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By Mark Ferra

Flotation is used in mining to produce concentrates of copper, gold and several other valuable ores. In 2017, a copper mine near Globe, Arizona improved their rougher cells productivity using technically advanced electro-hydraulic actuators in the flotation process by enabling excellent tank pulp level process stability. The new actuators controlled the dart valve position to allow pulp to leave the cell. Tank cell pulp level can change due to feed and discharge fluctuations from neighboring tanks. When traditional pneumatic actuators are used, they have sluggish response times and overshoot due to the inherent physical property of air being compressible. Electro-hydraulic actuators have the benefit of hydraulic stiffness to deliver accurate and repeatable (0.1%) dart valve positioning. The froth layer has more opportunity time to maximize mass transfer into the launderer. The results are an increase in copper recovery by 2-4%. INTRODUCTION In 2013 there was an international flotation technical conference well attended by respected flotation specialists for both mining companies and academia. During the technical session a leading metallurgist was discussing pulp level measurement and said that when he was on the cell deck he stated, pneumatic actuators air cylinders stroking up and down. The presenter then claimed with confidence that "I listened to actuator move so the pulp level in the tank was being controlled!" No one questioned his assumption and I can assert that the audience was quite technical and not shy in their critiques of speakers. The flotation community simply believed that the existing pneumatic technology was enough with no alternative. Having a stable flotation cell pulp level is critical to effective copper recovery. Controlling pulp levels in flotation cells is a complex task that includes modulating dart valves in each cell. The use of REXA Electraulic actuators will decrease the process dead time and maintain froth height in a controlled manner, especially from pulp slurry volume fluctuations from neighboring cells. By reducing flotation cell pulp level tank height variation, a copper mine in Arizona has realized a 2-4% recovery improvement by increasing the froth transfer to the launderers in the rougher cell circuits compared to pneumatic actuators. This paper examines the benefits of using an electro-hydraulic actuator to ensure proper pulp level control and reduce the process operational cost. It will focus on actuator positioning the dart valves to maintain pulp level setpoint at a copper mine in Arizona.

Jan 1, 2019

By Christoph Mueller

Mining operations today are characterized by a high degree of mechanization and single machine automation. However, their potential for cost cuttings and increase of productivity in the future is quite limited. Enabled by newest IT and networking technology, the operation of underground mines more and more can be seen from a process related point of view: Standardized Ethernet and Wireless LAN are the basis for a seamless and unified communication backbones providing an integrated infrastructure for data, telephony and video. All the components are available as off-the-shelf devices leading to an excellent cost efficiency. Basing on this standardized infrastructure, the equipment is able to become part of the infrastructure. To enable machines to be integrated smoothly into IT networks, the machine also has to have enhanced networking capabilities. This results in a new system architecture for the on board machine electronics separating real time control from IT and networking level functionality which can be implemented by a Machine Server. This machine server communicates with all kinds of above ground systems using mainly standardized formats like html or the IREDES standard. This information is made available mainly in 3D mine visualization tools. The paper explains this technology and shows implementations by two working examples.

May 1, 2006

Plan de l?exposé ?? Présentation du site de la mine Restigouche et du mandat confié à Genivar ??Dénoyage de la mine ??Processus d?enlèvement des boues au fond de la fosse ??Utilisation de Géotubes dans le procédé à l?usine de traitement des eaux.

Feb 1, 2008

By D. Hatfield

"Flotation plants typically aim to maximise recovery at or above a target grade. As the ore from the mine varies, operators increase or decrease the mass pull in different flotation banks by adjusting air and level set points in order to achieve target concentrate grade. A methodology has been developed to maximise overall recovery at target grade by determining the optimal mass pull for each bank. However, the approach of targeting equal grade for each ore type in the deposit leads to sub-optimal overall recovery. This is because some ore types sacrifice a large amount of recovery to reach target grade while others easily achieve target grade and can be processed at higher than target grade for little or no loss in recovery. Processing different ore types at different grades and blending the concentrates therefore gives a higher overall recovery.This paper presents a case study where an 80 year production forecast was made for a large Chilean copper concentrator in feasibility stage. A circuit model was created using SGS’s Integrated Geometallurgical Simulator (IGS) for the different ore types to be processed. The model was calibrated from standard rougher flotation tests (MFT), cleaner tests and from the results of plant surveys of similar operations. The pull rates for each bank in the circuit were determined to achieve an optimal graderecovery curve for each ore type. These curves were combined at different concentrate grades for each ore type to obtain the mathematically optimal overall recovery at target grade. The paper shows a methodology for obtaining an optimal combination of operating conditions for each ore type to maximise overall recovery at a set combined concentrate grade."

Jan 1, 2013

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By Brian Hart, Hong Zhong, Liuyin Xia, Kyle Douglas

"The application of hydroxamic acid as flotation collectors is fast becoming of significant interest for the selective flotation of oxide minerals along with upgrading oxidised based metal ores and minerals. In the hydroxamate molecule, both O and N atoms in the -CONHOH group are identified as coordination atoms in many complexes and their characteristic structure determines the strength of the chelation complex between the hydroxamate and metal ion. The chelating performance of hydroxamates with transition metals including Cu, Ni, Zn, Fe, Cr, Mn and Co, the alkaline-earth metals (Be, Ca) and heavy metal (Pb) has been studied. Cytec has developed and patented a range of alkyl hydroxamates as flotation collectors for oxidised base metal sulphides, metal oxide minerals and precious metals. This paper introduces two new structures of hydroxamate collectors (Cyclohexyl and 4-tert-butylbenzoyl hydroxamates) and evaluates their characteristics relative to alkyl and benzoyl hydroxamates. Laboratory small-scale flotation tests were conducted with ilmenite and wolframite. The use of 4-tert-butyl benzoyl hydroxamate resulted in a best flotation performance for ilmenite. A relatively low cyclohexyl hydroxamate dosage was required in the flotation of wolframite to obtain comparable results to the alkyl and benzoyl hydroxamates. It is also shown a significantly improved flotation performance with 4-tertbutyl benzoyl hydroxamate in the flotation of ilmenite plant ore in comparison to the oleic acid or fatty acid collectors typically used for ilmenite flotation.INTRODUCTIONHydroxamic acid has been reported as an effective collector in small-scale flotation tests for a wide variety of oxide minerals and ores including copper (Lee et al., 1998, Lee et al., 2009), iron (Quast, 2000), tin (Sreenivas and Padmanabhan, 2002; Wu and Zhu, 2006), tungsten (Marinakis and Kelsall, 1987; Xia et al.,2004), and rare earth metal minerals (Ren et al., 1997; Pradip and Fuerstenau, 1991; Assis et al., 1996; Pavez et al., 1996; Zheng et al., 1996; Chen et al.,2005).As part of our previous research project, a selected suite of hydroxamic acid collectors including fatty, aromatic and modified hydroxamates (naphthoyl, cyclohexyl, benzoyl, octyl, 4-tert-butyl benzoyl, salicylic hydroxamates) were tested in order to examine their potential for recovery and selectivity of rare earth minerals. In these tests it was shown that the flotation performance with the hydroxamate collectors was significantly better than the phosphoric acid collectors on no slimes removed samples (Brian, et al., 2014; Liuyin, et al., 2014 and unpublished internal technical reports). Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the phosphoric acid collectors. Recovery of both La and Ce was significantly better for the salicylic hydroxamate and that Nb, Y and Zr recovery were favoured by the octyl and benzoyl hydroxamates (Brian, et al., 2014; Liuyin, et al., 2014). Comparison among the hydroxamate collectors showed that the flotation and recovery performance of cyclohexyl (CHH) and 4-tert-butyl benzoyl (TBH) was not as good as the other hydroxamates for rare earth recovery."

Jan 1, 2015

By M. Lahtinen, P. Latostenmaa, I. Kojo, E. Peuraniemi, M. Lindgren, S. Jyrkönen, M. Jåfs

The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. Since then Flash Smelting technology, now owned and developed by Outotec Oyj and the first plant, now owned by Boliden Harjavalta Oy, have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a popular theme during the first days of Flash Smelting, it has still been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. This paper describes the history and improvements of the Outotec® Flash Smelting process by looking into the early days of operation and how the development of the process and equipment has taken place over time as a joint effort between the technology provider and the users of the technology. INTRODUCTION In the 1940s, Outokumpu Oy refined the concentrate produced in the Outokumpu mine into metallic copper initially in Imatra, and later from 1945 to 1949 in Harjavalta, based on the most modern electrical melting process of the world at that time. After the war, Finland lost a significant part of its hydropower production, and due to the increasing use of electricity, the availability of electricity weakened, and the price rose. To maintain Outokumpu's profitability, it was forced to look for a melting solution that was not based on electricity.

Jan 1, 2019

By X. Yuan

"The processing behaviours of ores such as their liberation characteristics in comminution and their response in separation processes are affected by their mineralogical characteristics. Key ore characteristics which are relevant to processing, such as mineral proportions, mineral grain size, grain shape and mineral associations are routinely measured at the micro-scale in polished section using optical microscopes and SEM-based automated mineralogy systems. The application of X-ray micro-tomography to mineral processing provides the means to quantify these important micro-textural characteristics in three dimensions, removing the stereological issues encountered when measuring volumetric information in two-dimensional polished sections. In this paper we present several examples of ore textures to illustrate where X-ray micro-tomography can be applied successfully to obtain quantitative measures of ore characteristics which are useful in a variety of process modelling applications.INTRODUCTION X-ray tomography has been used as a tool in medicine for some years and is being applied in a wider range of fields including geology, palaeontology and mineralogy. In this paper we present some applications of X-ray tomography in mineral processing applications being developed at JKMRC. The availability of SEM-based automated mineralogy systems such as MLA and QEMSCAN has seen the increased use of quantitative mineralogical data measured in two dimensions in the design, operation and simulation of mineral processing plants. When the ore is amenable to measurement by X-ray tomography this technique can provide quantitative data for characteristics such as mineral grain size, shape, mineral associations and liberation in three-dimensions. The advantage of measuring these characteristics in three-dimensions is that the stereological issues which bias measurements made on polished sections are removed. X-ray tomography also quantifies the location of mineral grains relative to one another in space - a useful descriptor of ore texture. Like many measurement techniques X-ray tomography has advantages and disadvantages when compared to other techniques. One limitation is that the ability of the X-ray tomography system to discriminate between minerals is a function of the X-ray attenuation of those minerals. While the X-ray attenuation of many common minerals is sufficiently different for X-ray tomography to distinguish between them, there are some where the overlap in X-ray attenuation makes discrimination on the basis of this characteristic alone impossible. An example of this would be chalcopyrite and magnetite. However where the ore mineralogy is suitable to apply X-ray tomography, the technique provides some exciting opportunities to explore the relationship between texture and ore processability."

Jan 1, 2012

By Robert E. McIvor

"The Functional Performance Equation for ball milling circuits allows us to isolate the circuit classification system efficiency (CSE) from the mill’s grinding performance. The factors which affect circuit CSE are reviewed, with emphasis on water usage at the classifiers. It is shown that manipulation of such water usage can be carried out to improve plant grinding circuit efficiency, at times by more than 30 percent.THE FUNCTIONAL PERFORMANCE EQUATIONObservation of the feed and product size distributions going into and discharging from the mill in grinding circuits with low versus high circulating load ratios initially led to the definition of “circuit classification system efficiency” (or CSE, McIvor, 1988a), and ultimately the discovery of the Functional Performance Equation (McIvor, 1988b, and McIvor et al, 1992). The CSE is the percentage of “coarse” (typically with reference to the plus P80) size material occupying the mill (versus “fines” or product size material, finer than the circuit P80), and can be calculated by taking the average of the percentage of coarse material in the mill feed and mill discharge. As this also represents the percentage of the mill energy expended on targeted, coarse size material, it is directly proportional to overall grinding circuit efficiency and production rate. This is all clearly expressed in the Functional Performance Equation for ball milling circuits, which is derived as follows.We define “fines” as any product size material, and “coarse” as that targeted to be further ground, the two typically differentiated by the circuit target P80. For any grinding circuit, the production rate of new, product size material (fines) must equal the specific grinding rate of the coarse material (i.e. fine product generated per unit of energy applied to the coarse material) times the power applied to the coarse material."

Jan 1, 2009

By F. Malek

At Creighton Mine, magnitude events are a regular occurrence due to depth and major seismically-active structures. Over the last ten years, major advances have been made in research and development to develop strategies for the management of these major events. Today, the number of rockbursts has been drastically reduced at the mine and damage due to seismic events, when they occur, is often minimal. This paper describes the evolution and implementation of appropriate geomechanics strategies, designs, and practical ground control measures undertaken for the management of seismicity at Vale Inco?s Creighton Mine. A description of the research and development approach, implementation, and ground control strategy is provided for placement of enhanced support systems to manage the consequences of magnitude events at Creighton

May 1, 2009

By G. A. Mallory

"The South Bay Division of Selco Mining is located fifty-four miles northeast of Ear Falls Ontario on Confederation Lake. The concentrator operates five days a week and processes six hundred tons per day of copper zinc silver sulphide ore. The concentrator is comprised of crushing, grinding, differential flotation, thickening and drying circuits. The major constituents of the concentrator feed are: chalcopyrite 7%, sphalerite 20%, pyrrhotite 3%, pyrite 25 - 30% and felsitic volcanics 40 - 50%. The mine went into production in March 1971 with an anticipated three year life and is now scheduled for closure in the summer of 1981. Recent mine production has been limited to three cut and fill stopes which have widely varying ore grades, therefore mill feeds vary from 0.25 to 4% copper, 3.5 to 27% zinc, 0 to 0.4% lead and 15 to 30% iron.In mid 1977 Selco negotiated a six month rental purchase agreement with Outokumpu Instruments Canada Limited for a five stream analyser system. The Minexan 202 probes were the first Outokumpu probe type analysers installed in Canada although Outokumpus' Courier systems are well known. Installation of the system took place in April 1978 and after numerous hardware faults the six month evaluation began in August. By December it was obvious that the Minexan 202 probes with proportional detectors did not have adequate resolution to determine low copper values in either of the tailings streams. Outokumpu offered to replace the tailings analysers with a new prototype solid state detector probe the following summer. The evaluation on the five Minexan 202 probes continued until August 1979 when the new solid probe was installed. The Minexan S (solid state) probe was evaluated with the three remaining Minexan 202 probes until December 1979 when Selco elected to purchase the system."

Jan 1, 1981

By Barrick Pierina, John Frostiak, Igor Gonzales, Kenneth G. Thomas, Ken Manning

"1.0 SummaryThe Pierina deposit was acquired in August 1996 when Barrick Gold Corporation purchased Arequipa Resources, a junior mining company with extensive land positions in Peru. At the time of acquisition, Arequipa had developed two exploration tunnels and drilled 9 exploration holes on the property. Metallurgical tests, conducted on samples taken from the tunnels and the exploration holes indicated that the ore was amenable to heap leaching. Barrick’s exploration team recognised from the outset, the potential of the mineralisation and convinced Barrick’s senior management that this was indeed a world class deposit that should be pursued. On November 25, 1998, the first dore was poured at Pierina, 27 months from the time of acquisition. During that period Barrick completed its exploration programme, prepared a development plan including capital and operating costs, production profiles and cash flow forecasts, and a schedule to develop a mine and construct a leach pad and gold recovery plant, including all supporting infrastructure. All permits and environmental approvals were obtained and all necessary land was acquired. The project was completed on schedule and under budget. This was the first greenfield mine development for Barrick outside of North America.This paper details, mainly, the research and development, engineering, construction and commissioning of the metallurgical process facilities.2.0 The Develonment ProgrammeImmediately after the acquisition, Barrick began the process of gathering information required to prepare a project development plan. Kilborn Engineering was retained to assemble all of the information collected and collated into a development plan document. This document was completed by June 16,1997. The objective was to bring the mine into production as quickly as possible with critical activities identified as follows:"

Jan 1, 2000

By R. A. Hill, J. D. Pitts

"Long distance slurry pipeline systems have been successfully trans-porting steam coal, iron concentrates, copper concentrates and limestone for an aggregate of nearly 60 years and nearly three billion ton-miles annually. A phosphate concentrate pipeline is nearing start-up and systems for coking coal, lead/zinc concentrates and fly ash are planned. The solids pipeline concept, first patented in the early 1900's and commercialized in the 1950's, is now a proven technology providing an economic, environmentally pleasing and safe method for long distance bulk transport.The challenge for larger tonnage and longer distance movements of solids, for traversing increasingly rugged terrain in grass roots mineral developments, for transporting untried materials and for shipping more economic forms of proven materials still remains. This has necessitated continued refinements and optimization of the technology. The economic and environmental incentives for slurry pipelines when compared to other transport alternatives has justified substantial activity in this area. The scope of planned systems in coal, iron and other minerals is indicative of the firm place slurry pipelines will have in worldwide mineral development.In this presentation, the state-of-the-art in long distance slurry pipelines is reviewed with a focus on major systems of interest to the mineral processing industry. An overview of new developments in the application of this concept is presented, and finally, a projection of the future of pipelines in mineral development both worldwide and in Canada is discussed."

Jan 1, 1978

By Y. Shu, A. R. Laplante

"A laboratory Knelson Concentrator (LKC), 7.5 cm in diameter, was used to study the performance of a similar unit at plant scale, 76 cm in diameter, This paper reports on sampling and assaying procedures and problems, and discusses the performance of the plant unit.The sampling procedure was based on the extraction of large samples, 5-15 kg, and their complete processing with a LKC, to characterize size-by-size performance. The procedure yielded reliable estimates of overall gold assays, after blatant assaying errors were corrected. The plant centrifugal unit concentrate was sampled in situ, which yielded very erratic grades, with a large overall negative bias. Due to the very heterogeneous nature of the concentrate, which can be linked to flow patterns in the riffles of the unit, it is recommended that for future testwork, the concentrate be recovered separately, blended and then sampled.The plant centrifugal separator, when operated at a feed rate of 25 t/h, yielded total and free gold recoveries of 41 % and 62%, respectively. This is much lower than previously reported data, and suggest that at 25 t/h, the unit is overloaded. However, recovery did not decrease with time over a loading cycle of 2 hours, which suggests that present loading cycles, generally 1 hour, can be significantly increased. INTRODUCTIONThe study of gold gravity circuits is plagued with the statistical problem of determining the behaviour of particles occurring with a very low frequency. This problem becomes particularly acute with increasing particle size. For example, considering the average weight of a gold flake in the 840-1200 µm (20/28 mesh) to be about 5 mg (Banisi et al, 1991), a reasonably high grade feed of 10 git would require, for a relative error (standard deviation) of 10% on grade, 100 particles, that is 0.5 g of gold, or 50 kg of 840-1200 µm material (a Poisson distribution is assumed). Gy's formula, for the same data, yields a weight of 33 kg, with a shape factor of 0.1 and a size distribution factor of 0.5. Both results are comparable; to obtain the suggested weight of material, a stream containing 5% weight in the 840-1200 µm would require 1 tonne samples (of unsized material). The problem rapidly disappears with decreasing particle size. Still with Banisi et al's data, a gold flake in the 300-420 µm range averages 0.5 mg in weight; the same 10% error on grade corresponds to a weight of 5 kg. Gy's formula for the same size distribution and particle shape factors as above predicts a required mass of 1.4 kg. This would correspond to an unsized sample weight of 10 kg with 14% weight in the 300-420 µm, for example."

Jan 1, 1992

By Claude Deveau

"Studies on the performance of Falcon batch type concentrators treating ultrafine tantalum at Tanco have revealed that very fine heavy minerals are concentrated within certain areas of the concentrate bed. This information led to the design of a bowl which would allow entrapped lighter low grade particles to escape while providing more space for heavier particles to be recovered in the bed.Numerous tests were then completed with a modified batch-type and non-fluidized Falcon bowl in which the diameter of the discharge lip was adjusted downward manually in steps. This allowed for the gradual building of a higher grade concentrate bed.This work ultimately led to the design of a new Falcon with an automated continuously variable lip. In April 2005, Tanco commissioned the first Falcon UF600.This paper will discuss laboratory scale results and also plant performance of the Falcon’s UF technology.INTRODUCTIONTantalum Mining Corporation of Canada, also known as Tanco, is a wholly owned subsidiary of Cabot Corporation based in Boston, Mass. Operating since 1969, the underground highly mechanized room and pillar operation produces tantalum, lithium and cesium minerals and is located a 2 hour drive east-northeast of Winnipeg Manitoba, Canada.At Tanco, tantalum is recovered using conventional gravity concentration, enhanced gravity concentration and flotation. This paper will discuss how the need for improved equipment to treat very fine tantalum particles was filled by a machine which was modified to the point of creating a completely new technology.In November 2003, Tanco began the investigation for the potential use of a high g-force smooth walled concentrator for treating ultra fine tantalum produced by its flotation circuit. Until then, the tantalum flotation concentrate had been treated by a circuit which consisted of a Mozley Multi-Gravity Separator 902 (MGS), a Mozley MGS 900 and a Bartles cross belt concentrator. Through QemScan analysis, it was found that the majority of the losses from this circuit were of an extremely fine nature which exceeded the recovery limits of equipment on hand. Mean particle size of the tantalum losses was less than 10 µm."

Jan 1, 2006

By Jack Zhang, Chuck Edwards

"The versatility and specificity of rare earth elements (REEs) have led to their use in an ever increasing variety of applications in new technologies. Consequently, demand for REEs has increased significantly. However, to separate REEs safely and effectively is a complex and expensive process. While China has consistently invested in R&D of REE processing technologies, there have been only sporadic activities in REE mineral processing in North America in the past 20 years. This paper presents a review of REE mineral processing technology, providing an update on current capabilities in REE mineral processing. This paper reviews REE extraction from the major commercially valuable REE-bearing minerals such as bastnaesite, monazite, and xenotime, and also from the ion-absorption type of REE deposits. Currently, there are four major REE mining areas in China, one in the United Sates, and one in Australia. A review of the REE extraction processes in these major REE mining areas closes out the paper.INTRODUCTION The rare earth elements (REEs) include the 15 lanthanide elements, plus yttrium and scandium. The lanthanide elements are normally categorized in two groups: the light rare earth elements (LREEs), i.e. lanthanum through europium (atomic number (Z) = 57 through 63); and the heavy rare earth elements (HREEs), i.e. gadolinium through lutetium (Z = 64 through 71). Yttrium is usually grouped with the HREEs due to similarity in physical and chemical properties. Table 1 lists the REEs, atomic numbers, and abundances in earth’s crust (Taylor and McCleannan, 1985). Promethium is the rarest due to lack of stable isotopes. REEs with low atomic numbers are more abundant than those with high atomic numbers. More interesting is that the REEs with even atomic numbers are much more abundant than adjacent lanthanide elements with odd atomic numbers as shown in Table 1."

Jan 1, 2012

By Tiziana Apuani

The study refers to an area of about 70 km2, extended in the Italian Central Alps along the the San Giacomo Valley where different civil and mining works are present The regional geological setting is related to the Pennidic Nappe arrangement, characterized by the emplacement of sub-horizontal gneissic bodies resulting from the Mesoalpine isoclinalic folding of crystalline basements, emplaced throw East, and separated by matasedimentary cover units. The investigated geological rocks, belong to the ?Tambò?Unit, overlapped by its meta-sedimentary cover and by the ?Suretta? Unit. The tectonic contact gently dips to the E?NE. The valley, furrowed by the Liro Torrent, follows a N?S striking tectonic lineament, almost parallel to the nappe contact. A number of more then 70 sites, distributed in the studied area, were chosen and detailed structural and geomechanical field surveys were performed to characterize the rock masses, its intact rock and discontinuities. The procedure identifies the number of joint sets, their representative orientation, the set spacing, the type of movement, the amount of dilatation, the degree of alteration, the roughness coefficient, the presence and nature of infill. Rock mass quality indexes, such as the Rock Mass Rating (Bieniawski, 1989) or the Geological Strength Index (Hoek et al. 2002) have been evaluated in each surveyed site. The work is a contribute in assessing how the geometrical and geomechanical properties of the rock masses can be regarded as regionalized variables. The spatial distribution of these properties is a function of the geological and structural phenomena at which the rock masses have been subjected. The presented geostatistical analysis regards the spatial variation of the orientation of the most representative joint set.

May 1, 2009

By Rory Cameron, Chuck Edwards

"Stringent environmental performance criteria and regulations, and the desire to minimize water use have made membrane-based treatment and separation processes an attractive option. This has lead to many advances in all aspects of the technology. Membrane separation processes have found application in sea water desalination, brackish water treatment, decontamination of ground water, and wastewater treatment. Development of membranes with better resistance to harsh feed conditions has created new opportunities for the broader application of membrane separation technologies to mineral processing streams. There are examples in mineral processing operations, including treatment of acidic drainage, pre-concentration of pregnant leaching solution in heap leaching operations, separation of acids and metals from waste streams and intermediate process streams, as well as gold and cyanide recovery from a heap leaching operation. This paper provides a brief overview of membrane technology principles, followed by a discussion of current membrane technology applications relevant to the mining and mineral processing industry. The paper further explores the potential for the application of membrane separation as an integrated component in mineral processing operations.INTRODUCTION Increased regulatory pressures, emphasis on water conservation, and scarcity of water in arid regions have resulted in substantial changes in industrial practices in recent years. As a result, many industries have become more open to adopting innovative technologies such as membrane separation. The mining industry, which is typically very conservative, has adopted membrane separation as an effective end-of-pipe solution for effluent and acidic drainage (AD) treatment; however, its use as an integrated component in plant operations has progressed more slowly. With increasingly stringent environmental regulations coupled with the desire for low- and zero-discharge operations, the use of membrane separation technology for achieving acceptable environmental performance may be unavoidable in the future. The relatively small footprint requirement, versatility, and modular construction of membrane separation units facilitate their introduction into existing processes with a suitable feed stream. Membrane separation is not a stand-alone process that provides the ultimate solution to water and wastewater treatment; however, it can often be economically added to conventional waste treatment plants to increase throughput and/or decrease contaminant output (Mortazavi, 2008). Although membrane separation technology has become an established separation technique that is widely used in drinking water production and other industries, it is still considered an emerging technology within the mining and mineral processing industry. This technology offers many potential benefits such as clean water recovery from wastewater, significant reduction of volume requiring conventional treatment, decreased usage of reagents, and acid recovery, all of which lead to increased treatment efficiencies and lower reagent consumption. This could translate to smaller and more efficient plants with lower capital and operating costs and lower environmental impacts. Plant expansion may be facilitated by incorporating a membrane separation unit operation in order to utilize existing treatment systems at higher throughputs."

Jan 1, 2012

By R. J. Visintainer, W. L. Whitlock

"Difficulties with the sizing and operation of centrifugal froth pumps are common and the underlying fluid dynamics are complex. Design and selection often relies on previous experience, offering unreliable guidance for novel applications or unexpected problems. The current paper describes a program of extensive laboratory testing on froth handling centrifugal pumps, covering a range of flows, heads, speeds, viscosity, air content and froth stability. Variations in impeller vane design and the effectiveness of an airlock venting apparatus were also examined. The program resulted in a better understanding of centrifugal froth pump dynamics and insight for the troubleshooting of field applications.INTRODUCTION The Challenge of Pumping Froth In pumping mineral processing froth, the handling of large quantities of air within the fluid is often unavoidable. Efforts to reduce the amount of air present at the pump suction, while always recommended for improving pump performance, may have limitations. Some strategies may also carry an economic penalty, such as unwanted process dilution (e.g. due to water spray or injection), or increased capital cost of equipment due to oversized pumps, sumps and/or piping. Froth pumping losses fall into several categories, as described below and represented graphically in Figure 1. • Density effects: Entrained air reduces the pressure created by the centrifugal pump in direct proportion to the reduction in bulk density. This is not a true “loss”, since the head produced by the pump (in meters of froth), may remain unaffected. However, the reduction in pressure often leads to a corresponding increase in pump speed required to drive the system, which itself leads to increased NPSH required by the pump (NPSHR). Furthermore, by adding a gas phase, the overall volumetric flowrate is increased, assuming a fixed quantity of de-aerated liquid being handled. This leads to increased suction velocity which further reduces the NPSH margin by simultaneously increasing pump NPSHR and decreasing system NPSH available at the pump suction (NPSHA). • Viscosity effects: Increased viscosity introduces an additional factor in some froth pumping applications, such as oil sands bitumen froth. Losses result from increased shear stress within the fluid flow, which increase with flowrate. Viscosity also facilitates the formation of airlock by reducing turbulence and allowing individual bubbles to coalesce more easily within the flow stream. Finally, it increases pump NPSHR by increasing local pressure drop in the vicinity of the vane inlet edges. • Airlock effects: Also known as air binding, it occurs when air or gas coalesces within the pump suction or impeller passages and begins to collect there, held by buoyancy forces within the rotating flow field. In essence, the liquid “floats upwards” towards the pump suction against the outward directed centrifugal forces. The airlock acts as a blockage, with corresponding reductions in flow, head and efficiency. NPSHR also increases, due to increased velocity and distorted streamlines in the flow circumventing the blockage."

Jan 1, 2012

We report the studies of Proton-Exchange Membrane Fuel Cells (PEM FC) and hydrogen storage materials at McMaster University for the last 14 years. From the initial investigation of ionic conduction mechanism to the revelation of the origin of non-Arrhenius temperature dependence, as well as the synthesis and characterization of high temperature polymer electrolytes, both experimental and theoretical works have been compiled for the fuel cell membranes. In addition to the discovery of suppressed ionic conduction in Electrode-Membrane Assembly (EMA) and novel hydrocarbon PEMs based on micro-emulsion, the first evidence of hydrogen adsorption saturation by carbon nano-tubes was also achieved, which has been the bottleneck for the application of PEM FC. Prior to our study, a number of controversial publications have claimed the hydrogen capacity of these materials to be between 0.1 to 10.0 wt.%, and none demonstrated a plateau of adsorption with pressure that is consistent with monolayer saturation. Others suggested that the tube bundle structure is opened under high pressure to enable higher adsorption on newly uncovered surfaces, but received no confirmation. Using our home made high-pressure instrument with in-situ electrical probes, we found that a plateau is nearly achieved at about 300 atm in the room temperature isotherm, and that nanotube bundles actually compress with pressure instead of splitting, using in-situ electrical measurements.

Jan 1, 2005