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By Craig Dirk

Agenda Applications of ?GPS ?Drill Navigation ?Cycle time monitoring ?UDS / Boom Stress monitoring ?Payload systems ?Laser Surveying Future Applications

May 1, 2006

By R. H. Duval

"In May 1936, Pamour started producing gold by cyanidation of flotation concentrates, and in 1939 was milling about 1, 600 tons per day.Refining records dating from 1939 show two oil-fired furnaces in use, (Rockwell type 46 11 x 29 11 inside oval shell).Refining time averaged 7. 83 hours during the year 1939, indicating a complete refining shift of about 9. 33 hours. That year appears to be characteristic of the period with regard to time required and results obtained.For that year total fineness (gold + silver) of the bars averaged 940 (approx.), but it frequently dropped below this figure, sometimes far below.Furnace lining life varied widely from three to seven or more months. Sillimanite was the standard lining but Mullfrax 41 was frequently used.For many years refining practice remained practically unchanged, and in 1960 procedure still consisted essentially of mixing a flux(% Composition Borax 41, Silica 11, Soda-Ash 11, Nitre 15, Mn02 22) with cyanidation precipitate in the ratio of l. 2 to l and heating to a medium heat (yellowishred, 2000° F) with a low flame for a long time. Time required was about 10. 5 hours per refining. Results were still much as detailed above.At this time it was decided to revise refining procedure, in an effort to shorten refining time and obtain consistently good bullion fineness."

Jan 1, 1965

By Jeff Smith

Agenda About NORTHPARKES The NEED The INITIATIVE The SEARCH The PRODUCTS The SOLUTION The RESULTS The Northparkes copper-gold mine in Central Western NSW commenced operations in 1994. Copper concentrate is produced and shipped to smelters in Japan, China & India under long term contracts with spot sales to other Asian countries.

May 1, 2006

By S. N. Dixon

"Maximizing the value of each tonne of processed ore is the goal for all operations. Cyanidation processing of gold-copper ores has been challenging since its first use in 1889. The current practice treats a bleed or the total flow of mill solution to recover copper as copper sulfide (by sulfidization, acidification, recycling, and thickening), or to recover the cyanide (by acidification-volatilization neutralization). The process presented uses the adsorption of copper cyanide by carbon and the selective elution of copper from carbon to concentrate copper into a smaller stream. Copper contained in the smaller stream is precipitated as copper cyanide.RÉSUMÉ Toutes les exploitations ont pour objectif commun d’optimiser la valeur de chaque tonne de minerai traité. Depuis sa première utilisation en 1889, la méthode de traitement par cyanuration des minerais aurifère et cuprifère s’est révélée complexe. La pratique actuelle traite la saignée ou le débit total d’une solution de traitement du concentrateur pour récupérer le cuivre sous la forme de sulfure de cuivre (par sulfuration, acidification, recyclage et épaississement), ou pour récupérer le cyanure (par acidification, volatilisation et neutralisation). Le procédé présenté dans cet article utilise l’adsorption sur charbon actif de la solution de cyanure de cuivre et l’élution sélective du cuivre depuis le charbon pour concentrer le cuivre en un plus petit jet. Le cuivre contenu dans ce plus petit jet est précipité sous forme de cyanure de cuivre.INTRODUCTIONProcessing gold-copper ores by cyanidation has been a cost-control challenge since the cyanidation process was first used in 1889. Copper cyanide is stable only in the cuprous state, not the cupric. This factor results in the oxidation of a mole of cyanide per mole of nonchalcocite copper extracted. Each mole of copper extracted forms a cyanide complex with a minimum of 3 mol of cyanide. This cyanide-to-copper mole ratio is required to dissolve gold. The oxidation of cyanide and copper complexation with cyanide results in high cyanide consumption for copper-gold ores, which is a significant operating cost.One challenge in processing gold-copper ore is the cost of cyanide related to the extraction of copper. Processing 10,000 t/d of ore containing 1,000 mg/kg copper and 10% copper extraction yields 1,000 kg/d of copper. Currently, processes to remove copper from cyanide leach solution treat either the total flow of the barren or a bleed of the barren. The two processes used for copper-gold ores are sulfidization, acidification, recycling, and thickening (SART), which produces a copper sulfide product for sale; and acidification- volatilization-neutralization (AVR), which recovers the cyanide from a gas and produces a low–cyanide content solution. This low–cyanide content solution can be recycled to the process or might require additional treatment before being disposed from the operation."

Jan 1, 2017

By John A. Meech

"Oleic acid flotation of Mount Wright thickener underflow tailing material has been shown to be capable of increasing plant recovery by 3%. High levels of oleic acid addition (1.5 kg/t) are required, which limit the economic practicality of the system at this time. Nevertheless, from a technical viewpoint, the process is stable with respect to extreme fluctuations in oleic acid requirements, pulp pH and pulp temperature. Methods to reduce the average consumption of oleic acid need to be found. One technique that merits further testwork uses the ""piggy-back"" principle to float hematite fines with coarsegrained hematite particles.IntroductionWith most large-scale iron mining operations treating specular hematite ores, flotation is not often conside red a necessary processing step. The bulk of the iron minerals can be concentrated by gravity techniques and the generation of fines can be minimized because of the course- grained nature of the mineralization. Nevertheless, production of some fine material is unavoidable, and recovery of iron from this fraction by spirals is poor (10-30%).When the proportion of the iron in these fines becomes excessive, alternative methods to conventional spirals are considered(11), Many of the techniques that have been developed suffer from either poor recovery (e.g. the Reichert cones at 36010 recovery)(11) or low throughput rates (e.g. wet highintensity magnetic separation)(12), Flotation is often passed over because of excessive reagent costs, pollution problems and/or balling difficulties from the reagents used.However, of all the processes available, flotation can yield high recoveries (60-90%) at reasonable throughput rates with excellent process control features (reagent addition and/or cell level). The key parameter is reagent cost.This paper describes testwork on the use of oleic acid to float hematite from the fine fractions of the Mount Wright concentrator tailing. The concentrate product from this plant is directly shipped, so no balling problems exist. As well, oleic acid may be considered a lesser pollution hazard than many of the cationic collectors used in other iron ore flotation systems. A reduction in fine hematite slimes discharged as tailing into lakes may also reduce environmental damage."

Jan 1, 1981

By John S. Stevenson

Zeballos mining camp is on the west coast of Vancouver island; 195 nautical miles northwest from Victoria.; The spectacularly rich gold-bearing veins that made Zeballos an important; gold camp were found early in 1934. Small pockets of very coarse; gold had been found earlier under large boulders at the mouth of Spud; creek; and in the autumn of 1933 rich gold-quartz float was found near the; mouth of the creek. The rocky beds of the steep creeks entering Spud creek; were searched for its source and as a result the veins on the White Star property; were found. The Goldfield vein on the Spud Valley property was discovered; in 1935; and the No. 1 vein on the Privateer in 1936. In the general; prospecting activity that quickly followed; other veins were found; not; only in Spud creek but in other creeks draining into Zeballos river.

Jan 1, 1954

By Tim Mann

"Like other operating mine sites, Placer Dome Inc. - Campbell Mine has taken important steps over the last few years to address environmental issues.This paper will provide specific insights into the implementation of an environmental management system at Campbell. In particular, it will focus on how Campbell developed its plan of action; the lessons that have been learned; the over-all steps that are being taken to enhance environmental stewardship and effectively manage relationships with key stakeholders.IntroductionThe development of an Environmental Management System at Campbell Mine has been part of a general development in management practices which has taken place at the mine during 1990. This paper will discuss the components of the management system in the topic areas of: direction setting; environmental organization; issue assessment; emergency response plan; training ; monitoring/verification; reporting and data management; and relationship management.Although this paper focuses on environmental management systems, the development of this system has partly been a function of responses to other issues which have been addressed concurrently with environmental concerns. These other issues include development of operations management, human resources practices, and safety management practices at the mine. As the Environmental Management System developed, various stakeholders associated with local environmental concerns were identified. This group of stakeholders include the local community; municipal, provincial and federal governments; government agencies; Campbell employees; and the Placer Dome Inc. Corporation."

Jan 1, 1991

By T. G. Joseph

The chicken and egg scenario where adverse truck motions cause ground deterioration and poor ground profiles that in turn cause adverse truck motions is a downward deterioration spiral that dominates in our industry. If we can remove one action, the reaction must stop and vice-versa. A simple 'truck to excavator' load data analysis and wireless communication system is outlined in this paper; that will provide visual assistance to the excavator operator in achieving improved load placement and balance in a truck body. In turn this will reduce the subsequent hauler duty cycle adverse motions and g levels that contribute to structural fatigue, higher tkph, reduced tire life and ongoing maintenance of haul roads

Nov 1, 2011

By Zoltan Hajnal

Magnetic studies have been carried out on 88 surface and 157 underground samples from the Coronation Mine area of northern Saskatchewan. The intensity of the surface samples was compared to trace element determinations from the same locality. A good correlation was found between the titaniferous constituent of the rocks and the intensity of magnetization. From the direction of the remanent magnetism, two virtual geomagnetic poles were determined -latitude 12° 54' North, longitude 158" 17' West; and latitude 23" 42' North, longitude 163° 45' West. The sulphide ore specimens showed anisotropic susceptibility characteristics. A relationship was found between the measured maximum susceptibility values of the ore specimens and the direction of the tectonic forces which are considered to have formed the structure at the Coronation mine. Introduction T HIS paper summarizes the results of a study of the magnetic properties of samples from well-known Precambrian formations. The observed data give information for an interpretation of the magnetic field conditions in Precambrian times. The high magnetic intensity values indicate the importance of the study

Jan 1, 1965

By Ramesh Subramanian

Overview Background / History Undergraduate Programs Mining Engineering Chemical Engineering Mechanical Engineering Graduate Programs and Research Student Enrolment (2002 -) Future Plans

Oct 1, 2010

By L. A. Forsyth

"SINCE I received and accepted your invitation to present to this meeting a paper on A Canadian Integrated Coal and Steel Industry, I have given the subject a great deal of intensive study.Two conclusions have emerged from my considerations: first, that the subject should be dealt with by a person having a firm grasp of its technical aspects; and second, that it is a subject which requires expert analysis of the complicated problems it presents in pure economics.A third conclusion inevitably results from the two just mentioned -namely, that the mantle of the prophet which has been draped up-on my shoulders is too large for me to wear, because I am neither a practical nor a theoretical coal and steel man; and I am not an economist.With the warning that I have discovered, and am keenly conscious of, the inadequacy of my background for the task, I shall attempt to place before you those aspects of my subject which appear to high-light it from a layman's point of view.In the first place, in .order to avoid confusion as between my audience and myself, some definition of terms may be required.As I interpret it I am discussing -a coal and steel industry, using the last word in the generic and not the unit sense, self-sufficient in the provision of all its needs from within the geographical limits of Canada.Now, I start with the proposition that, in the very broadest aspects of such a concept, the Corporation of which I happen to be the executive head meets my definition as a combination of operations resulting in one fully integrated unit of a coal and steel industry."

Jan 1, 1952

By C. H. Bucknam

Net carbonate value (NCV) characterization methods for acid generation potential measurement originated from studies on the Carlin Trend during the 1990's and have been subsequently standardized through cooperation of the Acid Drainage Technology Initiative Metal Mining Sector and the American Society of Testing and Materials International. The paper describes the evolution and standardization of the NCV methods, the importance of mineralogy in interpreting the results and application of the methods to implementation of the Global Acid Rock Drainage (GARD) Guide.

Jan 1, 2011

By T. R. Stanley

Introduction The purpose of this paper is to interest mining men in the economic possibilities of sand deposits suitable for modern foundry work. Many members of the profession are constantly travelling over the country and it is felt that some knowledge of the necessary properties of foundry sands will enable these men t0 recognize such deposits. It is the experience of the writer that good sands suitable for the varied work of a foundry, such as that of the Consolidated Mining and Smelting Company, at Trail, are almost impossible to obtain from western Canadian sources. It is hoped that the following discussion may arouse some interest in the search for such sands. Sands are used in foundries for two purposes. The main use is for making moulds suitable for receiving hot metal. The mould must retain the? required shape until the metal has solidified. The second use of sand in the foundry is as an abrasive in sand blasting. This is a relatively minor use, and consequently will not be dealt with in detail. Any coarse sand with a high content of quartz will serve this purpose, but round-grained sands are superior to angular types, because they have not the same tendency to shatter on impact with the casting. Sand plays an extremely important part in the successful production of sound castings. This is more evident today than ever before, due to the greater variety of castings and alloys, each of which requires special sand characteristics. Poor sand is responsible for a great many foundry troubles which formerly were attributed to bad? metal; in fact, one investigator goes so far as to say that ninety per cent of bad castings can be traced directly to the sand. Very little of the vast amount of sand distributed over the earth's surface is suitable for moulding. It is the purpose of this paper to describe briefly the properties which are essential in good moulding sand. Sand for this work must be able to withstand the wash and hydrostatic pressure of molten metal, and yet be sufficiently porous to allow the gases generated in the mould to escape.

Jan 1, 1935

By C. H. Ash

"Abstract-The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of western Canada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits. The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bornite± magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprise quartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite is the main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+ carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)], contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite composition which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By E. Yan, M. Mankosa, E. B. Wasmund

Mechanical cells are the dominant unit operation in base metal rougher flotation applications worldwide. As economic demand for metals increase, and as the feasible ore grades decrease, the installed capacity of mechanical flotation units worldwide has greatly increased, adding significant capital and operating cost. One opportunity to improve this situation is to use fundamental knowledge to make the industrial flotation process more efficient. A key insight is that the flotation process can be optimized by dividing the processing of the pulp into two distinct fluidic environments; a collection cell where air and pulp mix in a highly energetic compartment, and a low energy gravity separation cell. This is the basis of the “2-stage flotation device” that has been patented by Eriez and marketed under the tradename StackCell™. Two industrial case studies will be presented to highlight the potential metallurgical and commercial advantages of the StackCell. In the first, a train consisting of three pilot scale StackCells (each 0.6 metre diameter) was run in parallel with a train of conventional mechanical cells in a major copper concentrator and benchmarked against a batch Denver test. In the second, the performance of a 3 metre diameter StackCell in a nickel sulfide cleaning application was benchmarked against a batch Denver test. The flotation kinetics observed in the StackCells were 2.4 to 2.9 times faster when compared with the lab Denver test. In the first case study, the kinetics of the StackCell was about six times faster than conventional mechanical cells. It is hypothesized that the efficiency improvement in kinetics is because of reduced “drop-back” during the froth recovery phase, which is reduced because of the reduction in the shear that is present in a conventional mechanical tank cell. This result suggests that a 2-stage flotation system can be used to reduce the working volume of flotation units by five to six times. This would allow operators to significantly reduce the size of their flotation lines for a comparable flotation objective. Some discussion will follow about the scale-up criteria, maintenance and operability issues, comparisons of layout, and possible cost savings. INTRODUCTION The solution that most equipment suppliers have offered to reduce the cost of mechanical flotation equipment over the last 30 years has been to increase the size of the flotation unit cell (Mankosa, 2017). For example, three 100 m3 machines with three smaller motors, mechanisms and control valves could be replaced with a geometrically similar 300 m3 with a larger version of each ancillary component. While there are some efficiencies and cost improvements to be gained by this approach, it does not take advantage of fundamental insights into the flotation process, and it does not represent a step-change in terms of process design or economic benefit for the customer. The advantage of the “bigger is better” approach is that there is past experience of incremental improvements by making cells larger and there is a well-established scale-up method, which allows practitioners to estimate equipment capital costs based on very simple laboratory test- work. A different paradigm, which is gaining interest rapidly is to use a unit operation in which it is easier to optimize the flotation process, which will be described in this paper. This approach is often referred to “2- stage flotation”. Because this approach is new, it is important to benchmark it against existing conventional technology and to demonstrate a robust methodology for sizing equipment and flowsheets. This paper aims to address these issues with two case studies.

Jan 1, 2019

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers' ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999

By E. Faria

"The Santa Rita mine is located in north eastern part of Bahia in Brazil and is owned and operated by Mirabela Mineração do Brasil Ltda. Typical SABC circuit was designed as the preferred option for the 4.0 mtpa (500tph) to produce a P80 of 125um for flotation. Although the SAG was originally designed to operate with conventional radial pulp lifters, later it was fitted with Outotec’s Turbo Pulp Lifters – TPL (Latchireddi, 2005). The milling circuit commenced commissioning on the 24th of October 2009 and the milling circuit achieved the nameplate capacity within days. with small and relatively simple measures to rectify. Since commissioning, the SAG mill has been working in fully autogenous grinding (FAG) mode with no balls (in contrast to the estimated 10% ball charge) and has been consistently treated up to 650tph.This paper examines the comminution design process, the operating philosophies, start-up experiences, post commissioning optimization and future development works. An evaluation of mill performance relative to the design criteria for the project life to date is also included."

Jan 1, 2012

By K. Reipas

"Westmin Resources Ltd. operates the 3300 TPD H-W underground copper/zinc mine on Vancouver Island. Ore storage underground is handled in a 6000 tonne coarse ore bin and a 3000 tonne fine ore bin. Both of these bins have experienced significant wear since excavation and construction in 1985. Wear problems have included both deteriorating rock walls as well as worn out steel liners and concrete at the discharge points from the bins. Extensive rehabilitation work was completed in 1993.The basis o/this paper is the rehabilitation work done on the coarse ore bin. The design and installation of ground control measures are discussed. The bin access methods used to allow the work to proceed quickly and safely are also presented. This involved the use of a Tekfoam safety bulkhead to protect workers.IntroductionMine DescriptionThe H-W mine was commissioned in 1985. Mine access is by vertical shaft with most production areas at a depth of about 500 m. Host rocks are composed of andesite and rhyolite. Mine capacity of 3300 tonnes per day is achieved mainly by longhole open stoping methods, complemented by room and pillar mining. Metals recovered from the massive sulphide ore are copper, zinc, gold, and silver. Mineable reserves at January I, 1994 were 9.7 million tonnes."

Jan 1, 1995

By Kenneth Williamson

La découverte de nouveaux gisements métallifères constitue le point de départ du développement de l'industrie minérale. Or, au cours de ces dernières années, le nombre de ces découvertes a fortement diminué dans les territoires classiquement explorés, entraînant une recrudescence de l?exploration dans les terrains géologiques de grade métamorphique élevé (e.g., Province de Grenville, Grand Nord du Québec). Ces derniers ont été traditionnellement considérés comme stériles à cause (i) de la monotonie apparente des gneiss qui les composent, (ii) de la difficulté d?identifier leurs protolites, (iii) des changements importants dans l?apparence des gîtes recherchés reliés au fort degré de déformation et de métamorphisme et (iv) des théories qui prônent un lessivage important des cations et des métaux d?intérêt économique par les processus de déshydratation des roches lors du métamorphisme régional (Weaver et Tarney, 1985; Vokes, 2000). Cependant, l?avancée des connaissances dans la compréhension des gîtes métallifères et de leurs terrains hôtes gneissiques intensément métamorphisés, montre que les systèmes géochimiques des roches altérées demeurent robustes (p. ex. ; Trägårdh, 1991; Craig et Vokes, 1993; Geringer et al., 1994; Schandl et al., 1995; Zaleski et Peterson, 1995; Vokes, 2000; Blein et al., 2003, sous presse). Bien sûr, les sulfures peuvent être localement remobilisés et même fondre, mais cette remobilisation n?implique pas forcément la disparition du gîte hôte (Williams, 1990) et peut s?avérer, bien au contraire, bénéfique pour la rentabilité d?un gîte en augmentant sa teneur en minerais (Marshall et al., 2000). Jusqu?à présent, dans les terrains métamorphiques, les contextes sédimentaires et plutoniques ont été reconnus et respectivement explorés pour les gîtes de type SEDEX et les gîtes magmatiques de Ni-Cu. L?étude de gîtes de métaux de base et précieux intensément métamorphisés (faciès des granulites) et leur comparaison avec des gîtes équivalents peu on non métamorphisés a permis d?établir, au cours des dernières décennies, des outils pour l?exploration des terrains de haut-grade métamorphique (Vokes, 1991, 2000; Slack et al., 1993; Spry et al., 2000). Ces outils sont basés sur la reconnaissance de roches diagnostiques d?une circulation ou d?une exhalation de fluides hydrothermaux telles que les méta-exhalites (formation de fer, coticules, tourmalinites, roches riches en quartz-gahnite, en apatite, en barite ou en staurolite zincifère) (Spry, 2000; Spry et al., 2000). Ils sont utilisés constamment dans les ceintures supracrustales riches en roches métasédimentaires.

May 1, 2003

By O. Benavente, M. C. Hernández

Selenium is obtained mainly from copper anode slimes, which is a by-product of the copper electrorefining process. Selenium is present in copper anode slimes as silver and copper selenides. Traditionally, selenium has been obtained by pyrometallurgical processes; however, hydrometallurgy has now been incorporated either full or partial to the conventional process. Some hydrometallurgical processes are been developed and used at laboratory level an industrial scale. This document describes theoretical background and results of characterization and dissolution of selenium from a decopperized anode slimes in an alkaline oxidizing system. The results have indicated that the oxidizing leaching process reaches a practically complete dissolution of selenium (up to 90 %); the undissolved portion is due to the generation of a AgCl around the particle surfaces that delays the progression of the reaction. The results indicated that 90% of selenium extraction can be obtained by dissolution under moderate conditions of pH, temperature and reagent concentration in oxidizing medium. INTRODUCTION Selenium is distributed in the earth's crust in most rocks and soils. Selenium is essential, as it has wide range of applications in the medical and food industries as well as, used in semiconductor, sensors and photochemical devices. Selenium is rarely found in the native state, 90% of selenium is obtained from copper anode slimes, which is a byproduct of the copper electrorefining process (Lu, Chang, Yang, & Xie, 2015; Xiao et al., 2017; Yang et al., 2018). In anode slimes, selenium is present as an intermetallic compound, as Ag-Cu selenides. Currently, selenium is recovered from the anode slimes via hydrometallurgical and pyrometallurgical processes (Lu et al., 2015). The traditional pyrometallurgical method recovers selenium effectively, but faces difficulty as a result of increased energy costs and strict environmental regulations associated with the process (Li, Yang, Jin, Chen, & Tong, 2017). Therefore, hydrometallurgical processes are proposed in oxidizing medium such as nitric acid, alkaline leaching with sodium nitrate, wet chlorination and pressure leaching, amongst others (Hait, Jana, & Sanyal, 2012; Kim & Wang, 2010; Xiao et al., 2017; Yang et al., 2018).

Jan 1, 2019