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By A. B. Luz, A. Middea

Kaolin clay is heavily used in the paper industry as a coating and a filler, however to attend the specifications required by the industry it has to be processed. Kaolin is also used as a filler and pigment in various materials, such as paint, plastic, rubber etc. Some crude kaolins as mined in Northern Brazil, contain colored impurities such as iron oxide and rutile/anatase. These minerals normally are stained by iron and as a result vary from yellow to dark brown in color. The kaolin beneficiation process used in that region consists mainly of degritting, fractionation by centrifuge, high gradient magnetic separation, bleaching with sodium dithionite, filtering and drying. In some kaolin clays from that region, titanium oxide mineral occurs in fine fraction, lower than 2 µm, and so making the industrial process more difficult. The conventional method of classification and bleaching with sodium dithionite, markedly improves kaolin brightness, but has little effect on anatase removal. In fact, the fine fractions resulting from centrifugation, in many cases contain more TiO2 minerals than the original whole clay or the coarse fraction. The present work is related to purification of Brasilian kaolin clay using selective flocculation for removing its colored impurities such as rutile and anatase. This study was conducted in bench scale and it consisted of: blunging, screening, conditioning and decantation. Overflow and underflow resulting from settling of the flocculated material were then dried and submitted to TiO2 and brightness analyses. Sodium polyacrylate and sodium silicate were added to kaolin clay suspension as dispersant and ammonium hydroxide was also added to adjust pH. After degritting, the minus 44 µm fraction was conditioned with hydroxamate surfactant and then polymers of different anionic charge were added. The influence of pH and type of polymer on efficiency of TiO2 removal, as well as kaolin mass recovery were studied. The results obtained in the present study are quite promising. It was possible to diminish TiO2 content and increase kaolin brightness (ISO) from 82 to 88%.

Jan 1, 2004

By J. W. Matousek

"More copper concentrates are treated in flash smelting furnaces than by any other process, and such furnaces are located in most of the world's major copper producing areas. Except for perhaps two furnaces treating chalcocite-type materials, little difference is seen between the grades of the concentrates being smelted. Within individual smelters, even less variation in feed grades is found. This is both accidental and intended. Many furnaces treat concentrates from captive ores, and these tend to be of relatively constant composition over long periods. Toll smelting operations blend concentrates to ensure delivery of feeds of fixed compositions to their furnaces to avoid upset conditions. Matte grades vary between flash smelting furnaces, but most commonly, these are the result of differences in operating practices rather than because of differences in concentrate grades. This paper reviews an industrial flash smelting test in which the copper content of the furnace feed was intentionally altered over a wide range. IntroductionExcept in a few copper mining regions of the world, the principal copper mineral is chalcopyrite (CuFeSz). This results in the almost universal production of concentrates containing 25070 to 30% copper (and similar amounts of iron and sulphur). Many operators of copper flash furnaces spend their entire metallurgical careers smelting concentrates of essentially fixed grades. This is true both of smelters treating concentrates from captive mines and those processing concentrates on a toll basis. From the production staff's point-of-view, the less variation in grades seen by the furnace, the better. Fixed analyses of concentrates and constant feed rates produce consistent quantities of matte at a consistent grade for processing by the converters. The result is, even in smelters treating a variety of concentrates, efforts are expended in sampling and blending to ensure feeds of relatively uniform compositions being sent to the furnaces."

Jan 1, 1993

By Akira Miura, Katsuyuki Sato, Yuken Fukano

JX Nippon Mining and Metals Corporation has developed the JX Iodine Process, which is an innovative and patented copper-leaching process for low-grade primary sulfide ores. This process consists of the irrigation of ferric iron and a low concentration of iodide solutions. One-meter column leaching tests were conducted on ore samples from two different mines. At the end of experiments, the total copper recovery exceeded 70% for Sample A and 50% for Sample B with the iodine method, which was significantly higher than that with conventional ferric leaching of 14% for Sample A and 20% for Sample B. To elucidate the reason for the JX Iodine Process effectiveness, cross sections of leached residues were studied. Reaction products were confirmed around chalcopyrite even in the central area of particles in Sample A, however, reaction products were recognized at a depth of only 1 mm from the ore rim in Sample The resistance of Sample A to the leachate appeared to be lower than that of Sample B because Sample A had a high permeability and porosity, whereas Sample B had been affected strongly by a potassium alteration. No reaction products were visible on conventional leaching samples, even at the ore surfaces. INTRODUCTION Hydrometallurgical copper leaching (heap leaching or dump leaching) has been used extensively for copper recovery from oxide and secondary-sulfide ores, but not for primary copper sulfides, which contain mainly chalcopyrite as copper minerals. Although they are major resources of copper, primary copper sulfides are difficult to process because of their refractory nature. Extensive leaching studies have been carried out to leach primary copper sulfides (chalcopyrite), including biological and chemical, using a variety of oxidants and additives to enhance copper recovery. Watling (2013) reviewed acid-chloride-oxidizing agents with chalcopyrite. Abdollahi et al. (2015) tested silver as a catalyst for bioleaching with a chalcopyrite-bearing molybdenite concentrate. Hiroyoshi, Miki, Hirajima and Tsunekawa (2000) found a specific redox-potential zone for high-speed chalcopyrite leaching by controlling the ratio of ferric and ferrous iron. However, no ambient-temperature economic process has been developed for leaching primary copper sulfide, which usually has a low copper grade.

Jan 1, 2019

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By Mei-Yan Yang, Ltd. Yunnan Yuntong Zinc Co., Yong-Xiang Li, Xing-Zheng Dai, Hong-Liang Wang, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"The removal of iron asgoethite from the high iron bearing solutions generated in zinc hydrometallurgy using a strong airflow device was investigated. The influence of oxygen flow, copper ion concentration, temperature and reaction time on iron precipitation as goethite was studied. The optimum conditions were: oxygen flow 0.2-0.35m3/h, copper ion concentration 0.25-0.5g/L, temperature 80-90oC, zinc oxide powder neutralizing agent and a reaction time of5to 7hours. Under the optimal conditions, the Fe2+concentration was reduced to 0.025g/L after iron precipitation, and the goethite residue contained 38.7wt.%Fe. The SEM and XRD analyses showed that the iron was present as well formed FeOOH crystals in the iron residue, and the amount of iron sulphate was very low. Production practice shows that, when the average iron concentration in the feed solution was 11.61g/L and 4.08g/L after precipitation, the weight of iron removed was 1,439kg/day. When the average iron concentration in the feed solution was 14.51g/L and 2.73g/L after precipitation, the weight of iron removed was 2,454kg/day. This represents a ~70 percent increase in iron removal.INTRODUCTIONThe objective of iron removal is to produce a small volume of iron residue, and our industrial goethite process meets this requirement. The high Fe(II) solution in our reactor isoxidized/hydrolyzed to precipitate goethite and the precipitate is sent to a pyro metallurgical furnace for final residue treatment. Some literature discusses (DengYong-guiet al., 2008;Meiguang-guiet al., 2001;Zhongzhu-qianet al., 1980) research on iron hydrolysis; one of the reported rate limiting parameters was the low availability of the oxidant when using air and another was the inhomogeneous air distribution. There are two iron hydrolysis-goethite precipitation methods; the Electrolytic Zinc process (EZ) and the Vieille Montagne process (VM) (Lei Xiang, 2006; Xuguo-qiang, 2007;ZhaoYonget al.,2005). The EZ method hydrolyzes the Fe3+directly to FeOOH. The weakness of the EZ process is the low recovery rate of the associated minor metals. The VM method reduces the iron to the ferrous state and then oxidizes the Fe(II)to Fe(III),with simultaneous hydrolysis/precipitation of the Fe(III) as FeOOH. Before iron hydrolysis, the minor metals, such as indium, could be selectively precipitated, because Fe(II)requires a high pH for hydrolysis. So the VM method has a high recovery rate for the minor metals. There levant goethite precipitation reaction is:"

Jan 1, 2016

"Technological innovation is an extremely complex activity. The author presents his interpretation of innovation and the innovative process. He reviews the strategy used by participants in coal mining innovation in the past and discusses changes required to meet the challenges of the future.Introduction if an industry is to be successful and viable in today's world, the companies active within the industry must remain close to the frontiers of knowledge. The coal mining industry is no exception. Technological problems facing the coal mining industry are basically economic and social. Economic problems are those concerned with the long-term growth and profitability and social problems, with the health and safety of the mine worker and the impact of the mining operation on the environment.Technological innovation can be a key factor in meeting these problems successfully. The general belief is that the information base for technological innovation exists within mining companies and governmental agencies but current industrial and governmental strategies and structures impede the transformation of this knowledge into the mining products and processes required for growth.The purpose of this paper is to determine where Canada is in terms of coal mining on the innovative ladder. The paper as presented: defines innovation and innovative process; gives an historical ""broad brush"" review o f innovation in the industry; and suggests the challenges to be faced in the future."

Jan 1, 1985

By Robert B. Parsons

"The pendulum in Ottawa has swung dramatically from fiscal policy to monetary policy over the last several years. International trends indicate that the pendulum has to start its swing the other way, if Canada's mining industry is to maintain its preeminent position in the global mining arena. This article, which is based on a paper presented by the author at the 37th Annual Meeting of the Newfoundland Branch of CIM, identifies these trends and how they could interact with Canadian policy.IntroductionThe title of this paper is not a very imaginative or catchy one, but it states the topic quite succinctly, if not tersely. This paper looks into a crystal ball to see what might be in store for mine financing over the balance of the current decade.In the event that the reader feels some trepidation about the prospect that such a paper could seek to be the definitive work on the subject, it should be made clear at the outset that this is not the case. The author is, after all, not an economist, a scholar, a financial analyst, or a soothsayer, but is rather a simple accountant who has been closely involved with the mining industry, and the financing thereof, for some twenty years.The paper recognizes that, while a mine may be born when production begins, the mine is conceived when exploration starts. As this act of conception is obviously an essential part of mining, the financing of exploration is also covered in this paper. To attain a focus, this paper approaches the topic of mine financing in the nineties as follows: first, the major emerging forces in the industry are identified: and, second, the implications of each of these forces on financing are considered."

Jan 1, 1991

By J. H. Nantel, J. F. Archibald

"The presence of radon from uranium-bearing ores, waste and from backfill material introduced underground to provide ground support, work platform and waste disposal functions, requires that ventilation controls be established to maintain safe working level concentrations. One approach has been developed at Queen's University to quantify radon and radon daughter source level s and to estimate ventilation requirements necessary to maintain these safe levels.Knowledge concerning the sources of radioactive contaminants and their production quantities is of value for planning and design stages of ventilation control systems. For any given mine layout, radiation level estimates may be forecast and modified by ventilation network design where excessive production quantities may exist.Behaviour of Radon Gas in MinesRadon gas, produced from the decay of Ra-226 in a host medium, will diffuse through porous media. In areas adjacent to mine workings, radon will be liberated into the mine atmosphere. The rate of radon emanation is proportional to the rate at which radon is produced within the host material (a function of the ore grade of U308) , to the radon concentration gradient in the host pores and to the diffusion properties of the material.The radon source concentration is determined by the rate at which Rn-222 is produced by the decay of Ra-226, and by the emanating coefficient (E), or fraction of the radon which escapes from the source matrix and is free to diffuse through the pore spaces."

Jan 1, 1984

By A. J. Williams

"Whenever a decision is made to bring a mineral deposit into production, the Owner in actual fact has decided to convert substantial sums of capital into productive capacity with the intenti6n of making a profit from such conversion.Escalating costs of construction, frustrating and costly delays in comp1etion, the increasing tempo of technological change and the increasing size and complexity of mineral processing projects have convinced Owners that the best way of implementing their capital must be sought and utilized. This requirement has stimulated a search for ways and means of applying modern management techniques to the design and construction of mineral processing plants.This search by consulting firms has resulted in the evolution of the concept of project management and the development of planning and con trolling techniques with the result that Owners can seek and obtain better assurance that their project objectives will be fulfilled.This paper will attempt to outline how a mineral processing plant can be brought into production through the implementation of project management techniques.Definition And Objectives Of Project ManagementThe design and construction of mineral processing plants is subject to the restraints of three inter-related parameters -Quality, Cost and Time each of which influences and is influenced by the other two.Project management is a technique where the Owner delegates complete responsibility to a single organization for all phases of a project (design, procurement, construction and commissioning) for the above parameters but retains freedom for major decision making. Normally, the consultant under-takes full responsibility for all phases, but partial project management services can be provided when the Owner so desires.The objective of project management is first to devise and define and then to implement a program in which the relationship between the three parameters of Quality, Cost and Time is optimized, i.e., the desired functional and other requirements are attained (but not exceeded) at the lowest practicable overall cost in the shortest practicable time. The measure of success of a project lies in the degree to which this objective is achieved."

Jan 1, 1974

By Roger Lacroix

Fuel cell application to mining has been indicated to be potentially beneficial to underground mine worker health and to energy efficiency. In order to define the economic advantages of using hydrogen fuel cell vehicles, a detailed study of operating and capital costs associated with underground loaders and power supply infrastructure has been carried out. The results show that for a typical medium-size mine, operating costs and infrastructure costs are less for the fuel cell option versus diesel. The reverse occurs for capital costs owing to the currently higher cost of fuels cells versus diesel engines. This disparity is expected to decrease given the decline in price associated with fuel cell technology advances. Related market issues for fuel cell manufacturers are also presented. Despite the difference in cost, the resources and mine infrastructure required to operate loaders, and base design of the mine loader, is similar for diesel and fuel call versions.

May 1, 2007

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By Denilson Coutinho, Euler Soares, Paulo de Tarso, Jordana Ferreira, John R. Goode, Andreas Sprecher, Alexandre Rocha

The Serra Verde Project is located in the northern part of Goiás state, Brazil, and comprises 49 mineral claims covering an area of 69,814 ha. The Serra Verde deposit is a rare earth element (REE) enriched weathered granite comparable to the weathered granite, or ionic-clay, deposits found in southeastern China. The Mineral Reserves of the Serra Verde Project total 388 Mt (Measured and Indicated) at an average grade of 1,484 ppm of REE oxide (REO). Several hundred agitated leach and column leach tests have confirmed recovery of about 40 to 55% of the REE, except for Ce, using simple desorption techniques. Present plans call for a heap leach operation followed by precipitation of impurities and precipitation of a pure REE carbonate suitable for refining and separation. The project plan includes initial production of 5,000 t/a of REO, with a high content of heavy and critical REO, rising to 10,000 t/a of REO. This production rate will be obtained by mining of the Mineral Reserves over a 22-year mine life at an initial rate of 6 Mt/a for the first four years with the mining rate thereafter increasing as required by grade and production targets.

Jan 1, 2014

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016

By John De La Vergne, Morri Medd

"This paper describes the sinking of a circular concrete ventilation shaft through 110feet of water-bearing overburden. The brine circulation freezing method was used to stabilize the walls during excavation. In order to take advantage of the cold winter weather, a custom-built heat exchanger (natural radiator) was installed in place of the standard mechanical refrigeration plant.IntroductionIn the late fall of 1979, Les Mines Selbaie awarded a contract to the firm of 1.S. Redpath Limited to sink a ventilation shaft on its property in northwestern Quebec. The shaft was to be sunk through 110 feet of water-bearing overburden and approximately 90 feet of rock to a final depth of 200 feet below surface. The water table was measured at 16 feet below the surface elevation.After examining the soils report and diamond drill core from the shaft area, Redpath came to the conclusion that freezing was the best way to stabilize the overburden for sinking. LocationThe mine site is 420 statute miles due north of Toronto, just east of the Ontario/Quebec border (Fig. 1). Access to the site is provided by a development road built by the Quebec government from the Matagami/lames Bay Highway. History of Ground Freezing In the Mining IndustryIn 1862, shortly after the development of mechanical refrigeration, a mine shaft was sunk through an artificially frozen water-bearing formation in the United Kingdom. The first application of ground freezing in North America was for a Michigan iron ore shaft in 1888. Since that time, the freezing method has been used to sink hundreds of shafts throughout the world. Its best known application was to sink sixteen shafts through the Blairmore Formation in Saskatchewan.The same method has been used in every case. It involves chilling a calcium chloride brine solution and circulating the brine in concentric pipes, spaced between 3 and 6 feet around the shaft perimeter and usually 4 to 5 feet from the limits of the proposed shaft excavation."

Jan 1, 1982

By E. Yalçin, A. Ünal

In transitional mineralization, the sill of the underlying variogram is relatively easily estimated, but the estimation of the nugget effect may be more difficult. This study aims to determine for massive copper deposits just how sensitive the estimations of ore reserve, economic copper content, total net value, and ultimate pit limits are to the errors of estimation in the nugget effect of the spherical variogram model. A massive copper deposit which has a log-normal distribution and a spherical variogram was simulated on a rectangular grid using the turning bands method. By using the three dimensional random kriging method, the mean block grades were estimated at four different sampling densities. The ultimate pit-limits were determined by using the two-dimensional dynamic programming algorithm. To calculate the estimation errors, the values obtained by using the actual nugget effect and structured component values were deducted from the estimations obtained using the incorrect nugget effect and structured component values. For isotropic massive copper deposits, it was found that the ratio of the nugget effect to the structured component of the spherical variogram has no significant effect on either the block grades estimated by the kriging method or on the ultimate pit limits.

Jan 1, 1992

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By P. Wanjara, M. Xiao, M. Jahazi, C. Poon

Using a robotic 4kW Nd:YAG-laser system, Inconel 718 (1 mm sheet) was welded with and without filler wire to investigate the effect of processing parameters, including power input and welding speed, on the weld geometry, microstructure and mechanical properties. By means of both nondestructive testing and microscopic examination, the weld quality was studied to determine the nature of the welding defects (porosity, cracking and bead shape) over the processing range of 3-3.5 kW for the power input and 4.5-6 m-min-1 for the welding speed. Application of the design of experiment methodology permitted the examination of the relationship between the process parameters and mechanical properties, from which the optimized laser welding conditions could be determined for joining Inconel 718. In particular, the research results indicate that Nd:YAG-laser welding technology can achieve defects free, mechanically sound welds with narrow fusion and heat effected zones.

Jan 1, 2006

By P. E. Mather, M. J. M. Krane

Uncertainty quantification is a means of articulating the reliability of model estimations. Models of copper pyrometallurgical processes have been published for decades but discussion of their reliability has typically been terse and qualitative, mitigating understanding of their exact applicability to industrial situations. This presentation shows basic uncertainty propagation and Bayesian model calibration, two powerful uncertainty quantification tools, applied to a reduced order model of copper fire/anode refining. The implications of the uncertainty quantification analyses on the applicability of the model results to industrial practice are then discussed. Finally, other possible applications of uncertainty quantification to copper extractive metallurgy are explored. INTRODUCTION Modern copper production operations, including mining operations through wire drawing factories, are ubiquitously heavily instrumented. Most mine-sites and smelters have large repositories of historical data. That said, much of this data is not exploited to its maximum effect. This proceeding provides examples of using uncertainty quantification (UQ) to maximize the informational yield of the data collected from a fire-refining operation. Anode/Fire Refining is the final pyrometallurgical step in the production of copper anodes; it is an essential and universally employed processing step at smelters (Schlesinger, King, Sole, & Davenport, 2011). Much like the smelting and converting furnaces further up the process stream, anode furnaces are difficult to instrument due to their high temperature and the corrosive and/or caking quality of their offgas. This makes continuous and accurate measurement of the streams leaving the unit operation, e.g. liquid copper, slag, and offgas very difficult. As an example, offgas flowmeters, while providing continuous draft values, could miss the actual draft value by tens of percent due to caking or corrosion. UQ methods account for the uncertainty in process measurements and parameter values; they use a process model with measurements of performance indices to provide better and better estimations of process performance. This proceeding will first introduce a surrogate model for copper fire refining, made from a 1D, transient, reacting flow model of the process presented elsewhere in these proceedings (Mather & Krane, 2019). Discussion of the data used to make the surrogate model, as well as the creation of the surrogate model, will be included. Then, a Monte Carlo simulation will be performed, showing the expected soot production rate based on the surrogate model and assumptions about the uncertainty in the model’s parameters. Finally, the surrogate model parameters will be calibrated in a Bayesian way; this will tell what the actual uncertainty in the parameters are, given a set of observed industrial data and prior assumptions of the observations’ and parameters’ uncertainty.

Jan 1, 2019

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By Anthony P. Makuch

Dynatec Corporation is an integrated mining services company, providing mine development, operations management, engineering, drilling and metallurgical services to the North American mining industry. Dynatec was the contract operator of the Ken Snyder Mine in Midas, Nevada from start of production in January 1999 to September 2001. This paper summarizes Dynatec?s experience and approach to the use of longhole stoping methods for mining to widths of 1.3 to 2 metres in a steeply dipping narrow vein orebody.

Oct 1, 2001