of the knowledge, to a wide range of industrial products and equipment, from ploughs to space equipment, from prosthesis to engines, from washing machines to railways, from computers to power stations, from paper mills to mines. Avoidable losses due to friction and"

Jan 1, 1997

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010

By H. P. Kang, Y. J. Feng

The hard roof in underground coal mines is generally considered as a main cause that induces disasters in working faces and entries, such as rock burst and windblast. Hydraulic fracturing technology is an effective approach to weaken hard roof to reduce ground pressure and control rock burst. The state and achievements associated with hydraulic fracturing technology applied in Chinese coal mines are summarized in this paper. Theories related to hydraulic fracturing are of the essence in fracture design to determine the fracture initiation and propagation pressure and predict the geometry and the characteristics of hydraulically induced fractures. Initially, theory of elasticity was employed to determine the breakdown pressure for a vertical borehole where the rock medium is assumed to be elastic. However, porosity and pore fluid have an influence on the borehole breakdown pressure, and then the poroelasticity theory was applied. Arbitrary deviated boreholes in practice are rather common and the maximum tensile stress criterion was employed to determine borehole breakdown pressure. The effect of natural crack in the rock medium on the initiation pressure has been taken into consideration through fracture mechanics. Meanwhile, considerable achievements have been made on hydraulic fracturing tools and equipment, and a set of mature hydraulic fracturing technologies for hard roof control are available. Some comprehensive investigations on the hydraulic fracturing for hard roof weakening are presented, and successful field applications in the Jincheng and Luan coal mining districts are introduced. Finally, the unsolved problems related to hydraulic fracturing are also put forward.

Jan 1, 2015

By Parissa Mirjafari, Ron Martel, Susan A. Baldwin, Luke Moger

Mine drainage contains metals and sulfate, which may be toxic to aquatic life at certain concentrations and should be removed to acceptable levels before release of any drainage to the environment. One method for treating mine drainage is passive treatment, which is increasing in popularity due to lower construction and operating costs. This method is based on the activity of sulfate reducing bacteria (SRB) respiring on sulfate while using fermentation products from decomposing complex organic materials. The product of this biological process is hydrogen sulfide, which reacts with metals in mine drainage and precipitates them as metal sulfides. However, in practice passive treatment systems are not always effective, reducing the reliability of this approach. In this study, a mixture of hay, cow manure and wood chips was tested in continuous flow experiments for efficacy at sustainable treatment of sulfate and selenium containing water from a mine tailings pond. Factors that contributed to a decline in performance included lowering of the pH due to acids leaching out of the organics, re-oxidation of sulfide back to sulfate and a reduction in dissolved organic compounds over time. In this paper methods are described to overcome these problems so that treatment is made more reliable.

Jan 1, 2011

By M. F. Ameur, M. Habak, H. Aouici, M. Kenane

Present study interest by aluminium alloy (Al 7175-T5173) drilled without cooling fluid. The influence of the machining parameters (spindle speed and feed rate) on the holes quality was analyzed. Drilling tools are made of carbide (WC); high speed steel (HSS) and TiN coated carbide (WC-Ti).The Experiment design was reinforced by the application of statistical analysis of variance (ANOVA).The results show that the thrust force is influenced principally by the spindle speed and feed rate. Though, both feed rate and tool materials have statistical significance on the surface roughness. In addition, the objective of correlations between spindle speed and feed rate with the evolution of the machining parameters was established. These correlations were obtained by quadratic regression using the response surface methodology. Finally, useful to select optimum values of drilling parameters, that would minimize thrust force, torque, cutting temperature and surface roughness.

Jan 1, 2015

By S. Broda

Waste rock piles (WRP) are made of heterogeneous, coarse grained waste rock, with inclined layers due to segregation along the slopes and haul traffic compacted layers, creating highly contrasted hydrogeological conditions. The internal structure of the pile has a major impact on water and oxygen movement and pore water pressure distribution. In the presence of reactive minerals, this influences the production of acid mine drainage (AMD) or contaminated neutral drainage (CND) with metal leaching from the WRP. Water flow and distribution may also affect slope stability, particularly following major infiltration events (rain/snow melts).The prediction and interpretation of water distribution in WRP is a challenging problem. Numerous numerical investigations of short and long term forecasts have been conducted, and many of these were found of limited reliability. The shortcomings of existing approaches are typically due to difficulties in representing preferential flow processes in macropores. Such phenomena are in fact often neglected in the assessment of water flow in WRP because these are unattainable with the classical porous media approach typically used in this field. This paper focuses on the use of modeling techniques originally designed for massive fractured rock media to simulate flow in WRP. Waste rock properties used in this study are retrieved from large scale laboratory permeability and water retention tests and from in situ infiltration tests. The effect of WRP configurations on water flow into potentially reactive zones is examined with the numerical 3D fully-integrated surface/subsurface, variably saturated flow model HydroGeoSphere. Material properties retrieved from the laboratory tests are represented by means of stochastic facies distribution generated within a probability framework. Modelled soil water contents and hydraulic head distributions, as well as fluxes within a simple waste rock pile, with compacted layers, are compared with results retrieved from simulations based on the classical equivalent porous medium approach. Results indicate significantly increased flow towards the looser waste rock zone by considering heterogeneous material distribution, causing weak or absent capillary barriers and preferential flow paths. Practical implications for the design of waste rock piles are also discussed.

Aug 1, 2013

By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By Michel Épiney, COREM, Mario Drapeau, Caroline Olsen, Claude Bolduc, Benoit Levasseur

"Several metal sulfide minerals (such as copper, zinc and iron), generally abundant in precious metal-containing ores, are known to dissolve during the cyanidation process. These unwanted reactions consume a significant amount of cyanide and oxygen, which is required for the extraction of gold and silver. Leaching kinetics of sulfide minerals are very fast in contact with oxygenated cyanide solutions. Therefore, the solution quickly becomes charged with oxidation products that are mostly metal ions, metallo-cyanide complexes, metal oxides and other sulfur species including thiocyanate, sulfides, polysulfides, thiosulfate, sulfites, sulfates, etc. COREM’s Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during pre-oxidation and cyanidation. The effect of pre-treatment under ozone was investigated using an industrial pulp recreated from process water (charged with thiocyanates) and homogenized flotation tailings material from Agnico Eagle's LaRonde mine. In terms of mechanisms, the ozone treatment provides a complete deactivation of the material surface (characterized by EDTA extraction) and the solution (characterized by Ionic chromatography). This resulted in a lower reactivity of sulfide minerals that led to substantial gains in terms of consumption of cyanide and thiocyanate formation during the cyanidation process. The ozone-pre-treatment edges the classical pre-oxidation treatment (such as oxygen, hydrogen peroxides, etc) providing a quicker deactivation of the sulfide matrix and higher reagent savings in subsequent cyanidation process.INTRODUCTIONThe presence of sulfur in the process of gold leaching by cyanidation is a major drawback to optimizing the reagents consumption with suitable operating conditions. The coexistence of sulfide mineral species, such as pyrite, chalcopyrite, pyrrhotite or sphalerite along with the gold-bearing ore have, indeed, a negative impact on the extraction of precious metals by cyanidation (Bayat et al., 2003), (Azizi et al., 2010). These minerals are known to dissolve with cyanide under alkaline conditions and release in the slurry different kinds of sulfide by-products like polysulfides, thiosel, sulfite and sulfate (Seal II & Hammarstrom, 2003) (Breuer et al., 2008a), (Marsden & House, 2006) (Ghasemian Langeroudi et al., 2013). Once these sulfide by-products are released in solution they react with cyanide to form thiocyanate (Marsden & House, 2006) (Breuer et al., 2008b). The consequence of the dissolution of these cyanicides, is a significant increase in cyanide consumtpion as well as a slow-down of gold extraction."

Jan 1, 2016