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By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By J. Coffin, M. Muinonen, D. Fragomeni, R. Multani, C. Deredin

"Rejection of pyrrhotite from pentlandite is of critical importance to the economics of nickel concentrate production and the main goal of the Strathcona milling operations. A joint team of XPS, Glencore Technology and Strathcona Mill personnel executed a comprehensive program of work to develop and implement strategies for increased Po rejection with focus on challenging ores containing high feed Po/Pn ratios (> 7) and significant hexagonal Po content (> 40% of total Po). This paper describes the team results including minerology, bench-scale flotation tests, and plant validation tests and modeling that have defined the path forward to improving the metallurgical performance and economics of the mill operation. Techniques to quantify hexagonal and monoclinic pyrrhotites were developed at XPS to assess the differences in their metallurgical behavior since their flotation responses are quite different. Mineralogical tools including QEMScan were extensively used to determine mineral liberation, associations, optimum grind size, and nickel deportment into pentlandite, pyrrhotite and non-sulphide gangue. Several reagents/strategies were evaluated during bench-scale flotation testing to significantly increase Po rejection. A significant shift in the Po-Pn selectivity and grade recovery curves was achieved using several strategies including the use of DETA and sodium metabisulfite, and regrind of the rougher concentrate and rougher cleaner/rougher tails.INTRODUCTION The Strathcona Mill is owned and operated by Glencore Nickel – Sudbury Integrated Nickel Operations and has been processing Ni-Cu ores from the Sudbury Basin since 1968 (valuable sulphides: pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2). Currently Strathcona Mill receives ore mined from two main sources in the Sudbury area and produces two concentrate streams – a nickel-copper concentrate that is shipped to the Sudbury Smelter and a copper concentrate that is sent to the Fonderie Horne (Glencore Copper, Rouyn-Noranda). The general flowsheet currently used at Strathcona is displayed in Figure 1. It is highlighted by separate feed circuits for regular grade Ni ores and high grade copper ores. The copper circuit has a preflotation stage prior to a rougher-scavenger stage, a copper-nickel separation circuit, and a pyrrhotite (Po) rejection circuit."

Jan 1, 2018

To create a successful growth oriented diamond company that succeeds in the practical business of mining and selling rough diamonds, and which pursues an aggressive exploration strategy to seek and develop worldclass diamond mining opportunities in a market that has become increasingly under-supplied.

May 1, 2008

By David Eichenberg

A154S A154N After 3 Years of Mining ?Current mining Level A154S 280RL ?110 Vertical metres of A154S ?Current mining Level A154N 300RL ?100 Vertical metres of A154N ?Variations in Kimberlite Volume ?Ore Types and Plant Production

May 1, 2006

By C. Doyle, D. M. Hoffman, C. Díaz, J. Hrepic, W. J. Koshut, R. H. Hanewald

"Recently, lining life of the INMETCO submerged arc furnace has been dramatically extended from an average of eleven months in the 1980s to a current record of 34 months. This paper summarizes test work and operating results describing the development and establishment of slag parameters that reduce corrosion of the magnesite-chrome refractory lining.The desired slag parameters are now maintained by utilizing waste streams as slag additives. This paper also discusses the successful evaluation of a rebonded-fused-grain magnesite- chrome refractory as a lower cost, more thermo-mechanically forgiving alternative to a fused-cast magnesite-chrome refractory that had been the refractory of choice in previous years at INMETCO.IntroductionSince 1978, INMETCO, a wholly owned subsidiary of INCO Limited, has been well known for recycling by-products from the production of stainless steel, namely, EAF bag- house dust, mill scale and grinding swarf. INMETCO operates the only smelter in North America dedicated to the recovery of nickel, chromium, and iron from hazardous and nonhazardous waste. The process was developed in the research laboratories of INCO. In recent years, the process has been successfully modified to accept a wider variety of other specialty steel waste streams including: spent pickling solutions, pickling and waste water treatment filter cakes, acid scale, carbon brick, spent bag-house bags, torch cutter dust, spent dolomitic and chromium-bearing refractories, and rechargeable nickel-cadmium batteries."

Jan 1, 1997

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal

In copper Eta plants the optimal current density setpoint depends on the electrolyte composition and temperature. However, conventional plants operate with large standard deviations. A value of 14% with current densities offsets up to ±50% is typical. For worst, during opencircuit or shortcircuit events this variation can be from -100% to +200%. Naturally, energy consumption and copper quality are compromised. Several devices have been successfully employed to reduce set point deviations. Last developments include; Optibar Segmented Intercell Bars, Outotec Electrodes Arranging Method and NTC Selective Electrodeposition Enhancers. This paper researches and compares these technologies. It is shown that short circuits can be effectively reduced in occurrence and magnitude. Moreover, 95% of the electrodes can be forced to operate within ±10% of the set point. The specific energy consumption is reduced from 2,000 KW per Ton to values close to 1,900 KW per Ton.

Jan 1, 2011

By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013

By M. Walawalkar, C. K. Nichol, G. Azimi

Rare earth elements (REEs) are essential to the production of technologically advanced products, including wind turbines, electric and hybrid cars, automotive catalytic convertors, hand held electronic devices, and military defense systems. Their application in environmentally beneficial technologies puts them at a high priority for ameliorating environmental concerns. Because of their increasingly high demand and limiting resources, it is highly beneficial to find new sources for them. The present study is focused on leaching REEs from a phosphate based fertilizer by-product, known as phosphogypsum (PG). Global estimated world production of PG is about 240 million tonnes that is stored in the form of wet stacks adjacent to fertilizer production facilities, occupying vast amounts of land. PG also contains trace metals, which are detrimental to the environment, and hence it is crucial to monitor these stacks. We obtained our PG sample from Agrium Inc. (a fertilizer manufacturing company in Canada). We performed a comprehensive characterization of the PG sample and found that it predominantly contains Y, La, Ce, Nd, and Sm. For leaching purposes, we used hydrometallurgical acid leaching techniques. We investigated three acids over a range of operating conditions such as acid concentration, temperature, solid-to-liquid ratio, and residence time. We achieved an average leaching of 81% with hydrochloric acid as leachant using operating conditions that can be easily replicated in industrial settings. If our process is implemented, not only will it reduce the size of the existing PG stacks (mitigating their environmental risks), but also enable the development of new innovative routes for extracting REEs, making countries like Canada less vulnerable to supply disruptions.

Jan 1, 2016

By F. Hampshire

"IntroductionThis paper is intended to cover questions raised by operating staff at various installations and is not intended to give comprehensive coverage of power plant and power system design. The paper is concerned mainly with the electrics , although a brief section gives the reasons for selection of diesels rather than other prime movers.The material is not new but brings out points which seem to be raised regularly during the design , commissioning and operation o f a new plant. Diesels versus other Prime MoversDiesel-electric plant for the mining industry falls into two major categories -emergency power and prim e power.1) Emergency power (for use only when the regular utility supply has failed) requires reliable starting and operation and reasonable first cost. Fuel economy and maintenance are of little importance as the machine(s) generate few kilowatt hours only. The diesel's competition in this field is the gas turbine, however diesels are more widely used than gas turbines in this application.2) Prime power is a different situation as the bottom line of total cost is highly affected by fuel costs.In general , mines which are within reasonable transmission distance of an existing utility find the lowest net cost result s from hooking up to the utility. If a min e is remote from an electric utility then the possible alternatives are:a) Hydro- electric power if there is a site capable of development at reasonable cost including the cost of transmission facilities. Such sites are not common, but brief and inexpensive considerationof this possibility is warranted .b) Diesel power with consideration of different grades of fuel.c) Thermal (steam) power generation from coal or oil.d) Gas turbines.In addition to the above there is the possibility of wind power (as a supplementary source) and a number of technologies which may become feasible in the future (e.g. small nuclear plants, fuel cells). For obvious reasons, small isolated generating systems required for remote mines, tend to lean to conservative technology.Among the fossil fuel plants, the diesel enjoys advantage on over-all costs as summarized in Table 1."

Jan 1, 1986

By L. Magne, A. Pinto, M. Maldonado, J. A. Finch

Estimation of gas holdup from electrical conductivity measurements has been used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the electrical conductivity of the dispersed phase, continuous medium and the resulting mixture (dispersion). When applied to inferring the collection zone gas holdup in a three phase system and to facilitate real-time on-line measurement, the slurry is assumed to behave as the continuous medium and gas bubbles as a nonconducting dispersed phase. This article derives an equation for estimating gas holdup in a three phase system, eliminating the assumption that the slurry behaves as a continuous medium but rather as a dispersion of non-conducting solid particles in water. In this formulation only water behaves as the continuous medium in the sense of Maxwell, and gas holdup in a three phase system is then calculated from the application of the Maxwell model twice: (1) to determine solid content in a two-phase system, and (2) to determine solid plus gas holdup in a three phase system. To validate the new equation and quantify the errors incurred by assuming slurry is the continuous phase a laboratory flotation cell was instrumented to continuously measure the conductivity of two and three phase dispersions with known solids contents. As the amount of gas in a lab flotation machine is difficult to measure directly or by another indirect technique such as using pressure signals, 2.5 mm dielectric plastic spheres having a density of ca. 1.3 g/cm3 were used instead of air bubbles for validation. Experimental results demonstrated that the continuous medium assumption underestimates gas holdup and that the resulting bias error increases linearly with the solid content and decreases with the magnitude of gas holdup.

Jan 1, 2016

By A. Golpaygan

Application of Computational Fluid Dynamics (CFD) modeling for simulation of fluid flow and combustion in industrial scale electric furnace is presented. Poor combustion efficiency, roof and/or side wall overheating, carry over to off-gas system and non-ideal radiative heat transfer to processes or cooling systems have been common limiting factors causing inadequate process performance of the furnace, operational problems, and safety hazards. This paper describes how CFD analysis can be used to obtain a better understanding of commonly observed problems associated with freeboard combustion. Examples are presented to describe using combustion CFD modeling to understand requirements to diagnose a problem with furnace design including required freeboard volume or possible roof/side wall overheating.

Jan 1, 2011

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By V. V. Zubkov

The systems of geophysical monitoring have been already put into operation at coal mines and ore mines. Since at present it is rather difficult to conduct mine experiments; it is necessary to start a new step in joining of geomechanics and seismic. The linking geomechanical and geophysical monitoring at coal mines and ore mines today became possible due to progress in development of numerical methods of modeling of stress state and technology for processing of seismic information. This paper describes one potential step in linking geomechanical and seismic monitoring at coal mines and ore mines.

Aug 1, 2013

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By A. Taylor, E. Thorn Corthay, R. Storey

In response to requests from its stakeholders, the International Standards Organisation is engaged in development of an international standard for Energy Management Systems (EnMS) which will become "ISO 50001". This new standard will build on the successes of both the EN16001 EnMS standard that has been used by dozens of European companies, as well as the ANSI/MSE 2000:2008 EnMS standard that is currently being used in several pilot projects in the USA and Ontario. This paper provides an overview of the key points of the EnMS standards, and describes how they can be used to drive sustainable energy reductions in the metallurgy industry.

Jan 1, 2010

By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By R. A. (Dick) McIvor

"It is important to ensure that the basic mine hoist plant design fundamentals are incorporated into any new mine hoist plant project before detailed design engineering is commenced. Some of the basic design fundamentals to be considered are: hoist rope fleet and flight angles for good hoist rope coiling, hoist rope harmonic frequency study to ensure that the hoist rope does not run at full speed at a rope resonance frequency, head frame and shaft clearance diagrams to establish the optimum positions for the loading and dumping of the shaft conveyances, access in the head frame and shaft collar for hoist rope and shaft conveyance installation and removal. Failure to consider the hoist plant fundamentals before detailed engineering commences will result in extra costs for hoist plant redesign or a significant increase in operating and maintenance costs for the mine due to increased hoist plant downtime to perform tasks and a lower mine operating efficiency. INTRODUCTION The mine hoisting plant is the most critical single line component in the operation of a shaft sinking operation or a permanent installation. Bad decisions in the design and selection of the hoist plant equipment can significantly add to the operating costs and up-time in the operation of the mine. Mine hoisting plant equipment installed costs represent approximately 5 to 8 percent of the capital cost of a new mine, yet price sometimes becomes the deciding factor for procuring the hoist plant components, sometimes selecting used equipment that may compromise the design and maintainability of the mine hoist plant. Mine downtime can cost upwards of $100,000 per hour and it will not take a very long time to eat up all the so-called savings on hoist plant equipment purchases. This paper will provide guidelines for the design, selection, installation and maintenance of mine hoist plant equipment with the objective to having the right mine hoist plant with the highest operational availability and best maintainability. PRELIMINARY DESIGN INFORMATION Before any engineering commences, the following information needs to be obtained to allow the preliminary sizing of the hoist plant equipment: • Shaft depth: The shaft depth will influence the hoist rope selection based on the material and personnel loads anticipated for the mine design. The shaft depth will also influence the maximum speed of the shaft conveyances. • Annual production: The desired annual production will influence the required payload sizing with allowances for maintenance and inspections of the hoist plant equipment."

Jan 1, 2019