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By Zara Hosseini

?Microseismicity ?Seismic Systems ?Intrinsically Safe and Explosion Proof Seismic System ?Case studies: ?Gas Drainage Optimization ?Fault Identification ?Conclusion Seismic Event ?Occurrences in which energy is released in the rockmass creating a series of seismic waves propagating throughout the rockmass ?Can cause a Fall of Ground or CoalBurst Factors creating Seismicity: ?Mining at Depth ?High stress zones ?Major geological structures ?Mining practices and strategies ?Mining activities i.e. drilling and blasting

Aug 1, 2013

By M. Pelegrin Rodríguez, J. Castellanos Suarez, R. Causse Miyares, A. Mosqueda Martínez, Rubén Aja

"This paper will describe the methods and the results of studies to integrate polymetallic nodule extractive metallurgy methods into existing and operating technologies or plants with the aim of reducing the capital cost of deep-sea mining challenges and to streamline the supply chain of raw materials where such opportunities exist (Moa Bay and others). It will also assess the possibility to carry out pre-industrial processing operations with productivity corresponding to pilot mining operation in the Clarion Clipperton Fracture Zone (5–10% of assumed annual production) with the use of existing facilities. The present study shows the results of high pressure acid leaching of polymetallic nodules (PN) mixed with laterite non-commercial ore. It also presents PN processing in the presence of ammoniacal tailings obtained from the Caron process. The experiments were carried out according to 24 full factorial design. The regression equations were determined for extractions of Ni, Co, Cu, Zn, Fe and Mn. The obtained results show that increasing temperature, the acid/ mineral ratio and the leaching time have a positive and significant effect on extraction of all the studied metals. However, increasing the tailings addition favors the extraction of the Co, Zn and Mn. The extraction of Fe diminishes, while the extraction of Ni is not affected. In the following conditions; 180 min, 260°C, 0.5 kg acid /kg minerals and 2.5 kg PN/kg tailing; the following extractions were achieved; 96% Ni, 90% Co, 97% Cu, 99.9% Zn, 43% Mn and 26% Fe."

Jan 1, 2017

By Elmer Palmer

As part of the Goldcorp Inc growth plan Minera Peñasquito SA de CV has developed its polymetallic deposit with a large ?state of the art? concentrator to process lead and zinc ores. The plant consists of two grinding lines including 38ft diameter SAG mills and 24ft diameter ball mills. During mid to late 2009 concentrator commissioning activities commenced. First concentrates were produced in October 2009 and now the plant is meeting its design basis of 65,000 mtpd per line. This paper describes the design and operational experience to date for its grinding circuit design, together with the recently commissioned HPGR crushing circuit.

Jan 1, 2012

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By H. Arima

The Akita Zinc Company is the only refinery which produces hematite from the iron content in the zinc leach residue. The Akita Hematite Process consists of five stages, which are SO2 pressure leaching, the first neutralization stage, the de-arsenic process, the second neutralization stage and pressure hematite precipitation. In order to strengthen its cost competitiveness and stabilize its operation, the Akita Hematite Process has been modified continuously. Most recently, two process modifications were carried out. The first was an improved ability to maintain a lower arsenic concentration in the de-arsenic process, and the second was an increased throughput in the hematite precipitation autoclave. The details of these recent changes in the Akita Hematite Process are presented in this paper.

Jan 1, 2006

By J. A. Allan

The utilization of natural deposits of salt is one of the oldest industries in Alberta. In 1820, Sir James Richardson visited Salt river, and in the same year D. W. Harmon states chat "clown Slave river, there are several places, where almost any quantity of excellent dean white salt may be taken, with as much ease as sand along the seashore. From these places the greater part of the northwest is supplied with this valuable article". This reference is to the salt chat occurs around springs on Salt river at the northern boundary of the Province. This and other occurrences will be described later in this paper. It is not on account of the development of salt and gypsum in Alberta chat this paper has been prepared, but rather to draw attention to the widespread distribution of salt-bearing and gypsum-bearing rocks, and to the stratigraphic importance of these rocks . The origin of the deposits of salt, gypsum, anhydrite, and dolomite is discussed, and the economic significance of these minerals is considered. There is no salt production reported from Alberta in 1928.

Jan 1, 1929

By Kenneth M. Haley

THE development of Reserve Mining Company's pelletizing practices began in 1949 in a pilot plant located at Ashland, Kentucky. Three years later the participating companies -Armco Steel Corporation, Cleveland Cliffs Iron Mining Company and Republic Steel Corporation concluded the work and the small plant was shut down. Oglebay Norton and Company was the operating manager and Armco Steel Corporation furnished labor and services. Arthur G. McKee and Company were the designers and constructors. The equipment flow sheet that was employed in that pilot operation is shown in Figure 1. This was Reserve's first step from the laboratory work per-formed by the Mines Experiment Station of the University of Minnesota in developing a commercial operation. The plant used New York state concentrate, purchased from Jones and Laughlin Steel Corporation's Benson Mine. This concentrate, minus 14 mesh, 64.3 per cent Fe, 5.7 per cent Si02, was processed at Ashland to 80 per cent minus 325 mesh in conventional ball mill, classifier, thickener, filtering

Jan 1, 1961

By N. Parnian

"Carryover of caustic soda (NaOH) in the steam path caused catastrophic failure of superheater 304H stainless steel tubes in a steam generator and led to an unexpected shutdown after just five months of continuous service of petrochemical following the start of production. The cause of the failure was studied, with a focus on the formation of sigma phase in the weld joint and effect of caustic embrittlement on stress corrosion cracking (SCC). The cracks were examined at the seam weld, heat affected zone (HAZ), and Ubend areas. Hardness was measured for the base metal, HAZ, and weld metal, and microstructures were examined using optical microscopy and scanning electron microscopy (SEM). Crack initiation is attributed to gouging on the precipitated carbide at the HAZ and also the formation of sigma phase in the weld metal, as shown by energy dispersive X-ray (EDX) analysis. In addition, cracking was propagated by caustic embrittlement because of residual stresses and hammering. Finally, the characteristic feature of fracture was illustrated by SEM fractography, and consists mostly of intergranular SCC and some quasicleavage transgranular. INTRODUCTIONThree key factors are needed for the initiation and propagation of intergranular stress corrosion cracking (IGSCC): a susceptible material, a corrosive environment, and sufficient stress. Although austenitic stainless steels are susceptible to sensitization and IGSCC, they are widely used in boiler and superheater tubes because of their high corrosion resistance, high oxidation resistance, acceptable mechanical characteristics at elevated temperatures, and low cost.Sodium hydroxide is injected to neutralize acidic constituents in the steam path, but caustic can concentrate in boiler tubes and attack the surface metal (known as gouging) even traces of caustic in the steam can deposit on surfaces and cause local concentrations of several percent (ASM handbook, 1992). Not only sensitized grains but also sigma phase formed in the weld metal can initiate caustic cracking. In this research, the cause of the failure of 304H stainless steel superheater tubes in a methanol petrochemical plant in Iran was studied with a focus on the effects of caustic embrittlement on IGSCC."

Jan 1, 2012

By J. -C. Parisien-La Salle, D. Blais, G. P. Demopoulos

"In this work the dissolution, precipitation and adsorption behaviour of gold in acidic iron sulphate media containing small amounts of chloride ions is investigated via batch laboratory tests and OLI thermodynamic calculations over the temperature range 25-250°C. Chloride ions may be present in industrial pressure oxidation/pressure leaching (POX/PL) operations due to elevated water salinity levels or due to intentional addition as is the case of the CESL Copper Pressure Leaching Process. Thermodynamic calculations show that AuCl4 - may form depending on the free Cl-/Au ratio and temperature, its stability increasing with increasing Cl- concentration and decreasing with increasing temperature. On the other hand during POX/PL, we know that massive precipitation of iron in various hydrolysis products and compounds occurs. Hence of interest is the question how AuCl4 - that may form during leaching interacts with the iron precipitation products. Gold(III) chloride was found to co-precipitate with iron(III) (oxy) hydroxides and arsenates forming in the autoclave but not with natrojarosite. Upon further investigation it was discovered that activated carbon added in the autoclave (as done in CIL) acts as preferential sink for the mobilized gold, hence opening the potential for the development of a direct cyanide-free gold recovery process in acidic sulphate leach reactors.INTRODUCTIONThe recovery of gold from ores and concentrates has evolved over the years with processing routes becoming increasingly complex. Given the high value of gold, any reduction in losses during recovery operations constitutes an important economic benefit. One such loss that needs to be addressed is the potential solubilisation of gold during pressure oxidation (POX) of refractory sulphidic gold feedstocks. For example, Agnico Eagle Mines reported a loss in gold recovery due to the formation of a gold chloride complex (Garofalo, 2009). Gold is known to form complexes in solution, such as gold(III) chloride, if an excess of chloride ions are present. The fate of such soluble gold chloride during pressure oxidation and the subsequent neutralization of the acidic discharge slurry will determine if gold is lost or recovered in the downstream cyanidation operation. Thus it is of interest to know under what conditions gold chloride may stay soluble or co-precipitate along primary (formed in the autoclave) or secondary (formed during neutralization) precipitates. Furthermore, the mode of co-precipitated gold, such as adsorption on iron compounds, like goethite and hematite (Machesky et al., 1990; Nachayev, 1984); substitution in one of the precipitated phases; or finally chemical reduction to metallic state would have consequences in terms of gold recovery."

Jan 1, 2012

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By J. George Gregr

"This paper gives a brief review of grinding mills installation procedures with special emphasis on future maintenance. The importance of cooperation between the customer, construction contractor and manufacturer's representative is discussed, as well as the imparlance of complying with standards, specifications and the keeping comprehensive installation records.Fundamentals of mill maintenance are explained with the aim being to maximize the equipment availability and to minimize unscheduled downtime. The paper also includes development of wear items design, based on operating conditions, drive components and bearings, and how to keep large gears healthy thus eliminating surprise failures.Experience with installation of a large gear on a 34-foot diameter mill in Lornex and successful application of a computer program for the gear alignment on the mill are given.IntroductionSuccessful operation of a concentrator begins with the engineering of the project and continues through selecting the right equipment, its installation , start-up period, and ends with final tuning of the process. machinery and the human factor into an efficient and viable industrial complex.The following is a brief review of grinding mill installation procedures with special emphasis on future maintenance. Fundamentals of mill maintenance are discussed with the aim being to maximize the equipment availability and to minimize unscheduled downtime, with some specific points on key grinding mill components such as bearings and drives.Finally, the experience is recounted with the installation of a large ring gear on a 34-foot diameter mill at Lornex, and the successful application of a computer program for the gear alignment on the mill."

Jan 1, 1985

By F. H. Wheeler

CONSIDERING the nature of this audience, I perhaps, in addressing you on the subject of air transportation as related to the mining industry, should speak with tongue in check or at least with some reservation. I know full well that many of you, veterans in the great mineral development in Canada, are perhaps more conversant with the overall aviation picture than I, for aviation to you has been the means to an end, and in many instances has been part and ?parcel in the success of your particular projects, in the form of the initial means of transport. I feel, however, that we in this room today have somewhat parallel geographic interests - yours in relation to what is in the ground, mine in the air - and also in the forests and in the streams - aviation, hunting, and fishing - things which have occupied my attention practically all my adult years. In the light of what has gone. before, and in view of present developments, I think you will agree with me when I say that I do not think there could be a more intriguing pursuit than playing a hand in rolling back Canada's tremendous northern frontiers, even if, at this stage, we have made but slight impression on the untold opportunities which lie in our wide-spread, undeveloped areas.

Jan 1, 1956

By Arthur. H. Winckers, Stephan L. Chryssoulis

"The deportment of gold in residue samples of cyanide leach tests of David Bell ore from level 6A block 13 was established using a comprehensive quantitative mineralogical approach. In every test the feed was first pre-aerated for 4 hours, followed by 48h cyanidation. Test no. 2 was done without lead nitrate and yielded a residue assaying 3.03g Au/t. In test nos. 4 and 9 lead nitrate was added before pre-aeration at 0.03kg/t and 0.3kg/t respectively yielding residues of 1.04 and 0.81 g Au/t.The mineralogical approach employed to establish the deportment of gold involved superpanning, to preconcentrate the free gold and assaying of the tailing fraction to determine the gold associated with quartz. It was thus determined that without lead nitrate added 47.2% of the lost gold is in the form of residual free gold particles less than 20 µm in size. It is this form of gold which is under represented in the residues of leach tests with lead nitrate added.Having eliminated coarseness of gold particles as a factor for lower recovery, it was determined that the residual gold particles have extensively contaminated surfaces. Amongst the deleterious surface contaminants identified: S, As, Ag, Sb and Hg, the two most harmful are S and Hg because of their concentration on the surface and rate of accumulation.Mercury and Ag are minor constituents of native gold at David Bell (average composition Au: 78.9 wt%, Hg: 18.5 wt% and Ag: 2.6 wt%) and they become enriched on the surface of residual gold particles because of their slower rate of dissolution in cyanide. The other elements absorb onto the gold particles from solution.The beneficial effect of lead nitrate was documented by comparative surface analysis of gold from residue samples of 48 hour leach testing with and without lead nitrate added and from time dependent (0-2 hour) leach tests in the presence and absence of lead nitrate. Lead nitrate accelerates the dissolution of gold by performing the following functions: (i) catalytic effect on the cyanidation of gold by accepting electrons; (ii) reaction with surface sulphur to form PbS which is then removed by oxidation; (iii) catalytic reaction on amalgam and Ag facilitating the cyanidation of Hg and Ag thus slowing down their build up onto the dissolving gold particles and (iv) the precipitation of sulphide sulphur from solution thus minimizing its build up on the surface of dissolving gold particles which is believed to facilitate the access of cyanide ions."

Jan 1, 1996

By D. Harrington

Ventilation of underground workings consists in establishment of such control of air currents that the underground workers may work in safety, with maximum comfort and efficiency, and without impairment of health; and requires that the mine openings may be made subject to such control of air flow as to remove from these workings at ordinary times harmful gases and dusts, and that, at time of emergency, such as fire or explosion, there may be maintained as much or as little air flow as may be desired covering portions of the mine or the mine in its entirety. Control of air flow is the keystone of any ventilating structure, and this very essential feature is obtainable only by the installation of mechanically-operated fans, together with other;. ventilating devices such as doors, over-casts, regulators, etc. Every mine, large or small, coal or metal, should from the outset be equipped with a fan. While much has been written about natural ventilation and many claims made that in specific mines there is sufficient natural air flow, there are few if any mines, coal or metal, where natural ventilation supplies anything like adequately safe or healthful conditions for underground workers even at ordinary times; and at a time of mine fire or explosion, mines depending upon natural ventilation are practically helpless, and certainly are decidedly dangerous to those unfortunates forced to be in them. While ventilation has practically always been deemed an integral part of coal mining, metal mines have rarely paid much, if any, attention to air circulation until forced to do so by occurrence of some untoward condition or accident. Yet metal mines actually have as great need of efficient circulation of air as have coal mines. The coal mine must remove the dangerous explosive gas, methane, also fumes from explosives and, in occasional places, other gases such as carbon dioxide or nitrogen.

Jan 1, 1933

By R. Amata

"The Gakara Rare Earth deposit in Burundi (East Africa) is unique for its high grade (e.g., 54.3% TREO on average) and low uranium and thorium levels. The majority of the light rare earth (RE) elements in material from Gakara are contained within the familiar RE minerals bastnaesite and monazite. Extensive metallurgical test work was conducted by SGS Minerals Services on mineral samples collected from the Gakara deposit. Various whole ore hydrometallurgical processing routes were examined in a scoping level test program. Preliminary beneficiation testing was also conducted, though it was determined that only marginal upgrading would be achieved with significant RE losses. Thus a hydrometallurgical process on whole ore was developed to minimize the overall process complexity and achieve maximum RE recovery. Results from the test work will be presented, along with the selected base case flowsheet involving agitated atmospheric sulphation of the RE minerals, RE double sulphate precipitation, caustic conversion, redissolution, and carbonate precipitation. Following the base case flowsheet, a purified cerium free mixed RE carbonate with low levels of radioactive elements was produced.INTRODUCTIONRainbow Rare Earths Limited (Rainbow) is a mining company engaged in the exploration and development of the Gakara rare earth deposit in Burundi; Figure 1 shows the project location. The project is located in the Bujumbura Province and 45 km from the Burundi capital of Bujumbura. Notable for its exceedingly high in-situ grade – 54.3% on average total rare earth oxide (TREO), low uranium and thorium levels and familiar rare earth minerals, bastnaesite and monazite – Gakara is the world’s richest rare earth deposit. The project, a previously operating mine from 1948–1978, has a significant mineral inventory base, a long life of mine, well understood mineralogy, and robust economics. Rainbow is focused on bringing Gakara into production in the near term, ramping up to produce 5,000 t/y of a 54%+ TREO concentrate."

Jan 1, 2016

By J. J. Denny

IN November, 1932, an investigation of silicosis was undertaken at the Mcintyre Porcupine mine, Schumacher, Ont., after a discussion of the p"roblem with Sir Frederick Banting and his staff. As a result, it was decided to carry on dusting experiments with animals at the mine in a manner that would duplicate as far as possible actual industrial conditions. At that time 50 guinea pigs were placed in the crusher house tunnel of the mill where a considerable quantity of fine dust, containing approximately 35 per cent of free silica, was being constantly produced. These animals lived in this atmosphere for periods up to one year, and, while on autopsy large amounts of dust were found in the lungs, not a single case of silicosis had developed. These negative results suggested, among other things, that the mine gases might be a predisposing factor in the production of silicosis, and the results of this investigation (1) led us to undertake the study of the hydrogen-ion concentration of the condensate of the atmosphere, both in the mine and in various sections of the mill. The CO, combining power of blood serum on a series of 400 miners was also studied at this time. While these results were inconclusive, the variation in the hydrogen-ion concentration of the condensate between the surface and underground atmospheres encouraged us to investigate the effect of neutral, weak acid, and alkaline solutions on the solubility of siliceous materials. Gye and Purdy (2) were the first to point out that the chemical reaction, and not the physical presence of siliceous material, was responsible for the production of the fibrosis in silicosis. This work was investigated by Gardner and Cummings (3), who showed that the tissue reaction to quartz was definitely proportional to the size of the particle. They found that 1-3 micron particles of quartz produced an acute proliferative fibrotic response, while the 10-12 micron particles produced only a foreign-body reaction up to a period of three years. It is accepted that the dangerous silica particles retained by the lung are under 5 microns in diameter.

Jan 1, 1937

By D. S. Hines

The purchase of mechanical equipment for mines is not unlike the purchase of other materials or supplies in general principle, but on account of the major part such equipment plays in the operations, and of the fact that life and valuable property are at stake, the matter demands the most careful attention on the part of the purchaser. The problems and difficulties encountered are dealt with below in their sequence in the purchasing procedure. Requisiting Although it is quite a common practice to submit a tentative specification of requirements to recognized manufacturers of equipment- soliciting alternative propositions or recommendations for study in the selection of certain equipment-as a rule the first step in purchasing procedure is the requisition. Primarily, it is the form that carries to the purchasing department the record of equipment wanted. A full and complete description or specification, and accuracy of record, are the important points to be insisted on in a requisition. Too much attention cannot be given to this detail, as this is one of 'the most important phases of purchasing work. Incomplete information, either in specification or detail, leads to delay in handling the requisition, and, if not detected in the purchasing department, may mean receipt of material which cannot be used for the purpose intended. In addition to description of material or equipment to be ordered, the requisition should also show where or what the equipment is for, whether for operating or new work. If for capital account, the number of the authority for expenditure should be given for record and distribution purposes.

Jan 1, 1930

By B. D. Pandey, D. Bagchi, Premchand

During the separation and recovery of metals from the ammoniacal leach liquor of Indian Ocean nodules by solvent extraction-electrowinning (SX-EW) in close-loop operation, the copper electrolyte containing ~40g/L Cu, 20 g/L Ni and 180 g/L sulphuric acid is bled-off to control the impurities. The recovery of copper and nickel as powders has been examined from the copper bleed solution following partial decopperisation, crystallization of mixed sulphate of the two metals and aqueous hydrogen reduction. From the dissolved sulphate solution containing 17.68 g/L Cu, 18.83 g/L Ni and 0.03 g/L Fe, the copper powder was precipitated at initial hydrogen pressure of 26 bar in an autoclave in 90 min at 140 °C. The residual copper from the spent solution was removed as sulphide and nickel powder was then recovered (99%) in two stages from a solution of pH 4.5 at 40 bar pressure and 190 °C. However, 98% nickel recovery in one stage was achieved when hydrogen reduction was carried out from an ammoniacal solution in the pH range 9-11. Copper and nickel powders were produced from the bleed solution with acceptable purity and specifications suitable for P/M applications.

Jan 1, 2004