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By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By M. M. Helm

Samples sourced from the Goldstrike property in Nevada USA, have been evaluated in terms of their preg-robbing capacity and the physical structure of the graphitic carbon component in the carbonaceous gold ore. The study highlights a wide range in preg-robbing capacity between samples collected from the Betze-Post open pit and Rodeo underground mine. The physical structure of the graphitic carbon was assessed using Raman spectroscopy, and is found to play an important role in influencing preg-robbing behaviour. Differences observed in the physical structure of graphitic carbon are thought to be the result of hydrothermal events that occurred at Goldstrike.

Jan 1, 2011

By R. D. Brown

"Taxation tends to be a depressing subject. Taxes are unfair, taxes are too high and, above all, taxes are too complicated.In a recent address to the Canadian Tax Foundation, the author discussed in a rather more lighthearted way the possible causes of the complexity of the present Canadian taxation system. In order to provide an element of relief in this series of articles on taxation matters, extracts from these remarks are quoted below :"

Jan 1, 1976

By J. W. Merks

"Simulation is the process of designing a computerized model, of a system or procedure, for the purpose of understanding its behaviour and developing strategies to control its operation. Simulation models are rapidly becoming an effective tool for mineral processing plants. Powerful software and fast hardware are more readily available than a basic understanding of the theory of mathematical probability and applied statistics that process simulation models demand.Simple spreadsheet software can be used to develop simulation models that take into account any set of conditions at a mineral processing plant. In addition to an unbiased estimate for each variable in the set on which two-and three-product formulas are based, reliable variance estimates for all variables are required. How to estimate variances, effectively and at the lowest possible cost, and how to compute variances for simple functions such as the metal content of a quantity of ore or concentrate, or more complex functions such as the percentage recovery at a mineral processing plant, are the key to useful simulation models.IntroductionSimulation models for systems and procedures have become one of the most powerful and effective applications for computers( 2.6). Simulations are applied to a wide range of scientific and engineering disciplines. Generally, a model is designed to investigate the effects of changes in and interactions between a set of variables before a system is in operation or a procedure is implemented, by simulating weeks, months, and even years of operation, in a few minutes of computer time. Along with practical and useful applications always comeabuse and misuse. For a simulation process cannot be more reliable than the methodology that was applied to design the model, to estimate variables and variances, to check performance, and to verify validity. A mineral processing plant is a dynamic system that changes continuously as a function of time but within probabilistic constraints that can be estimated by applying statistical tools and techniques to the variables and variances that interact in the system.A model should be designed to simulate not only the set of variables but also the variance for each variable. Models in which constant variances are used to generate normally distributed random numbers, are less realistic than models in which the variances are simulated first, and then used to simulate the variables."

Jan 1, 1991

By P. V. Amosov, V. A. Masloboev, D. V. Makarov, S. G. Seleznev, A. A. Baklanov

"The development of industry and intensive use of natural resources leads to a significant decrease in the share of reserves of rich ores, deposits of which have nearly all been exploited. Large amounts of displaced rock mass are accumulated, significant emissions of gas and dust from mining, dust from dumps and tailing pits, ingress of chemicals and toxic elements in surface and groundwater all can have negative effects on existing ecosystems and human health. Especially dangerous is the impact in Arctic regions with extreme climate conditions. The maintenance of overburden dumps and tailings dams requires significant capital and material costs. In this paper, some mining enterprises of the Murmansk region, in the Russian Federation, consider the environmental problems of the industry and propose some solutions.INTRODUCTIONThe safety of environment during the extraction and processing of minerals is a very acute problem throughout the whole world. The problem acquires a specific character in the Russian Federation. There, rather poor minerals, often existing in unconventional forms and including several mineral components are processed. The Russian mineral base has a specific geographical location; most of the deposits under operation are located in the Subarctic or Arctic regions, as well as in Siberia and in the Far East. Vast amounts of rock waste and tailings pose serious economic and ecological problems in mining regions. The operation of overburden heaps and tailings requires considerable capital and material costs. The dumps withdraw vast lands from potential commercial use. Large amounts of mined rock disturb the existing geological balance; emissions of gas and dust which accompany the mining operations, dusting of waste heaps and tailings, emissions of reagents and heavy metals into natural surface and ground waters all can produce negative effects on existing ecosystems and human health."

Jan 1, 2016

By S. J. Schofield

INTRODUCTION ONE of the greatest and most interesting problems of economic geology is to discover criteria bearing on the persistence of ore in depth. It is a question which is very much to the fore in connection with many of our important mines in British Columbia, and, as is to be expected, it is a most controversial one. The present paper, summarizing the views of the writers concerning the possibilities, in some of the mining districts of the Province, for the persistence of commercial ore to greater depths than have been, or are at present, mined, is offered as a basis for a general discussion on the subject and to call attention to the need for renewed study and research on the problem. Sooner or later-at some depth or other-individual ore-shoots become impoverished and bottom. In many mines where this has happened, either at the same or at a lower horizon, another ore-shoot, which had no surface outcrop, has been encountered and has continued downward until it, in turn, has pinched out. The Kolar (Mysore, India) gold field, for instance, presents interesting examples of this recurrence of ore-shoots at depth (1). For many years these mines have been under the management of Messrs. John Taylor and Sons. On more than one occasion they have persisted in sinking or drifting on barren quartz or along a narrow fracture for many hundreds of feet before values were again encountered. Their earliest experiment in such bold development took place at a depth comparable to that at which most mines in British Columbia are considered to be bottomed. In the past, is has been concluded that the ores in British Columbian mines do not go below approximately 2,000 feet, and to that depth only in a few instances. Consideration of the depth to which ores have been mined in the Province appears to support this view. The figures shown in the accompaning table have been gathered from various sources and are approximate.

Jan 1, 1935

By Imane Benhamed, Jaouher Diouani, Laurent Cassayre, Florent Bourgeois, Carine Julcour-Lebigue, Université de Carthage

The attrition-leaching process aims at improving leaching performance when formation of passivation layers at the surface of leached particles is a severe limiting factor, as discussed recently by Julcour and coworkers (Julcour et al., 2015). This paper proposes a geochemistry-based modelling scheme for deriving the window of possible operating conditions for the attrition-leaching process to match the properties of the processed ore. The rationale is that the attrition-leaching process maintains the surface of reacting particles in an unpassivated state by continuous mechanical removal of surface leach layers, so that the process reactions can be modelled from thermodynamic equilibria throughout the duration of the process. The strength of the proposed modelling approach is that it bridges the gap between the properties of the ore and the process operating conditions. The present paper exemplifies the proposed process modelling route for derivation of the attrition-leaching process operating conditions in the context of the leaching of silicate ores, matching model predictions against controlled laboratory experiments. It is shown how thermodynamic modelling, when used in conjunction with a solid knowledge of the phases present in the system, can assist with deciding upon suitable process operating conditions. As an example, this firstprinciple modelling approach predicted that steel grinding medium would be converted into siderite (FeCO3) under a wide range of operating conditions, which led to questioning this initial choice of grinding medium for the attrition-leaching process under mineral carbonation conditions. It is emphasised that the same approach could be applied to ores of greater economic significance.

Jan 1, 2016

By I. Filzwieser, A. Filzwieser

The Peirce Smith converter is the key metallurgical vessel in the majority of copper smelters. During the two step process, oxygen enriched air is injected through a row of tuyeres into the matte received from a primary smelting unit. Additionally, in the first step the iron content is oxidized into a fayalite slag by the addition of silica. During the second step, the remaining copper sulphide is converted into blister copper with a final sulphur content of approximately 200 ppm. The overall efficiency of this process is determined by the total reaction time, the slag quality and quantity, and the chemistry of the final blister copper. To increase the reaction kinetics during both stages, the METTOP Process Control and Regulation (MPCR) system was developed, which consists of four elements: OPC - Optical product control ACR - Automatic computer regulation GCU - Gas control unit GIS - Gas injection system The OPC system from SEMTECH records the optical spectrum emitted by the off gas flame providing immediate, detailed process information. Using this online data, additional gas can be automatically injected into the converter through a gas injection system opposite the tuyere zone. An improved oxygen distribution in the melt and the accurate determination of the process end point results in a significant reduction in the process cycle time. Furthermore, by maintaining the reaction closer to the equilibrium the final sulphur and oxygen content can be reduced compared to the conventional process. In particular, the final sulphur content can be lower than 70 ppm, eliminating the need for an oxidation step in the anode furnace.

Jan 1, 2007

By R. Le

"The principles of noise control aredescribed with particular emphasis on personalactive units as opposed to passive ear muffspresently in general use. A discussion followsfor their potential use in a mining environment.RÉSUMÉNous décrivons brièvement quelquesprincipes de contrôle de bruit à l’usage person-nel, puis nous passons en revue quelquescasques commerciaux dotés de ces circuits àprincipe actif. Enfn nous discutons de leurusage potentiel dans le contexte minier.IntroductionLe casque à principe actif est un produitqui existe commercialement, mais encore peurépandu en usage, sûrement à cause du prix,mais aussi de sa méconnaissance par le grand public. Il arrive parfois qu’un journaliste trouvele produit fantastique et le médiatise commeune réalisation de son pays (ou de sa province),mais peu savent qu’il s’agit là d’un principe quia commencé dans les années 30. Par delà lesensationnel, il reste que si l’on veut mettre lamain sur un de ces casques pour l’essayer, on nesait où l’obtenir. De plus, les casques n’utilisentpas tous le même principe actif. C’est la raisonpour laquelle nous faisons cette brève compara-ison. Nous le faisons en mettant l’accent pourune possible utilisation dans le domaine minier,car c’est dans ce milieu que les usagers sontconfrontés aux bruits les plus intenses qui peu-vent endommager leur système auditif, ce quin’exclut pas les autres situations (travaux publics, foresterie, écoute hi-f, etc.)."

Jan 1, 1997

By E. Viljamaa

In this research, earlier developed information integration method and novel web technologies are applied to intensify infrastructure construction process control. The applied method uses semantic methods to integrate scattered information that is later on exploited by process management using state-of-the-art web technologies. The applied method and web technologies not only improve the process management situation awareness by integrated up-todate multi-source process data but also provide platform independent access and visualization tool for process data. Utilization of such technologies potentially lead on cost savings, make processes safer and also more environmentally friendly. The integration method also enables intelligent queries to the integrated data making possible to use machine based inferring to the data.

Aug 1, 2013

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By J. E. Gebhardt, D. McBride, M. Cross

Heap leach processes can encounter diverse flow conditions, such as infiltration into dry ore material, drainage, perched water tables and heterogeneous materials, leading to large variations in permeability and the creation of preferential flow pathways. Climate and meteorological conditions, such as precipitation, evaporation, and temperature, can also have a significant effect on the hydrodynamics of the heap. Nonuniform and adverse flow behavior within the heap contributes to reducing the leaching efficiency of the heap leading to lower metal recoveries. The variability of flow within the heap can result in solute transport problems, which limit the leach reaction kinetics. Therefore, understanding the flow and transport phenomena within the heap is critical in its design and optimization. A comprehensive heap leach model, developed within a computational fluid dynamics (CFD) framework, employs robust algorithms to solve diverse variably saturated flow conditions. The model allows for a wide array of complex thermo-fluid physics to be represented and captures suites of very complex reactions that are closely coupled with thermal conditions and key microbial populations. Employing a three-dimensional heterogeneous ‘test’ heap, a number of flow conditions are investigated and the sensitivity of metal recovery is discussed.

Jan 1, 2014

Reaction between xanthate ions in solution and oxidized compounds present on the surface of galena to form lead xanthate is considered to be a side reaction not contributing to flotation, although accounting for some consumption of reagent. The direct reaction of lead sulphide with xanthate and oxygen to form lead xanthate is the most significant to flotation. Coadsorntion of dixanthogen is also involved. Previous work has shown lead recovery in lead rougher flotation to be a function of m [H+] where: m = concentration of xanthate in solution rHl = hydrogen ion concentration. A plausible explanation for this relationship is suggest-ed. Likewise, the experimental findings that the amount of xanthate adsorbed under certain conditions is a function of m'[H+] are explained in terms of reaction between xanthate ions and soluble basic lead salts such as PbO.PbS04? It is also shown that m[H+] should have a constant value in lead cleaners operating at a higher pH than the roughers. This conclusion is confirmed by plant data, and the value of the constant agrees well with the calculated value. The finding is useful in mill control.

Jan 1, 1965

By Q. Li

"The precursor of In2O3 was prepared by hydrolysis precipitation/hydrothermal method using In(NO3)3 solution as the feed material and ammonium hydroxide as the neutralizing agent. The crystallinity, morphology and particle size of the products were characterized by SEM, XRD, BET and LPSA. The results showed that the hydrolysis product consists of an aggregate of cubic In(OH)3 particles with a short rod morphology. In the hydrothermal process, the structure, morphology and size of the particles changes through the mechanisms of Ostwald ripening and phase transition, respectively. When the hydrothermal temperature was less than 280 ?, the Ostwald ripening process took place, which changed the morphology of the particles from short rods to cuboids through dissolution-recrystallization. When the hydrothermal temperature was higher than 280 ?, the processes of Ostwald ripening and phase transition took place successively. Firstly, the morphology of the particles changed from short rods to cuboids through Ostwald ripening, and then, the phase transition from cubic In(OH)3 to orthorhombic InOOH occurred and the morphology of the particles changed from cuboids to polyhedron. INTRODUCTIONDue to its excellent electrical conductivity and optical transparency, indium tin oxide (ITO) film has been wildly used in flat-panel display, solar cell, antistatic coating and EMI shielding (Medvedovski et al., 2008). Indium oxide powder is one of the fundamental materials for preparing ITO film. Along with the development of ITO targets of both high density and large size, high quality indium oxide powders, such as single phase, nano-size, spherical morphology and mono-disperse, have been in high demand (Nakashima and Kumahara, 2002; Betz et al., 2006; Kim et al., 2007). The main preparation methods for indium tin oxide or indium oxide powders include chemical precipitation (Nam et al., 2001; Xu and Yu, 2007), melt atomizing-combustion (Chen et al., 2000) and spray pyrolysis (Ogi et al., 2009). Among them, chemical precipitation has been preferred, since it is simple, easy to control and suitable for industrial scale-up. In chemical precipitation method, indium oxide powders were prepared through the following steps: firstly, indium hydrate precursor was precipitated from an indium salt solution by neutralization using an alkali, such as ammonia; and then, indium oxide (In2O3) powders can be obtained from the precursor through calcination (Li et al., 2006), or solvothermal method (Lee and Choi, 2005), or hydrothermal processing/roasting (Xu et al., 2005; Chen and Li, 2007), respectively. However, the indium oxide powders obtained by direct roasting are polycrystalline, dispersable with a wide size distribution (Liao, 2006). The disadvantages of the solvothermal method are high cost, complicated after-treatment processes, as well as bad performances of the powders (Udawatte and Yanagisawa, 2000). Therefore, among three methods of obtaining indium oxide from the hydrolysis precursor, the hydrothermal process/roasting method is the most feasible to synthesize high quality In2O3 powder with uniform crystallinity and size (Kim et al., 2002; Zhu et al., 2004; Xu et al., 2005; Xu et al., 2005; Chen and Li, 2007; Seetha et al., 2009). However, current research on hydrothermal process-roasting method has been limited to the synthesis of a certain ITO or In2O3 powders under specific conditions. A systematic study on the phase transition, as well as the change of the morphology and size of the particles in the hydrothermal process is still missing. In this paper, the effects of hydrothermal processing on the mineralogy, morphology and size of products were investigated. The results showed that the evolution of crystal structure, morphology and size in the hydrothermal process was affected through the mechanisms of Ostwald ripening and phase transition successively. These results are novel and have guidance for improving the hydrothermal process for In2O3"

Jan 1, 2012

By Joseph Hirschi, Behrooz Abbasi, Harrold Gurley, Yoginder P. Chugh

"The research goal was to assess if analytical tool/s can be developed to quantify displacements around a geological fault as longwall face moves toward it and past it. A company was faced with crossing a 2-3 m (6-10 ft.) normal up-thrown fault in the development entries and the face while mining a 375 m (1,200 ft.) wide longwall face. A field monitoring and numerical modeling study was performed to develop data. Field measurements consisted of roof-to-floor convergence and rectangular rosettes in the immediate roof. Numerical modeling consisted of constructing a 3-D structural model using the FLAC3D software with the fault plane incorporated as ubiquitous joint. Based on analyses and field observations data, the coal company was informed of impending movements along the fault plane and likely impacts on the development entries. Additional stiff supports were installed in head gate entries around the stage loader and equipment about 60 m (200 ft.) outby of the longwall face (solid). As the longwall face approached the fault, predicted displacements were documented and manifested by severe loading on the installed supports.BACKGROUND AND STUDY OVERVIEWThis paper summarizes results of a cooperative study aimed at improving longwall mining operations in Illinois. More specifically, the study focused on: 1) In-mine measurements in development entries while mining ahead of and behind a faulted zone, 2) Making observations on stability of pillars and entries while mining through the fault, and 3) Developing simplified analytical structural models using FLAC3D to assess if predictive techniques can be developed to plan mining operations through fault zone. Available data on geometry of the fault with estimates of the cohesion and frictional parameters were used for modeling."

Jan 1, 2015

By J. R. Morris

"A hoisting plant design should satisfy two basic requirements:1. to provide the necessary materials handling capacity, including ventilation where applicable, while meeting the requirements of good practice and, as a minimum, government regulation; and2. to optimize the economics of the project. Selection of hoisting equipment to meet the first objective is a complex but logical engineering process. The necessary calculations of payloads, accelerations, speeds, rope strength, hoist size, and power requirements are very readily carried out on computers or programmable calculators. A variety of hoist options can be quickly examined to assess the effects of changes in design parameters.Meeting the second requirement involves balancing the costs of various hoist arrangements and shaft designs, together with the time cost effects of differing shaft sinking rates and potential advances to be gained by concurrent level development. The proposed mine layout is significant here, as is the possibility of future shaft deepening and/or production increase. The availability of used equipment may be significant, both as regards first cost and delivery time. The factors are interactive, with their relative effects .varying from project to project. This paper sets out the primary factors to be considered."

Jan 1, 1990

By F. Crundwell, N. Steenekamp

"The leaching of sulphide minerals generates a significant amount of energy. There are three systems that might be used to remove this energy. These are: cooling coils, quench water, and flash recycle. Flash recycle is the recycling of slurry from the autoclave to the feed tank. Heat is removed in this arrangement when the slurry at elevated temperature and pressure is flashed to atmosphere, releasing steam. The slurry is returned to the autoclave at lower temperature, resulting in cooling. The cooling is directly proportional to the steam released from the recycled slurry. Design equations and results for the flash recycle system are presented. A fourth proposal for removing heat is to recycle slurry from the back of the autoclave. These four alternatives not only remove the heat, but also have an effect on the leaching efficiency. Amongst the four alternatives, design calculations indicate that the flash recycle option is the optimal solution in terms of leaching efficiency and heat removal, and recycling product from the back of the autoclave is the worst. In spite of its efficiency in terms of heat removal and leaching, the implementation of the flash recycle system is limited to a few operations in the platinum industry.INTRODUCTIONIn considering ways to improve leaching operations, focus is placed on the chemistry, on the kinetics, the agitation and perhaps even on the gas mass transfer conditions. Attention is less frequently placed on the removal of energy from these reactors and how this might limit performance.The pressure leaching of sulphides releases a significant amount of heat. For example, the reaction for the leaching of chalcocite, Cu2S, given by"

Jan 1, 2012

By McNeely DuBose

INTRODUCTORY PROSPECTING for aluminum has always been, and still is, a peculiar combination of the technical with the physical approach, and 1 want to explain my conception of the term 'prospecting' when applied to aluminum, which differs in some respects from the ordinarily accepted idea of prospecting. In the early days of gold mining, prospecting was a search in the hills and the river beds for the metal, not for its chemical combinations. And so it was in the early days of aluminum, with the difference that the search for the metal was carried on, not in the hills and dales, but in chemical laboratories. Aluminum is never found in the elemental state and at that time the metal bad never been seen, but scientists of that day bad forecast that such a metal must exist and in 1807 Sir Humphrey Davy went so far as to give this unseen metal a name, aluminum, from the Greek word alumen. This word applies to our alum, and it was from alum that Davy sought to produce the metal. It is strange to think that, in laboratories throughout England and on the continent, prospecting for aluminum was busily under way by men who had never seen the metal they were searching for. Their situation was something like that of the fisherman and the 'big one' that got away. They could describe the metal, give its exact weight, and even name it, but they could not produce visual evidence of its existence. Eventually, however, the efforts of the scientist 'prospectors' were rewarded and in 1826 the metal was actually produced, possibly first by Wohler, though Oerstedt, a Danish chemist, is usually credited with the achievement.

Jan 1, 1951

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By M. Bustin, A. Hosseinian, G. Preisig

Hydraulic fracturing and hydraulic shearing techniques are essential for the development of unconventional oil & gas and geothermal resources. Such techniques will also play a key role in the development of CO2 sequestration, and management of high stresses encountered with deep mining. However, the optimal design of hydraulic injections is often limited by continuum treatments of the rock mass without consideration of the influence of the natural fractures present. These may interact with the hydraulic fracture to promote offsets or arrest, or may cause the natural fractures to undergo shear and dilation. Given the limited access to the rock afforded by deep boreholes common to oil & gas and geothermal projects, advanced numerical modeling is critical for understanding key mechanisms and interactions. In this work, we first present a coupled hydromechanical distinct-element model focusing on the propagation of a hydraulic fracture. Normal and shear displacements arising from the generated hydraulic fractures are subsequently integrated into a fracture flow model for detailed analysis of specific flow behaviour and fracture permeability. For this, a scanned 3-D profile of a natural fracture is used to correlate surface roughness to dilation as a function of shearing. Fracture flow is computed at different time steps corresponding to different fracture propagation states and geometries. Modeling results indicate that the opening of a tensile hydraulic fracture is accompanied by millimetre-scale shear displacements associated with slip and wedging between adjacent blocks. This may leads to a mismatch between the upper and lower walls of the fracture if asperities are irregular and strong enough. However, fluid-induced tensile fractures have low Joint Roughness Coefficients (JRC), and associated millimetre-scale shear displacements are too small to ensure a significant offset of asperities that prevent a fully-elastic closure when the hydraulic fracture is depressurized. Injection of proppant is thus critical to keeping hydraulic fracture apertures open. Future work is planned that will see the models calibrated against field data including microseismic event locations, magnitudes and source mechanisms, tiltmeter deformations, stress change, and pore pressures.

Jan 1, 2015