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By Andrew Kerr

Abstract - The base-metal and PGE contents of samples from magmatic sulfide mineralization are commonly correlated with their sulfide contents, indicating that the metal contents of bulk sulfides remain approximately constant within a given prospect or part thereof. Calculated sulfide metal contents provide valuable information in mineral exploration and research, but there are few formal descriptions and analyses of the procedures. Sulfide metal contents are best calculated using an assumed value (35.7% S) for a typical pyrrhotite-chalcopyrite-pentlandite mixture, and there appears to be little advantage in accounting for sulfide species separately. Regression of metal data against sulfur is probably the most rigorous approach, but is not always practical. Above 10% S, calculations are very robust, but lower sulfide contents generally demand at least some correction for non-sulfidehosted metals. Such corrections can become significant below 5% S, and/or in olivine-rich samples. They are best accomplished by mass-balance calculations, using concentration data from unmineralized host rocks. Significant uncertainties are introduced by analytical errors for sulfur, base-metals, and PGE, which are commonly measured from separate sample aliquots. These combined errors in sulfide metal contents generally exceed ±10%, but expand further at low S contents. In general, treatment of data from samples containing <2.5% S must be approached with caution, especially for PGE, for which the exact host minerals may not be known. Application of the method in simple grade-potential assessment is straightforward, but research studies involving sulfide-poor samples are inherently more complex. Under-correction or over-correction of data for non-sulfide-hosted metals can lead to false negative or positive correlations between sulfide metal contents and sulfide content. As the latter may itself be linked to geological parameters, such as depth within an intrusive body, undue significance could be ascribed to such trends. There are also valid geological reasons for such correlations, and such data require careful assessment to separate true and artificial variations. Propagated analytical uncertainties increase significantly in sulfide-poor samples, and must also be borne in mind whenever data from different localities or units are compared and contrasted.

Jan 1, 2001

By H. Polkowska-Motrenko

Analytical methods for the determination of uranium and other precious elements in ores, industrial wastes and by-products have been developed. The analytical techniques employed are NAA and ICP-MS. Two procedures of digestion were applied: microwave acid digestion and alkali fusion. Accuracy was checked by using CRMs. Results of analysis of the same samples by the elaborated methods have been presented and compared. The methods will be used for estimating the capacity of uranium production for the Polish nuclear power programme.

Aug 1, 2010

By Charles G. Kemsley

IN view of the truly remarkable development of special steels for special purposes, the mining industry has for years looked forward to a time when steel makers would come forward with a product which would be an improvement over the straight carbon steel which has always held the field for drilling rock. In order to avoid making changes in conventional shop practice, the industry has perhaps been too insistent upon obtaining a water hardening steel which could be handled in the blacksmith shop by long established methods. As early as 1932 or 1933, an oil-hardening tool-steel of the one per cent carbon, plus chrome, plus molybdenum type was applied to hollow drill steel. It was known as a hard as well as a tough steel, and one that, theoretically, should give a good account of itself as a rock drill, if properly heat-treated; and so it has proved in actual trials. There were numerous deterrents which retarded adoption of this steel. For several years there has been a constant improvement in the drilling qualities of the straight carbon steel, and, considering the higher unit price ? of the alloy, there has been considerable doubt in the minds of some mining? men as to what advantage there might be in the use of alloy over straight carbon for hollow drill steel. The alloy being an oil-hardening steel, its adoption meant having two kinds of steel in the mine, for a time, and that spelled trouble, unless some positive means of identification was adopted. The hardening and forging ranges of alloy steel being narrow also made necessary much closer control over these operations if poor results were to be avoided. These thoughts undoubtedly prevented its use becoming wide-spread, for, as a matter of actual record, less than fifteen per cent of all the hollow drill steel used in Canada today is alloy.

Jan 1, 1942

By E. H. Henderson

MR. R. V. NEILY stated that he had at one time operated at Goldenville. The practice and results are much the same now as in the olden days. Inside plates were then found to be a source of trouble and had been removed. At the Libbey mine, Queen&apos;s county, the sulphides carried considerable gold, and $45.00 to $60.00 per ton had been recovered from the concentrates by roasting and chlorinating. Later, concentrates were treated with bromocyanide. Following that practice, a cyanide leaching plant was installed, which did not require concentration of the tailings. Cyanidation brought a recovery of around 95 per cent, with but $300 worth of plant. In Nova Scotia, the ore of each locality presents an individual problem of its own as to treatment required. Ma. W. B. Timm stated that, in the majority of Nova Scotia gold ores, more than 75 per cent of the gold content is free-milling and, naturally, stamps are most efficient for collecting and amalgamating this gold. In Ontario and the West, they had got away from stamps, and perhaps the main reason was that the supply of battery-men, who came from Nova Scotia, had died off. Ball-mills had been installed, which required smaller space and handled large tonnage, even though, as far as amalgamation goes, the stamps were probably more efficient. If concentration is to be done, ore from stamps is usually in better shape for recovery in passing over the tables, as there is no slime. With the ball-mill, flotation is necessary. The better practice, undoubtedly, is to take out what gold is possible before it is all smashed up, as in the ball-mill, though recent developments in the ball-mill make it possible to trap and take coarse gold directly from the mill. In this way, cyanidation is speeded-up, due to saving of the time the coarse gold would take before going into solution. PROFESSOR A. E. FLYNN found it unusual in these days to read anything in favour of the stamp mill, and thanked Mr. Henderson for the excellent paper in which he upholds the stamps and backs his opinion with facts from actual operations. For the typical Nova Scotia ore, containing coarse gold, stamps are un¬excelled. It used to be said that the virtue of stamps is that they brighten the gold for amalgamation. Although this saying is almost classical, it is not true, for gold is never brighter than in the native, untouched state. Any hammering that gold gets makes it more difficult to amalgamate.

Jan 1, 1935

By J. M. Toye

The Canadian nuclear fuel business relates primarily to supplying fuel for Candu reactors. The product development, manufacturing and marketing activities of our nuclear fuel industry will therefore be determined by the rate of growth of the Candu nuclear reactor business. The nature of this relationship between the Canadian nuclear fuel industry and the Canadian Heavy Water Reactor program will be considered, with particular reference to the factors influencing future economic growth.

Jan 1, 1969

By G. R. Guillet

Important resources of kaolin, refractory clay and lignite, not found elsewhere in Ontario, occur with quartz sand of glassgrade quality in unconsolidated Mesozoic sediments of the Moose River Basin in northeastern Ontario. These materials comprise the Mattagami Formation of Lower Cretaceous age, which overlie in some places a thin Jurassic unit and a thick Paleozoic section, and underlie as much as JOO m or more of glacial and marine sediments and a uniform capping of muskeg. The Mallagami Formation is known from deep boreholes to exceed 100 m in thickness and to consist of two phases: an earlier Type A unit of dark-coloured carbonaceous clays and lignite, and a later light-coloured (Type B) unit of kaolin-bearing quartz sands and bright-coloured refractory clays. Remoteness, poor access, and difficult physical environment have inhibited the exploration and development of these resources.

Jan 1, 1984

By E. W. Coderre, R. C. Baxter

"This paper describes the townsite of Wabush and the two railways operated by Wabush Mines for the loading and unloading of iron ore concentrate. The town of Wabush is located approximately 200 air miles north of Sept-Iles, Quebec and is in the Province of Newfoundland and Labrador. Construction of the town-site began in 1961 to provide housing accommodation for the construction force and permanent employees in the mining and milling operations located 4 miles away. Wabush Mines operates two short railway lines in loading and unloading concentrate between the concentrator, located at Wabush, and the pellet plant at Pointe Noire, Quebec. Both of these railways connect with the main line of the Quebec North Shore and Labrador Railway and provide a shuttle service between the two phases of the operation."

Jan 1, 1969

By Richard Q. Fox, Joe L. Pinson

This paper provides guidelines jo1• analyzing and selecting electric power demand controlled. Error calculations, load selections and timing criteria are identified as the three key functions which affect the suitability of a demand controller for any particular application. The advantages of simulating the demand control application on a computer are described, and applications of a demand controller to an iron ore concentrator and a copper refinery are shown. Finally, the paper studies the return on investment for a demand controller.

Jan 1, 1976

By V. Pouyafar

In recent years semi-solid processing of steel alloys has gain more attention among researchers. Production of high quality complex steel parts with higher mechanical properties is the final goal for all these researches. A thorough understanding of the flow behavior of the metal under investigation is the key for a successful process design. The material used in this research is M2 tool steel. The experiments were performed using a Searl-type concentric cylindrical rheometer which is specially designed for high temperature rheological measurements up to 1500 ºC. The rheological techniques were consisted of continuous cooling experiments and isothermal holding and also shear rate step change experiments for different solid fractions. Based on the rheological data a single phase thixotropic model has been derived and adopted to the measured data. The state of the microstructure has been applied through a structural parameter. The model fits well with the experiments.

Oct 1, 2011

By J. Jackman

North America has been aggressively pursuing approaches to improve the fuel efficiency of vehicles, and to develop alternatives to petroleum-based fuels used in automotive applications, for over ten years, Increasing energy demand due to emerging economies, coupled with probable peaking of conventional petroleum production in the coming decades are increasing the need to reduce dependence on petroleum-based fuels for transportation, Vehicle lightweighting is seen as an important strategy to improve fuel efficiency of conventional as well as highly innovative vehicles, Magnesium has recently emerged as a serious candidate for lightweighting, as a result of lower global prices, Automotive vehicles produced in North America currently use more Mg than vehicles produced elsewhere in the world, but the amounts per vehicle are very small in comparison to other materials such as steel, aluminum and plastics, The reasons, besides price, are primarily a less-developed state of technology for Mg in automotive transportation applications and lack of familiarity by the vehicle manufacturers with the material, This paper reviews the major government-funded research programs in the USA and Canada that are dedicated to advancing the state of Mg technology for automotive applications, It provides examples of research in the areas of high-pressure and other types of castings, corrosion solutions, sheet development and other wrought applications.

Jan 1, 2006

By B. D. Wood, J. A. Fowler, H. S. Grütter, J. M. Kong

Abstract- The phased approach used by De Beers for diamond exploration is briefly outlined. The Victor kimberlite is one of 19 kimberlites in a cluster near Attawapiskat, Ontario. The progress at the Victor kimberlite is summarized, and the operations are described within the framework of this staged approach. An evaluation program is currently under way on the Victor kimberlite, but although results are encouraging, insufficient diamonds have been recovered to permit disclosure of estimates for the grade and value.

Jan 1, 2001

By Kremena Dedelyanova

The paper presents research of mechanism for the creation of air bubbles in vibratory a column flotation machine. Factors are discussed that influence the increase in the duration of the bubble in the area of contact with the mineral particles. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in a vibratory column flotation machine is determined.

Aug 1, 2013

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By J .. R. Dalton

"Blasting in high sulphide content ores presents at least two major safety considerations: (1) compatibility of the explosives with the ore while resident in the borehole; and (2) introduction of a flame and shock producing explosive into this environment, while minimizing the risk of reactive ignition in the chemical reaction products/sulphide dust cloud resulting from the detonation. This paper will discuss only the second consideration, i.e. post detonation reactivity.The ETI (Explosives Technologies International) Technical organization, in consultation with the U.S. Bureau of Mines, reasoned that the most relevant considerations in the development of an explosive for this application are:• minimization of reactive gaseous detonation reaction products;• flame duration reduction;• flame temperature reduction;• increased explosive sensitivity;• reduced probability of ""low order"" detonation; and• maintenance of energy level as high as possible.Obviously, not all of these are totally independent properties, i.e. increased sensitivity will reduce the probability oj low order detonation as will higher energy levels. However, these considerations were examined separately as if they were independent."

Jan 1, 1994

By N. B. Clarke

LIMESTONE, as a name, covers a great variety of stone consisting of varying amounts of calcium carbonate, magnesium carbonate, and impurities such as silica, alumina, and sulphate of lime. In the iron and steel industry, limestone is roughly divided into two classes, namely Calcite, when the magnesium carbonate content is below 10 per cent, and Dolomite, when the magnesium carbonate is over 10 per cent. In practically all metallurgical melting, the quality of the finished product is related to the character of the slag, and limestone is used as a flux to achieve the proper analysis and consistency. The function of the slag is to absorb the undesired elements of the bath and also to act as a protective cover over the metal. The carbonates of calcium and magnesium are the effective agents in fluxing, and the silica, alumina, sulphur, and other foreign matter are objectionable impurities which should be as low as possible, totalling not over S per cent and preferably below 3 per cent, since all of these so-called impurities must be fluxed by the lime and magnesia of the stone. When the lime and magnesia of the stone have to be used to flux its own impurities, there is that much less of these two oxides left for fluxing the impurities from the balance of the charge, and, as a result, more lime-stone must be used than is desirable with good practice.

Jan 1, 1939

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By Y. Sugiyama, K. Kitazono, T. Miura, K. Matsuo

"Impact energy absorbing system for automotive is an important technology. Open-cell porous aluminum alloys were manufactured through Powder Bed Fusion (PBF) process. Compressive properties of the porous aluminum alloy depend on the cell structure as well as the porosity. The authors manufactured two ordered cell structures, truncated octahedron and rhombic dodecahedron, and one disordered cell structure, random Voronoi structure using a 3D-CAD software. Compression tests revealed the anisotropic deformation of the porous aluminum alloy with ordered cell structure. On the other hand, the porous aluminum alloy with disordered cell structure showed relatively isotropic and uniform deformation, which is suitable for energy absorbing applications. Therefore, controlling the disordered cell structure designed by Voronoi diagram enables to develop the advanced porous aluminum alloy having various mechanical properties.INTRODUCTIONAdditive manufacturing (AM) process enables to manufacture near net-shape mechanical parts. The AM technology is typically focused on titanium alloys due to their high specific strength and biocompatibility (Attar, 2014). Recently, aluminum alloy parts can be manufactured through selective laser melting method (Leary, 2016). Metal foams or porous metals are lightweight cellular materials having closed-or open-cell structures (Banhart, 2001). Aluminum foams are focused on as an energy absorbing material for transport industries (Baumeister, 1997). The purpose of the present study is to investigate the optimal cell structure of open-cell porous aluminum alloy manufactured through AM process. Most previous researches on the AM aluminum lattice structure has been considered ordered and periodic cell structures. On the other hand, classical aluminum foams manufactured through cast or powder metallurgical processes have disordered and heterogeneous cell structures (Körner, 2000). The authors use a concept of Voronoi diagram (Moukarzel, 1993) in order to manufacture various cell structures."

Jan 1, 2018

By Louise Corriveau

Exploration strategies have traditionally considered felsic gneiss complexes of the Canadian Shield sterile. This paradigm is challenged with the discovery of extensive granulite-facies Cu-Au, Fe oxides-bearing hydrothermal systems in the 1.4 Ga Bondy and 1.5 Ga La Romaine volcano-plutonic complexes of the Grenville Province. Early identification of magnetite-rich units in association with meta-exhalite and pelite-like units was key to targeting the search for mineralization, protolith information and indicators of pre-metamorphic hydrothermal activity during regional surveys of these frontier terrains. Textural evidences for a volcano-plutonic setting were found. There remained, however, numerous impediments to the recognition that the ubiquitous magnetite-laden units and associated aluminous gneiss were hydrothermal in origin. Many metamorphic reactions form magnetite at the amphibolite to granulite facies transition, and hydrothermally-leached rocks resemble metapelite or migmatitic restite, while carbonate alteration zones may look like marble or calc-silicate rock. Non-typical metamorphic mineral assemblages, modes and colours arise when hydrothermally-derived rock types are metamorphosed. These effective markers served as tools for reliable field identification of hydrothermally-altered rocks. In our case-studies, we traced pre-metamorphic hydrothermally-driven Fe-oxide precipitation in association with sericitization, albitization, pyrophyllite alteration, chloritization, and B enrichment by mapping unusually high contents of (1) magnetite or hematite, (2) biotite, (3) albite, (4) sillimanite, (5) orthopyroxene or phlogopite with cordierite, and (6) tourmaline or kornerupine. The unveiled garnetite, tourmalinite, and aluminous gneiss had assemblages that vary according to metamorphic grade and composition. To assess if high mode of Fe-Mg-Al phases resulted from partial melting (restitic residue) or metamorphism of hydrothermal rocks, we compared leucosome mineral assemblages, shape and amount with that expected of in situ partial melting reactions. In both areas there is no compelling evidence for these units to be restites. In contrast, the presence of lapilli in garnet-cordierite-sillimanite gneiss, though extremely rare, constitutes conclusive evidence for extreme pre-metamorphic high-sulphidation alteration of a volcanic protolith, while Fe-oxides or sillimanite-bearing nodules and veins record a less pervasive alteration. Geochemical research on element mobility and mass balance calculations further testified of an hydrothermal origin for these gneisses. The magnetite-rich units, together with calc-silicate rocks, garnetite, hornblendite, albitite among amphibolite, provided effective guides to sites of fluid discharge and led to the discovery of Cu and Cu-Au showings. With the presence of highsulphidation alteration, these features suggest early Cu-Au VHMS-type alteration halos within a predominantly felsic composite volcano-plutonic arc setting for both case-studies. Evidences for subsequent F-driven orthomagmatic fluid activity are also present.

May 1, 2003

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By A. J. Rigby

Anode vessels are often relined with refractory every one to two years and a typical reline time can take between 16-20 days. Modem refractory designs using dense, corrosion resistant brick applied directly to the vessel shell in the high wear areas around and above the tuyeres and at the slagline can yield a lining life of up to 4-5 years before a complete reline is necessary. Installation methods using brick delivery on roller conveyors through an endwall access port and complete anchoring of the brick to allow for lining self-support can take days off the installation time. It is possible, therefore, to reduce the refractory relining period by 50% and increase lining life by 100% compared to typical anode repair schemes. Cu2007

Jan 1, 2007