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This paper presents a resume of the likely profitable mining areas in New Zealand. It covers the main "minerals" - gold, coal, oil and gas, ironsands, silica sands, clays, lump silica, perlite, sulphur and limestone.The potential mining projects are depicted on a map of New Zealand together with the associated works involved in hydro-electric and geothermal power development requirement for industries such as aluminium, nickel ferro-silicon or silicon carbide production.The political need for mining development to relieve unemployment and reverse emigration is stressed. A case is made for exploration and development assistance by government in labour re-training, energy supply and transportation, if the tremendous losses through lack of use of human and industrial resources are to be rapidly reduced. These losses are currently estimated at $10,000,000,000 per year.The need for protection of the sanctity of contract and security of tenure of all mining operations is touched on briefly as is the need for a reasonably balanced view on conservation. However as both of these are more properly covered in papers on the legal and environmental aspects of the mining climate they are presented here only as they affect the economy of the mining operation.Finally there is a brief comment on the mining climate in New Zealand relative to Australia and South Pacific mining operations.

Jan 1, 1990

By J. D. Marchant

As part of its mission to assure the maximum recovery and use of the Nation's mineral resources, the Bureau of Mines, investigated an improved procedure for producing rare earth-silicon alloys. For example, a charge consisting of 681 grams of mixed rare-earth oxides, 309 grams of ferrosilicon (75 wt-pct Si), and 182 grams of aluminum metal along with a flux consisting of 681 grams of CaO and 45 grams of MgO was reacted at 1,500° C in an induction furnace. Good slag-metal separation was achieved. The alloy product contained, in weight-percent, 53 RE, 28 Si, 11 Fe, and 4 Al with a rare earch recovery of 80 pct. In current industrial practice rare earth recoveries are usually about 60 pct in alloy products that contain approximately 30 wt-pct each of rare earths and silicon. Metallurgical evaluations showed the alloys prepared in this investigation to be as effective in controlling the detrimental effect of sulfur in steel and cast iron as the commercial rare earth-silicon-iron alloys presently used in the steel industry.

Jan 1, 1980

By D S. Nicholson, T Marshall

Reserves of high-grade quartz gravel, lignite and timber suitable for the production of silicon metal and ferrosilicon on large scale occur within 40 miles of Bluff Harbour. Undeveloped hydroelectric power resources on the Clutha River are located within 50 miles of the most promising quartz gravel deposits while opencastable lignite, potentially suitable for electric power production, occurs in the same locality as the quartz gravels. A preliminary study of production economics indicates that the commercial feasibility of silicon/ferro-silicon production would depend mainly on the cost of electric power, total capital cost of plant, and the market value of the products. The proximity of Bluff Harbour is advantageous for the export of products.

Jan 1, 1971

By T. P. Floridis

It was deemed desirable to obtain an understanding of the vacuum desulfurization process. McKechnie1 has reported that the sulfur content of nickel- and cobalt-base alloys is reduced in vacuo. Keverian and Taylor2 have observed that vacuum melting causes desulfurization of iron-carbon-silicon alloys. Garnyk and samarin3 have desulfurized transformer steel by vacuum treatment. Experiments were conducted in order to investigate the desulfurization of liquid iron under reduced pressures, and to establish the effect of some alloying elements, and various crucible materials. A vacuum-induction furnace of 50-lb capacity was used. The charge was Armco iron. Silicon was added as 90 pct ferrosilicon, carbon as electrode graphite, and aluminum as high-purity aluminum metal. Magnesia and silica crucibles were used, their inside diameters were 5 1/2 and 5 3/8 in., respectively. The temperature was measured with an optical pyrometer and it was held at 1600 1 15°C. Samples were withdrawn with quartz tubes of 6 mm ID, without disturbing the furnace atmosphere. Pressures were measured with an alphatron gage. The experimental results are shown in Fig. 1. They indicate that: 1) Sulfur can be removed from liquid iron alloys by vacuum treatment; 2) The desulfurization is enhanced by the presence of silicon, carbon, and aluminum, all these elements increase the activity of sulfur dissolved in liquid iron;4 3) The pronounced effect of silicon indicates that probably a volatile silicon sulfide is formed, Alcock and Richardson5 have observed a similar phenomenon; 4) The same rate of desulfurization was obtained when the metal was contained in either magnesia or silica crucibles. Dr. J. Keverian has contributed many discussions and recommendations. M. S. Sutliff has helped in conducting the heats. The permission of General Electric Co. for this publication is gratefully acknowledged.

Jan 1, 1960

By B. M. Loring, I. R. Krame, F. M. Walters

NO observations on the mechanical properties of man-manganese alloys have been published since pure manganese became readily available, either distilled manganese or electrolytic manganese. The purpose of this investigation was to determine whether iron-manganese alloys are essentially brittle, as reported by Hadfield,' or whether the lack of ductility observed was due to impurities in the alloys that he studied. Experimental Methods The alloys were melted in a roo-lb. high-frequency induction furnace with a magnesia crucible, using ingot iron and electrolytic manganese. The heats were split, the first giving six 18-lb, ingots and the second three. Each successive heat was higher in manganese and about 0.3 per cent silicon was added as ferrosilicon. The alloys forged without difficulty and were given a 9' per Published by permission of the Navy Department. Manuscript received at the office of the Institute June 28. 1941. Issued as T.P. 1369 in Metals Technology. September 1941. * Division of Physical Metallfirgy Naval Roscarch Laboratory. Anacostia Station Washington. D. C. 1 References are at the end of the paper. 4 cent reduction to ¾-in. rounds. The chemical analysis of the alloys is given in Table I. The forged rods were homogenized for 224 hr. at r150°C. (2100°F.) and air-cooled. The alloys were tested in two conditions of heat-treatment: (I) as normalized from 870°C. (1600°F.) and (2) normalized from 870°C. and tempered for I hr. at 540°C. (Iooo°F.) and air-cooled. The tensils specimens were 0.505 in. in diameter with a 2-in. gauge length, and the impact specimens were v-notch Charpy. The proportional limit and yield strength were taken from the stress-strain diagrams drawn by a Peters recorder. The data obtained from the tensile test and the hardness measurements are given in Table 2. Specimens that were normalized are designated by N; those that were normalized and tempered by T. Alloy G was tempered after forging (D).

Jan 1, 1942

By B. M. Loring, I. R. Krame, F. M. Walters

NO observations on the mechanical properties of man-manganese alloys have been published since pure manganese became readily available, either distilled manganese or electrolytic manganese. The purpose of this investigation was to determine whether iron-manganese alloys are essentially brittle, as reported by Hadfield,' or whether the lack of ductility observed was due to impurities in the alloys that he studied. Experimental Methods The alloys were melted in a roo-lb. high-frequency induction furnace with a magnesia crucible, using ingot iron and electrolytic manganese. The heats were split, the first giving six 18-lb, ingots and the second three. Each successive heat was higher in manganese and about 0.3 per cent silicon was added as ferrosilicon. The alloys forged without difficulty and were given a 9' per Published by permission of the Navy Department. Manuscript received at the office of the Institute June 28. 1941. Issued as T.P. 1369 in Metals Technology. September 1941. * Division of Physical Metallfirgy Naval Roscarch Laboratory. Anacostia Station Washington. D. C. 1 References are at the end of the paper. 4 cent reduction to ¾-in. rounds. The chemical analysis of the alloys is given in Table I. The forged rods were homogenized for 224 hr. at r150°C. (2100°F.) and air-cooled. The alloys were tested in two conditions of heat-treatment: (I) as normalized from 870°C. (1600°F.) and (2) normalized from 870°C. and tempered for I hr. at 540°C. (Iooo°F.) and air-cooled. The tensils specimens were 0.505 in. in diameter with a 2-in. gauge length, and the impact specimens were v-notch Charpy. The proportional limit and yield strength were taken from the stress-strain diagrams drawn by a Peters recorder. The data obtained from the tensile test and the hardness measurements are given in Table 2. Specimens that were normalized are designated by N; those that were normalized and tempered by T. Alloy G was tempered after forging (D).

Jan 1, 1942

By Wilkinson RDB, Van Der Meer FP

In order to overcome the statistical limitations imposed by the need to recover density tracers by hand, magnetic density tracers were developed to determine the efficiency of dense medium separators treating porous materials. The tracers were manufactured by extrusion of polypropylene ferrosilicon mixtures and subsequently coated with a distinctive paint to allow hand sorting according to density. Fifteen tracer batches were manufactured in the range 1.61 - 1.94 g/cm3. The tracer densities were determined by a hydrostatic method. The tracer method was applied to the dense medium separation of a Moroccan oil shale in a pilot scale Dyna Whirlpool separator. For each test, about 20,000 tracers were added with the plant feed and subsequently recovered from the products with a dry low intensity magnetic separator. The Tromp curve determined by conventional heavy liquid analysis was displaced towards lower densities compared with that determined by tracers, indicating that the porous shale particles absorb heavy liquid. It is concluded that for porous materials like oil shale and coal, the tracer method gives the most accurate results. In pilot scale testwork the tracer method is also much faster than the conventional heavy liquid analysis, as rather large samples have to be processed by the latter method to ensure Representativeness.

Jan 1, 1987

In 1972, metallurgical testwork on Renison ore indicated a significant proportion of low specific gravity, tin-barren material ideally suited to heavy medium separation (HMS). Further technical and financial studies provided adequate economic justification and in December 1974 the Renison HMS plant was cannissioned. Initial operations were interrupted by the imposition of tin production quotas for three months in 1976; they were also beset with difficulties particularly with regard to mechanical wear. During the first two operating years much develognent work was carried out including installation of a pyrrhotite flotation bank in the medium recovery circuit, investigations into various wear-resistant materials and the use of atanised rather than milled ferro-silicon. By 1977/78 financial year satisfactory performance had been achieved and since then the average floats rejection has been 18.8% of the total ore treated with an associated tin loss of 2.96%. Developnent has nevertheless continued during the last three years, principal modifications being the installation of larger aperture desliming screens and improvements to the overdense cyclone circuit.

Jan 1, 1978

By A. S. Yue

It was deemed desirable to obtain an understanding of the vacuum desulfurization process. McKechnie1 has reported that the sulfur content of nickel- and cobalt-base alloys is reduced in vacuo. Keverian and Taylor2 have observed that vacuum melting causes desulfurization of iron-carbon-silicon alloys. Garnyk and samarin3 have desulfurized transformer steel by vacuum treatment. Experiments were conducted in order to investigate the desulfurization of liquid iron under reduced pressures, and to establish the effect of some alloying elements, and various crucible materials. A vacuum-induction furnace of 50-lb capacity was used. The charge was Armco iron. Silicon was added as 90 pct ferrosilicon, carbon as electrode graphite, and aluminum as high-purity aluminum metal. Magnesia and silica crucibles were used, their inside diameters were 5 1/2 and 5 3/8 in., respectively. The temperature was measured with an optical pyrometer and it was held at 1600 1 15°C. Samples were withdrawn with quartz tubes of 6 mm ID, without disturbing the furnace atmosphere. Pressures were measured with an alphatron gage. The experimental results are shown in Fig. 1. They indicate that: 1) Sulfur can be removed from liquid iron alloys by vacuum treatment; 2) The desulfurization is enhanced by the presence of silicon, carbon, and aluminum, all these elements increase the activity of sulfur dissolved in liquid iron;4 3) The pronounced effect of silicon indicates that probably a volatile silicon sulfide is formed, Alcock and Richardson5 have observed a similar phenomenon; 4) The same rate of desulfurization was obtained when the metal was contained in either magnesia or silica crucibles. Dr. J. Keverian has contributed many discussions and recommendations. M. S. Sutliff has helped in conducting the heats. The permission of General Electric Co. for this publication is gratefully acknowledged.

Jan 1, 1960

1. Book reviews Phosphate rock, a bibliography of world resources. London, Mining Journal Books Limited, 1984. £10 (surface mail), £12.25 (airmail). Reviewer: P.Le. Grubb Ok Tedi, by William S. Pintz. London, Mining Journal Books Limited, 1984. 206 pp. £19 (surface mail), £22.25 (airmail). Reviewer: R.P. Plewman 2. Publications of the Canadian Mineral Policy Sector Lime by D.H. Stonehouse. 5 pp. Phosphates by G.S. Barry. 9 pp. Statistical summary of the mineral industry in Canada. 77 tables. Talc by M. Prud'homme. 6 pp. Zirconium by M.A. Boucher. 6 pp. Cement by D.H. Stonehouse. 13 pp. Gypsum and anhydrite by D.H. Stonehouse. 7 pp. Regional review by T.M. Buch. 12pp. SaltbyG.S. Barry. 7pp. Silicon, ferrosilicon and silicon carbide by D.G. Law-West. 6pp. SulphurbyB.W. Boyd. 9pp. Mineral Report 31. Canadian Minerals Yearbook 1981. Available from the above address at $40.75 per copy. 3. Mintek reports Report M18D The recovery of pyrite and gold from acid-leach residues from the Merriespruit Gold Mine. (First issued Feb. 1982; reissued Mar. 1984). Report M2OD The separation of ore from Cooke into high- and lowgrade fractions. (First issued Feb. 1982; reissued Mar. 1984). Report M33D Explanatory tests on the reduction of the sulphur content of sponge iron. (First issued Apr. 1982; reissued Mar. 1984). Report M43D Beneficiation tests on andalusite-bearing shales from a farm near Thabazimbi. (First issued Aug. 1982; reissuedMar. 1984). Report M129 The determination of tin, niobium, and tantalum in pegmatite by X-ray-fluorescence spectrometry. ReportM131 The determination of copper and nickel in iron- and chromium-bearing materials by a pressed-powder technique and X-ray-fluorescence spectrometry. Report M135 The installation of a 100 kV A plasma furnace at Mintek. The selection and installation of a 100 kV A a.c. plasma Report M136 The determination of gold in activated charcoal by use of a loose-powder technique and X-ray-fluorescence spectrometry. Report M140 The effect of physical and chemical factors on the corrosivity of a synthetic mine water.

Jan 1, 1984

By Victor C. Storhok, Batric Pesic, Marlyn D. Ballain

No1ihwest Alloys produces magnesium from dolomite by reduction with ferrosilicon and aluminum. This process produces alkaline by-products in quantities that allow their consideration for use as commercial products. Two such products are dicalci­um silicate, termed as Di-Cal, and magnesium oxide, termed simply MgO. The alkaline properties of these materials offer acid neutralizing power, comparable to traditionally used lime. Thus, the materials warrant study for their use in various appli­cations where neutralization of acidic waters or process solutions are required. One such application is the treatment of acid mine waters with the objective of removing heavy metals. The chem­ical stabilities of the produced metal precipitates are critically important, from an environmental point of view, for their safe disposal in tailing ponds. The EPA regulates waste material dis­posal according to the results from TCLP testing. In this ongoing study, three mine waters were selected for treatment with Di-Cal and MgO. Lime was used as the control for these experiments. The waters were collected from the Bunker Hill mine, Berkeley Pit, and the Blackbird Mine. In addi­tion to testing the chemical stability of produced metal precipi­tates by the TCLP procedure, two other parameters were studied as well. They are: 1. the effect of water pH on stability, and 2. the effect of pH on the stability of resulting precipitates. In the first three months of study, it was found that neutral­ization with Di-Cal results in precipitates that range from equiv­alent to superior in performance as compared to those produced using lime for the waters from all three mines. An additional beneficial characteristic of precipitation with Di-Cal is the fast filtering characteristics of produced precipitates, when compared to the precipitates produced by lime. This property may be of significance when considering the improvement in drainage of tailing ponds and the volume of solids produced. This paper will discuss in detail the stability of metal precipitates with respect to various pe1iinent metals found in mine waters of Berkeley Pit (Cu, Zn, Mn, etc.), Bunker Hill (Zn, Mn, Ni and Co), and Blackbird Mine (Cu, Co).

Jan 1, 1998

According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980

By F. E. Bachman

Although it has been apparent to me for a long time that too great weight was currently given to the silicon-contents of foundry-iron, and that the theory of the control by silicon of the carbon-contents of cast-iron is unsound, or that, at best, the influence of silicon is too small to be of much practical value as a guide in foundry-work, it never seemed to me desirable to enter the lists against either the " silicon-fad " or the theory, for the reason that I had neither the time nor the facilities to prove my position, nor any better theory to offer. But since Mr. Summers has taken the step, it seems but right that I should give such facts as are at hand in support of his contention. At the same time I do not think these are enough to prove the case if the contrary proposition were not itself, as it seems to me, based on insufficient evidence. Both Keep's and Turner's conclusions seem to be drawn from irons carrying less than the normal amount of carbon; Turner's " base " being, moreover, a steel rather than a pig-iron, and both the white base and the ferro-silicon of Keep being so low in carbon that compounds of them would not give a material approaching the carbon-contents of a normal casting, and having, therefore, little value as showing the effects of silicon on foundry-irons, even if his samples were treated under the same conditions as those to which pig-metal is subjected in making castings.

Jan 1, 1899

It is proposed to deal with those raw materials which are produced in South Australia to meet the needs of the country's steel industry. They are chiefly, iron ore, limestone and quartz.Iron ore and limestone are fed to the blast furnaces of Newcastle and Port Kembla together with coke to produce the hot metal charge for the open hearth steel furnaces.They are also qsed in the raw state in the steel furnaces to assist in the conversion of the hot metal to steel. The iron ore is quarried from' Iron Knob and shipped from Whyalla to Newcastle and Port Kembla, whilst the limestone is supplied from the deposits at Rapid Bay and shipped in the same manner.Quartz is used in the manufacture of ferro-silicon, an alloy which is added to the ladles of molten metal tapped from the open hearth furnace in the case of almost every grade of steel. It is obtained from a quarry situated between Iron Knob and Whyalla, and shipped to Newcastle.IRON OREWith the exception of several small quarries situated at Breadalbane, Cadia, Cowra, Crookwell, Michelago, Jerrawa and lerraama in New South Wales, the iron ore requirements of Australia's steel industry to date have been met from Iron Knob and the Middleback Range in South Australia.Several of the small deposits in New South Wales were worked during the war years of 1941-44 during the shipping emergency and produced 1,355,417 tons, compared with an output of approximately 43,000,000 tons from Iron Knob between 1901 and 1949.

Jan 1, 1951

By John W. Langley

The papers of Mr. W. J. Keep, read before this Institute, have called attention to the influence of aluminum in cast-iron and on iron and steel castings. The information in these papers is interesting and valuable, as showing the modifications which iron undergoes when dosed with sufficient aluminum to form a distinct alloy, the quantity of the alloying metal used being such that the amount remaining in the casting is sufficient to be readily discovered by analysis. The same is also true of the so-called aluminum-steel patented by R. A. Hadfield, where the proportions specified are such as to leave in the finished steel from one-twentieth to one-tenth of one per cent. of aluminum. Whether these alloys are of practical utility or not has thus far . not been proved by any extended tests on a large scale, and until such evidence is forthcoming it may be safely held, provisionally, that such a use of aluminum is of doubtful utility. But there is another function which this metal can perform that has been known for some time, and which has passed beyond the experimental stage, viz.: its beneficial effect in securing sound ingots. It appears to be a general property of all metals when in the fluid state and at a temperature considerably above their points of fusion, to contain gas, either dissolved from the air or frorn the furnace, or else self-evolved by internal reactions. Silver, perhaps, shows this power in the highest degree, and mercury and lead in the least; midway stands steel—the quantity of gas which it can hold in solution, or " occlusion " as it has been called, varies with its temperature, its composition, and its mode of manufacture. When the steel sets in the mould, a portion of this gas escapes, causing blow-holes, surface defects, boiling-over, wildness, and quite a long train of troubles, familiar to all practical steel-makers. Ferro-silicon has long been used as a quieting agent. The first extended use of it for this purpose was made at Terre-Noire, in

Jan 1, 1892

By C. H. Herty, J. L. Keats

In the literature on the elimination of metalloids in basic open-hearth practice, there are a great many heats recorded in which excellent data on changes in slag and metal composition during refining are given, but in almost all of these heats either temperature data or weights and analysis of charge are unrecorded and observations on the physical characteristics of the slag are almost always lacking. With these points in mind, a test heat was made in which as complete data as possible on all the factors that affect the elimination of metalloids were obtained. The Test Heat The test heat was made in a standard 100-ton stationary furnace at the Lackawanna Steel Co., Lackawanna, N. Y., on January 17, 1922. The Charge—Scrap.—The scrap consisted entirely of rail-heat butts, selected from a number of heats made the week before the test. The average analysis of the scrap was calculated from the analysis of these heats and from the weight of scrap from each heat. Pig Iron.—Two ladles of pig iron were used in the charge and two samples were taken from each ladle as it was poured into the furnace. These four samples were composited for the average pig-iron sample. Other Materials.—Weights of dolomite, ore and spar were obtained by weighing a quantity of each just before the test and weighing the amount of each left after the heat was completed. The limestone. was weighed on the charging pans. Coal for recarburizing, ferromanganese, ferro-silicon and aluminum were weighed out as used. All these materials were carefully sampled before the test was begun. Coal consumption at the producers was obtained by getting the average capacity of the hoppers that fed the producers, and then counting the number of hoppers of coal used during the course of the heat. Products Steel.—The steel made was rolled into billets, the rolling properties being very satisfactory. The weight of steel was obtained by taking a

Jan 1, 1926

By Wilbur Stout

IN Ohio, the annual output of coke made from native coals has averaged not more than 70,000 tons, or about enough to run a 200-ton blast furnace. Raw coal locally mined from the Sharon, or No. 1, bed was used for iron smelting in Mahoning furnace at Lowellville, Mahoning Co., as early as 1846. This practice was continued in the Youngstown district until the coal became scarce and the Connellsville coke more popular. At present, the Sharon bed contributes a part of the fuel for the production of ferrosilicon iron at Jackson, Jackson Co. About one-third native coal and two-thirds soft coal are used. In this state, coke, on a commercial basis, was first made in Jefferson County probably about 1861 or 1862. The coals used were the Steubenville Shaft, or Lower Freeport, and the Strip Vein or Middle Kittanning. The practice, however, was discontinued before 1880 because of the competition of superior foreign cokes. Beehive ovens, later built at Leetonia, Columbiana Co., were operated for only a few years; the coal used at this place is the Lower Kittanning or No. 5. In a desultory way, slack from the Pittsburgh coal has been coked at a few places in eastern Ohio, and attempts, either for experimental or for commercial purposes, have been made in other parts of the State. Small quantities of coke were made from the Upper. Freeport coal at Salineville, Columbiana Co., and near Nelsonville, Hocking Co.; the results were poor. Tests were made of the Middle Kittanning coal near Zanesville, Muskingum Co., at Moxahala Furnace, Perry Co., and at Washington Furnace, Lawrence Co.; the cokes were all high in sulfur and ash. Attempts were made to coke the Clarion coal at Vinton Furnace, Vinton Co.; a small battery of molding ovens and a pile of high-sulfur coke yet remain to tell the story. The Pittsburgh coal was coked on a commercial scale at Utley and at Lathrop, Athens Co.; but the operations were not successful and were soon abandoned.

Jan 9, 1919

By C. H. Johannes, N. B. Strydom, C. H. Van Graan, J. G. A. Van Heerden

Note: The practical application of microclimate cooling in an underground stope in a gold mine by C. H. JOHANNES, C. H. VAN GRAAN, N. B. STRYDOM and J. G. A. VAN HEERDEN INTRODUCTION Although much information was available on the use of pre-frozen jackets as micro climate coolers in underground situations!, 2, no information was available on their performance under practical conditions in stopes. The objectives of this study were. O.F .S. Branch Minutes of the General Meeting held in the upstairs lounge at the Harmony Country Club, Harmony G.M. Co. limited, on Wednesday 12th November, 1975 at 4.00 p.m. NIM reports Report no. 343 A mineralogical investigation of gold-bearing sulphidic ore from the Florence-Devonian Mine, Barberton.(20th May, 1968; re-issued Dec. 1975). Report no. 1384 . Flotation tests on samples of Canadian copper-zinc ores. (12th Nov., 1971; re-issued Nov. 1975). The results are given of laboratory Report no. 1488 Extraction of rutile from Highveld smelter slags. (28th Sep., 1972; re. issued Nov., 1975). Report no. 1499 The production of medium -carbon ferrochromi'um. (4th Dec., 1972; reissued Nov. 1975). Report no. 1521 The dissipation of electrical power in the burden of a submerged-arc furnace. (15th Feb., 1973; re-issued Nov. 1975). Report no. 1527 The physicochemical properties of slags associated with the smelting of nickel sulphide concentrates. (21st Feb., 1973; re-issued Nov. 1975). Report no. 1544 The recovery of salable ferrochromium from material discarded by Ferrometals Limited. (11th Jun., 1973; re-issued Nov. 1975). Report no. 1547 Physicochemical and thermodynamic properties of slags in the system MgO-AlOl.5SiO2. (23rd Aug., 1973; re-issued Nov. 1975). Report no. 1548 Physicochemical properties of slags in the system MgO-Al2O3-SiO2 and their application to the technology of ferro-alloy smelting. (13th Jul., 1973; re-issued Nov. 1975). Report no. 1553 Characterization of the flotation properties of fluorspar from smallscale batch and pilotplant tests. (27th Sep., 1973; re-issued Nov. 1975). Report no. 1555 The analysis, by atomic-absorption spectrophotometry, of matte-leach residues. (2nd Oct., 1973; re-issued Nov. 1975). Report no. 1590 The separation of osmium from ruthenium in hydrochloric acid solutions. (18th Jan., 1974; re-issued Oct. 1975.) Report no. 1606 The electrical-resistance characteristics of the charge in the electric reduction furnace. (1st Feb., 1974; re-issued Oct. 1975). Report no. 1622 The electrical conductivity of the charge in a ferrosilicon furnace. (2nd Apr., 1974; reissued Oct. 1975).

Jan 3, 1976

By E. N. Doyle

Since the mid-1930's a number of plants, using the principles of heavy media separation, have been installed throughout the world. In cases involving lead, zinc or lead-zinc ores the reasons for the choice of this type of beneficiation process have fallen into four major categories: A) The economic recovery of additional distinctly separate products, such as dolomite limestone at the Mascot Plant (1) of the American Zinc Co., and the ferrosilicon produced by St. Joseph Lead Company. (2) B) The elimination of a large portion of run-of-the-mine ore prior to grinding and flotation, to allow increased throughput with low capital cost. Examples of this approach are the Levante and Ponente plants of the Montevecchio Company in Italy (3) and the frequent choice of the Sink-Float process by the Penarroya Company of Paris. C) The processing of a sedimentary deposit, in which the valuable mineral is contained in the matrix separating the boulders, as was the case at the St. Joseph Lead Company plant at Haydon Creek (4) and also at Bunker Hill Mining and Smelting, Kellogg, Idaho. D) The simplification of Around support programs in mines by allowing greater freedom of action in the extractive pattern. An example of this choice is Cominco’s Sullivan plant which came into being as part of an extensive proposal to update the mining, crushing, transportation, grinding and beneficiation processes. (5)

Jan 1, 1970

By James Norman, O. C. Ralston, John Dasher

MOST mineral products are used in the finely divided state, but some are sold in larger sizes. Coal, gravel, metallurgical fluorspar, phosphate rock, hematite, chromite, and other products are sold in sizes coarser than can be treated by many mineral-dressing methods. Gravity separation of coarser sizes by log washing and jigging is probably as ancient as any process now in use. The performance of jigs on a feed with sufficient difference in density of the minerals is excellent, but many families of minerals are too similar in density to be separated effectively by this method. The use of heavy suspensions of fine solids to separate coarse coal from bone and slate has been in use for some years. This separation by sink-and-float was limited until recently to light minerals. Development of galena and ferrosilicon as suspension media, by Minerals Beneficiation, Inc., at Mascot, Tenn., Pitcher, Okla., and Crosby, Minn., under patents granted during and since 1938, has permitted excellent results to be obtained on minerals of very similar densities up to 3.3. This process has been put in the hands of American Cyanamid Co. for exploitation, and further research now in progress may increase the density of suspension obtainable so that separation, at a density of 4,0 may be practicable before this is published. The Huntington-Heberlein dense-medium process, developed in England, is also being commercialized in the United States by Sink and Float Corporation. Du Pont has developed a sink-and-float separation using halogenated hydrocarbons as parting liquids; at this writing, the method is used commercially only on coal but has been successful in the pilot plant on many other minerals using tetrabromethane at densities up to 2.95. While these processes were being developed to extend the range of separation by difference in density to the coarser sizes, the Bureau of Mines was engaged in developing a process that will extend the range of separation by difference in wettability up to 2-in, size. War work has pushed aside its further development indefinitely. The results are published here with the hope that some use may be suggested that will justify post-war development, and so that readers that may be able to make immediate use of the scheme may have the information. EARLIER WORK It has been known since the time of Herodotus (B.C. 484(?)-425) that water-repellent particles will adhere to sticky surfaces. That early historian reports the

Jan 1, 1942