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By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

The effect of long term exposure of full size bolts to corrosive environments is presented. A special test rig was used to test four bolts under different loading conditions. Four, X-grade identical profile bolts, each of 21.7 mm core diameters (23.7 mm full diameter) were subjected to prolonged corrosion testing using acid sulphate water. The pH value of the circulated water varied between 3.4 and 4.3. The corrosion exposure test period lasted three and half years. Two bolts were axially loaded to 10 and 20 tonnes force respectively, the third bolt was subjected to a 360 Nm torsion load and the fourth bolt was left unstressed to act as a reference bolt. After the test period ended, the bolts were stripped of their corroded coatings and weighted for weight loss. The diameter of each bolt was subsequently measured, and the loaded bolt samples were first tested non-destructively for tensile cracks and then tested for tensile failure. No cracks were found on post corrosion bolts tested non-destructively. The failure strength reduction on all four post-corroded bolts was significant, varying between 21% and 39%. The onset of corrosion was not confined to the targeted mid-section length of the bolt, however, the severest corrosion occurred at the anchored ends of the bolts.

Aug 1, 2013

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By P. M. Pearson

This paper describes the principles ()f systems engineering and their application to the various transport problems confronting the mining industry. The organization of mining operations into sub-system design problems is explained.

Jan 1, 1970

By Robert Lamarre

We will present the summary of a number of case studies whereby mining organizations have succeeded in maximizing equipment uptime by reducing the number of maintenance parts stock outs by more than 80% while scaling down total inventory maintenance parts by more than 20%. We will present a thorough comprehensive methodology to improve business processes in order to optimize inventory management and forecasting. We will examine: ? Demand management optimization ? Forecasting organization ? Inventory management parameters optimization ? Improved replenishment processes ? Inventory optimization and the right KPIs and exception reports We will provide cases in point such as Areva in Africa, Cambior (IAMGOLD) in South America, Osisko Mining Corporation, Barrick Gold/Bousquet Mine and Aurizon Mines Ltd./Casa Berardi in North America. We will discuss how Inventory Management World Best Practices operates in a maintenance environment. We will present how an integrated approach, coupled with a strong Enterprise Asset Management or CMMS system with an Inventory Optimization system specially designed to manage spare parts, actually promises and delivers results.

Nov 1, 2011

By E. Ozberk, N. Gibson, W. G. Davenport

"In the 1950s, Canada produced more than ninety-five percent of the non-communist world's nickel and achieved dominance in terms of production, technology and pricing policies.Over the past thirty years there have been dramatic changes in the nickel industry to the extent that Canadian production is now less than thirty per cent of the total.In this document we have presented statistics relevant to this transformation and reviewed the technology, particularly with regards to energy and environmental considerations.Under the new market conditions nickel producers are likely to face more difficult competition than they have encountered in the past.The economic scene and measured nickel reserves dictate that for the purpose of increasing production, new nickel smelters will not be built in Canada in the foreseeable future. However, in order to reduce sulphur dioxide emissions, Canadian nickel smelters will possibly go through some modifications or rebuilding.IntroductionThis paper presents a review of the Canadian nickel industry in relation to the world nickel industry. Major changes are described which have occurred in the characteristics of the nickel market over the last thirty years. The pre sent status of the nickel market with respect to Forecasting future trends is reviewed and attempts are made to predict what further changes will take place in the next two decades. Comparisons are made of the economics of producing nickel from sulphide ores and oxide ores and the advantages and disadvantages the Canadian nickel producers face.A brief critique of the existing and emerging nickel production technologies in Canada and the world is carried out and attempts are mad e to predict the changes which may take place in the foreseeable future."

Jan 1, 1983

By K R. Brentley

"Tshepong Mine, Harmony’s largest gold producing mine, is situated in the Free State portion of the Witwatersrand Basin, east of Odendaalsrus and north of Welkom, South Africa. The Basal reef is a narrow tabular conglomerate and is the main gold bearing ore body. The strata strikes mainly in a northsouth direction with an average dip of 22 degrees. Currently mining takes place at depths of between 1 690m and 2 150m below surface. The Basal reef unit consists of a conglomerate ranging between a few and 30cm in thickness. Some 80-90% of the gold occurs in the lower portion of the conglomerate. Directly above the conglomerate is a quartzite placer unit, the Basal quartzite, which is a clean, hard competent rock and varies in thickness between 50cm and 200cm. The Basal unit is overlain by the Khaki shale which can vary between 30cm and 500cm in width. It is weak and incompetent khaki coloured chloritic shale.A method of stoping, termed “undercut”, is practiced in order to remove the lower 15-20cm of the gold rich strata. The method entails removing this portion along with some 70-80cm of footwall host rock which is a strong competent quartzite. The hard competent quartzite overlying the conglomerate is left in-situ to form a competent hangingwall which can stabilize and prevent exposure of the weak Khakishale. This method of extraction was developed through trial and error and has been used reasonably successfully since its inception in the early 1960’s where the method was developed to extract the Basal reef at the Western Holdings Mines. Recently prospect drilling and a number of localised hangingwall failures indicated that the residual quartzite beam could be less than 60cm and in some instances as thin as 30cm in certain areas of the mine. The result of this is a less stable hangingwall which not only poses a safety risk to workers in these areas but also had the potential of locking up some 840 000 Tonnes of gold bearing ore. At the present gold price this amounts to revenue of approximately ZAR1.5 billion (U.S. $143 million).This paper discusses the method of “undercut stoping” and existing practices in place at Tshepong Mine. It also explores new initiatives such as the use of a simple freely-supported elastic beam solution to perform back analysis, on-site data capturing of beam thickness and support geometries in order to develop empirical design charts and numerical modelling to assist in the verification of the empirical design method."

Jan 1, 2015

By Michael J. Sapko, Ellsworth R. Spencer, Frank J. Perzak

"The fire resistance of several mine conveyor belts is evaluated using a new belt-flammability apparatus developed by the U.S. Bureau of Mines. The test apparatus, experimental details and a calculated flammability index (FI) are described.The FI values are useful for ranking the fir e resistance of mine conveyor belts. Values are determined using parameters readily measured with thermocouples, high-temperature flow probes and a methane-oxygen torch, all of which are components of the Bureau's new test apparatus. The FI varies directly with the flame-spread rate and the rate of heat release during burning and varies inversely with the critical (minimum) ignitor energy output.The fire-resistance ranking of nine different belt types using this moderately scaled apparatus is compared with available full-scale data on belt fires. This comparison shows that the ranking based on the FI is consistent with the full-scale data.IntroductionFull-scale fire hazard evaluations of mine conveyor belts are not easily related to the properties usually measured in small-scale flammability tests. The inadequacy of small-scale belt fire tests has been demonstrated in works by Mitchell, Warner and Reinke.Mitchell and Warner showed that certain neoprene (NP) and polyvinyl chloride (PVC) belts, which had been approved by the Code of Federal Regulations 30 CFR 18.65, were nevertheless capable of propagating flame over their entire length when full-scale fire conditions were simulated. Comparable results were also observed by Reinke at the Tremonia experimental mine in Dortmund, West Germany, where all belts burned in full-scale tests even though they passed the small-scale tests. Only by reducing the severity of the full-scale test could these fire-resistant belts be grouped on a pass-fail basis."

Jan 1, 1982

By Mihaita Matei

An adaptive approach to control the deformation in tube hydroforming process is presented. This requires: the use of an existing non-linear FE software (ABAQUS) that incorporates a user material model (VUMAT), the development and implementation of an adaptive control strategy to coordinate the internal pressure and the axial load so as to prevent fracture and wrinkling failures (knowledge-base controller) and the application of the developed adaptive simulation approach for finding the optimal loading path required to hydroform a defect-free part with as uniform thickness distribution as possible (user's load subroutine (VDLOAD). In order to validate the approach, the case of conical hydroforming and the case of bending followed by hydroforming component is discussed.

Jan 1, 2011

By V. Bruned, K. Mohamed, A. Michaut

Orano Mining Somaïr uranium treatment plant (Niger) uses a pugging-curing process to leach uranium. Sulfuric acid, nitrates and water are added to the finely grinded ore in a rotary drum to leach uranium bearing minerals and solubilize uranyl sulfate ions. Reagents, sulfuric acid and nitrates, are the main OpEx of this process step. The economical optimization of their addition requires a thorough knowledge of the ore behavior in solution with these reagents. Orano Mining technical direction and Somaïr laboratories developed a model to predict the curing process uranium recovery surface with a limited number of parameters. Experimental laboratory work to fit the model needs to be done for each type of ore which can require a lot of metallurgical tests and would be time consuming. In order to optimize the required number of tests, an innovative experience plan was designed in parallel to the development of this model reducing the required number of tests to only eight. Once the parameters of the models are correctly fit, the comparison between the estimated values and the actual values for the uranium recovery is excellent (less than 0.5% error in average). Associated with an updated cost model of the curing process, this new recovery model helps the plant operator find the best set of reagents to maximize curing process profitability in the Somaïr plant day after day.

Jan 1, 2020

By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling's T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007

By A. Mular, T. Bond, G. D. Farnell, J. F. Kingston

"ABSTRACT:-A 60—cm semiautogenous grinding-(SAG) mill was designed -for continuous wet operation in closed circuit with a vibrating screen. The circuit is fully instrumented and automated. Part of the control system incorporates Foxboro SPEC 200 controllers around the pump box to maintain level. The rest of the control system involves an ACTION model BC2 basic direct digital controller that handles all other inputs/outputs and contact closure sensing:·The success of the control system is attributed to the uniqueness of specially designed mass flow metering systems. Various control strategies are possible. Employed to date has been control of a mill load set-point by cascading the deviation from load set-point as the set-point to the fresh feed rate ""controller"". Mill feed water is ratioed to total flow rate of solids fed to the mill. The performance of the circuit is being correlated with the performance of full scale SAG circuits in British Columbia to develop models, to assess the feasibility of scale up and to investigate the effects of design variables on responses such as circuit throughput. 1 INTRODUCTIONWhere ore types are appropriate, semiautogenous grinding and/or autogenous grinding (AG) has replaced conventional grinding. Secondary/Tertiary crushing plants are thereby eliminated so that capital expenditures are less and overall comminution costs can be lower (Barratt 1982). To establish the suitability of an ore for SAG circuits, pilot scale tests with 1.7 to 1.8 M diameter mills are often conducted. At least one test per ore type in a deposit has been necessary. Often, each test involves a large amount (up to 50 tonne) of sample, so that the testwork can be expensive and may discourage the use of SAG or AG circuits. However, MacPherson (1977) has employed a continuous 45 cm dry Aerofall mill circuit closed with screens and an air classifier to determine whether ores are suitable for SAG milling. The amount of sample per ore type is of the order of 60 kg or less. Thus an established SAG mill scale up procedure that employs small circuits is highly desirable.The purpose of this paper is to describe a small 60 cm wet continuous SAG/ AG mill pilot circuit assembled at the University of British Columbia to study the feasibility of scale up, to assess the influence of design variables, to develop mathematical models and to evaluate the effects of alternative control strategies on circuit performance"

Jan 1, 1988

By M. Sukhram

This paper presents a technique to determine the direction of velocity in liquid aluminum (Al) by measuring the temperature distribution within a cylindrical rod while it is inserted into the flow. The heating pattern of the rod is a result of the interaction of the thermal fields of the rod with the liquid Al. This interaction freezes aluminum onto the cylinder in a characteristic pattern and as a result the temperature response within the rod also follows a distinctive heating pattern. Monitoring the temperature within the cylindrical rod as a function of spatial and temporal coordinates, the direction of velocity can be inferred. Experimental research work involving liquid Al was conducted at the University of Toronto using the Revolving Liquid Metal Tank (RLMT). The RLMT is a resistance furnace which can hold up to 50kg of liquid Al. In this RLMT tangential velocities up to 0.35m1s can be generated. Experimental data for different superheat and magnitude of velocity demonstrate that the sensor records different heating patterns under different fluid flow conditions. Using the transient temperature information, the direction of velocity of the molten Al flow field can be detected.

Jan 1, 2011

By Jochen Franke, Matt Bird, Thoma Perkins, Malcolm Powell, Jason Robertson, Paul Toor

zThe operation of SAG mills is variable over time due to their continually changing liner shape, mass and subsequent load motion. However, this tends to be poorly accommodated in liner design and mill control, with only limited compensation made for this influence, usually in the first few weeks after a new liner is installed. With ever-increasing ore competency, increasing energy costs and decreasing ore grades, simplified design and operational approaches that compromise the achievable mill efficiency are no longer adequate. This paper presents a methodology that has been developed to measure and account for the changes in mill performance as the liner wears. This involves monitoring all liner profiles – in other words the three-dimensional liner shape - over the life of the liner, then conducting controlled surveys at different stages of the liner wear life, and correlating the mill performance to the liner profiles. The measured liner mass is modelled to provide an ongoing meaningful load mass measure that excludes the liner mass.

Jan 1, 2012

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By T. Patching

"MINING operations at the Star Key Mine provided an example of a small-scale prairie-type coal mine that employed several interesting procedures and achieved good productivity with low capital expenditures. The mine was located about 11 miles north of the city of Edmonton, on the north side of the Sturgeon River valley. It opened in 1945 and operated until 1979. Output in the winters reached about 500 tons a day in the late 1940s, but in the spring and summer periods activity was usually limited to only servicing and development work. In the later years of the mine's life sales fell to less than 100 tons per day. Most of its output was bought for domestic use in furnaces and stoves so production of large sizes was desired. A modest market for stoker coal did exist for a time. Screenings (-5 / 8 in.) were sold to the city's power plant until it converted to natural gas and were also used for thawing frozen ground for work on pipelines. These markets were comparatively small and the small sizes did not command as high a price as did the larger sizes. However the extension of natural gas services to rural markets cut into the domestic heating market and finally led to closure of the mine. The coal was strong when freshly mined, but because of its high inherent moisture content, about 25%, it did not store well on surface but tended to disintegrate. It was of subbituminous Crank with a heating value of about 8000 Btu per pound and burned with a clean flame. The seam mined was in the Edmonton Formation, of Upper Cretaceous age, at a depth of 60 to 80 ft below the surface. The seam in the mine area was about 11 feet in thickness but thinned gradually to the north and south and split to the west (1). It was approximately horizontal but gentle rolls in the floor of several feet in height necessitated brushing in places to produce suitable haulage grades. The floor material was of bone and clay, overlying a thin layer of coal. Above the seam there were only a few feet of mudstones and weak sandy shales while the remainder of the overburden was clay and unconsolidated glacial till and surface soil. Because of the soft floor and weak roof material the miners usually left about a foot of coal in the floor to provide a firm working surface and about a foot of coal above the rooms and two feet of coal above the entries to provide a competent roof."

Jan 1, 1985

By Paul M. Lévesque

The Dome Mine has been in production for nearly 100 years and throughout the years many different mining methods were used to extract the ore. An exploration program late in the 1990s outlines new resources requiring the mine to extract the rock and some previously placed backfill (alluvial sand and/or classified tailings). It is therefore imperative to separate the backfill from the rock to reduce the negative impacts of handling the backfill on the ore pass, crushers and mill processes. Separating the backfill from the ore at the source would also reduce and/or eliminate the cost of handling this waste stream. The paper will touch on the backfill removal criteria, the risks, the alternatives and the selected method, screen decks, for backfill removal at the Dome Mine. The 155549 bulk zone case study will illustrate how the screen decks are in use at the mine. The paper will also illustrate how the lessons learned and conclusions of the work done for the 155549 bulk zone were applied to the second screen deck installation for the 257260 bulk zone.

May 1, 2009

By Yasuhiro Aoki, Akihiro Sato, Mikiya Arai

In this study, a freckle formation model based on the Rayleigh number was applied to actual multi-component Ni-base single crystal superalloys and verified in large scale casting trials. Finally, new Ni-base SC superalloys having a balance between castability and creep strength has been developed.

Jan 1, 2010