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By Jae-Chun Lee, Sadia Ilyas

"The present study was carried out to develop an economically feasible and environmentally friendly technique to extract metals such as Al, Fe, Cu, Zn and Ni from electronic scrap by employing Penicillium chrysogenum strain KBS3. Studies were carried out in various leaching modes, including one-step leaching with combined growth and leaching phases (Mode 1), two-step leaching with alternative growth and leaching phases (Mode 2), spent medium leaching with separated growth and leaching phases (Mode 3), leaching with fresh growth medium without fungal culture (Mode 4), leaching with deionized water (Mode 5) and leaching with commercial organic acids (Mode 6). The main lixiviants produced in leaching Mode 1 were citric, tartaric, oxalic and gluconic acids in concentrations of 12, 2.5, 1.8 and 152 mM, whereas in leaching Mode 2, the concentrations were 15, 0.5, 1.0 and 1,162 mM, respectively. In leaching Mode 3, 63 mM citric acid, 23 mM tartaric acid and 29 mM oxalic acid was observed. At 5% pulp density, both leaching Modes 1 and 2 showed similar metal extraction yields from the electronic scrap at 35º C. Approximately 96% Al, 98% Zn, 48% Cu, 25% Fe, 66% Pb and 73% Ni were extracted in leaching Mode 1 in 14 days. In leaching Mode 3, 85% Al, 81% Zn, 97% Cu, 22% Fe, 50% Pb and 63% Ni were extracted in 14 days. The extraction yield of Cu was much lower in leaching Modes 1 and 2 (48- 50%) than in leaching Mode 3 (97%), as well as in leaching Mode 6 (98%) with organic acids, including citric, tartaric, oxalic and gluconic acids.IntroductionTechnical innovations in electrical and electronic equipment with new functionalities and designs stimulate consumer purchasing and lead a rapid increase in the production of waste materials. Terazono et al. (2006) have reviewed the data on electronic waste generation in different parts of the world. Studies by Bertram et al. (2002) have also affirmed that waste electrical and electronic components are the fastest growing waste category, which emphasizes the need for efficient recycling strategies. The recycling of electronic waste is an important subject, not only from the perspective of waste treatment, but also from the perspective of the recovery of valuable materials. However, the recycling of electronic scrap is still limited, due to the heterogeneity of the materials present in the products (Veit et al., 2005).Bioleaching-based processes offer a number of advantages over conventional pyro or hydrometallurgical methods (Lee et al. 2007; Lee and Pandey, 2012). These advantages include simple, inexpensive (in some cases) and ecofriendly approaches and the generation of less active leach residue relative to other metallurgical processes. Although biohydrometallurgical processes have been successfully applied to the leaching of metals from ores (Olson et al., 2003; Rawlings, 2002), data pertaining to the application of these processes for the extraction of electronic scrap are still scarce. Recently, a few studies have been undertaken for the extraction of metals from electronic scrap/ printed circuit boards (Brandl et al., 2001; Faramarzi et al., 2004; Ilyas et al., 2007; Ilyas et al., 2010). These studies were conducted with mesophilic chemolithotrophic bacteria (Acidithiobacillus ferooxidans and Acidithiobacillus thiooxidans), cyanogenic bacteria (Chromobacterium violaceum) or moderate thermophilic bacteria (Sulfobacillus thermosulfidooxidans). However, compared to bacterial leaching, fungal leaching has several advantages, including (i) the ability to grow at a higher pH, thus making it more suitable for the bioleaching of alkaline solid waste; (ii) a generally faster leaching process with a shorter lag phase and (iii) the chelation of excreted metabolites (e.g., organic acids) with metal ions, thus reducing toxicity to the biomass (Burgstaller and Schinner, 1993; Aung and Ting, 2005)."

Jan 1, 2015

By P. E. Lenz

In Nevada, large deposits of diatomite were formed during the Miocene / Pliocene in deep, alkaline lakes. Associated sediments are predominately fine-grained lacustrine with varying fluvial-clastic layers. Tephra layers are common, and probably served as a source of soluble silica for the extensive diatom colonies. Four companies are currently producing diatomite from Nevada deposits. Nevada ranks second to California in annual domestic production. Nevada diatomite is used in filter aids, fillers, absorbents, catalyst supports, and many other products. Economics and mineral reserves indicate that diatomite production in Nevada will be significant well into the next century.

Jan 1, 1993

By Osvaldo A. Bascur

Standards and Technology for bringing information at the desktop has greatly evolved in recent years. The benefits to be realized depend on how these new tools are embraced at the performer level. A key operating challenge is to ensure collective effort is geared towards the most efficient achievement of identified operating and corporate objectives. Presentation, application and data repository modular software are emerging in successful client server applications. The industrial desktop emerges as the new tool for continuous improvement and innovation in industrial operations. Here, process information, reliability maintenance, process simulation, production schedules, performance monitoring are integrated using Microsoft enabling tools at the desktop. A workflow model is presented to assist in implementing a strategic information system in metallurgical plants.

Jan 1, 1996

By J. A. Bradbury

N. A. Degerstrom, Inc. has constructed and operated a processing plant approximately five miles north of Soda Springs, Idaho for processing a byproduct phosphate treater dust from Monsanto's elemental phosphorus plant, also located in Soda Springs. The plant is designed to produce agricultural-grade phosphoric acid, gallium, and silver. The design capacity of the plant is 54.4t (60 st) of treater dust per day, which can produce 16,326t (18,000 st) of phosphoric acid, 6,600 kg of gallium, and 6,033 kg (194,000 oz.) of silver per year.

Jan 1, 1993

By H. Kinilakodi

The authors previously developed a methodology that combines injury and citation measures into an overall mine safety performance evaluation tool, called the safe performance index (SPI). It can be easily adopted by mine operators to monitor trends in their injury and citation experiences as a risk assessment method. In this paper, six normalized safety measures and the SPI are used to evaluate the health and safety risk that existed at mines in the two years preceding the occurrence of a fatality. The percentage of mines is given for which the risk was high or where trends of some of the safety measures indicated moderate risk. In 50% of the mines, this mine safety performance tracking method could have been helpful to the companies, state agency or the U.S. Mine Safety and Health Administration (MSHA) in recognizing and addressing emerging problems with actions that may have been able to predict high-risk conditions, the fatality and/or other serious injuries. The approach would have given extra scrutiny to the risk for mines that encompassed 74% of the fatalities during 2007-2010.

Jan 1, 2012

By H. B. Oblad

Coal/pyrite fines were froth floated in a laboratory cell to examine the rate of pyrite recovery during conventional coal flotation. The effects of collector, particle size and carbon to total sulfur ratio on the kinetics of recovery were investigated. These data coupled with microscopic examination suggest that miniscule amounts of coal that remain attached to the pyrite surface affect the rate of flotation of pyrite.

Jan 1, 1985

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives (HydroStar® 4208, DXG®-F7, Cyquest® N-900) using a potentiostatic technique. The current-time data obtained at 0.16V vs. SHE was analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A m-2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current-time data from the electrolyte without organic additives indicate progressive nucleation with two-dimensional (2-D) growth under diffusion control. SEM images obtained confirmed progressive nucleation with 2-D growth. 20 mg/L Cl- and 2.5 mg/L organic additives did not change the nucleation and growth mechanism, however the additives increased the number and reduced the size of copper nuclei leading to more uniform coverage of the stainless steel substrate.INTRODUCTION Electrowinning of copper is an important process in the manufacture of high purity copper metal. It is approximated that 20% of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole, and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth, and nature of the initial deposit (Sun and O'Keefe, 1992). Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature, and copper concentration, small amounts of organic smoothing agents (traditionally guar products) are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper dendrites, which leads to improved deposit quality by producing bright, smooth, and dense cathodes."

Jan 1, 2015

By Billy W. Parks

This paper reports on the first 2 years in operation of a special-purpose coal handling rig which provides blending, temperature reduction, and continuous, automatic mechanical sampling as part of midstream barge to ship coal transfers. Briefly reviewing some of the characteristics of coal handling peculiar to midstream transfers, the paper discusses how the most beneficial aspects of midstreaming were enhanced through the design of this blending and sampling rig.

Jan 1, 1986

By E. O. Strahl

In the search for economic mineral deposits, the need for efficient mineral or chemical assays is of prime importance. Costly analytical methods and long delays in obtaining assay results severely limit the effectiveness of an exploration program. The assay problem becomes acute once a potential ore body is located and large numbers of samples are generated in close interval drilling programs. In order to avoid the delays and high costs of extensive assays, the exploration geologist or mining engineer is likely to be required to curtail his drilling program, composite samples, or restrict the required analyses to a limited number of critical elements. As a result, the definition of the potential ore body may be less than needed for final economic evaluation. The assay requirements for bauxite exploration usually involve a considerable number of total elemental and empirical analysis. Since the Bayer process for extracting alumina from bauxite involves the selective dissolution and reaction of specific minerals from the bauxite, a direct chemical analysis for elemental composition yields only a portion of the data required to effectively describe the potential economic value of ore body or deposit. To fully characterize the economic value of a bauxite requires digestion, mud separation and mud settling tests under conditions approximating a commercial Bayer plant. A close approximation of the process behavior of a bauxite also can be calculated from a combination of the chemical and mineralogical analyses. By determining the elemental chemistry, mineralogy, and Bayer plant processing characteristics of a few samples of a given bauxite, correlations can be derived that permit defining a bauxite in terms of a given set of process conditions.

Jan 1, 1977

By K. P. Chong

Fracture toughness of oil shale is an essential property in fragmentation to optimize particle sizes and permeability distributions in in-situ processes. Fracture mechanics of oil shale has been based on conventional fracture mechanics using notched samples and assuming the material to be isotropic and elastic. Oil shale is a layered material more accurately characterized as transversely isotropic. The senior author proposes to use a semi- circular core specimen with a center crack subjected to three point bending. Singular crack tip elements with isoparametric elements are used. The precracked semi-circular disk is modeled under displacement loading. The effect of crack length on the non-dimensionalized stress intensity factor is investigated by strain energy method, ellipse method, and stress method. Very close agreements are found. The fracture toughness is obtained by compressing the specimen in to failure. Parameters such as oil yield are investigated.

Jan 1, 1984

By B. J. Timmons

An initial point that I would like to make very emphatically?and as our title might erroneously suggest for those of you old enough to remember . . . Peter Harben and myself do not intend to shoot ourselves in the foot. We derive our livelihood from a number of aggregate, industrial and other minerals producers, both here in the United States and outside. This paper, therefore, is a fence-straddler or for information purposes (we hope) only, rather than any "fur or agin" stances. In essence, some of you may consider it a U.S.G.S. publication! In fact, we hope that it serves to inspire aggregates producers to do some radical thinking, to promote introspection, and to that end it would benefit both domestic and foreign producers. The title could be shortened into a brief question of "Aggregates Travel?" with an emphatic no for the answer. In the past, the success of a construction materials venture depended upon your ability, through siting, to provide the customer f.o.b. the job site, a product at the lowest possible cost.

Jan 1, 1987

By Dexter C. Hatch

At MacIntyre Development of the National Lead Company, Taha s, New York,, the flotation plant was set up to recover ilmenite from the finer size fraction of the ore that cannot be efficiently treated in the main gravity-magnetic separa¬tion process. It was later expanded to handle the reground middlings from the tables wetherill magnetic separators. The ilmenite-magnetite ore is ground to minus 20 mesh in five 6 x 12 ft. rod mills in closed circuit with DSM screens. The minus 20 mesh screen undersize is pumped to four parallel sections each consisting of two rougher wet-magnetic separators and one cleaner separator for magnatite removal. The screen undersize from the fifth section is distributed to all four sections. The magnetite removed in the roughers is pumped back to the cleaners and the cleaner magnetite is dewatered in rake classifiers and carried by belt to the winter plant or the stockpile area. The nonmagnetic sands from rougher and cleaner magnetic separator are sized for table feed in eight pocket hydraulic sizers. The slime overflows from the Crocketts, the sizers, and the magnetite rakes are collected and pumped to three-inch cyclones for thickening and desliming. The cyclone underflow is the principal flotation plant feed.

Jan 1, 1962

By L. R. Moore

The World Health Organization (WHO) considers contamination from oxyanions, such as selenium and arsenic, a global concern. While their elemental forms are toxic, the aqueous oxyanions are more so. These aqueous forms, which exist at a higher oxidation state, are the most common forms released during mining processes. Many technologies are capable of meeting the governmental discharge criteria for oxyanionic contaminants, but may possess limitations due to redox chemistry as well as the water matrices. An innovative technology was developed that can successfully reduce such aqueous forms generated during mining processes to a level below the discharge criteria. This paper discusses how an understanding of the sensitivities of this novel adsorbent towards these variations in water matrices and redox chemistry can be used to optimize its application.

Feb 27, 2013

By N. Sahin, M. Can, Z. Ekmekçi, Y. Öztürk, Ö. Biçak, I. B. Çelik, B. Kocabiyik

"In this paper, a case study from Çayeli Bakir Isletmeleri A.S. (Rize, Turkey) about the selective flotation of copper minerals from sphalerite is discussed. Çayeli Cu-Zn Sulfide Ore contains different ore types, such as yellow ore, clastic ore, bornite-clastic ore, bornite-yellow ore, and black ore. For some of these ore types, selective flotation of copper and zinc is very difficult presumably due to presence of secondary copper minerals such as bornite, chalcocite and covellite, and also surface oxidation. These factors affect Cu-Zn selectivity due to activation of sphalerite particles in the ore during the process. The main objective of this work was to improve Cu-Zn selectivity by optimization of the pulp chemistry for different ore types of Çayeli ore. After preliminary flotation tests investigating effects of different chemical conditions, a plant survey was performed to determine the plant performance and sources of the problems when problematic bornite-clastic ore is treated in the plant. Various chemical conditions are tested in the laboratory scale test for better depression of sphalerite in copper flotation circuit. Combination of Na2S+ZnSO4+MBS was found to be the most effective depressant scheme. INTRODUCTION Ore variability is one of the most important factors affecting performance of a process plant both in short and long term planning. The geometallurgical modelling becomes a common tool to determine ore variability problems and develop the most efficient solution during life of mine (1, 2). Flowsheet design and equipment selection and sizing are usually done based on the results of ore variability test works. However, in some cases ore variability may not be foreseen during the design stage and therefore the solutions should be developed based on the existing flowsheet and equipment in the plant. In this situation, ore characterisation, problem statement and diagnostic testing should be applied step by step. The problem could be due to changing feed grade, mineralogical characteristics, grindability and surface characteristics when flotation is involved. The variability in feed grade with fixed mineralogy can be handled with relatively simple modifications (i.e. adjusting throughput or equipment capacity) in the plant. Variability in ore mineralogy is the most complex and difficult problem to tackle. Because, mineralogical variations could bring variations in mineral composition, texture and liberation. These variations can potentially lead to the variations in grindability of the ore and flotation behaviour. Variations in grindability are usually managed by optimization of operational parameters in grinding circuit, as it would be costly to replace the existing equipment in the circuit (3). The variations in flotation behaviour are mainly due to variations in mineral types and distribution, texture and surface oxidation. One or all of these factors could be observed in a flotation operation. Therefore, a comprehensive investigation both in plant and lab scale should be conducted for definition of source of the problem. The testwork to solve the problem and retrieve the performance is planned and conducted depending on the source of the problem (4, 5)."

Jan 1, 2017

By D. Lauriski

The recent spate of catastrophic events at U.S. mines raises the question as to whether or not the mine safety and health system in the U.S. is broken. The prescriptive regulatory regime in the U.S. is not a cure-all for a broken system. Without totally dismissing the contribution of a prescriptive regulatory approach, this paper argues that safety in the U.S. mining industry would be enhanced if the nation adopted a scheme that provides a balance between specification standards and two alternatives: performance and systems-based standards. This would allow effective and flexible means to continuous health and safety performance improvement. Mine operators, regulators and politicians could then go beyond thinking that compliance alone equals strong safety by creating a proactive system that emphasizes continuous improvement. By adopting performance and systems-based standards, exemplary safety and health performers can be recognized, allowing regulators to focus their efforts on those without sound occupational safety systems and who have substandard safety performance. Mining Engineering, 2011, Vol. 63, No. 7, pp. 77-82. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By V. O. Tenorio

The implementation of autonomous technologies for production in surface mines demands changes in the existing monitoring and control systems. The present study deals with the concepts involved in the development of a decision support system (DSS) for the supervision of a combined fleet of manned and unmanned equipment operating in a surface mine. The project was carried out as part of an autonomous mining program that lasted from early 2006 until the end of 2008. The objective of the DSS was to achieve short-term planning goals while maintaining safe working conditions. Supervisory tasks become more complex when several autonomous vehicles operate simultaneously alongside manned equipment. The operation center where the DSS was installed allowed autonomous vehicle operations to be controlled while tracking technology reliability experiments performed on control display interfaces and interaction provided design parameters for more complex supervisory systems for autonomous mines. Mining Engineering, 2011, vol. 63, no. 11, pp. 80-86. Official publication of the Society for mining, metallurgy and exploration, Inc.

Jan 1, 2011

By R. Bishop, J. Baggett, J. Monsalve, J. Hole, N. Ripepi, A. Abassi

This work focuses on the operational and safety issues associated with karst voids in large opening underground mines. Issues include water inrush, structural instability, and engineering uncertainty in these environments. Coupled with the fracturing prevalent in folded sedimentary rocks, karsts are complex and challenging ground control risks. Traditional methods of predicting karst locations, such as probe drilling, are impeded by the inconsistent spatial distribution and variable sizes of the features. Ground penetrating radar (GPR) is a geophysical technique that transmits radio waves into a medium and subsequently detects reflected waves via a receiver. The travel time and energy of received signals are then processed and interpreted. The difference in material properties between limestone and open karsts causes strong reflections. GPR is frequently used as a geophysical surveying technique in several industries, however there is a lack of published research on underground mining GPR applications. The purpose of this work is to prove the viability of GPR in underground stone mines for karst detection, and to discuss the importance of karst detection ahead of mining. INTRODUCTION The Mine Safety and Health Administration (MSHA) currently lists 116 active underground stone mines in the United States, the vast majority of which extract limestone for crushed stone products. These limestone mines have the potential to encounter karst voids at some point in their operation, as most karstic regions of the United States develop in limestone rock masses (Kuniansky, Weary, & Kaufmann, 2016). Karsts, the cavities formed by the dissolution of carbonate rock, have long plagued the mining and tunneling industries, as well as been a hindrance on the Earth’s surface, producing sinkholes and ruining otherwise valuable land for construction and public use. The impact of karsts on the Gavarres tunnel in Spain is well documented by Alija et al; constant instability conditions, material spills into the tunnel, and unexpected cavities seriously delayed the project deadlines and “were not foreseen in the design” (Alija, Torrijo, & Qunita-Ferreira, 2013). At the water supply project in Sohngua River, China, Bin et al detail the presence of both water and sediment filled karsts which are sources of disastrous conditions at this tunnel (Bin, et al., 2017). A hydrological tunnel in Lebanon encountered numerous massive karsts in the tunneling path which required remediation via friction anchors, rockbolts, welded wire fabric, channel steel arch segments, invert steel beams, and shotcrete (Leech, Jaoude, & Ghanem, 2008). From a design standpoint, rock mass classification schemes, such as the RMR from Bieniawski and the Q-system from Barton, are not able to represent the true nature of a karstified carbonate rock mass, and therefore complex case-by-case analyses of underground conditions are necessary (Andriani & Parise, 2017).

Jan 1, 2019

By J. W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct iron making pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicate that 69% are less than 2.5 µm across, 21 % are 2.5-5 µm, and 10% are larger than 5 µm. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By R. H. Hanewald

The processing of EAF baghouse dusts from both the specialty steel industry and low alloy producers will be reviewed. In addition, the INMETCO process has been modified so as to recover nickel, chromium and iron from many other waste materials such as pickling solutions or filter cakes, spent nickel and chromium plating baths, carbon refractories from pickling tanks, and super alloy wastes including baghouse bags. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high temperature metals recovery. This, along with the details of INMETCO's BDAT Test Program and results performed to pre-agreed standards with the EPA will be discussed.

Jan 1, 1992

By E. E. Caba

Copper smelter flue dusts containing arsenic are hazardous materials requiring environmentally accept-able disposal, preferably with re-source recovery under the RCRA and CRCLA regulations. However, the known resource recovery processes entail capital and operating costs greater than can be justified by the revenue of the recovered metal. Consequently, the smelting industry is tending to forego resource recovery in favor of encapsulation and storage in a certified class I hazardous waste site, or in a dedicated facility located at the source Superfund site. Order of magnitude costs for this option with portland cement encapsulation are estimated at $100 per ton, not including transportation. Industrial adoption of a new resource recovery process re-quires that its cost, including capital amortization, exceed the cost of encapsulation and storage only by the amount of the offsetting revenue from sale of metal. The lime-roast/ammoniacal leaching process is expected to meet this goal.

Jan 1, 1992