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By V. G. Papangelakis, I. Guzman, S. J. Thorpe

Pressure oxidation (POX) leaching has been commercially applied to refractory gold ores since the 1980s. In the process, sulphide material is oxidized and dissolved in order to release the gold encapsulated in the sulphide matrix, making the gold available for further recovery. Redox potential is a significant parameter during POX, however it is only measured ex-situ at atmospheric conditions. In-situ redox potential measurement would provide instant information that allowing adjusting the process parameters accordingly. In the present study, redox potential measurements were performed during POX of sulphide material at high temperatures and high pressures. The working electrode was an Ir electrode combined with a flow-through reference electrode in a novel and robust configuration. Experiments were performed in a 2 L titanium autoclave, at 200–220°C, 50–110 psi oxygen overpressure, and 10–30% solids mass fraction. Temperature and oxygen pressure conditions were selected in order to reflect POX of refractory gold ores. Results show that the Ir electrode is consistent with theory and is able to perform well under these conditions, showing promise as a new in-situ sensor.

Jan 1, 2017

By Kevin P. Plucknett, Z. Memarrashidi

"In the current work, factors influencing the corrosion mechanisms of TiC and Ti(C,N) based cermets are reviewed. Cermets were typically prepared with 30 vol.% of metal binder, in the form of various in-situ reaction-formed Ni3Al alloys. Commercial WC-Co hardmetals were also examined as baseline materials. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential and potentiodynamic polarisation. The corrosion potential and current density were determined, following Tafel extrapolation, allowing estimation of the corrosion rates. Post-corrosion characterisation involved scanning electron microscopy analysis and associated energy dispersive X-ray spectroscopy of the sample surfaces. It is demonstrated that the primary corrosion mechanism for this type of cermet is dissolution of the metallic phase during oxidation attack, and thus this response can be expected to increase with the amount of binder in the cermet, although degradation can be subtly affected by composition (i.e. alloy composition, C:N ratio, impurities in the ceramic phase, etc.) and test procedure (i.e. aerated vs. de-aerated electrolytes). It was observed that addition of N content into the ceramic phase is beneficial to the corrosion characteristics of TiC based cermets, through significant refinement in the grain size of the hard phase. Similarly, elimination of impurities, such as W in selected TiC powders, also improves the corrosion resistance.INTRODUCTION Cermets are prepared using the combination of a hard, high elastic modulus ceramic phase with a ductile, high toughness metallic binder. This pairing of hard and ductile components ensures wide application of cermets in demanding wear environments. These materials are consequently used industrially in both bulk and coating form. The most common example of such a composite system is based on the use of tungsten carbide with a cobalt-based binder (WC-Co), which has been widely examined over the past 80 years. However, while WC-Co has been shown to exhibit an excellent combination of high strength and wear resistance, the corrosion and high temperature properties of this material are relatively poor. In addition, WC-Co possesses a high density (~13–14 g/cm3), which makes it a less desirable option when the component mass is a design factor (i.e. use in aerospace). In particular, the aqueous corrosion response of WC-Co limits its use in wear environments where combined corrosive degradation may occur (i.e. tribo-corrosion scenarios). Alternate cermet systems are therefore being actively developed due to these performance limitations."

Jan 1, 2017

PROFIL D'ENTREPRISE Léandre Gervais & Associé(e)s est une société d'experts-conseils en ingénierie de la structure, de la mécanique & de la tuyauterie, et de l'électricité et de l'instrumentation. Nous offrons des services hautement spécialisés à notre clientèle des secteurs industriels des mines et de la métallurgie, au Québec, au Canada ainsi que dans plusieurs autres pays du monde. Notre mission est d'assurer à nos clients un ensemble de services d'ingénierie de haute qualité contribuant à la mise en oeuvre et à la réalisation de leurs projets d'affaires. Léandre Gervais & Associé(e)s emploie 36 employés à temps pleins et opère à partir de Val-d'Or, province de Québec. SERVICES OFFERTS Nous avons réalisé de multiples mandats pour notre clientèle de différent pays du monde dans les domaines d'expertise les plus variés : ?Études de faisabilité ; ?Ingénierie conceptuelle ; ?Ingénierie de détail ; ?Gestion de projets ; ?Ré-ingénierie de la maintenance.

May 1, 2001

By Tibor Horvath

Dust abatement is possible on bulk materials, whether conveyed or stockpiled. Minimum (ppm) quantities of chemical additives can efficiently and rapidly control dust of conveyed substrates with no effect on floatation chemistry. Top coating of large surface areas can control surface dust and wind erosion. Environmental and toxicity impact must be considered in any treatment, especially on areas with percolation runoff, leachates, or limited containment. The most effective dust control is preventing release of substrate fines rather than trapping and removing air borne dust. Techniques to prevent release of fines from conveyed substrates will be discussed. Dust control dynamics are a very complex combination of solid phase physical and chemical interactions between the substrate and the fines. ?Smart Technology? products permit dust abatement of stockpiled substrates and tailing fields with no environmental impact. Using ?Smart Technology?, the dust abatement products remain active and can re-seal damaged areas. Efficient, low environmental and toxicity impact, dust control will be demonstrated through case studies where these principals have been applied.

Oct 1, 2010

By D. Paul Bishop, Kevin P. Plucknett, Hung-wei Liu

"Spark plasma sintering (SPS) process has been evaluated for producing the commercially pure (CP) Ti, TiAl and a TiAl-B4C composite. Comparisons were made between the materials in terms of the sintered density, resultant hardness and microstructures. In the present work, the titanium aluminide powders (Ti-48Al, producing a mixture of y-TiAl/a2-Ti3Al) were synthesised „in-house? using a simple reaction-sintering and mechanical attrition approach. This allowed various size distributions to be generated. The powders were then blended with a fine boron carbide (B4C) powder (up to 6 wt.%), and the resulting mixtures were consolidated using spark plasma sintering (SPS) under vacuum in graphite dies. An applied stress of 50 MPa was used for all SPS runs. The SPS parameters were varied in terms of the ultimate sintering temperature (up to 1300°C) and hold time (up to 10 minutes) for each material. It is demonstrated that high densities can be achieved this approach (exceeding 95% of theoretical, with optimised samples close to full density). Microstructural characterisation was conducted using optical microscopy, scanning electron microscopy, and X-ray diffraction. The B4C additions were seen to partially react with the TiAl to form reinforcements, such as TiCx and TiBx. Preliminary mechanical property assessment will also be briefly discussed.INTRODUCTION Titanium- and titanium aluminide-based alloys possess many unique properties, such as excellent corrosion resistance and high temperature strength, respectively (Cardarelli, 2001; Leyens & Peters, 2003). Compared to many other competing materials (e.g. stainless steel or Ni-based alloys), Ti- and TiAl-based alloys also have relatively low densities (~4.5 and ~3.9-4.1 g/cm3, respectively), which is critical for performance in aviation and automobile applications. However, the manufacturing cost is high, due to the expensive raw Ti material and difficulties in machining. TiAl-based alloys are particularly difficult to produce because of their limited ductility (Lütjering & Williams, 2007). To overcome those problems, powder metallurgy (PM) technologies have shown great potential as near-net shape processes for Ti- and TiAl-based alloys. The general PM process largely avoids laborious post-machining and minimises material use. In industrial production, the PM approach has been successfully utilised to manufacture aluminium- and iron-based alloys (Huo & Heath, 2008)."

Jan 1, 2017

By Margaret Armstrong, Chris Roth

Abstract -Estimating ore reserves for vein type deposits is a two-stage procedure: first, calculate the geometry of the vein system, and second, estimate the grades within this system. The grade estimation can only be consistently performed if the vein geometry - its size, shape and orientation - has been correctly characterized. Getting the size and shape of the different veins right means that the ore tonnages will not be artificially inflated, e.g., by falsely classifying host rock as veins. Similarly, correctly estimating their orientation and location helps mine management decide on the appropriate mining technique, selective or not. When applying geostatistics to estimate the vein geometry all available information needs to be used and not just the standard lithologic indicator of being or not being in a vein.

Jan 1, 1998

By Dougla McDonald, Richard Poulin

"Most mine managers in Canada today will agree that one of the keys to mining efficiency and productivity is their human resources. A5 a result, many mines develop some sort of incentive designed to tap their employees' capabilities to the fullest extent. Historically, the most common plans used have been ""piece-rate"" plans, where individual or small groups of miners are paid a financial bonus based on some measure of their productivity. Recently, however, incentive plans that take a more team-based approach have been developed in some Canadian mines. One such plan will be defined in this paper, and its popularity in the industry today discussed.Gainsharing PlansThere are two primary components to a gainsharing plan. The first is a cash incentive, which is paid to all employees and based on factors that are highly correlated with employee productivity, and key to the profitability of the mine. For example, the typical gainsharing cash incentive is based on the cost/unit of metal produced. Management (in consultation with employees in some cases) will establish the budgeted cost per tonne, and any savings in this amount is shared between the company and the employees. The second is a management philosophy and associated communication network, which is designed to foster an environment that encourages information exchanges, communication, participation, and trust between employees and management. The typical gainsharing communication network consists of two tiers of committees. The first, operational committees, include all employees working in the same department or departments which frequently interact. The employees meet monthly with management personnel to discuss problems encountered and brainstorm for solutions. In most cases, these committees will nominate a person in the group to structure the meeting to maximize its efficiency. The second, the screening committee, is a single group consisting of representatives from the various operational groups, whose primary job is to ensure that the plan is effective, and the objectives and results generated by the plan remain consistent with the mine objectives. In short, gainsharing plans tell employees that their bonus depends upon performance and then gives them the opportunity and incentive to affect that performance. The opportunity is provided by a communication network and positive management practices, and the incentive comes in the form of ""intrinsic"" rewards of participation and the ""extrinsic"" rewards of the bonus payments. Figure I will clarify the relationship between the intrinsic and extrinsic rewards."

Jan 1, 1995

By W. D. Freeborn

Slim-hole drilling and completion techniques were first used in the Cynthia area of the Pembina field, Alberta, by the Texaco Exploration Company in the summer of 1957. Prior to that time, eighty-eight wells had been drilled and completed in this area in a conventional manner. Subsequent to the initial four-well evaluation programme, twenty-one additional wells have been drilled using slim-hole techniques. No difficulty was encountered in the drilling and completion of slim-hole wells, or in obtaining production from them. A comparison of drilling and completion economics and practices has been made for slim-hole and conventionally completed wells. Penetration rates for both bit sizes (614 in. and 9 in.) were relatively equal. The shorter life of the smaller bits required the use of 15 per cent more bits per well, but the total trip time to change bits was similar for both hole sizes because of the higher hoisting speeds possible with the lighter drilling strings used in the slim holes and better hole conditions. Completion costs of the slim holes were reduced by 37 per cent as compared to the costs of conventional-type completions. This was made possible through the use of smaller well equipment, the elimination of tubing, and a reduction in rig time for completion operations.

Jan 1, 1958

By G. Minhas, M. Pule, Y. Laffitte, M. c. McGurn, T. Tzanetakis, Peacey. J., R. Susilo

Titanium (Ti) metal production from titanium tetrachloride (TiCl4) using magnesium (Mg) as a reducing agent is the well-known Kroll process. A chloride route is used to avoid oxidation of the titanium sponge. The sponge is consolidated into ingots and can then be made into powder by melting and atomizing or by hydriding/dehydriding. Attempts at direct powder production have met with difficulties, including low Ti yield and the formation of very fine particles (particles between 25-100 µm are desired). This paper discusses two methods to produce Ti powder in a molten salt medium using magnesium powder as a starting material instead of a pool of molten magnesium. The first method is a direct reduction of gaseous TiCl4 injected in the melt with the magnesium powder in suspension in the molten salt. The second method is a two stage TiCl4 reduction reaction where recycled Ti was used to form titanium dichloride (TiCl2) in the first stage followed by addition of magnesium powder into molten salt in the second stage. A correlation between Ti yield and processing variables such as TiCl4 to Mg ratio, Mg particle size, TiCl2 concentration in the melt, and reaction temperature was studied. The Ti powder formed was also analyzed for particle size distribution. Despite challenges and difficulties encountered, this paper shows some promising results which could provide guidance to others working on direct Ti powder production.

Jan 1, 2015

By Z. X. Cui, X. D. Ma, L. Contreras, X. Jiang

The bath smelting process is one of the key techniques applied in the current copper smelting production, which includes bottom-blown and side-blown furnaces differently from the direction of gas injection. Liquid matte and slag form the bath in the smelting furnace. To better understand the fluid dynamic of the bath and further optimise the operational efficiencies in the smelting furnace, physical simulation of the bath in the horizontal cylindrical reactor was investigated. The mixing behaviour and wave motion of the bath in the bottom-blown and side-blown furnaces have been studied systematically. The mixing time is reduced with increasing gas flowrate and height of the lower layer, while it increases significantly with increasing the height of the upper layer. The wave motion in the furnaces can be suppressed with the presence of the upper layer, but the bath with a lower density generates higher wave amplitude. Overall, in comparison to bottom-blown mixing, side-blown mixing shows better mixing efficiency and lower wave amplitude. In addition, the plume eye and splash phenomena occurred in the bottom-blown furnace have also been studied. INTRODUCTION The bath smelting process is one of the principal techniques used in the current copper making industry. The bath smelting techniques have some advantages of high smelting efficiencies, low capital costs, low energy consumptions and reduced dust generations. From the direction of gas injection, the bath smelting techniques can be classified into five general types: (1) top-submerged blown, e.g. Ausmelt and Isasmelt; (2) top-suspended blown, such as Mitsubishi smelting; (3) top direct-to-copper smelting, such as Outokumpu smelting; (4) submerged side-blown, such as Noranda and Teniente smelting; (5) bottom-blown, such as Dongying Fangyuan bottom-blown copper smelting furnace (Schlesinger et al., 2002; Zhao, Cui, & Wang, 2013; Perez-Tello et al., 2018). In many metallurgical processes involving bath smelting situations, the objectives of agitation are to accelerate the bath homogenization inside the bath which makes a significant contribution to process efficiency and product quality. Extensive mixing studies have been performed for ladle refining and tundish associated to steelmaking processes through water physical models. Mixing time is the parameter used to quantify the efficiency of mixing in the liquid bath and the first empirical equation predicting mixing time was proposed by Nakanishi, Fujii and Szekely (1975). Later on, more systematic studies have been carried out on ladle mixing and researchers realized that the geometry of the vessel could also have a significant impact on mixing (Khajaviand & Barati, 2010). However, the investigations using ladles which are vertical cylindrical vessels, cannot be directly used in the study of mixing behaviour in horizontal cylindrical reactors. Understanding the fluid dynamics inside horizontal cylindrical bath smelter is useful from the industrial perspective. Recently fluid dynamics of horizontal cylindrical smelter related to copper smelting have been studied by the authors’ group (Shui et al., 2015a, 2015b, 2018a; 2018b; Xu et al., 2018, 2019).

Jan 1, 2019

By J. Clark

Erosion control during the mining cycle can be more effectively planned using Erosion and Sedimentation Control Plans (ESCPs). This raises the issue of who should develop an Erosion and Sedimentation Control Plan Guidance document (ESCPG) to standardize the content of ESCPs. A search for ESCPG documents in Canada revealed no examples for mine sites. In the U.S. there are a number of regulatory authorities who developed such documents for mine sites, including EPA. An ESCPG is expected to result in: (a) plans will be more standardized (b) more clarity and efficiency for those generating ESCPs; (c) assisting regulators tasked with reviewing/approving ESCPs; (d) providing guidance for the mine effluent permitting process relative to sediment control; (e) providing a basis for developing and including ESCPs in the Environmental Assessment (EA) phase and the mine economic assessment; (f) applying and optimizing ESCPs above the ?watersheds? of sediment ponds; (g) utilizing the ESCPG document for ?exploration? sites; (h) lowering the risk of adversely impacting water quality downstream of mining activities; (i) providing a methodology for determining the need for sedimentation pond(s) during the construction and production phases; and (j) providing a clear environmental sustainability message relative to sediment control if the mining industry takes the lead in developing an ESCPG. ESCPs will proactively create increased administrative (regulatory) efficiency in the EA and sub-EA reviews relative to erosion control and sediment release from mine sites. This also assists the new initiative in BC, One Project, One Process (OPOP) and synchronous permitting (a variation of concurrent permitting): as an example, enhanced erosion control planning at the EA phase then allows the synchronous permitting initiative to proceed efficiently, particularly for the mine permit (Ministry of Energy, Mines and Natural Gas) and effluent permit (Ministry of Environment). Approximately twenty more management plans (e.g. ARD/ML, explosive management, emergency response, hazardous waste, sediment pond operation, environmental effects, environmental sampling, etc.) may also be entered into the EA process to create increased efficiency, and then feed into the synchronous permitting effort. The BC OPOP initiative also adds support to the Canadian Federal ?One Project, One Review Process? approach. The ESCP and a sediment pond management plan will also address the Canadian Metal Mining Effluent Regulations requirement for all discharges from mine sites to meet a grab sample of 30 mg/L Total Suspended Solids.

Aug 1, 2013

By Robert Marchand

_ North-western Quebec _ Bousquet mining district _ 21 M oz mining camp _ 100,000 t/yr (400 t/d) _ Shrinkage : 52 % _ Longhole : 40% _ Development : 8% _ 5 days/week _ 120 employees _Discovered in 1936. _12 changes of ownership. _Exploration & development : 1987 _Commercial production : 1990 _Shaft deepening : 1995 _Internal shaft : 1999

Oct 1, 2001

Over five decades ago Kitchener et al. in England and La Mer and Healy in the US were advancing our understanding and application of flocculants, primarily related to water treatment and filtration of sludge. This paper identifies the beneficial uses of flocculants in the mining industry and revisits some less common applications. Flocculants are used in unique ways in the mining industry: (a) to increase the effectiveness of sediment ponds to achieve discharge compliance; (b) to eliminate air emissions and costs associated with concentrate drying; (c) to reduce soil loss by applying a flocculant to erodible soils, and reducing wind and water erosion; (d) to remove/thicken metal precipitates in acid rock drainage treatment; and (e) to enhance clarification and thickening in mineral processing. The mechanism of how flocculants, coagulations and potentially-determining ions function is described and how their use can be controlled and optimized. The potential toxic effects of flocculants and coagulants when used to achieve effluent permit discharge compliance for suspended solids is discussed. A review of numerous best management practice (BMP) guidelines for the design and operation of sediment ponds treating mine site runoff to remove total suspended solids (TSS) and turbidity revealed an absence of a predictive methodology to address regulatory discharge compliance for TSS concentration, turbidity and flocculant-induced toxicity. An essential component of pond design is the need to determine whether flocculants and/or other settling aids are required based on the site-specific soil particle size distributions upslope of the pond. Procedures are provided to predict the need for settling aids and estimate pond discharge quality and downstream impact for TSS, turbidity, toxicity and sub-lethal toxicity. The need to develop BMP guidelines are discussed for (a) the application of flocculant to surface soils to reduce erosion, (b) the application of flocblocks to increase the ?sediment control? aspects of erosion and sediment control, as part of the mine site erosion control plan strategy and (c) the application of flocculant to silt socks to treat mine site runoff.

Aug 1, 2013

By L. Torres, C. S. R. Rondestvedt, M. Bustos

In February 2010, Teck’s newest Concentrator at Mina Carmen de Andacollo (CDA), Andacollo, Chile was commissioned. The Concentrator is a single line configuration, comprising of one 36 ft diameter x 20 ft long SAG mill driven by an 18,000 hp gearless drive. The SAG mill feeds two ball mills each 25 ft in diameter x 40.5 ft long, each driven by a total of 19,000 hp through dual pinion drives. A series of four phases will be reviewed from operational readiness, mechanical completion, commissioning, and ramp-up. Also, now after 6 months of operation, this paper will review the significant steps taken during ramp-up enabling the announcement of commercial production, in October 2010.

Jan 1, 2012

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By Elaine Ellingham, Francis T. Manns

"The Orostar and Scadding were two small gold mines owned and operated by Orofino Resources Limited. Conventional statistical treatment indicates an identical arithmetic mean grade of 0.22 oz/T Au for both mineable reserves. Further, the deposits are both shown to have cut weighted average reserve grade of 0.21 oz/T. Orostar mined out at 0.206 oz/T and Scadding at 0.156 oz/T Au. The combined exploration and development database contained 1394 fire assays, more than enough for statistical confidence in a normal distribution. Therefore this study was initiated to determine, if possible, why the mill head grades were lower than the averages and to experiment with several methods to determine whether a reliable statistical mill head grade estimation method would emerge. Despite the identical reserve grades, distinct differences in the grade distribution histograms are present. By studying the arithmetic and log-normal grade distributions, with some attention to South African practices, this paper reports on those differences which may account for the considerable divergence in the mill head grades. Furthermore, this study casts considerable doubt on the industry standard method of cut weighted averages.The global mill head grades of the two deposits have been derived from the arithmetic average grades by graphic means. This precise method of mill head grade prediction, if applied to complex orebodies, could permit selective grade control and result in direct cost savings by allowing the operator to detect false value stopes, benches or levels and emphasize reliable regions of not only gold mines, but also uranium or base metal deposits."

Jan 1, 1992

By John A. Dresser

Seventy years ago a period of prospecting and mining activity began in the Eastern Townships of Quebec that seems to have been quite equal to that of recent years in the Rouyn field. In the following six or seven years a large amount of work was done over a widespread area. About fifty deposits gave some shipment of ore, from a few tons upwards, and as many as five hundred occurrences of copper were made known in the district by official records. Comparing the scale of commercial undertakings of that time and of the present day, these developments must have occupied quite as large a share of the capital and man-power of the Province as northern Quebec employs today. Working conditions at that time were not very favourable. The country was then only newly opened for settlement, and colonists were few and widely separated. Roads of the class built today were unknown. A single line of railway, the Grand Trunk, crossed the district from east to west. Colonization companies controlled large blocks of land on which they owned mining rights and usually reserved these rights in whole, or in part, when selling the lands. Then, as now, the precious metals belonged to the Crown. Yet the work was not without its successes. One of the first deposits discovered, the Acton, was, for a few years, one of the most profitable producing copper mines of its time. Another, the Eustis mine, has been in almost constant operation ever since, and is now vigorously pushing further development. At least two others, now quiescent, proved profitable operations, and several made considerable production. The manufacture of sulphuric acid in Canada was begun by the founder of the Nichols Company at Capelton, on a deposit that is now being re-developed, after a long and creditable career.

Jan 1, 1928

By Peter C. Jones, Wanda M. Carter, David H. Watkinson

"Abstract - Pyrrhotite, chalcopyrite, and pentlandite are the dominant sulfide minerals in the 740 zone of the Kelly Lake orebody (Inco Ltd.), Copper Cliff Offset, Sudbury. Petrographic and quantitative electron microprobe analyses of minerals, from sulfide assemblages and host quartz diorite, of the 740 deposit have revealed three processes that have affected sulfide mineralization and associated sulfarsenide and platinum-group-mineral (PGM) distribution: magmatic, hydrothermal, and tectonic. Accessory, zoned cobaltite, and gersdorffite occur in sulfides as a result of these three processes, and PGM occur dominantly in hydrothermally remobilized and deformed ores. Where PGM are present in sulfarsenides they provided nuclei for sulfarsenide growth. Solitary PGM are orders of magnitude larger than those PGM found within sulfarsenide minerals. Five varieties of PGM occur, michenerite and sperrylite being the most common, with lesser froodite, hollingworthite, and ruarsite.The effect of a deformation is a localized fabric in the ore, revealed by pyrrhotite and chalcopyrite bands; pentlandite porphyroblasts also partially define the foliation. The deformed ore is also characterized by alteration of the adjacent quartz diorite, which produced an alteration assemblage including almandine garnet, Fe-rich biotite, and chlorite."

Jan 1, 2001

By Brennan Lang

Why Seal Tunnels? ?Restore groundwater levels to pre-mining conditions. ?Saturate rock mass to reduce acid rock drainage. ?Reduce discharge flow to the environment. ?Reduce or regulate flows to a water treatment plant.

May 1, 2002

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019