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By R. R. Stone

"This paper will examine the role of debt and equity in project financing and will illustrate the impact on the return to the project sponsor of each type. Conventional debt sources will be examined, as will product purchaser advances, foreign export-import bank loans and lease financing. The paper will review guarantees, charges against the project, dividend restrictions and other commitments. It will also discuss various features of sales contracts and the degree to which they can assist in securing financing. IntroductionThe cost of bringing new mining projects on stream is escalating significantly more rapidly than general rates of inflation. Reasons for this include the higher costs of safeguarding the environment and ensuring the health and safety of workers. The need to develop properties in more remote areas is also a significant factor. These higher costs have not been matched by increases in metal prices, making the task of financing these projects ever more difficult. At the same time, the imagination of borrowers and lenders seems boundless, and innovative schemes for financing projects are constantly being unveiled.It is probably safe to say that no two projects have ever been financed in precisely the same way and the number of financing options for any project is limited only by the imagination of the sponsors themselves. The objectives of the project sponsor represent the most important factor in determining the scope of possible financial arrangements. For example, the sponsor may wish to maximize over-all company leverage by isolating each of its projects in separate companies. In so doing, it hopes to facilitate more ventures than would otherwise be the case. These objectives point toward true project financing. Additional objectives may be to develop a number of its properties by joint venture and to reduce the amount of debt on the sponsor's balance sheet. Those sponsors whose objectives include minimizing over-all financing costs will wish to increase the number of financial options and, as a result, will not be so concerned with effecting true project financing. This approach may also provide ""greater certainty that tax benefits are utilized quickly."

Jan 1, 1980

By Joseph Bradley

THROUGHOUT this article, minerals used in the paint industry are designated 'pigments'. They may be classified in two groups: (1) Pigments which are used in the state in which they occur in nature, requiring only mechanical preparation. (2) Pigments which require heating or chemical treatment before use, in order to obtain from them a product of the desired quality or shade of colour. They may be further classified according to colour, as follows: White Pigments .-These include calcium carbonate (chalk, marble), gypsum and alabaster, kaolin-or china-clay, and magnesia. However, the white pigments most extensively used are compounds prepared chemically from minerals containing lead, zinc, titanium, and antimony. The white pigments are of particular importance because, not only are they used by themselves, but they also serve as adjuncts to other colours for the production of special shades. Yellow Pigments.-These are mainly naturally occurring ferric hydroxides, as limonite and bog iron ore, or similar. compounds prepared artificially. Brown Pigments .-Pigments of this group are distinguished for their beauty and depth of colour, and many of them are used in the finest of paintings. Familiar names are sienna, umber, and Vandyke brown. They are for the most part ferric hydroxides, containing varying amounts of water; but the group also includes a manganese brown, which consists chiefly of a mixture of oxide and hydroxide of manganese. Red Pigments.-Chief among this group is ferric oxide, known under various trade-names, such as Canadian red, Persian red, etc., and also the much prized and somewhat rare vermilion. The pigment used is either naturally occurring hematite, de-hydrated limonite, or artificially produced red ferric oxide.

Jan 1, 1937

By W. A. Crosby, W. K. Smith, K. L. McDonald

"IntroductionThis paper describes how the introduction of two blasting techniques and the resuItant development of new dragline digging methods have increased the productivity of single- and double-seam dragline operations at the Rietspruit opencast mine.LocationRietspruit , one of South Africa's largest opencast strip mines, is situated some 11 5 kilometres east of Johannesburg in the Witbank coal field.BusinessRietspruit is a joint venture between Transvaal Consolidate d Land and Exploration Company (T.C.L.) and Shell, South Africa. Rietspruit is administered and managed by Rand Mines, the Mining division of Barlow Rand, transportation and marketing being the responsibility of Shell. The total saleable coal product, approximately 5,5 million tons per annum, is exported via Richards Bay.Presplitting and Throw BlastingPresplitting was initially introduced in September 1980, as a means of dewatering t he overburden and mid burden to facilitate the use of dry-mix explosives a s opposed to slurry explosives.The utilization of the throw blasting technique arose as a direct result of observed ground movement after the successful introduction of presplitting. The first trials commenced in March 1981 on the double-seam operation. The methods, economics and resulting advantages are fully described elsewhere. A brief description follows.Method of PresplittingAfter determining the desired presplit line, 250-mm holes are drilled to top of coal at 4-m to 6-m intervals, dependent on the competency of the rock overlying the coal. A single 60-kg charge of slurry explosives is located at the bottom of each hole, no tamping is used and all the holes are detonated simultaneously. The results are a competent, straight, vertical highwall. This enables accurate control of the first row of blast holes closest to the highwall, which is a prime requisite for successful throw blasting."

Jan 1, 1983

By R. Gatzweiler

The Key Lake nickel-uranium deposits are situated within the Wollaston domain of the Churchill structural province. The host rocks of the two orebodies are of Aphebian and Helikian age. The orebodies occur mainly within a 5.2-km-Iong, northeast-trending zone which coincides with the intersection of the sub-Athabasca unconformity and a reverse fault striking east-northeast. The principal controls of mineralization are structural and lithostratigraphic (i.e., post-Athabasca faults, the sub-Athabasca unconformity and graphitic metapelites in the lower Aphebian, close to the Aphebian/Archean unconformity). Grades of up to 35% U3O8 and 20% Ni are recorded over intervals of up to 2 m. Some hypogene zonation exists and the nickel mineralization tends to underlie the high-grade uranium ore. The ore minerals include pitchblende, a-U307, coffinite, gersdorffite, millerite, niccolite, bravoite, zoisite, sericite, chlorite and kaolinite. The kaolinite is a post-ore, supergene alteration product. Chemical studies of the sub-Athabasca paleo weathering profile sho w that regolithization is characterized by depletion in Si02 and K20 and concomitant enrichment in Al203 and perhaps MgO. In the paleoweathering profile the ferromagnes ian minerals are chloritized, the Ksfeldspars sericitized and the plagioclase saussuritized. Preliminary geochronologic data from the ores reveal U/Pb ages of -1228 my, - 960 my and 89 my, and Rb /Sr data indicate basement ages of -1850 my and - 1372 my. Aphebian pelitic protoliths, carrying U and Ni, may have released some metals during post-Hudsonian weathering, and minor concentration in structural and geochemical traps may have taken place prior to the deposition of the Athabasca strata. However, it is felt that the bulk ofthe ore-grade mineralization wasgenerated after the deposition of the Athabasca formation and after faulting, probably during a major regional thermal/ intrusive episode of Grenvillian age. Several episodes of remobilization took place between 1228and 89 my ago.

Jan 1, 1979

By Y. H. Hatzor, D. Bakun Mazor

"A new model for thermally-induced block displacement in discontinuous rock slopes is being explored inside a Controlled Climate Laboratory (CCL). The model is based on a hypothesized wedging mechanism that takes place inside the filled tension crack of a discrete block that rests on an inclined plane. Irreversible block sliding is assumed to develop in response to climatic thermal fluctuations and consequent contraction and expansion of the sliding block material. While an analytical expression for this model is already available, we are exploring the possibility of obtaining such a permanent, thermallyinduced, rock block displacement, under fully controlled conditions in the laboratory, to enable effective analysis of the sensitivity of the mechanism to geometry, mechanical properties, and temperature fluctuations.A large scale (approximately 0.5 m3 in volume) model consisting of four blocks has been installed in the CCL. The CCL permits accurate control of atmospheric temperature (?0.5 °C) from 6 °C to 45 °C. Harmonic temperature function is planned in advance and is controlled by a computer program throughout the experiment process. The minimum length of the temperature cyclic period for thermally-induced block displacement is calculated here based on the existing analytical model.Due to the fact that this experiment is still in progress, preliminary results will be available in the next few months. The obtained results may explain sudden triggering of rock slope failures that are not correlated with common failure triggers such as seismic activities, pore pressure build-up, or freezing and thawing of water inside rock joints."

Jan 1, 2015

By X. J. Luo, F. Zhang

"Metallurgical slag (MS) such as steel slag, copper slag is a renewable resource and its compressive strength exceeds 200MPa in general. Because pure metal slug can easily be mixed into MS, complex recycle system is necessary in order to realize MS’s recycling. Meanwhile, there is high equipment failure rate in conventional crushing system. New crushing systems with inertial cone crusher could solve this problem very well. Recovery rate of MS tailings requires that crushing product can’t contain too much oversize product, so the essential equipment include two crushers and one sieve in the traditional crushing system. The new crushing system which only includes two crushers can meet the requirement and simplify the crush process. Investment of crushing equipment and infrastructure can be cut down. Operating and maintenance costs can be obviously reduced due to the simple process, which also could achieve high energy saving and excellent economic efficiency.INTRODUCTIONMetallurgical Slag (MS) such as steel slag, copper slag is a typical industrial solid waste and it threatens our environment’s safe. Metallurgical enterprises must take action to settle these wastes in order to protect our environment. Because pure metal slug can easily be mixed into MS, its uniaxial compressive strength (UCS) will exceed 200Mpa. If crushing station employs traditional crushing equipment, equipment failure will be easily caused because of these pure metal slugs. Coarse crushing equipment usually adapts jaw crusher in traditional Crushing technology and rod mill will be utilized to finish the secondary and fine crushing works. And the same time screening machinery should be used to ensure the suitable particle size (Figure 1)."

Jan 1, 2016

By Margaret Armstrong, Normand Champigny

"In order to define the ore/waste boundaries as finely as possible, mine planners often insist on kriging very small blocks (relative to the spacing of the available sample grades). These kriged estimates for very small blocks are over-smoothed. For several simple sampling patterns the relation between the block size and the variogram range, and the kriging results were studied. Meaningful estimates of individual blocks are obtained when the variogram range is large compared to the block size and the sample spacing. For a variogram range less than half the sample spacing, the kriged block estimates were found to be uncorrelated with the actual grades. The over-smoothed estimates should not be used for calculating recoverable reserves IntroductionNowadays most mining companies know that the geostatistical estimation method, kriging, gives the best estimates of individual block grades. As most mining engineers and geologists are now familiar with the basics of geostatistics, the definitions of the variogram and of kriging will not be repeated here. An appendix containing definitions and mathematical formulae is given at the end of the article for the sake of completeness.Even though it is well known that the kriged estimates for very small blocks are over-smoothed, mine planners who want to define the ore/waste limits as finely as possible (especially for selective underground mines), are often tempted to krige very small blocks. So we ask how small is ""too small""? Clearly ""smallness"" cannot be expressed in yards or metres. It depends on the nature of the orebody under study and this is reflected in the variogram model chosen to describe it.To answer this question, the changes in four key parameters are studied:• the kriging variance,• the variance of the estimated grade,• the slope of the linear regression of the true but unknown grade on its estimated value, and• the coefficient of correlation between the actual grade and the estimate;as a function of the block size and the variogram range. (Definitions of these four parameters are given in the appendix). Ideally the kriging variance should be low while the variance of the estimated grade should be equal to the dispersion variance of the blocks. The slope should be l.0, and so should the correlation coefficient.These four parameters have been calculated for several simple 2-D examples. The effect of using kriged block estimates that are too heavily smoothed are shown, and the dangers of trying to use these estimates for predicting recoverable reserves for small blocks (i.e. selective mining units) are pointed out."

Jan 1, 1989

By H. Weissenbaeck, B. Nowak, M. Oesterreicher, R. Stastny

The producers of certain metals like nickel and cobalt increasingly face a shortage of easy-to-mine and easy-to-process ore bodies. Their focus is shifting towards alternative raw materials which in turn demand new, different extraction techniques. One potential route for processing a ferrous ore with a non-ferrous target metal is atmospheric leaching with hydrochloric acid followed by purification of the pregnant leach solution (PLS). For the separation of iron from the PLS, and, in turn, the extraction of the non-ferrous compounds, the following flow sheet is proposed. Pre-concentration of the PLS, oxidation of ferrous (if present) to ferric chloride, hydrolysis of ferric chloride leading to the precipitation of hematite and the evaporation of hydrochloric acid, followed by crystallization of non-hydrolysable metal chlorides by means of sparging hydrogen chloride into the solution. Hydrogen chloride required in the latter step is produced internally by super-azeotropic distillation of regenerated hydrochloric acid. The liquid filtrate from the crystallization step is recycled to hydrolysis. Depending on the specific composition of the PLS, the hematite produced contains only traces of other impurities, whereas the crystallized mix of non-hydrolysable metal chlorides – containing also the target metal in enriched form – contains ferric chloride only in an amount referring to the filter cake moisture. These crystals can then undergo further hydrometallurgical separation and extraction processes. As an example, this flow sheet is proposed for treating nickel laterite ores. Experiments related to the demonstration of crucial assumptions in the flow sheet are presented. Based on those experiments a mass and energy balance of the flow sheet was calculated and is presented here together with a table of the major consumables in order to provide a basis for an operating cost estimate and other process economics.

Jan 1, 2016

By D. A. Whitley, R. P. Carone

"Shaft sinking by blind shaft drilling offers the mining industry a different approach to shaft construction. Benefits of blind drilling include less construction time and fewer safety problems while being economically competitive with conventional sinking methods under certain conditions in soft water-bearing formations.Technology and equipment are available today to drill blind shafts up to 20 feet in diameter and over 3,000 feet deep. This is an extension of proven techniques developed by private industry. To drill a 20-foot-diameter hole requires a specially manufactured hydraulic drill unit with a rated hoist of 2 million pounds and 500,000 ft/lb of torque.This brief paper will discuss the following aspects of blind shaft drilling:• benefits;• equipment f or drilling;• circulation methods;• circulation rates;• shaft alignment; and• progress rates to be expected.IntroductionShaft sinking by blind shaft drilling offers the mining industry an improved alternative method for shaft construction. The drilling of 20-foot -diameter shafts to depth s in excess of 3,000 feet can be done by utilizing equipment specifically designed and manufactured for this purpose. This equipment is a distant cousin, at best, to standard oil well drilling rigs. The actual configuration of these drilling machines will be discussed in a following section.To most people, the drilling of mine shafts may seem to be a new or at least recent technology. However, as early as the I920s, German and Dutch miners were drilling 24-foot diameter shafts for coal mines. What led ""miners to resort to drilling were ground conditions that still plague conventional shaft sinkers today: soft , water-bearing formations. The major drawback to these early attempts was a low penetration rate due to poor bit cleaning. This, however, was not the end of early shaft drilling activity. From 1936 to 1950, a number of mine shafts were drilled by the calyx or coring method. This method employs a bit with a large bore down the center. As it drills, it cuts a core. When 5 to 10 feet have been drilled, the core is removed. The disadvantages of this method were the time and work involved in breaking the core free, and it was inadequate in soft water-bearing ground."

Jan 1, 1981

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013

By D. Raicevic

After more than 93% of the uranium is extracted from Elliot Lake uranium ores by a sulphuric acid leaching process, the leach residue (tailings) contains small amounts of uranium and radioactive isotopes, particularly radium-226, which is the most serious health hazard. Heavy metal components and pyrite are also present, along with the gangue minerals. Currently, over /000 acres of the Elliot Lake area are covered with these tailings, which contain over five million tons of pyrite. Because of constant oxidation of the pyrite by bacteria (thiobacillus) and the presence of moisture, pyrite slowly generates sulphuric acid, which steadily leaches the metal-bearing constituents from the tailings. The seepage-flows of the dissolved contaminants, although often quite low in volume, have an environmental impact on the Elliot Lake area. Although these seepages are treated and most of the contaminants removed and impounded, a small amount of the radioactive contaminants reaches Lake Huron via the Serpent River. This paper describes a flotation approach for treatment of the Elliot Lake uranium tailings to produce new, decontaminated tailings practically free of pyrite, with radium, thorium and uranium contents considerably reduced. The decontaminated tailing produced, which comprises about 75% by weight of the current uranium tailings, appears to be suitable for mine backfill. Because mine backfilling normally uses about 50% of the plant tailings, the surface storage of about half of the uranium tailings, therefore, would be eliminated by this process. Mine backfilling would also increase the mine production and thus enlarge the over-all uranium resources due to recovery of the ore from pillars. The pyrite concentrate produced from the current uranium tailings would be suitable for sulphuric acid production. The possibility of uranium recovery, and disposal of radium and thorium from the concentrates produced, is now being studied at CANMET.

Jan 1, 1979

By Colin Jones

Canadian Clay Products Inc., which mines bentonite in Saskatchewan near Truax and operates a plant at Wilcox, is the sole producer of swelling bentonite, often called western bentonite, in Canada. Seven products produced by the company are used in binders, sealants, water and waste water treatment, plasticizing agents, foundries and absorbents. Reserves are reported at about one million tonnes for the deposit but the area in general contains significant additional reserves.

Jan 1, 2001

By Sarah Belair, Gauthier Deblonde, Valerie Weigel, Alexandre Chagnes, Gerard Cote

"Niobium and tantalum are strategic metals for electronic and alloys industries. They are produced by pyrometallurgy and hydrometallurgy but most of the niobium and tantalum production processes are not environmentally friendly. For instance, in the hydrometallurgical route, niobium and tantalum separation can only be achieved by liquid-liquid extraction in the presence of hydrofluoric acid by taking advantage of the difference in niobium(V) and tantalum(V) speciation in fluoride-based media. Therefore, the environmental footprint of hydrometallurgical processes for the production of niobium and tantalum could be clearly lowered by replacing HF or NH4F by greener media such as alkaline solutions in which high solubility of niobium(V) and tantalum(V) can be achieved.The development of such new efficient and environmentally friendly hydrometallurgical processes requires a fine description of the physicochemistry of niobium(V) and tantalum(V) in alkaline solutions. Unfortunately, literature data show a huge discrepancy on niobium(V) and tantalum(V) speciation in such media. This paper gives a brief overview of the niobium(V)-tantalum(V) production processes and paves the way to the development of alternative processes in alkaline media by presenting and discussing recent advances in the physicochemistry of niobium(V) and tantalum(V) in these media.INTRODUCTIONNiobium and tantalum are strategic metals since they are used for the production of alloys and super alloys, capacitors and magnets in strategic industries such as electronic, aeronautics and automobile. The main sources of niobium and tantalum are given in Table 1."

Jan 1, 2016

By I. Kylmakorpi

In non-ferrous metal smelting, when the concentrate entering the furnace contains high levels of moisture, energy requirement for heating and drying increases and large volumes of exhaust are produced. To solve this problem, rotary dryers and flash dryers using direct heating, and also steam dryers using indirect heating have all been used for drying concentrate. The focus of this paper is to present the development and current applications of the Kumera Rotary steam dryer. The advantages of this technology are numerous, including reduced heating requirements, environmental friendliness, operation reliability and minimum maintenance needs; making it a top choice for drying concentrate.

Jan 1, 2008

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By Russell A. Luke

"Modular Mining&apos;s computerized LHD position monitoring and dispatching system commenced operation at the De Beers Finsch Mine in mid- J99J. A sophisticated blend of proven and new technologies links the dispatcher at the workstation console on the surface with the LHD operators several hundred metres below. The dispatcher allocates each LHD to a priority tip and loading drive based on instructions provided by the miners and shift bosses underground. LHD operators receive tip and loading drive allocations on the vehicle computer console which communicates data via a Leaky Feeder radio network. The operators interact with the console to notify the dispatcher of delays, breakdowns, and changes in tip and tunnel status. The underground terminal displays allow shift bosses to monitor the progress of the LHDs as they pass infrared beacons (IRs) located in the tips loading drives and rim tunnel main haulage ways. The terminals also provide on-line statistics for the current and previous shifts. Future enhancements include optimized dispatching and interfacing to a PLC system controlling ventilation. Further, token ring-based loop UHF radios are being investigated as an alternative to the Leaky Feeder data radio network. IntroductionFinsch first contacted Modular about an LHD monitoring and dispatching system in late 1988. At that time, Modular declined a request for a formal quotation but agreed to perform an engineering feasibility study. The study was issued in mid-1989 and confirmed Finsch&apos;s belief that an underground system could be developed with technology available at that time. A contract for the system was signed the following year and, in May of 1991, the system began operation. By the end of 1991, LHDs on both production levels of the mine were under the control of the system."

Jan 1, 1993

By Rob Scott

Making a difference with Zinc & Health Two billion people do not get enough zinc in their diets. Every year 450,000 children die from complications arising from zinc deficiency Our Zinc Alliance For Child Health partnership with CIDA and Micronutrient Initiative, our involvement with UNICEF through the IZA and our partnership with BASF are gaining wide recognition. Sustainability at Teck ? Integrating into our Core Business Strategy Our strategy Long term goals Our approach Managing risks and finding opportunities Our progress Early reports Moving Forward Metrics and indicators

May 1, 2013

By Mario Giavani

"IntroductionBy the 1980s, the continuous casting process had almost replaced the ingot casting of steel in Japan, Europe and North America. While economic benefits were probably initially the prime motivator, the transition rapidly proved that continuous casting in conjunction with ladle metallurgy offered a much greater degree of process control and made possible routine steel specifications not previously available.This new technology demanded improved procedures for the quantitative addition of the required metallurgical reagents, especially as regards the more volatile or toxic elements such as calcium , boron, carbon, sulphur, lead and tellurium. The injection of a thin steel tube containing the additive into the metal bath of a ladle refining station offers the best procedure for this. In the industry this has been referred to as ""Cored Wire "".Operators using this technology find that they are faced with balancing the injection speed against the small cross section of the tube to feed the required amount of reagent within the short time span available to the operation. Large-ladle shops requiring major quantities usually resort to multiple machines and high speeds. Many machines approach a maximum feed rate of 400 m/min. Higher speeds exceed the melting rate of the system, and the ferro static buoyancy of the tube will cause it to coil up the ladle wall and possibly resurface into the slag layer, and even eject itself above the surface. Under these conditions, exact control of element recovery becomes difficult, especially with the commonest addition, calcium silicon alloy.Many experts are persuaded that the final melting position of the carrier tube has major importance in establishing consistent element yield to the bath.For instance, the vapour pressure of calcium at l500 °C is close to I bar. Reaching a melting depth sufficient to accommodate this value is considered to be critical to achieving an acceptable and reproducible yield.Many studies have elaborated semi-empirical formulae to establish the melt zone depth, connecting this value essentially to the diameter of the tube , the injection rate and the superheat of the steel. The author&apos;s experience in steelmaking could not confirm such formulae in many cases, and he set about to develop a mathematical model which would be useful in addressing this problem, taking into account the several parameters which will regulate the behaviour of a filled tube immersed in molten steel."

Jan 1, 1991