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By Ferri P. Hassani, Riadh Bouzaïene

"Selected methods of pressure loss predictions in horizontal slurry flow in pipelines are presented. For a given combination of flow velocity, solids concentration and particle size, the slurry and its flow conditions are described, and an appropriate method of pressure loss prediction is outlined. The wide range of conditions treated in this paper may be found in practice in areas varying from the hydraulic transport of low concentration slurries to dense-phase conveying of paste backfill in underground mines.IntroductionThe hydraulic conveying of solid particles in pipelines is a major component of the mining and mineral processing industry. Whether the objective is to transport ore to the processing plant or to make use of mill tailing as backfill material; the need for well designed, economical hydraulic conveying systems is recognized.The contribution of this paper is part of an on-going research program at McGill University involved in optimizing and developing techniques for total mine waste disposal. One of the main concerns in the conveying of solid-liquid mixtures is the prior knowledge of the pumping power input required. This energy requirement is directly proportional to the pressure losses incurred in the pipeline system. Understanding the sources of such pressure losses and predicting their magnitudes should enable the system designer to make informed decisions regarding the optimum mode of hydraulic transportation commensurate with the over-all requirements of the operation.This paper is an attempt to classify pressure loss prediction methods encountered in the literature for solid-liquid mixtures. In spite of the large number of publications spanning thirty years of research in the field of slurry transportation, it is sometimes difficult to correctly identify the appropriate methods applicable to a given situation. This is partly due to the inherent complexity of the mechanics of slurry flow and the ensuing uncertainty about the nature of the flow regime under investigation.Our approach is to use three fundamental parameters, namely: flow velocity, solids concentration and particle size (for solid particles with a given density) to characterize the slurry and the flow conditions, and to match them with an adequate pressure loss prediction method. For each combination of flow velocity, solids concentration and particle size, a description of the most likely prevalent flow conditions and some known methods of dealing with them will be presented. Qualitative definitions of ""high"" and ""low"" magnitudes of the aforementioned parameters will be given as a general guide to the classification scheme presented in this paper."

Jan 1, 1992

By D. A. Trotter

"Low-pressure sodium light sources have been available for several years, but have not received wide acceptance in underground mining. This is because they are difficult to operate using DC power, they are not an intrinsically safe light where explosive gases may be encountered and they give poor colour rendition.With the need for energy conservation, several Canadian hard-rock metal mines are now changing their lighting to low pressure sodium, as it has the highest efficacy of any light source in terms of lumens per watt. Studies have pointed out several other advantages as well. Glare can be controlled, they penetrate fog well, they are easily maintained, they have a long life and they give the highest visual acuity when compared to other types of lighting. As well, in an underground mine, contrast is much more important than colour for task identification. For close work, the colour problem is alleviated with the use of cap lamps.Case studies are presented from Canadian practice. These show how the lights are modified for underground use, calculations preceding light installation, and how and where the lights are installed in the underground environment. Mention is made of worker reaction to the lights and possible physiological effects.IntroductionThe importance of good underground lighting to the total environment of mining cannot be overemphasized. In addition to the obvious benefits of improved worker morale, available studies show that good lighting practices reduce accident severity and frequency as well as increase production."

Jan 1, 1982

By G. M. Ritcey, M. Silver

"The processing of uranium ores produces tailings that could constitute environmental problems. At most operations the tailings are dumped into a designated area, with the ultimate acid drainage occurring if sulphides are present, together with the release of metal constituents to the rivers and streams. If the chemical reactions occurring within the tailings could be predicted, perhaps methods could be developed to either increase or decrease 'the rates of reaction. One such study has been in progress at CANMET during the past three years. The paper describes the use of Iysimeters containing low-grade and complex uranium tailings to determine the effects and interactions of bacteria, sulphides and solvent extraction organics on the release of radionuclides and on acid production. A simulated rain cycle nine-fold the normal was used and the Iysimeters were subjected to timed intervals of light and darkness. As a result, the tests simulated a 25-year period.IntroductionAlthough Canadians derive major benefits from uranium, there are environmental and health consequences, not yet fully understood, from the associated mining and milling operations. A major project at CANMET (Canada Centre for Mineral and Energ y Technology) has the ultimate goal of ensuring that any adverse effects on man and environment, now or in the future, resulting from the processing of uranium should be acceptably low. The magnitude of the task was exacerbated by the fact that the increased demand for electrical energy and the resultant increased prices for uranium oxide during the 1970s led to a rapid expansion in the industry. Annual world demand for uranium was expected to increase 12-15 fold in the next quarter century, with annual requirements of between 200,000 and 300,000 metric tonnes anticipated by the year 2000. Currently, the demand is low and the prices for the oxide have decreased."

Jan 1, 1982

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By E. Busse, J. E. Burgener, J. G. Eacott, M. C. Robinson, P. E. Burgener

"This paper presents a preliminary assessment of the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from electric arc furnace baghouse dust at a mini-steelplant. Recent studies and literature are referenced briefly as they pertain to the formation and characterization of dust, toxicity considerations and alternative dust treatment and disposal options.Laboratory testwork results, published data, pilot plant experience and anticipated influences resulting from recycling residues are used for the purpose of developing a conceptual design for a caustic leach - electrowinning plant to treat 15,000 tonnes/year of dust at a one million tonnes /year capacity steelplant in Canada.Target economic studies, comprising preliminary estimates of capital and operating costs, revenues and rate of return are presented. Economic and commercial considerations concerning the relative merits of dust treatment at a centralized facility compared with an on-site plant are discussed.IntroductionThe treatment or disposal of mini-steelplant electric arc furnace (EAF) baghouse dust has been given increasing attention in recent years for two principal reasons. Firstly, the dust is now classed as a hazardous waste material under V.S. EPA regulations which prohibit its disposal in dumps other than controlled landfill sites. Secondly, the dust contains certain metal values, notably zinc and lead, which may be economically recoverable, depending on the costs associated with disposal resulting from enforcement of the EPA regulations. Other metallurgical dusts and waste materials, from both ferrous and non-ferrous operations, may require the same considerations as EAF baghouse dust.Several studies have been carried out to examine various aspects of dust treatment but few commercial plants are in operation. Technology employed uses pyrometallurgical techniques. Commercial-scale hydrometallurgical plants are not known to exist although small-scale plants are frequently more economically attractive than their pyrometallurgical counterparts which generally require economies of scale to be viable.The concentration of mini-steelplants in northeast V.S.A. and southeast Canada merits study to determine whether or not dust treatment for metals recovery is a commercially feasible alternative to disposal.This paper examines the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from EAF baghouse dust at an on-site ministeel plant processing carbon steel scrap and discusses economic and commercial considerations pertaining to dust treatment at a larger, centralized facility."

Jan 1, 1984

By Derek H. C. Wilton

"The Cape Ray Fault Zone of southwestern Newfoundland contains two notable electrum/ base metal sulphide quartz vein lode occurrences hosted by two contrasting lithological units, viz. a graphite schist horizon and a granite. The two occurrences, although in proximity, are not in direct contact, but, based on geochronological, geochemical and isotopic evidence, they were apparently deposited from hydrothermal fluids generated as a vapour phase from the magmatic progenitor of the Windowglass Hill granite.This paper provides further evidence, from REE and background A u and Ag data, for the magmatic origin of the hydrothermal fluids. Wall rocks to the electrum-bearing quartz veins in both the schists and granite have experienced a LREE depletion probably due to leaching by Cl-bearing solutions. Gold and silver contents are typically low in all rock types but there is a slight elevation in gold concentrations in those units in contact with the Window glass Hill granite. The granite also has the relatively highest gold and silver contents of any unit in the region.IntroductionThis paper presents the evidence from rare earth element (REE) and gold/silver concentration data for the magmatic origin of hydrothermal fluids responsible for deposition of the Cape Ray electrum deposits of southwestern Newfoundland. The two deposits occur in the Cape Ray Fault Zone (Fig. I) within the Windsor Point Group and Window glass Hill granite. The larger occurrence is called the Main Shear Showing and consists of a deformed quartz vein horizon, which extends for - 6 km, within the late Devonian Windsor Point Group. This unit is an intermixed ignimbrite and mafic tuff sequence with associated schists (metasediments) and gabbros. The host rocks to the mineralized quartz veins are interleaved graphite, chlorite and sericite schists. Basal ignimbrites within the Windsor Point Group have been dated, by Rb/Sr isotopic methods, at 377 ±21 Ma (Wilton, 1983a). The basal ignimbrites also have enriched REE patterns, an elevated initial Sr ratio (0.709) and a peraluminous-siliceous nature which suggest they resulted from the partial melting of continental crust (Wilton, 1984)."

Jan 1, 1985

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By R. G. Gillies, C. A. Shook, W. H. W. Husband

"The current state of knowledge concerning pipeline transport of coal in water slurry form is summarized for the four categories: coal-water fuels, conventional fine coal slurries, coarse coals and stabilized mixtures of coarse and fine particles. Surface chemistry is of dominant importance for coal-water fuels and considerable progress in understanding the role of surfactants has been achieved in recent years. Little generalized research on the flow of conventional fine coal slurries has been done in the past 17years, although innumerable conceptual designs and feasibility studies have been undertaken. Coarse coal slurries are fairly well understood but the model which explains their flow requires more data to be established fully. Stabilized flow mixtures should probably obey the same model as coarse coal slurries but experimental results for stabilized mixtures have not yet been incorporated in a comprehensive theory.IntroductionPipeline transportation of coal in a water vehicle has been employed for many years in coal washeries. It has been used less frequently in hydraulic mining and thermal power station fuel supply systems. The suitability of coal for pipeline transport arises from its moderate specific gravity relative to the carrier fluid and the fact that throughputs are often large and steady over long periods of time."

Jan 1, 1990

By A. G. Roach

IT IS generally stated that the gold ores of Nova Scotia are free-milling, and for the most part this is true. However, there is a certain proportion of the gold finely disseminated throughout the sulphides, notably arsenopyrite, and this gold is definitely not recoverable as &apos;free-milling&apos; gold by amalgamation. The proportion of free-milling gold to total gold seems to vary widely in different localities in the Province and is lowest in deposits of the fissure-vein type. The problem of recovery of these relatively recalcitrant values is usually one of economics, in some plac.es a simple gravity concentrate being of such low tenor that its extraction and subsequent disposal will not bear the costs involved. In other cases, such a high percentage of values escapes from the mortars and plates that concentration is definitely indicated. The size of the mining operation is also an important factor. In the large majority of cases, however, some concentrating step is warranted, even if the resulting concentrate is stock-piled until sufficient has accumulated to justify further treatment.

Jan 1, 1940

By R. Frank Chiappetta, E. B. Wilson

"The maintenance records for AL-60 airlegs at Falconbridge Ltd. are used to demonstrate some of the procedures for the analysis of such data.The data are not representative of pure failure s of one type or another. In fact, the records are for the undefined pseudo-failures which are usually found in industrial operations. However, because the machines are brought to the shop only when inoperative, the individual recorded components are treated as failures. Manual calculations are conducted to show the analysis of variance (ANO VA) approach to determine whether certain data can be combined; only a limited number of the 206 machines being considered. The manual procedures continue with the weighting of the suspensions; i.e. terminations f or reasons other than the failure of the given component. After the data are sequenced in the proper order, the nature or pattern of the data is determined using the Kolmogorov-Smirnov (KS) test.It is recognized that these manual examples must be replaced by compute r methods 10 process voluminous data of this nature. Such programs are developed and available. However, a program called RELCODE is used in this case to correspond to the manual examples and to take into account the suspensions. These analytical procedures form the basis for those studies required for good maintenance management."

Jan 1, 1985

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014

By L. M. Guayacán-Carrillo, G. Armand, A. Noiret, D. Seyedi, S. Ghabezloo, J. Sulem

"The main purpose of this paper is to analyze the convergence measurements in a drift excavated in the Callovo-Oxfordian claystone. The drift axis is in the direction of the major principal horizontal stress whereas the stress state is quasi-isotropic in the drift’s section. The initial geometry of the drift being circular, the anisotropic character of the deformation is taken into account by assuming that the drift shape evolves in an elliptical shape. The convergence measurement data on six different points around the drift are analyzed to identify the main axes of the deformation ellipse, following the methodology proposed by Vu et al. (2013, Rock Mech Rock Eng, 46, 231-246). Then, using the semi-empirical law proposed by Sulem et al. (1987, Int J Rock Mech Min Sci, 24, 145–154), the convergence evolution is fitted independently for each axis of the ellipse. This method permits to distinguish two effects: the face advance effect and the time-dependent behavior of the ground. The results for the two directions of the ellipse axes show very close values for the parameters describing the time-dependent properties of the ground, the distance of influence of the face, and the extension of the decompressed zone around the gallery. Such model can provide valuable insights for predictions of the convergence evolution in the long-term. INTRODUCTIONDeep disposal of radioactive waste has been studied in France for more than two decades. The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. The optimization of supports design for long-term behavior is an important point to develop. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to in-situ principal stresses’ directions. In each drift different sections have been instrumented to monitor the convergence evolution and the rock deformation. Continuous monitoring of the excavated zone around the drifts revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on both the drift orientation and the in-situ stress field (Armand et al., 2014). Indeed, the fractures distribution has an important influence on the convergence of the drifts."

Jan 1, 2015

By Renato Macciotta

The argillaceous formation known as the Opalinus Clay is host to the Mont Terri Underground Research Laboratory. The URL was developed to investigate the hydrogeological, geochemical and geotechnical properties of the formation. Underground excavations at the site are characterized by non-elastic and time-dependent deformations. Excavations trending perpendicular to the strike of the bedding presented relatively minor deformations, however, tunnels parallel to the strike of the bedding showed much larger non-elastic deformations. This paper presents an analysis of the measured response of a tunnel trending parallel to the strike of the bedding in Opalinus Clay. The measured convergence is compared to tunnel experience in weak rocks to assess the tunnel stability.

Jun 1, 2012

"One of the workhorses of the minerals industry is the autogenous grinding (AG) mill and its derivative the semi-autogenous (SAG) mill. These are relatively well understood, but not so Scrubbers. Scrubbers are mechanically of the same appearance/function, so what is the difference between an AG mill and a scrubber? When, or under what conditions should a scrubber be used and when should an AG mill be used? Can the processes within be mathematically modelled?In the past decades, the minerals industry has focused most of its attention on the modelling of unit processes such as cone crushers, HPGR’s, AG/SAG mills and ball mills within conventional processing circuits. Less attention has been placed on the modelling of scrubbers. This paper reviews the difference between scrubber and AG mill modelling, highlighting some of the similarities, with a view to confident comminution circuit designs.Engineering practitioners should be comfortable with these circuit designs and not shy away from considering AG mills for both small and large scale plants. AG mills can treat both harder or softer ore and scrubbers are for only softer ores. This paper differentiates scrubber and AG mill modelling in a similar way that overflow ball mills and grate discharge ball mills are analysed. Smaller scrubbers (600 kW) are suited to small scale soft ore (100-300 t/h) operations. Larger scrubbers up to 2,500 kW have the capability of very high throughput, in excess of 1,750 t/h with soft fine feed ore. AG mills are scalable up to 28 MW and are capable of treating harder ores at rates exceeding 2,000 to 4,500 t/h. Observations are that the specific energy requirements for the mill grinding duty is wide and varied. This is to a large degree the crux of the matter in sizing, as well as, differentiating, scrubbers from AG mills.INTRODUCTIONAG milling is a mature technology that has been used in minerals processing applications for more than 100 years. In the last 50 years, harder metalliferous ores have seen the introduction of steel balls to assist in the grinding/milling action. Tumbling mills used in such a configuration are called semiautogenous mills (SAG). The greater minerals industry is no newcomer to the use of fully autogenous (AG) mills. Perhaps scrubbers are. What is the difference? When should a scrubber be used versus an AG mill? How are they mathematically modelled?"

Jan 1, 2016

By P. Mayer

"Determining the correct mechanism of a boiler tube failure is important for the prevention of future tube failures. Proper corrective measures can be undertaken to alleviate the root cause or causes for a failure only when the correct mechanism is known. A mechanism of boiler tube failure is defined as the process which degrades the tube and produces a failure.An expert system package was developed for use by electric utility power plant personnel during investigation into the cause of a boiler tube failure. It is intended to assist their efforts to recognize and identify a basic failure mechanism that can produce the type of boiler tube failure under investigation. The program guides the user to the most likely failure mechanism by asking simple questions, answers which can be obtained by determining the failure location, type of fuel, and from visual inspection of the failed tube. Expert systems are a form of artificial intelligence which imitate the decision-making process of experts.IntroductionBoiler tube failures (BTFs) continue to be the single largest source of forced outages in fossil fired electricity generating stations. Because of this a concentrated effort is being made to minimize boiler tube failure occurrences. Eliminating boiler tube failures could be worth $5 billion a year to the electric power industry(1).The aggressive service environment of fossil-fired boilers is largely the reason for these failures because the combined effects of stress, temperature, corrosion, erosion and vibration cause deterioration of boiler tube material properties and reduction in wall thickness.Determination of the boiler tube failure mechanism is important for the prevention of future problems. The root cause for a failure can be established and proper ameliorative measures taken only when the failure mechanism is identified correctly. The correct identification of failure mechanism is a complex process which may include many individuals and institutions. Technical specialists in metallurgy, chemistry, combustion, and boiler design frequently cooperate with the station staff in a failure investigation . These individuals rely on personal experience and numerous reports , theories, studies, private communications and investigations concerning the different failure modes and mechanisms."

Jan 1, 1990

By M. A. Mahtab, A. S. Burgess, R. G. Charlwood, P. O. Sandstrom, J. L. Ratigan

"Addressing a current operating and environmental concern, this paper first presents an overview of the design program for an underground radioactive waste storage vault. It then reviews the construction, operational and thermal-mechanical aspects of such a project. The relevant experience from major underground construction projects is reviewed and the paper concludes with brief comments on the design-oriented research and development requirements . 1. IntroductionA program to develop techniques for the ultimate disposal of high-level radioactive waste into geologic formations was announced by AECL in 1975 (Tamrnernagi, 1976), and is discussed more fully in a later document (Boulton, 1978). Our paper summarizes the studies caried out, as part of the AECL waste management program, by the authors and associates on the development of design concepts for a vault situated in crystalline rocks of the type present in the Canadian Shield.The design studies have been carried out in three phases, the elements of which are described in Section 2.1 (also see Fig. 1). The general vault designs are presented in Section 2.2. These provide for emplacement of either immobilized fuel or solidified reprocessing wastes in a room-and-pillar facility at a depth of 1,000 m.Section 3 reviews the principal design considerations from the construction, operation and thermal-mechanical response aspects. The concepts have been studied in both temporal and spatial domains, and the requirements and responses assessed in each as appropriate.Section 4 briefly reviews the availability of relevant experience from previous major underground construction projects. Finally, in Section 5, brief comments are given regarding design-oriented research and development requirements."

Jan 1, 1980

By M. Brochu

In this paper, we present a computer-vision approach developed for wall-thickness measurements of corroded pipes inspected by double-wall radiography. The main objective of the work is to optimize data collection and film interpretation using computerized image analysis. To date, the system is able to identify the inner and outer contours of a pipe and perform wall thickness measurements at each pixel of a radiograph. This will be presented by analysing pipes having different dimensions. Another important feature of the system concerns the algorithms&apos; adaptability to pipe wall texture. In other words, image analysis is automatically refined around rough or corroded areas. This allows more precise thickness measurements and shape identification in critical sections as will be demonstrated with examples. Finally a brief overview of results exploitation will be given and compared with human interpretation. It will show the reliability of automated image analysis and the many possibilities offered by complete output analysis.

Jan 1, 2005

By C. M. Acuna, M. Sherrington

In high temperature processes thermodynamic equilibrium is assumed and therefore chemical potential of elements, among the condensed phases, have to be the same. In such situation impurities distribute accordingly and their fractional distributions are affected by the masses of the coexisting phases. It has been claimed Teniente Converters perform quite well for smelting high impurity concentrates, especially in respect to volatilization and/or slagging. Production of high matte grade near white metal composition, requiring moderate oxygen enrichment in the process air, results in a huge mass of gas and therefore a high fraction of impurities report to it. Similarly, by recycling different sources of slag, flue dust or other materials, the mass of the final slag is increased and so do the masses of impurities reporting to the slag. Nevertheless, above a certain level the recycling of smelter byproducts is no longer feasible and the cycle has to be halted, unless higher impurity mattes are accepted. Although the process might be continued during converting and refining, lengthy and expensive measures have to be taken if suitable anode copper for electrolytic refining is to be achieved. In the present study samples of high arsenic matte grade and slag were obtained on a pilot scale. The matte samples, on the order 75%Cu, were equilibrated with slag at varying ratios in magnesia crucibles under CO/C02 atmospheres at 1523 K. After 24 hours equilibrium matte and slag were rapidly solidified and analyzed by copper, sulfur, iron and arsenic. Furthermore, industrial samples of matte and slag, in the order 75%Cu at 1523 K, were obtained via a special quenching sampling device to determine the association of copper and suspension of matte and copper in slag. Based on the results, the distribution coefficient of arsenic between slag and matte was evaluated along with copper species in slag and the fractional distribution of arsenic, in the coexisting phases, was determined as a function of the ratio mass of slag to mass of matte.

Jan 1, 2007

By Dave N. K., T. P. Lim

"A fast, reliable and accurate method for radium-226 determination in environmental water samples has been devised, using an alpha spectroscopic technique. The correlation between barium-133 and radium-226 in the barium-radium sulphate precipitation mechanism was studied and in the limited experimental recovery range, the coefficient of correlation was r = 0.986. A self-absorption study for various barium carrier concentrations was also undertaken to obtain the least broadening of alpha energy line widths. An optimum value of 0.3 mg barium carrier was obtained for chemical recovery in the range of 85%.IntroductionWith the increase in uranium mining activities, the migration and spread of radioactivity via various environmental pathways is of great concern. Because of its inherent biological hazard and relatively long half-life, (approximately 1620 years), raidum-226 is frequently monitored as a measure of radioactive contamination of the environment. It is, therefore, necessary to modify existing methods for rapid determination of radium-226 in environmental samples for quick corrective measures in the event of seepage, dam leakage or discharge violations."

Jan 1, 1981

By K. Sakai, M. Miyaue, T. Aoki, T. Tani, S. Tanaka, N. Kudo

In the planning stage of a tunnel, due to limited technology in the geological survey and the financial restriction, tunnel supports are often designed from unsatisfactory information, and the tunnel construction is started. Therefore, "Information-oriented construction" is carried out in the construction stage, in which the design is rationally verified and modified by observations/measurements. Moreover, the ground conditions ahead of a tunnel face must be predicted for efficient and safe tunnel construction. The authors have examined effective prediction methods to the ground conditions ahead of a tunnel face under construction of mountain tunnels (Aoki et al., 2010) in view of the established method (Schubert et al., 1995). Though the prediction method of Schubert requires the displacement in the direction of tunnel axis, it is difficult to obtain its accurate data by the electronic distance meter. Then, we have proposed a method that uses tilt sensors installed at the tunnel crown near the face to obtain the slight tilting information. To measure inclination of the tunnel crown, this inclinometer was originally developed as a daily control measurement, such that the geological condition and its possible change behind the face could be detected early, and a steady advance and construction safety could be ensured. This paper describes the method of forward prediction mechanism and advantages of this suggested method. It then presents the typical results of a field verification test at a tunnel under construction and an example of evaluation of the ground conditions ahead of the face based on the 3D numerical analysis in three types of condition changes of ground deformation moduli.

Jan 1, 2015