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By J. R. Thoenen

The enormous and constantly increasing demand for limestone to supply a multitude of uses is a remarkable feature of the mineral industries. As approximately 130,000,000 tons of limestone are produced annually, it is not surprising that deposits at or near the surface are gradually being exhausted and that less advantageous supplies are being worked. Quarries are becoming deeper and wider year by year, and in many places the volume of overburden that must be removed to allow open-pit work has increased alarmingly. Quarrymen are also gradually learning how expensive it is to sort and clean stone from a deposit overlain by poor material. As such conditions confront the limestone industry, the natural tendency is to seek some modification in method whereby the handicaps of increasing cost may be met and overcome. Operators, some of them unwillingly, have been forced to conclude that underground work in drifts and tunnels is the most logical solution of the problem. The unwillingness of some is largely due to unfamiliarity with mining and to the unfounded fear that costs must increase and dangers multiply when mining is undertaken.

Jan 1, 1926

By E. L. Singleton

This Bureau of Mines investigation was initiated to study and establish some of the chemical and physical characteristics of the condensed Mno-Si02 system. To prevent oxidation of the manganous ion, I atmosphere of purified helium was used in the furnaces. Solidus-liquidus curves and invariant points were established from melting-point determinations and were supplemented from data obtained by the static-quenching method. Experimental findings and data are for the intermediate compounds of tephroite and rhodonite with their respective eutectics represented at 25.5 and 37.2 weight-percent silica. Tephroite melts congruently at 1,347° C., and rhodonite melts incongruently at 1,286° 8.. A metastable transformation was determined to exist at the 1,347° C. isotherm, the congruent melting point of tephroite. A composite X-ray-diffraction pattern was formulated for synthetic rhodonite. This investigation contributes fundamental data leading toward a better understanding of the more complex slag systems.

Jan 1, 1962

By John W. Nebgen

This report contains findings from a U.S. Bureau of Mines study concerning the inhibition of acid mine drainage formation from underground coal mines. A series of experiments was performed in which three different pyritic materials (wastes from coal production plants) were evaluated using several candidate inhibiting agents. Data obtained from the inhibitor-treated pyrites were compared with data from control experiments in which untreated pyritic wastes were used. The experiments were conducted by placing treated and untreated pyrite in columns, passing moist air through the columns to promote oxidation of pyrite, and washing the columns weekly to collect oxidation products for analysis. Experimental results indicate that quantities of acid mine drainage can be substantially reduced if soluble iron III (ferric) ion is controlled. The best inhibitors are neutral or alkaline siliceous materials such as fly ash, blast furnace slag, portland cement, and cement kiln dust. These materials appear to insolubilize iron III species to make them unavailable for reaction with pyrite. The data strongly suggest that the soluble ferric ion aqueous is a key oxidant for pyrite to produce acid mine drainage. The role of aqueous ferric ion as an oxidizing agent is substantiated further by data obtained using metallic iron (nails) as an inhibitor. The iron nails tended to keep the soluble iron in the iron 11 (ferrous) state. Experimental results indicate that sulfate and acidity levels are reduced when pyrite is in contact with the metallic iron.

Jan 1, 1979

By Otto Ruhl

The zinc-lead ore reserves of the Tri-State district of Kansas, Missouri, and Oklahoma, as of December 31, 1947, are estimated at a total of 66,100,000 tons of crude ore containing 2.18 percent metallic zinc and 0.38 percent metallic lead. The Bureau of Mines began estimating the reserves in October 1945 and completed the' work December 31, 1947. A total of 38,900 acres of land representing approximately 5 percent of the area of the district is covered in this report. The work was confined for the most part to properties developed or partly developed by drilling and underground workings, and to acreage sufficiently drilled out to indicate ore of enough tonnage to make a commercial undertaking. The acreage in which ore reserves exist is widely distributed in all three States. A map of the Tri-State area is shown in figure 1. The remaining 95 percent of the area is not necessarily nonproductive but represents, possibilities for future exploration and development of additional mineral resources when and if economic conditions or national necessity encourage such work. Of the total reserves, 41 percent are in Missouri, 38 percent in Kansas, and 21 percent in Oklahoma.

Jan 1, 1949

By Dean H. Ambrose

This paper presents the results of a study using computer human modeling to examine machine appendage speed. The objective was to determine the impact of roof bolter machine appendage speed on the likelihood of the operator coming in contact with. A contact means two or more objects intersecting or touching each other, e.g., appendage makes contact with the operator?s hand, arm, head or leg. Incident investigation reports do not usually contain enough information to aid in studying this problem and laboratory experiments with human subjects are also not feasible because of safety and ethical issues. As an alternative, researchers developed a computer model approach as the primary means to gather data. By simulating an operator?s random behavior and machine?s appendage velocity, researchers can study potential hazards of tasks where it is not possible to perform experiments with human subjects. Analysis information is helpful to the mining industry in terms of making recommendations that reduce the likelihood that roof-bolter operators experience injury due to contact with a moving boom. Data analysis of roof bolter simulations show that the virtual-operator?s response time has little effect on the number of contacts experienced. Based on frequency and cross-tabulation, regardless of other variables, contact incidents were always greater when the boom was moving up, were always greater on the palm, and were always greater for the boom part of the machine. Also, regardless of boom speed, the 25th-percentile-sized operators experienced more contacts than did other operator sizes. Furthermore, regardless of boom speed, the 152-cm mine seam experienced more contacts than did other seam heights tested. Results of a survival analytic approach suggest that controlling the boom speed is the most important factor in determining the risk of an operator making contact. Based on the data collected, boom speed greater than 41 cm/s results in a substantial increase in risk to the roof bolter operator and should probably be avoided. At speeds less than or equal to 25 cm/s are associated with a more modest relative risk, which represents an acceptable level of risk. Also, at speeds between 25 and 41 cm/s, there could be a particular boom speed in this range at which a significant inflection point in the relative risk estimates occurs. Based on the results, this issue needs to be addressed by future research.

Jan 1, 2003

By David A. Summers

Coal is increasingly viewed as one of the major fuel resources of this country for the remainder of this century. The need to extract a greater percentage of the coal in a given seam, together with advantages of improved safety, indicates that longwall mining will become more widely used within this time frame. A novel method of mining coal on a longwall face, utilizing high pressure water jets, is herein described. The mining machine proposed will exploit the stress conditions which exist on a longwall panel in order to achieve the required productivity while at the same time reducing respirable dust and methane ignition hazards. The water jets will excavate only the boundary of the extracted seam section, and thus the energy requirement of the machine will be minimized. The action of the machine is similar to that of an existing coal plow, except in that the wedge teeth of the plow are replaced by oscillating high pressure water jets. The machine can, therefore, cut to the depth and at the speed of existing shearer units at equivalent power levels. The removal of impact stresses from the machine will reduce downtime required for maintenance and replacement of picks and lower the load on the haulage motor of the system. The ability of the machine to increase the depth of cut without an increase in horsepower will further improve productivity when transportation systems to remove the greater production are in operation.

Jan 1, 1974

By R. A. Cattell

Since the return of the Petroleum and Natural Gas Division of the Bureau of Mines to normal peacetime functions following World War II, a coordinated program of oil and gas development and production research has been in prog- ress, and the importance of the problems has been evaluated so that the Bureau can render greater service to the oil and gas industry. Among the problems associated with development and production research, those concerned with efficient utilization of the Nation's reserves of hydro- carbons contained in gas-condensate type reservoirs continue to receive major emphasis. For a number of years an important part of the Bureau's work has been the study of two pressing problems associated with production from such reservoirs; first; an investigation of fluid properties, and the second, finding a means of controlling corrosion. Studies of the characteristics of gas-condensate fluids have resulted in the publication of a number of reports, which cover a broad field. In general they deal with subjects such as the properties of a fluid from a well; development of research equipment, means of combatting corrosion, and the many aspects of gas-condensate engineering. To provide experimental data on relative liquid and gas volumes and critical pressures and temperatures, a windowed cell was constructed that permits ob- servation of the fluid phase while making the tests. Experimentation in the field on the use of inhibitors to control corro- sion of equipment in gas-condensate wells has disclosed that solutions of chromate are effective retardants of corrosion. Engineering field studies of the Carthage and New Hope gas-condensate fields are in progress, and reports on the Sheridan and Lake Creek fields have been completed. Following a plan of making studies of important newly discovered oil fields, the Bureau is investigating the physical properties of reservoir oil

Dec 1, 1948

By Joseph A. DeCarlo

The rapid growth of the organic chemical industry in the United States and abroad has focused attention on the future raw-material sources for this important industry. Chemical products are essential to modern civilization; and millions of tons of organic chemicals are used annually, ranging from basic raw materials to finished chemical products such as drugs, cosmetics, and soaps. Hundreds of chemical products are made directly or indirectly from coal, but in this report "coal chemicals" will be limited to crude tar, crud light oil, and ammonia recovered in the high-temperature carbonization of bituminous coal and the important principal products obtained by processing these materials. Specifically these include benzene} toluene, xylene, naphthalene, creosote oil, tar acid oil, pitch, and ammonium sulfate. Therefore the term "coal chemicals", wherever used in this report, includes only these products and does not include the secondary or intermediate products such as styrene, synthetic phenol, aniline, phthalic anhydride, or finished products made from these, such as synthetic rubber, plastics, and dyes. The United States leads the world in production and consumption of coal chemicals. In the past five years nearly one-fourth of the total output of coal-tar crudes in the world was produced in the United States. Consumption of some of the more important products derived from these crudes such as benzene, toluene, xylene, and naphthalene, however, ranged from about one-third to one-half of the world total because of imports and production of benzene, toluene, and xylene from petroleum. The synthetic organic chemical industry of the United States was established during World War I on chemical raw materials obtained by the high-temperature carbonization of bituminous coal but this source of supply currently furnishes less than 40 percent. More than 60 percent of the chemical raw materials used to produce organic and inorganic chemical is supplied by the petroleum industry and production of petrochemicals is rising rapidly.

Jan 1, 1960

By P. R. Tisot

Structural response and/or deformation was determined for each of four different grade Green River oil shales (27.0-, 34.5-, 45.5-, and 63.5-gal/ton) as they were heated in an inert atmosphere, under constant compressive stress, from ambient to subretorting temperatures; that is, below those required for rapid pyrolysis of the organic matter. Small cores and small columns of confined fragments comprised the test specimens, which were heated, in a specially designed microunit, at a uniform rate either to 725° or to 825° F under three different stress levels, 80, 200, and 325 psi. Structural response of some cores was observed as they were heated in a stress-free environment. The obtained stress-strain-time-temperature relationships provide information regarding the oil shale's yield temperature, yield stress, rate of compressive strain, loss of mechanical strength, and nature of structural deformation. Effects of structural deformation on induced permeability in small columns of fragments are presented. Results indicate that underground retorting of Green River oil shale may be seriously impaired through loss of induced permeability brought about by structural deformation of rich oil shale under the influence of heat and compressive stress.

Jan 1, 1971

By R. V. Higgins, G. B. Shea

"FOREWORDIn the second year of World War II, the petroleum industry in California was taxed to near capacity to satisfy the expanded war demand for petroleum products, particularly fuel oil. With discoveries of crude oil in California declining and known reserves being depleted rapidly, conditions appeared to warrant study of the possibilities of utilizing the outcropping bituminous sandstone deposits in California for obtaining new sources of oil if the war should he prolonged. At conferences in Washington, D. C., with members of the Petroleum Administration for War and the Geological Survey, Bureau of Mines engineers emphasized the importance of determining the extent of those outcropping deposits of oil-impregnated rocks and of developing a practical process for commercial recovery of the contained bitumen to assure, if necessary, a supplementary supply of fuels. The desirability of such a study was recognized, and in July 1943 the Petroleum Field Office of the Bureau of Mines at San Francisco, Calif., in cooperation with the Geological Survey and the Petroleum Administration for War, initiated a study of the bituminouss sandstone problem. It was agreed that all mapping and geological work in connection with the study would be done by the Geological Survey, all engineering studies in developing a process for extracting the oil would be carried out, by the Bureau of Mines, and that the Petroleum Administration for War would aid in final adoption of the results in the field if circumstances warranted such action.Deposits of bituminous sandstones in California occur principally in the immediate region of the Coast Range mountains, notably at Pt. Arena, in Mendocino County, about 110 miles north of San Francisco; near Santa Cruz, in Santa Cruz County; in the Edna area in San Luis Obispo County; in the Sisquoc area in Santa Barbara County; and in the Ojai and Santa Clara Valleys in Ventura County. 4/ In addition oil-bearing sands outcrop near McKittrick and Maricopa, in western Kern County, and along the east edge of the Kern River oil field. Among the several prominent deposits of these source materials, those occurring near the cities of Santa Cruz and San Luis Obispo, and the town of Sisquoc are the largess."

Oct 1, 1948

By H. P. Greenwald, H. C. Howarth

There was reported in Bureau of Mines Technical Paper 5754/ a series of tests to determine the compressibility and bearing strength of specimens prepared from blocks of potash salt obtained from a mine near Carlsbad , N. Mex . The events leading up to the investigation were sketched in a foreword by George S. Rice , then chief mining engineer of the Bureau ( retired September 30 , 1937 ) ; this foreword also gives a discussion of the possibility of increasing the ultimate total recovery of the potash salt by " second mining" of pillars or by use of a longwall system . In June 1936 , Rice and the senior author visited Carlsbad with H. I. Smith , chief of the mining division of the Geological Survey , to observe mining then in progress and to discuss with the management of one of the mines records of convergence of roof and floor which they were obtaining . It developed that serious thought was being given to the possibility of roof failure resulting from shear at the faces of pillars . There was envisioned the danger of such cracks extending upward to water - bearing strata . Obviously , the simple compression tests of the potash salt then being made would throw no light on this question , and tests of assemblies of potash and roof salts would have to be made . In this connection it is to be remembered that in the mine no sharp division exists between the potash salt being recovered and the nearly pure halite which forms the roof . The interlocked crystalline structure is continuous , and there is merely a very rapid decrease in the proportion of sylvite in a short distance vertically . Figure 2 of Technical Paper 575 shows that two samples near the top of the salt being mined contained , respectively , 51 and 65 percent potassium chloride . Contrasted with this is an analysis of the roof salt given on page 24 of that publication , which showed only 3.6 percent potassium chloride . As the data given in Technical Paper 575 show , the roof salt is much less plastic than the potash salt . The immediate roof may then be thought of as a more rigid stratum of indefinite extent resting on and continuous with yielding supports and loaded uniformly at the rate of 900 to 950 pounds per square inch . Just what thickness of the salt should be considered as immediate roof is uncertain .

Feb 1, 1938

By L. Nahai

An important objective of the Australian Government's policies on resources development is to encourage further processing of raw materials domestically, to the extent that this is economically feasible and consistent with sound industrial development. This Bureau of Mines report examines the extent to which Australia is able to pursue this policy in terms of its own competitive advantages and the implications of such a policy for the United States. Such factors as the impact of other competing producers and their advantages, expected world demand, and infrastructural problem--which may limit pursuit of this policy to the fullest extent--are discussed. After a broad review of the re-source, economic, social, and environmental factors, the perspective for increased processing is examined for a number of mineral commodities.

Jan 1, 1982

By Paul M. Ambrose

Overall the domestic abrasives industry had one of its best years in 1965. Production and value of all commodities increased over that of 1964 which also was a good year. Production of tripoli that was down in the previous year rebounded and production from two new mines was reported. Plant capacities for production of silicon carbide and fused crude aluminum oxide and production from plants in the United States and Canada increased, but demand was high and yearend stocks were less than at the end of 1964. Foreign Trade.-Increases in value of most imports of abrasive materials in 1965 were offset by a decrease in the value of imported industrial diamond. Production of fused aluminum oxide and silicon car-bide in the United States and Canada and imports of these commodities into the United States increased, but combined exports of finished grain of these materials was virtually unchanged from the previous year.

Jan 1, 1966

By W. P. Diamond, F. Garcia, J. K. Marshall

Many longwall mines rely on methane drainage to supplement traditional fan-based ventilation systems. However, the surface production facilities for methane drainage systems, including gob gas ventholes, are commonly located in remote locations, sometimes without convenient access to electrical power, and they may be monitored infrequently. The first evidence that a methane drainage system may not be operating efficiently, or not operating at all, can be an increase in methane concentrations at a return air shaft or underground where the workforce is exposed to the risk of a methane explosion. A solar powered, remote gob gas venthole monitoring and cellular telephone-based real-time data transmission system has been developed and successfully field tested by the National Institute for Occupational Safety and Health (NIOSH) to address this problem. With this system, individual methane drainage boreholes can be monitored from the mine office to determine current operational performance parameters, as well as review past data to anticipate maintenance needs and troubleshoot operational problems.

By Doris M. Hyde

The economy of Belize continued to show a very slight but still positive growth during 1986. The gross domestic product (GDP) was estimated to have been about $164 million,2 almost the same as those of 1984 and 1985. Foreign investors looked favorably on Belize because it had remained isolated from the sometimes turbulent political and social strife elsewhere in Central America. Reportedly, in late 1986, Guatemala had decided not to pursue its claim to Belizean territory and to give full recognition to that country. Discussions were to be held regarding any matters of mutual concern. New investment possibilities were oriented toward agriculture or manufacturing endeavors. Except for some interest in petroleum exploration, the minerals sector remained limited to the quarrying of construction-related materials.

Jan 1, 1988

By M. A. Trevits, J. E. Urosek, A. C. Smith, M. P. Valoski

The National Institute for Occupational Safety and Health (NIOSH), in partnership with the Mine Safety and Health Administration (MSHA), is conducting research to test, evaluate, improve or modify coal mine fire-fighting strategies and methodologies through large-scale tests. Since wood is the second most abundant fuel available during a coal mine fire, it was decided that series of large-scale wood crib fire tests were needed to measure the products of combustion and to observe the capability of commonly available direct application fire suppression equipment, namely, fire extinguishers, water and gas-enhanced foam. This paper discusses the wood crib fire tests, provides insight into the products of combustion and describes observations made during the application of the fire suppression agents.

By Joseph Daniels

[Adequate supplies of suitable coal and coke are prime requisites in many industries, particularly those dealing with the utilization of mineral resources, recently interest has been focused on the possibilities of using electricity produced at Bonneville and Grand Coulee, Wash., in many electrochemical and electrometallurgical processes, in which core or some form of carbon is necessary in addition, discussion has been revived on the possibility of making iron and steel by the conventional methods employed in blast and open-hearth furnaces. The subject also is important at this time because of its relationship to industrial preparedness for national defense. A supply of coke from local sources on the Pacific coast is necessary in any program of production for strategic sufficiency of certain materials. An anal trio involving tae establishment of such industries should include detailed data on available supplies of coal, the quality and properties of the coke produced, and the technologic and economic factors involved in manufacture of echo and disposal of byproducts.]

Jan 1, 1941

By J. P. Walker

"INTRODUCTION Sponge iron has been made commercially since 1912 at a Swedish ceramic plant; and the product, known as Swedish disk-type nagger sponge iron, has an excellent reputation as a superior furnace feed wherever high-grade steels are made.The general procedure for making brickyard sponge iron was described frequent in Swedish technical journals before 1932 and at that time consisted in filling clay refractory containers, called saggers, with iron ore plus the necessary quantity of solid reducing agent and then firing in an ordinary ceramic kiln. Two types of sponge iron were made in this way: (1) An inferior, high-sulfur product obtained by mixing the ore and solid reducing agent; and (2) a high-grade, low-sulfur product made by filling the sagger with alternete layers of unmixed ore and reducer, yielding sintered disks of metallic iron particles.Swedish disk-type sponge iron of interest to the steel industry because it has a very low sulfur content, even when made by the use of low-grade, high-sulfur coals for reducing and firing. The Swedish product also contains little siliceous gangue residue and is almost phos¬phorus-free. To those features must be added the high metallic-iron content -90 to 96 percent - and freedom from even small amounts of the metals that are undesirable in steel making.The details essential for successful operation of this procedure are not known, especially as regards improvements said to have been made since 19;2. The Bureau of Mines therefore decided to determine some of these missing details, and this report records the results of the first set of experiments on the manufacture of brickyard or sagger sponge iron."

Sep 1, 1945

By Jürgen F. Brune, Liming Yuan, Alex C. Smith

To provide insights and assistances for the optimization of ventilation systems for U. S. under-ground coal mines facing both methane control and spontaneous combustion issues, a computational fluid dynamics (CFD) study is being conducted to investigate the effect of the ventilation scheme on the prevention of spontaneous combustion in longwall gob areas. This report focuses on the flow patterns within the gob under three different ventilation systems; one-entry and two-entry bleederless systems as well as a three-entry bleeder system. The gas flow in the caved gob area is simulated as a laminar flow through porous media while the gas flow in ventilation airways is simulated as a fully developed turbulent flow. The air flow patterns are visualized using flow path lines. Air velocity contours and vector data are also obtained. The possible location of critical velocity zones where the gob is most liable to spontaneous heating is discussed.

By R. K. Linn

The New Idria Mining and Chemical Co. owns and operates the New Idria mine in southern San Benito County, Calif. During 1957-59, the New Idria mine was the largest producer of mercury in the United States and its alltime production of over a half-million flasks was exceeded only by one mine. It is one of the oldest and most consistent producers in California. With the exception of 1921-22, the mine has an annual production of mercury dating back to 1854. This paper by the Federal Bureau of Mines describes the exploration, development, mining, and furnacing of mercury ore at the New Idria mine. Figure 1 is a view of the furnace plant of the New Idria mine. The purpose of this report is to promote the development and conservation of our mineral resources by dissemination of technological information on mining and processing procedures, and related practices at operating mines.

Jan 1, 1961