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By D. W. Lawler

Prior to the manufacture of sulphuric acid in metallurgical plants, the SO2 rich gas from the smelter, roaster, or furnace must be cleaned to removed particulates, volatile contaminants, SO3, and water. Cleaning is accomplished by contacting the. gas with cooled weak acid. The system is designed so that all the contaminants, originally in the gas are captured in the weak acid, which then becomes an effluent from the plant. Historically, the entire weak acid effluent stream has been treated for disposal, with no attempt to recycle or recover any part if it. This is becoming increasingly environmentally unacceptable, and operators must consider better methods of treatment and recovery. In this paper, Kvaerner Chemetics discuss a number of options that allow the contaminants to 'be separated from the acid' value. This will result in an acid byproduct that can be sold or used elsewhere, and will minimize the volume of hazardous byproducts that must be discharged.

Jan 1, 1998

By S. Viswanathan, A. S. Sabau

"Dimensional changes between a pattern die and its corresponding investment casting part occur as a result of complex phenomena such as thermal expansion/contraction and hot deformation (elastic, plastic, and creep) during the processing of the pattern material (wax), mold material (shell) and solidifying alloy. Determining the pattern tooling dimensions is crucial to the dimensional control of the investment casting process. To date, computational methodologies have not been applied to the prediction of dimensional changes in investment castings.This paper deals with the evaluation of wax pattern dimensions, which is one important factor in determining pattern tooling dimensions in investment casting. Cerita 29-51, an industrial wax, is considered in this study. The wax pattern dimensions are determined by considering its thermo physical and thermomechanical properties, restraint of geometrical features by the metal die, and process parameters such as dwell time, platen temperature, injection pressure, and injection temperature.IntroductionThe investment casting process involves making a disposable wax pattern by injecting wax into a metal mold, building a ceramic shell mold around the wax pattern by the application of a series of ceramic coatings to the wax pattern, dewaxing the ceramic shell mold, and casting the alloy into the shell mold. Dimensional changes between the pattern tooling and its corresponding cast part occur as a result of thermal expansion, shrinkage, hot deformation, and creep of the pattern .material (wax), mold material (shell), and solidifying alloy during the processing [1]."

Jan 1, 2001

By K. Krishnapisharody

The phenomenon of slag droplet formation under the action of gas-stirring in steel ladles has been analyzed with experiments conducted in a thin-slice room-temperature model using water and mineral oils as the working fluids. Visual and video investigations have been performed on the interface behaviour along with measurements of liquid velocities in both phases, using the Particle Image Velocimetry (PIV) technique. The measured velocity data and observations on the interface break-up establish that the droplet formation results primarily from an instability mechanism at the interface.

Jan 1, 2008

By R. W. Charles

The Los Alamos National Laboratory, under the sponsorship of the U.S. Department of Energy; is involved with laboratory and field experiments to assist in development of the Hot Dry Rock concept of geothermal energy. The field program consists of experiments in which hot rock of low permeability is hydraulically fractured between two wellbores. Water is circulated from one well to the other through the fractured hot rock. Our field experiments are designed to test reservoir engineering parameters such as heat-extraction rates, water-loss rates, flow characteristics including impedance and buoyancy, seismic activity, and fluid chemistry. Laboratory experiments were designed to provide information on the mineral-water reactivity encountered during the field program. Two experimental circulation systems tested the rates of dissolution and alteration during dynamic flow. SOlubil ity of rock in agitated systems was studied. Moreover, pure minerals, samples of the granodiorite from the actual reservoir, and Tijeras Canyon granite have been reacted with distilled water and various solutions of NaCl, NaOH, and Na.CO.. The results of these experimental systems are compared to the observations made in field experiments done within the hot dry rock reservoir at a depth of approxi-mately 3 km where the initial rock temperature was 150 to 200°C.

Jan 1, 1981

By Benoit DeBecker

Laboratory-scale experiments have shown that chromium metal could be recovered from chromate wastes by modifying slightly the chromium electrowinning flow-sheet. After reduction by sulhr dioxide and precipitation of chromic hydroxide, the solid residue is dissolved in the chrome alum solution and the metallic impurities are removed by cementation on manganese. The presence of dissolved manganese in the electrolyte does not affect the cathodic deposition of chromium and it eliminates the anodic production of Cr(V1).

Jan 1, 1994

By S. R. Reddy, R. G. Reddy

"The Margules equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.1 IntroductionIn most of the pyrometallurgical high temperatures processes, interactions of solutes such as oxygen, nitrogen and sulfur, with the solvent atoms are most important during refining processes. There are numerous theories are developed [1-25] to interpret the thermodynamics of solutes in multicomponent alloy systems. Which are mainly developed using statistical or Quasichemical equations.Wagner [4] developed one energy parameter ideal solvent model based on activity coefficient of solutes compositional dependency. He used one energy interaction term which is not able to account for interaction energy parameters for the same solute concentration at different solvent compositions and also it is ineffective model to predict for strong interacting systems."

Jan 1, 1996

By J. E. Dutrizac

A mineralogical study of a weak acid leach residue from the Clarksville zinc plant of Savage Zinc Inc. was carried out. The study focused on Pb and Cd as these elements most significantly impact on the environmentally acceptable disposal of the residue. The residue consists of major amounts of bassanite, zinc ferrite and various Zn-Pb-Fe-Cd silicate species. Also present are lesser quantities of PbSO4, sphalerite, Fe2O3 quartz, Mn-Pb-Fe oxides, SrS04, (Pb,Sr)SO4 iron gel-silica gel, jarosite and Ti oxide. The principal Cd carriers are the zinc ferrite, which contains up to 9.00% Cd and likely accounts for -45% of the total Cd content of the residue, and the various silicate species which contain up to 6.97% Cd and account for about 45 % of the total Cd. The sphalerite is a minor Cd carrier containing an average of 0.35 % Cd and accounting for -5 % of the total Cd; the other carriers contribute only trace amounts to the total Cd content. The major Pb carriers are PbS04, Pb-bearing silicates and Mn-Pb-Fe oxides. Minor proportions of the total 1.09% Pb content of the residue are carried by SrS04 and (pb,Sr)S04' Trace Ph carriers include the iron gel-silica gel, Fe-Zn-AI oxide and bassanite. The residue after the toxicity characteristic leaching procedure (TCLP) is mineralogically very similar to the initial weak acid leach residue; the amounts of calcium sulphate are approximately the same in the two products. The principal Cd and Pb carriers are also the same as those noted in the initial residue, except that some dissolution and reprecipitation of Pb-Sr sulphate takes place. That the residue fails the TCLP test is likely a consequence of the superficial dissolution of Pb and Cd from species such as PbS04 or Zn-Pb-Fe-Cd silicate.

Jan 1, 1995

By John W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct ironmaking pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicates that 69% are less than 2.5 um across, 21 % are 2.5-5 um, and 10% are larger than 5 um. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By Ximeng Zhu

The electrochemical behavior of mineral and coal pyrites in stirred and quiescent alkaline boratelsulfate solutions @H 7.9-10.5) have been investigated using cyclic voltammetry. Significant differences in the electrochemical response of these pyrites were observed. At the mineral pyrite surface, three anodic peaks at about -0.8 V, -0.1 V and +0.5 V (SCE) have been detected along with their corresponding reduction peaks. The first two peaks correspond to FeIFeOI) and FeOI)lFe(III) oxidation. The third peak is present for quiescent conditions but disappears as a distinct peak when the electrolyte is stirred. In the upper voltage region +0.30V (SCE), the current increases markedly during stirring and the reactions correspond to the oxidation of pyrite with the formation FeOII) oxides plus elemental sulfur. Also there is evidence that Fe oxy-ions form. Coal pyrites, under rapid sweep conditions display only the first two anodic peaks, the associated reduction peaks and an additional reduction peak corresponding to one or more of the high voltage oxidation products. After prolonged exposure to high potentials, coal pyrite displays reactions similar to those of mineral pyrite but at much higher current densities demonstrating the much higher reactivity of the coal pyrite. The reactivity sequence was Upper Freeport coal pyrite > Pittsburgh coal pyrite > mineral pyrite.

Jan 1, 1991

By Gordon D. Jarvinen

Polymer Filtration (PF) Is an innovative, selecthle metal removal technology. Chelating, water-soluble polymers are used to selectively bind the desired metal ions and ultrafiltration is used to concentrate the polymer-metal complex producing a permeate with low levels of the targeted metal ion. When applied to the treatment of, Industrial metal-bearing aqueous process streams, the permeate water can often be reused within the process and the metal ions reclaimed. This technology is applicable to many types of industrial aqueous streams with widely varying chemistries. Application of PF to 'aqueous streams from nuclear materials processing and electroplating operations will be described.

Jan 1, 1999

By Lijun Lu, Honghui Fang

This article carried out the experimental study on using desulfurization ash in steel slag composite material. This was done by investigating the desulfurization ash content in formula one and formula two samples on the influence of setting time and strength of mortar. Through this study the following conclusions were reached for formula one: (1) a setting time of more than 10 hours is required, (2) a dosage of desulfurization ash of 1 ~ 2% is optimal, where flexural strength is reduced by 10% ~ 23% and compressive strength reduced by 5.7% ~ 16.4%. The conclusions of formula two were: (1) when the dosage of desulfurization ash is within 5%, the setting time is within 10 hours; (2) when the dosage of desulfurization ash is 1 ~ 2%, the flexural strength is increased by 5 ~ 7% and the compressive strength is reduced by 1 ~ 2%. The results show that the formula two is better.

Jan 1, 2015

By Daniel S. Gwinner

The tolling, or processing for a fixed fee, of aluminum drosses to recover the metal units is a common practice in the Aluminum Industry. The Dross Toller is acting for the owner, and since most dross processes result in material going to landfill, it is important for the owner of the dross to insure that the toiler is processing the material and handling waste disposal in an environmentally responsible manner. The paper discusses the Dross Toiler Audit Program, first from the Reynolds Metals Company perspective. Included are the reasons the company deems it necessary to audit and a description of the items covered during the audit. Finally, there will be a discussion of the audit from the Tollers perspective - what the Toiler can expect when the auditor arrives.

Jan 1, 1995

By Shengqin Zhang, Yousef Mohassab, Feng Chen, Hong Yong Sohn, Mohamed Elzohiery, Amr Abdelghany

The kinetics of hematite concentrate reduction by mixtures of hydrogen and CO of various compositions has been investigated as part of the development of a flash ironmaking process at the University of Utah. This process produces iron directly from iron oxides concentrates by the gas-solid flash reaction based on the partial oxidation of natural gas, resulting in a significant reduction in energy consumption and greenhouse gas emission. The reduction kinetics of hematite concentrate of an average particle size 21.3 μm by the above mentioned gases in the temperature range 1423 to 1623 K (1150 to 1350 ºC) was investigated. Hematite concentrate particles can be reduced to > 90% by any of these reductants in several seconds of residence time typically available in a flash reactor. The activation energy ranged from 214 kJ/mol for hydrogen to 231 kJ/mol for CO.

Jan 1, 2016

By D. H. Rubisov

The neural networks modelling approach is one of the most elegant black-box type methods to model industrial processes. In this paper, this approach is applied to model the performance of the CEZ zinc electrowinning plant. The model that was built was found to exhibit an excellent predictive ability for voltage and current density. The model was also used to investigate the sensitivity of the process to various key variables such as temperature, current density, zinc and sulphuric acid concentration, etc. Optimal regimes for zinc production were identified from the power consumption standpoint.

Jan 1, 1996

By V. B. Telles, J. A. S. Tenorio, J. O. Alves, D. C. R. Espinosa

"The world production of crude steel in 2009 reached 1.2 billion tons. For each ton of steel produced, 150 kg of steelmaking slag and 20 kg of steelmaking dust are generated. These are wastes with considerable production and limited applications, therefore this work studied the recovery of these wastes into useful sub-products. The slag was used as raw material in the production of rock wool (a thermo-acoustic insulator) and the dust was inserted in the iron ore sintering process. Results showed that produced materials have exceptional proprieties, therefore the recovery of these wastes can contribute to decrease extraction of non-renewable resources, reduce the costs and impact of disposals, and aggregate value to the slag and dust.1. IntroductionSteel production using Eletric Arc Furnace (EAF) has grown over 119 million tones in the last years. In 2008 30.7% of all steel produced, was obtained through EAF. In United States of America (USA) the percentage of this process in the production of steel was about 58% in 2008, while in 2000 this percentage was only 47% [1]."

Jan 1, 2011

By Sen-xiang Yang, Xin-teng Liang, Gui-jun Li, Jian-hua Zeng, Yong Chen

"This research is based on PANSTEEL 120t steelmaking converter technology to have the quantitative description of the time needed in uniform mixing of molten steel in the converter with the computer. In present work, the numerical simulation approach is used to analyze oxygen lance nozzle, the flow condition of oxygen and flow status of molten steel in the converter. The various oxygen jet flows that come out from different angles and the flow status of all kinds of jet flows in the converter have also been simulated. All of the simulation parameters are based on the specifically practical conditions according to the physical conditions of PANSTEEL 120 t steelmaking converter. Through numerical simulation, the angle parameter of the oxygen lance nozzle is 16 °. The optimized oxygen lance 536-16 has a good performance in industrial application. This kind of phenomenon shows that the ways and processes of numerical simulation in this research are right.IntroductionThe oxygen lance system is the significant process in semi-steel making converter. It's related to whether the converter or even the whole system can function well. While in actual production, many problems emerge in the process of using the former oxygen lance, such as re-drying, slopping, high lance position, dead burning and even blowing out. In continuous fast-paced process, the unstableness of oxygen lance will lead to speed droop or even stop pouring. Analysis shows that all these problems are not only related to the raw materials but also the design of oxygen lance. Bad oxygen lance's scorification kinetics condition and low content of FeOn in early slag are the direct factors that we cannot easily control in steelmaking at present [l]. Therefore, the good scorification kinetics condition which is related to nozzle has good influence on BOF steel making."

Jan 1, 2013

By Shengfan Zhou, XUEWEN WANG, Changjun Jiang, Mingyu Wang

In the process of extracting vanadium from stone coal by sulfuric acid leaching - P204 solvent extraction, Fe(III) can accumulate in the organic phase which reduces the extraction of vanadium. In order to eliminate the effects of the accumulation of iron, oxalic acid was used as the stripping agent to strip the Fe(III). The effects of oxalic acid concentration, phase ratio O/A, stripping time and shake velocity on the stripping of Fe(III) were studied. The results showed that the Fe(III) stripping rate can reach beyond 96% at the room temperature with 70g/L oxalic acid using an O/A of 2 at 160 rpm shake velocity for 20min. After 2-stage stripping, the concentration of Fe(III) in organic phase was 0.008g/L.

Jan 1, 2016

By J. E. Dutrizac

Fracture-exposed surfaces of sphalerite samples having five different solid solution iron contents ranging from 0.0 wt% to 14.8 wt% Fe were leached for 15 to 120 s at 100°C in 0.3 M Fe(S04)1.5 -0.3 M H2S04 media. The reacted samples were examined using X-ray photoelectron spectroscopy (XPS) which provides chemical state information on the first few nanometers of the solid surface. Surface compositions show that the leaching rate increases with increasing solid solution iron content of the sphalerite. Detailed evaluation of high resolution S2p spectra show that the leaching progresses via the formation of polysulphide species. Disulphide species were not detected in any of the experiments. Examination of the Zn2p and Fe2p spectra indicate little change in the chemical states of these elements over the duration of the experiments. Longer leaching times resulted in the generation of elemental sulphur. The ratios of elemental sulphur to dissolved ferrous ions and zinc suggest that less than 5% of the sulphide is oxidized to sulphate. Morphological studies showed that the elemental sulphur commonly formed at a few isolated sites, such as the grain boundaries. Furthermore, euhedral sulphur crystals were often identified. These observations suggest that at least part of the elemental sulphur forms via dissolved sulphide species which are oxidized in solution by ferric sulphate.

Jan 1, 2003

By Wei Gao, Qing-cai Liu, Cun-fang Lu, Huimin Zheng, Jian Yang, Chun-ling Yao

"Mercury in flue gas of coal-fired plants was concerned as another serious pollution when sulfur dioxide pollution was controlled now. The adsorbent made from fly ash by thermal precipitation sulfur to remove mercury in fuel gas from coal combustion plant, SEM, BET, TGA and other measurement methods were used to characterize the effect on surface morphology, sulfur distribution and specific surface. High temperature deposition furnace was applied to increase sulfur content in fly ash based adsorbents produced in lab. The study found that sulfur attached to the adsorbent surface, mesopore and microporous structure, increasing its sulfur content of adsorbent. Sulfur was filled in interspace as small molecule S2, S5, increased their surface area and enhanced their adsorption capacity. The specific surface area increased by thermal precipitation sulfur, and specific surface area which increased with increasing temperature.1. IntroductionThe mercury emission caused by human activity has accounted for 10%-30% of total mercury emission all over the world[11, and the emission from coal-fired power plant have a huge proportion of these emission caused by human activity. Active carbon microstructure and surface morphology play an important role in its adsorption capability, which offers the potential for controlling environmental pollutant, such as sewage, fuel gas, atmosphere and et al [2,31, because it is a material with high specific surface area that long been considered as an excellent adsorbent. At present, include activated carbon, fly ash, calcium-based sorbents and other novel adsorbents. The adsorption capacity and production cost were very important in the process of mercury removal by adsorbents, so the mercury removal has focus on developing adsorbents of highly-efficient. In particular, the waste of metallurgical from coal combustion and the others have a significant advantage about the cost, and they have the highly-efficient in mercury removal after modified to enhance their adsorption capacity, such as fly ash of coal-fired. Apart from specific surface area, element content, pore structure, and surface morphology of activated carbon have great effect on its adsorption ability. Compared to adsorbents without modification, active carbon impregnated with other elements, such as chlorine, sulfur, bromine and et al. had more excellent characteristics to remove specific pollutants."

Jan 1, 2011

By William Petruk

The mineralogy of the primary and oxidized ores from the Malanjkhand porphyry copper deposit in India was studied to determine ore characteristics that affect metallurgy, and to assess applicable processes for recovering the copper. Three mineral assemblages were found. One occurs in primary ore, another in moderately oxidized ore, and a thir:d in intensely oxidized ore. Chalcopyrite, the main mineral in the primary ore, is relatively coarse-grained, with grain size increasing as the ore grade increases. High chalcopyrite liberations should be achieved at a relatively coarse grind, and good chalcopyrite recoveries should be obtained. The chalcopyrite, however, tarnishes readily and oXidizes to chalcocite in a relatively short time (several months). The presence of both the tarnished chalcopyrite and chalcocite may affect chalcopyrite flotation and reduce copper recoveries, The moderately oxidized ore occurs in an oxidized cap immediately above the primary ore, and stockpiled primary ore alters quickly to a moderately oxidized ore. Chalcocite is a major copper-bearing mineral in moderately OXidized ore. The concentrator processing this ore should be capable of handling a chalcocite-rich ore. The intensely OXidized ore contains a wide variety of acid-soluble copper-bearing minerals. Leaching may be required to recover the copper from them.

Jan 1, 1987