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By H. Soto, J. Jara, F. Nava

"A combination of oxidation and precipitation was used to eliminate cyanide from gold milling effluents. Preliminary laboratory work developed with both synthetic cyanide solutions and with industrial effluents indicated that ozone can easily destroy free cyanide and weakly complexed cyanide (i.e. copper and zinc cyanide). In this case the reaction is quite fast and seems to be controlled by the mass transfer of ozone to the solution. Experimental results indicate that free cyanide and weak-acid dissociable cyanide in mill effluents can be reduced to less than 1 ppm. However, the iron-cyanide complexes proved to be quite resilient to destruction with ozone and they remained in the solution even after most of the free and weakly complexed cyanide was destroyed with ozone. These results were confirmed in a pilot trial developed at the Sphinx plant in northern Quebec.To deal with the problem presented by the presence of the iron complexes two different approaches were studied: use of a combination ozone-ultraviolet light oxidation, and the precipitation of iron-ferrocyanide complexes in the residual solution after ozonation. This last method proved quite promising since reduced the total cyanide levels of industrial solutions assaying as much as 250 ppm to less than 1 ppm of total cyanide. Control of the · pH of the solution was the key to obtain the precipitation of the iron complexes. The use of iron to precipitate cyanide complexes has the advantage of being less expensive and less toxic than copper (used by the Inco process)."

Jan 1, 1992

By R. Webber, D. Averill, L. Whittle, D. Moffeti, G. Kassakhian

"This paper describes the recent pilot-plant work carried out on two alternative processes capable of producing an effluent containing less than 10 pCi/L total radium-226 activity and very close to 3 pCi/L dissolved radium-226. The processes incorporate coprecipitation of radium with barium sulphate by the addition of barium chloride in continuously stirred tank reactors followed by either chemical coagulation with ferric chloride, flocculation and clarification, or polymer-aided dual-media filtration. IntroductionUranium mines in Canada have practiced radium removal from tailings basin effluents since 1965. Treatment consists of addition of barium chloride to precipitate radium as barium- radium sulphate and provision of natural or constructed settling ponds for sedimentation. This process, however, has been identified as being deficient in that it allows particulate or suspended radium-226 releases which are higher than the regulated dissolved values». Also, the large size of some of the settling ponds is believed to represent a real limitation of the present technology because of inferred difficulty in recovery of barium-radium sulphate precipitates.The Federal Government Mining Task Force established a Radioactivity Sub-Group in 1974 to assist in the development of effluent regulations and guidelines for the uranium mining industry. Among the recommendations of the Sub-Group was the need to seek more effective methods of radium removal, including development of physical/chemical treatment systems as an alternative to settling ponds. In response to the SubGroup recommendations, a bench-scale study began in March 1976at the Wastewater Technology Centre (WTC) of Environment Canada . The results of this study indicated that coagulation and flocculation of the precipitate from barium chloride addition is a viable alternative to sedimentation in settling ponds(3). The bench work was expanded and accelerated in 1977, with financial assistance provided by the Atomic Energy Control Board. Subsequently, a research program with a larger scope was developed; this program is jointly managed and funded by government and industry, as shown in Table I.One of the goals of the joint program is to develop, at pilot scale, a physicalI chemical process to reduce the radium-226 content of uranium mining and milling effluents. Target radium-226 activities for treated tailings basin effluents were set: namely, 10 pCil L total and 3 pCil L dissolved radium 226. Extensive bench-scale and pilot-scale work was conducted through 1978 and 1979 and has culminated in the development of two physical/chemical processes. This paper describes work carried out at a pilot plant which led to the selection of the two physical I chemical processes for demonstration. In short-term tests, the processes produced effluents meeting the radium-226 target activities."

Jan 1, 1980

By J. P. Jarrell

Environmental considerations are of increasing importance in determining the acceptability, schedule and cost of expansion ofCanada's uranium processing industry. Environmental considerations must be addressed in the early stages of facility planning. This results in a dilemma, as the process data needed to predict physical environmental impacts are not yet available from process design activities. Hence, a business risk is incurred if plant design is carried forward to meet these requirements prior to project (or site) approval. On the other hand, project scheduling normally mitigates against leaving process design engineering until such time as project approval is obtained. This paper examines the experience gained in Eldorado Nuclear's proposed expansion of refining capacity as viewed by an environmental engineering consultant. The history of the project and the relationship to process design functions in the two-year period prior to the Port Granby environmental hearings are reviewed. During the Port Granby public hearing, there was a consensus that normal operation of the proposed refinery could be successfully integrated with the site's natural environmental constraints. Moreover, the radiological impact from plant operations was demonstrated to be inconsequential. However, concerns were raised relating to plant upset and accident situations. These concerns are summarized. Process data requirements identified during the environmental hearings are discussed. Finally, the concerns for on-site burial of radioactive waste are reviewed. These concerns focussed on long-term stability of the waste in the presence ofgroundwater transport, erosion and glaciers. The AECB's position on waste management with regard to this project is reviewed in light ofthe implications for design.

Jan 1, 1979

By J. G. Price

"The paper reviews state-of-the art welding processes and consumables for structural and pressure equipment applications in offshore environments, particularly the Arctic. Optimum selection of consumables will be discussed with regard to the facility to meet tentative toughness requirements in weldments. Finally, the development of welding procedure specifications will be considered in relation to the prevention of hot or cold cracking and lamellar tearing.Welding RequirementsGeneralThe exploitation of Canadian frontier oil and gas reserves will require a fleet of various types of offshore structures. These will include fixed jacket types and semi-submersibles for the East Coast with huge man-made islands and icebreakers for the Arctic regions. Both these regions will also require supply and drill ships plus subsea pipelines and cargo tankers for transportation. Clearly the welding of these items will plays large part in the over-all integrity and safety of exploration and production operations.The required development in structural steels and pressure vessel steels, for current and future offshore structures, to improve properties, particularly toughness for lower temperature service, has also prompted welding researchers to develop process and consumable combinations to match the parent plate specifications. This development has had to consider particular aspects of weldability such as a low susceptibility to cold cracking and preventing low HAZ toughness. Current research has centred on attempts to increase HAZ toughness with higher heat input welding of newly developed structural steels.The installation of Arctic region pipelines has provided a sound base for future, more complex fabrications in the most severe service temperatures in the Canadian frontier although few of the installations have been designed to the lowest possible exposed temperature of -62°C."

Jan 1, 1987

By Gordon E. Agar, Brian Lyons, Gregory H. Styles, William B. Kipkie

"Rock rejection during the flotation of a copper-nickel ore was improved by adding carboxymethyl cellulose to both a rougher and cleaner flotation stage. The selection of the rock depressant was based on laboratory rates studies. Plant operating results are presented which confirm the laboratory selection of two particular brands of carboxymethyl cellulose.The rock assay of the concentrate was reduced from more than 40% to less than 15%.IntroductionThe traditional method of selecting flotation reagents relied upon batch bench scale tests, conducted under arbitrary conditions, to identify the effect of the reagent under examination. Too often these were ""one-off"" tests with little or no regard paid to the reproducibility of the results. Sophisticated researchers used statistical methods to design and evaluate the experiments but they were still obliged to rely on the arbitrary and often unreliable batch tests to generate the numbers that were analyzed statistically. An interesting side-effect of the enhanced sophistication of the statistical analysis was often that no significant effects would be uncovered in a series of experiments that would have generated many positive conclusions and much further experimentation if the same results had been evaluated by the traditional method.In the recent past, at least two groups of researchers a have directed their attention to the reliability of the batch experiments with a view toward improving the reproducibility of the test data. In this work the best of the improvements advocated by both of these groups have been adopted in order to generate kinetic data from batch tests that are as reproducible as possible.The objective of the work was to reduce the rock content of a bulk sulphide concentrate produced at Inco's Shebandowan mill. During 1982 the Shebandowan concentrate analyzed 3.5% Cu, 7.4010 Ni, 25% pyrrhotite and more than 40% rock, which resulted in an MgO content of 10.4%. Besides the expense of shipping all of this rock to Sudbury, the rock also contributed to the poor filterability of the concentrate. On favourable occasions the moisture content of the filter cake was slightly over 20% by weight. The magnesia content of the concentrate was deleterious to the reverberatory furnaces used by Inco for smelting nickel concentrate because the slag viscosity increased as the magnesia content increased, and the nickel lost in the slag went up."

Jan 1, 1987

By Claude Bazin

"Laboratory semi-batch flotation tests were conducted using two different sulphide ore samples. The size reduction was adjusted to cover a wide range of flotation feed size distributions. Results show that similar recoveries can be achieved independently of the fineness of grind. This result suggests that possible energy savings could be achieved by a redistribution of the power between the grinding and regrinding mills. The behaviour of the selectivity curves shows that some gangue minerals are more sensitive to particle size than other ones, implying the existence of preferential associations between minerals in the ore.INTRODUCTIONInteractions between grinding and flotation have been studied for many years, and still a robust model to link the two processes lacks to be developed (Girard et al., 2005; Bazin et al., 2001). The ore size reduction liberates mineral grains, while flotation separates them into valuable minerals and gangue. The more size reduction that is applied to the ore the more important is the mineral liberation but also the production of fine particles that can pose problems during flotation (Trahar and Warren, 1976). The definition of the grinding requirement for flotation is a complex problem (Rickelton and Dell, 1977; Sosa Blanca et al., 2000; Morrison, 1993; Wei and Gay, 1999).This paper analyzes the effect of the fineness of grind using semi-batch flotation test results. The first two sections describe the test procedure and the results. The third section analyzes the results in terms of liberation and selectivity, and proposes a possible redistribution of power between grinding and regrinding mills."

Jan 1, 2006

By C. J. Martin, M. P. Hay

"A methodology was developed in the mid-1980’s to predict plant performance from standard laboratory flotation tests. The technique is based on a simple, empirical kinetics model, and is tailored for use by the practical metallurgist.To date the performance of more than 20 flotation plants has been predicted, including copper, lead, zinc, phosphate, pyrite, graphite, cassiterite, platinum, nickel and various slags. The method has successfully been used to predict and size four flotation plants directly from bench-scale laboratory flotation testwork. All have since been commissioned, and have performed as predicted.The technique has now received broad acceptance within the South African mining industry, for example in the last year alone it has been used to drive flowsheet development for at least seven new plants. It is also being used to assist in the optimisation of existing operating plants.The methodology is described in this paper and verification of the methodology is presented using case studies of porphyry, polymetallic and PGM operations.INTRODUCTIONThere is considerable interest these days in the use of modelling to simulate flotation circuits, for process design and plant optimisation purposes. Although these models are proving to be useful tools for plant design and optimisation, their complexity can make them cumbersome – expensive to use and difficult for metallurgists to visualise and mentally absorb, without a background in each specific technique. In “SUPASIM” no attempt is made to measure flotation fundamentals, rather to use empirical relationships between laboratory flotation kinetics and plant performance – relationships that hold up well to validation exercises as will be demonstrated later in this paper. Although not designed to be as comprehensive as other models, “SUPASIM” is easily understood by the operating metallurgist and can be quickly and easily applied."

Jan 1, 2004

By J. B. Scott

"A computerized cost estimating program developed with the use of the Lotus 1-2-3 spreadsheet program has produced dramatic savings in preparing estimates for operating costs, equipment fleet size and manpower requirements for underground mines.The program is used by Dynatec to support its consulting engineering projects, particularly feasibility studies. The 'first principles' approach is used to prepare detailed estimates under direct labour and supplies categories and maintenance costs for each mining operation . User notes have been developed to guide the estimator and ensure appropriate consideration is given to the specifics of the particular mine.A typical case history is illustrated and the ease by which alternatives and sensitivity analyses can be prepared is demonstrated. IntroductionHistorical MethodsMining engineers have used one or a combination of methods to prepare operating cost estimates for new or existing mine s. Operating companies have access to historical cost data and generally use this for preparing estimates. Consulting engineers do not usually have direct access to such information and must rely on mining companies (the present or previous clients); publications (text books, equipment manufacturers manuals, CMJ reference manual, etc.); annual reports (applicable to public companies); previous studies (to be used with caution as conditions change from mine to mine); and first principles (the subject of this paper), for cost information:Definition of First PrinciplesA first principles approach to cost estimating considers individual primary work elements of an operation. Quantities of work items are developed from the mine plans, production rates, geographic and physical layouts etc. The knowledgeable estimator, assisted by experienced operations personnel, can assign appropriate resources (equipment, labour, supplies and services) to each work element and establish productivities. Completion of the cost estimate is then largely arithmetic."

Jan 1, 1988

"The characterisation of resources and description of variability across different ore domains is key to accurate prediction of probable metallurgical performance. Such characterisation testwork often has limited drill-core from which to work and this immediately confines the characterisation method to smallscale. For flotation feeds, the JKMSI (Mineral Separability Indicator) is being developed as a potential characterisation tool, building on earlier work by Chudacek, (1990), which used shaken test tubes, and was called the EMDEE device. In addition, the consistency of flotation recovery for specified size fractions has shown to be preserved, irrespective of the amount of material in that size fraction obtained by different milling conditions, so that the overall recovery can be estimated from knowing the particle size distribution (McIvor and Finch, 1991; Bazin et al, 1994, Runge, 2007 and Wightman et al, 2010) The JKMSI unit uses less than 10 g of material per test in narrowly sized classes and results to date have demonstrated the value of the test. This paper discusses the potential of the test by demonstrating the link between JKMSI performance and mineralogy of five different ores from Laguna Seca, Escondida Minera Limitada as well as the correlation to plant scale performance obtained in an earlier survey (Coleman et al, 2006). Further work to tie down the proof of representatively of the small sample has been identified and is discussed and included in the paper. INTRODUCTIONSince the uptake of the flotation process at the turn of the twentieth century, small scale, laboratory methods have been sought to characterise flotation response. Although laboratory batch flotation tests are the most widely used method to evaluate reagents, characterise ore variability and obtain suitable model parameters using various scale up factors Runge (2101) other methods using less ore would be useful where ore samples were limited.A method using test tubes for testing ores’s flotation response to reagents was first developed by Ian Walk (Wark & Wark, 1935; Wark; 1938; Sutherland and Wark 1955). In these tests a 50 cc stoppered measuring cylinder served as a means for a qualitative experiment, the aeration being effected through violent shaking by hand. In these experiments about 10 g of mineral was ground by pestle and mortar under water after which the ground material was deslimed and adequately conditioned with the appropriate reagents."

Jan 1, 2013

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By Neil R. Burns, Michael Doggett

Abstract - The Nanisivik mine offers a unique opportunity to examine the economics of a mining scenario from its original feasibility study through to closure. In the early 1970s, the Strathcona Sound project (exploration around the Nanisivik mine) had advanced to the point where a significant mineralized body had been defined and a feasibility study was initiated. The study supported development of the Nanisivik mine, with government investment in regional infrastructure, and the mine was constructed and operated for 26 years. Many elements of the feasibility study were difficult to estimate because the project was unique in its high Arctic setting. As a result, many differences were found when comparing the actual mining data to the feasibility study. The majority of these differences were the result of an actual mine life of 26 years instead of the planned 12.5 years. Most of the mining costs were higher than estimated and production occurred at a much higher extraction rate than planned. On a constant dollar basis, the metal prices were, on average, below the feasibility estimates. For the most part, these differences balanced out, with the actual mining being only slightly more profitable than anticipated in the feasibility study.

Jan 1, 2004

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By Robert Cluff

The Campo Morado precious-metal-bearing, volcanogenic massive sulphide district occurs in a Lower Cretaceous felsic volcanic sequence in a northerly trending belt in the Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. The deposits belong to a low-sulfidation, volcanogenic massive sulphide system formed in a subaqueous environment, and are of the siliciclastic type. Most are on the flanks of felsic domes or in adjacent basins and many are associated with heterolithic volcaniclastic rocks. The Reforma and possibly the El Rey massive sulphide deposits are interpreted to be overturned, and the Naranjo, El Largo, and Estrella de Oro deposits and the El Profundo occurrence to the south are upright. The G9 deposit and the La Lucha and San Rafael occurrences are in an over-thrust plate further to the southwest. In several of the deposits, zinc, lead, silver, and gold are concentrated near the stratigraphic top, and copper is concentrated near the stratigraphic base; copper also is concentrated in replacement bodies near the top of some domes. Major minerals are pyrite, quartz, ankerite, sphalerite, chalcopyrite, and galena. Gold and silver occur in argentian gold, and silver also occurs in tennantite/freibergite and galena. Underlying stockwork zones contain disseminated and vein quartz, pyrite, chlorite, and ankerite, with locally abundant chalcopyrite and/or sphalerite. Exploration since 2004 has enlarged greatly the El Largo and the high-grade G-9 deposits, and slightly enlarged the El Rey deposit. The cumulative in situ massive sulphides for the Reforma, Naranjo, El Rey, El Largo, and G9 deposits exceed 45 Mt.

May 1, 2006

By Jan E. Nesset, Phillip J. Mackey

"Studies have shown that there is a correlation between commissioning and start-up time, i.e. time to reach full plant design capacity, and the degree of innovation and technical/engineering uncertainty in the project design. The paper describes the types of start-up curves for plants according to the level of technology or uncertainty in the process design. The need to properly describe and understand the commissioning and start-up time is examined using these curves and the importance on project success is highlighted. A number of case histories of recent mining and metallurgical projects are also reviewed. Finally, the paper reviews how to better assess the level of start-up uncertainty associated with a project and makes suggestions for decreasing the commissioning time due to technological risk.INTRODUCTIOThe start-up of a new mining and metallurgical facility, a much anticipated event, is a critical step in the life of such a project. Achieving a successful start-up and reaching the design capacity on-time requires careful planning, a thorough understanding of the key technological and engineering components involved and a well-trained and adequatelystaffed start-up crew. In this paper, some of the aspects related to start-up of a mining/metallurgical project will be explored, and in particular, the impact of the technology component will be examined. In order to illustrate this, a number of case histories based on recent mining and metallurgical projects will be discussed. Ways of assessing and understanding the uncertainty associated with technological issues related to start-up of a mining and metallurgical plant will also be examined.The history on mining and metallurgy is full of success stories of great mines and mills that are now considered “company makers” (well known examples of such successes include the Horne mine for Noranda which had a 1 year start-up in 1926-27, the Dome mine for Placer Dome, the Grasberg deposit for FMI in Indonesia). Less well documented are specific studies relating to plant start-ups and what constitutes a success or a failure, however there are a few notable references in the literature and these will be reviewed."

Jan 1, 2003

By James L. Oleson, Hunter R. Propsom, Kevan J. R. Ford, Robert D. Henderson, Bob Musgrove

"Kinross’ Fort Knox Gold mine, near Fairbanks, Alaska has successfully implemented two major metallurgical continuous improvement projects resulting in growth of gold production and an extension of mine life. In 2009, Fort Knox produced 263,153 oz of gold at a cash operating cost of $543/oz. In 2010, approximately 63% of the gold will be produced from the CIP circuit, 15% of the gold from the gravity circuit and 22% of the gold from the heap leach.In 2009, a 44,000 ton per day run-of-mine valley fill heap leach facility was constructed and commissioned as a cost effective treatment option for low grade ores to supplement the higher grade mill. The heap leach facility will produce approximately 100,000 ounces of gold per year under severe winter conditions. Heap leach gold recovery, based on test work shows 30% after a 55-day leach cycle, with long term ultimate gold recovery targeted at 65%. The paper presents the heap leach design concepts and production data.Additionally in 2009, installation of a Knelson gravity concentrator unit (XD70) was completed. This together with an Acacia intense leach reactor (AILR) has increased overall mill gold recovery from 79.3% to 80.7%. A manual shaking table gold recovery operation has been replaced by batch intensive cyanidation of the high grade Knelson concentrates. Increased removal of coarse gold and difficult-to-leach gold species from the grinding circuit, via the gravity circuit, has improved gold leach recovery in the conventional whole-ore tank leach CIP circuit. The paper presents plant operating data, showing the improvements over the old flowsheet.Focus on the metallurgical properties of the high grade and low grade end components of the Fort Knox ore has resulted in significant improvement to gold recovery."

Jan 1, 2011

By S. L. Aaroe

"TYRETHANE PRODUCTSTyrethane® is the family brand name which has been adopted by The W. S. Tyler Company of Canada, Limited to identify its polyurethane products. Since we have been manufacturing Woven Wire Cloth for over one hundred years and have been the innovator for most of the product improvements and developments of that industry, it is only natural that our first and primary efforts involve the use of Tyrethane® as a screening medium. The product is ideal for application in the mining industry and other operations where the rate of wear on existing media is exceptionally high.In the event that you have already had some experience with polyurethane it should be poirted cut that there are many grades of the material. The polyurethane used in Tyrethane® Products will be compounded in a variety of chemistries and different heat treatments will be used to develop best mechanical properties to handle specific applications. However Tyrethane® will not be a ""cure all"" but when it is properly applied as a screening medium it will assist by lowering the unit cost for screened materials.Prior to an explanation of the advantages of Tyrethane® let's review the conventional screening media whose applications may be considered as good candidates for replacement by Tyrethane®.1.,Woven Wire Cloth.2.,Perforated metal screens.3.,Rubber faced perforated metal screens.4.,Perforated rubber screens.5.,Cast steel screen segments and weldiments.6.,Profile wire.In most cases a Tyrethane® section is designed for a one for one replacement of the material now being used. It is rarely necessary to modify the screening equipment to enable you to install the Tyrethane® Product although it may be desirable to take some steps to improve the service life of hold down components such as Clamping Strips or Tension Members. Those parts can be encapsulated in polyurethane if necessary.To fabricate the Tyrethane® section we have three basic building blocks. They are: (1) Small molded segments having square or slotted openings, (2) Reinforcing material and (3) the raw liquid polyurethane."

Jan 1, 1976

By M. Maccagni, J. Nielsen

"Engitec developed the EZINEX® Technology some years ago to recover zinc from oxidized secondary sources. This process works at neutral pH and can take into solution any kind of metal, but iron is rejected and remains in the leach residue. Engitec has also developed the FLUOBORATE System, which is able to recover lead and copper from relevant concentrates. Some iron is leached into solution, but it is controlled through a solution purification bleed treatment. In this paper, we present the two above mentioned technologies. They are very different with regards to the chemical environments and the methods used to control the build-up of iron in solution, but both systems are suitable to treat iron bearing feeds.INTRODUCTIONIn the design of hydrometallurgical processes, the most important issues are the water balance, the filtration and the control of impurities. This is particularly important when the process includes an electrowinning unit. Iron has been one of the most problematic elements to remove, especially in acidic environments.Engitec Technologies has developed several hydrometallurgical processes divided in two different electrolyte lines: the Fluoborate Technology for the recovery of lead and copper from primary and secondary sources and the Ammonium Chloride System based on a chloride electrolyte for the recovery of different non-ferrous metals, among which zinc and lead are the most important. In both cases, iron is present in the feed and needs to be eliminated from the solution. It is not a problem for the quality of the metal produced, but when present in solution, it consumes the basic electrolyte reducing its free concentration which is very important both for both the leaching and electrowinning unit operations. Both process systems are very peculiar, the fluoborate case being much more intriguing."

Jan 1, 2016

By P. A. Distin, Jr. da Silva

The history of commercial processes for zirconium/hafnium production and separation is reviewed. A new technology is then proposed as a potential alternative for zirconium/ hafnium separation in a simpler, cleaner way than achieved with current processes. Primary sources of zirconium always contain small amounts of hafnium that must be removed during production of zirconium metal for nuclear applications. This separation is usually carried out by a solvent extraction process, developed in the 1950s, that selectively extracts hafnium, as a thiocyanate complex, using methyl isobutyl ketone (MIBK). Environmental problems inherent to this process are the high aqueous solubility and low flash point of MIBK, and possible gaseous contaminants formation generated by the decomposition of the thiocyanic complexes in hydrochloric acid medium (H2S, HCN, mercaptan’s formation). The present work shows how these problems could be avoided by using organophosphorous extractants that were unavailable when the MIBK process was developed.

Jan 1, 1998

By J. A. Jr. Carpenter

Expanding world economic prosperity, probable peaking of conventional petroleum production in the coming decades and environmental concerns require efforts to increase the efficiency of, and the development of alternatives to, petroleum-based fuels used in automotive transportation. In January 2002, the U.S. Department of Energy (USDOE) and the U.S. Council for Automotive Research (USCAR) of the "Big Three" traditionally-USA-based automakers, DaimlerChrysler, Ford and General Motors, formed the Freedom Cooperative Automotive Research (FreedomCAR) Partnership to fund high-risk, high-payoff research into advanced automotive technologies with the potential for eventually lowering the USA's nearly complete (95%) dependence on petroleum, 55% imported, for its transportation fuels. FreedomCAR replaced the Partnership for a New Generation of Vehicles (PNGV) which existed from 1993 to 2001. In January 2003, the energy-supply industry joined with the FreedomCAR Partnership forming the FreedomCAR and Fuel Initiative (FC&FI) to develop the technologies needed for the mass production of fuel-cell vehicles using hydrogen as fuel and the infrastructure needed to deliver the hydrogen to the consumer. The goal is to enable the automotive and energy-supply industries to make commercialization decisions in 2015 on large-scale introduction of such vehicles and on developing the infrastructure beginning in 2020. In addition to work on fuel cells and hydrogen infrastructure, the FC&FI conducts research on technologies with the potential for nearer-term energy efficiency and environmental benefits, such as new engine concepts, lightweight materials, and engine-electric hybrid propulsion systems. Lightweighting is seen as crucial for shorter and for longer term benefits because hybrid and fuel-cell powertrains are expected, at least in the early stages of adoption, to be heavier and more costly per unit of power than the standard internal-combustion, gasoline- or diesel-fueled powertrains they replace. Research and development (R&D) on casting of aluminum automotive components were major parts of the PNGV and R&D on casting of magnesium automotive components have been and are so under FreedomCAR. This presentation will review those efforts.

Jan 1, 2006

By S. D. D. Welsby

"A pilot-scale flotation column was used to evaluate four polyglycol frothers at Teck’s Highland Valley Copper Mine. The column was fed with flotation plant feed from the grinding circuit cyclone overflow. Frother dosage was changed by controlled addition to the column feed. Pulp, froth and metallurgical performance were assessed using gas dispersion measurements, water recovery and copper, molybdenum and gangue grades and recoveries. Ranking the frothers based on pulp and froth phase performance using gas dispersion measurements and water recovery yielded contradictory rankings. All of the frothers changed the froth structure in a similar manner such that, at the same structural conditions, they all gave the same degree of separation between water and entrained solids. The only difference between the frothers was what dosage was required to achieve a certain structure. Changes in pulp structure appeared to be related to the critical coalescence concentration (CCC) for each frother. Changes in froth structure were not completely described by the CCC and involved other factors, such as the hydrophobicity of particles in the froth. All of the frothers were capable of achieving the same metallurgical result, just at different dosages. Optimal dosages for the frothers were anywhere from the CCC, where copper and molybdenum grades were maximised, to 2 to 3 or 4 to 7 times the CCC, where copper and molybdenum recoveries, respectively, were maximised.INTRODUCTION Background Due to supply issues, Teck’s Highland Valley Copper (HVC) Mine replaced Dowfroth 250C, their auxiliary frother, with Huntsman Polyfroth W31. The primary criterion for selection was that the new frother gave the same performance as Dowfroth 250C, minimising disruption to the circuit. Frothers play a dual role in flotation, altering the bubble size in the pulp zone and the stability of the froth. A stronger or weaker frother, or a blend of both, will alter the balance between pulp and froth effects and, ultimately, metallurgy. Dowfroth 250C and Polyfroth W31 may not necessarily be the best frothers for HVC from a metallurgical standpoint. There may be a different frother or frother blend that could deliver higher recovery in the bulk roughers."

Jan 1, 2014