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Thermal Processing of Petroleum Fly Ash for Vanadium Recovery

Sep 13, 2010

By McGill RA

The Ranger Uranium Mine is surrounded by a World Heritage National Park. The strict environmental controls under which the mine operates are based on scientific and social requirements. Release of non-process storm runoff water to the Magela Creek during flood discharge and under controlled conditions has been identified as Best Practicable Technology for the operation of the water management system. Social and political factors have limited this release to a wet season with an Annual Exceedance Probability of one in ten. The first-generation trigger mechanism was based on a percentile analysis of monthly rainfall. The second-generation trigger is based on cumulative monthly volume increase in the retention ponds and is considered to be more applicable to the operation of the mine water management system.

Jan 1, 1988

By D Feng, G C. Lukey, J S. J, R R. Dagastine

An ongoing challenge in the coal industry is pyrite removal using the flotation method for fine particles. The use of a æseparation in frothÆ (SIF) technique to recover coarse particles of up to a few millimetres in size has presented a potential solution. However the commercial success of SIF is still limited due to the poor understanding of the separation mechanism. The particle floatability in SIF is determined by the constructive or destructive stresses resulting from the forces exerted by the particle on the bubble films. Hence, the surfactant properties and the mineral characteristics (eg hydrophobicity, shape, etc) are the key factors that control the interaction between the particle and froth. In the present work, the interaction forces between different particles (ie crushed glass, pyrite and coal) and a single air bubble are measured in a non-ionic surfactant solution (pentaethylene glycol mono n-dodecyl ether, C12E5) using an atomic force microscope (AFM). Experimental results show that the interaction is primarily dependent on the contact angle (ie the degree of hydrophobicity of the minerals). For crushed glass, the transition from repulsion to attraction was observed as the contact angle increased. As the concentration of C12E5 increased, the adhesion force was suppressed due to wrapping effect. For coal and pyrite with much higher hydrophobicity, long-range attraction was observed. The effect of shape factor was only visible at high surfactant coverage where sign of destabilisation became noticeable on the retracting force curve. These results provide a fundamental understanding of the direct interaction forces of a complex real system between an irregular particle of either crushed glass, pyrite or coal and a single air bubble. Theories developed for interpretation and modelling are thus far based upon the study of ideal systems of glass or polystyrene spheres and an air bubble and were incapable of explaining the interactions in complex real systems. The presented measurements were a first approach to the problem of real mineral-bubble interaction in flotation systems. Thus, the results can only best be interpreted semi-quantitatively.

Jan 1, 2005

By Nilsson C

Man has always been and will always be part of his environment, in ,a good, bad or indifferent manner. Until quite recently, this environment has been the atmospheric boundary layer above the land masses, and to a limited extent the air-sea interface of the oceans. Since the days when he lived in caves, he has built up a wealth of observations on these two environments,-with ever-increasing scientific precision which unfortunately until quite recently was completely insufficient for modern capabilities of data analysis. Consequently, in a sense, he has left in his wake thousands of years of missed, opportunities for making exact observations and increasing his understanding. The data of the past are lost and he has to be satisfied with what he can assemble from now on when his environ- ment, largely as a result of his actions, is exhibiting more and more rapid variations in time; in other words, time series of observations of phenomena are required, the length of which is critical for most purposes of analysis.

Jan 1, 1970

By B Dold

Western Europe is a dynamic region, with an emerging co-operation between the individual nations both politically, economically, technically and scientifically. The European Union, today with 15 member States and with a range of central European States applying for membership, is a catalyst for this Cupertino, using a combination of EU funds, for financing research initiatives, and legislation to enhance development of technology and environmental performance. Europe is a major net importer of metals but with a large potential for own production, in particular in the accession countries. The metals and mining sector is furthermore identified as having a large potential to generate wealth both in todayÆs EU and in the future, widened Union. This paper provides a chart of examples on the many research initiatives presently underway in Europe, addressing environmental issues related to mining. The list of programmes and projects does not claim to be complete; it is rather an illustration on the wideness of the approach, describing various ways for transboundary Cupertino. The approach taken by many of the programmes goes beyond the strict ARD scientific area and therefore only a limited number of the many programmes can be identified as ARD research programmes. Also national programmes, without EU funding, are operating, eg in Sweden, Germany, and UK. The picture is continuously changing with new programmes being commissioned and old ones being completed.

Jan 1, 2003

By Burford B. D, Johnson N. W, Rohner P

Under design philosophy, the Hilton concentrator produced lead, zinc and LGM (lead plus zinc) concentrates. The LGM (Iow grade middling) concentrate was produced by combining coarse middling streams from the lead and zinc circuits, regrinding and subsequent flotation. Mineralogical examination of the zinc circuit middling stream prior to regrinding suggested that production of zinc concentrate from the zinc circuit middling stream should be possible by rearranging existing plant equipment. Laboratory testing of samples of plant products, however, showed that regrinding combined wi th the usual reagent suite was nO1 sufficient to produce a zinc concentrate of the required specifications.Examination of the process water highlighted a problem with dissolved salts in the circuit water, which was solved by in-circuit precipitation of the dissolved ions with soda ash. Implementation of the procedure in the concentrator effectively transferred to the zinc concentrate all sphalerite previously recovered to the LGM concentrate.

Jan 1, 1994

By Palmer W. T

The successful re-opening of the Cobar min- eral field was dependent upon the success- ful introduction of highly productive, low cost mining. Mechanised cut and fill stop- ing with incline access was selected for the C.S.A. mine because it permitted flexi- bility, complete primary extraction with no secondary pillar recovery, minimised dilu- tion and oxidation, a minimum of pre-pro- duction development and because diesel powered load-haul-dump (L.H.D.) units were proving reliable and highly productive in the U.S.A. Although L.H.D. vehicles are the key to the success of the mining method, four other main groups of vehicles are utilised in the mine - trucks, scaling vehicles, ser- vicing vehicles and specialist vehicles. The operating requirements at the C.S.A. mine are more stringent than those encount- ered in many other underground mining oper- ations. The first L.H.D. vehicle used at Cobar - the Transloader - had considerable difficulty in loading and discharging coarse production ore. The Wagner ST5 Scoop Tram performed this duty much better. However, the first generation Scoop Trams were not robust enough to withstand the heavy duty and many modifications were necessary before acceptable availabilities were obtained. Similar modifications were necessary for the Eimco 916 vehicle but the Eimco 915 unit came much closer to meeting the duty requirements. Eventually Cobar technical personnel design- ed a L.H.D. vehicle to meet specific C.S.A. mine conditions. These units have proven most satisfactory. Over 8 years of operation the underground vehicle fleet has become a proliferation of vehicle types. A standardisation pro- gram has been initiated based upon common prime movers being mated with "trailer" units to serve specific functions. Standardisation will reduce inventory levels and facilitate training of operating and maintenance personnel.

Jan 1, 1973

By Prosser AP

The large body of knowledge about the relation between chemical process efficiency and mineralogical features is of only limited use. The profession ought to try to improve the methods of using information as well as adding to the knowledge. One attempt isòdescribed. Correlations between process efficiency factors and the mineralogical features of low- grade concentrates have been developed from both a theoretical analysis and experimental measurements. The ultimate recovery of a reactive phase in an inert matrix can be calcu- lated from simple measurements of the particle size, porosity and pore size of the concentrate, and the grain size of the reactive mineral., The rate of recovery, up to 98% recovery, can be calculated from simple measurements of particle size, porosity, proportion of reactive mineral and tortuosity. Some details are given. The correlations are of potential use in process selection and preliminary design. Satisfactory predictions have been made for near-ideal systems. Improvements in the measurement of pore size and tests on more realistic materials are required. The ultimate benefit of the correlations will be determined by the magnitude and frequency of the effects of mineralogical features other than those specified above.

Jan 1, 1975

By P Card

Some project managers accept unsatisfactory economic evaluation modelling because they are unaware of what constitutes good practice. They tend to leave it to the evaluation specialist or others to decide. The AusIMM has published on its website a draft set of guidelines for technical economic evaluation which will allow these project managers to take control and demand worldÆs best practices.The style of the guidelines is described and the source of a worked spreadsheet example in Excel is given.Economic evaluation in project management is described. A simple test for the acceptance or rejection of evaluation work is offered. The nature of modelling and evaluation in each of the three study phases of concept, prefeasibility and final feasibility are described. Suggestions on the selection of specialists for each phase are given. The three levels of evaluation thinking are described, namely, modelling, valuation and evaluation. Finally the meaning of æfinancial analysisÆ is explained.The conclusion is that æthe role of an economic evaluation specialist is to create models and evaluations for the whole project team to readily understand and use: it is not to create models for his/her own useÆ.CITATION:Card, P, 2012. What project managers must demand from an economic evaluation!, in Proceedings Project Evaluation 2012 , pp 173-176 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 24, 2012

On-line radioisotope gauges determine information on the characteristics of ore to enable improved control of processing operations. In the metalliferous mineral industry, in-stream analysis systems based on radioisotope X-ray techniques determine concentrations of valuable minerals at various stages of the concentration process. In the coal industry, on-line gauges determine ash and moisture contents, and the specific energy of coal.In-stream analysis systems developed in Australia are installed in about 30 mineral concentrators. Their use has led to the increased recovery of valuable minerals, and the time taken to recover the cost of installation is usually several months. The savings to Australia resulting from use of these analysis systems is estimated to be more than $A 15 million per year.Australian experience in the training of mineral industry personnel shows that the most effective approach is to combine courses on nuclear techniques and control of processing operations. This is the basis of Australia's contribution to the minerals sub-project of the United Nations Development Program (UNDP) Industrial Project.

Jan 1, 1985

The difficulty in creating and obtaining a competitive edge in the mineral industry is rapidly increasing. The Kiruna Iron Ore Mine in the far north of Sweden is currently thriving on the world market through firm managerial strategy. LKAB believes in upgrading its raw material to produce a high quality iron ore product for sale to steelworks throughout the world. It is vital that this product is also of uniform quality and quantity to provide quality assurance to customers. The first link in meeting these product requirements starts in the underground workings. Mining methods and operations are of large-scale. Automation and continuous production streamline operations and reduce operating costs. These factors have built Kiruna Iron Ore Mine into the world's biggest, most modern, underground iron ore mine. To remain competitive on the world market, LKAB relies heavily on research and development. The mine is currently in a phase of upgrading its operations. A 25-tonne Toro electric loader is being tested to improve the rate of output of ore from the mine. Long hole drills are being improved to increase accuracy and efficiency. An electronic detonating system will improve detonator delay precision. Projects are underway to better understand ore flow mechanisms from a caving orebody. Benefits include improved ore recovery along with better rock quality control at the caving front. The continued updating of mining operations at Kiruna will enable LKAB to continue to maintain its competitive advantage on the world market in the production of high quality iron ore products.

Jan 1, 1997

The original and most basic relationship between mining company and explosive supplier was a simple one of consumer and product supplier. The divide between the two was quite clear-cut with neither taking much interest in the activities of the other. The explosive supplier had little understanding or share in the outcome, efficient rock breakage and therefore impact on mining and milling. Likewise, the mining company did not encourage the improvement or development of products. The transactions were limited to product and funds. This environment does not encourage any form of knowledge sharing, trust or optimisation of the mining process.Conversely, there are now a variety of relationships to the point that the mining company may simply be an asset manager whereby all æoperationalÆ aspects are contracted out. For the drill and blast aspect this takes the form of a æRock-On-GroundÆ contract whereby the explosives company takes on design, drill, load and fire responsibilities and is paid a rate per volume of broken rock. This removes the majority of risk to the mining company derived from having to produce broken rock and guarantees the cost of a portion of the overall unit cost of mining. The onus is now on the explosives supplier to break rock to a specification as efficiently as possible.There exist a number of variations between the æbasic supplyÆ and æRock-On-GroundÆ. These contracts may also include value sharing to encourage the explosive supplier to optimise the mining operation to maximise profit.This paper looks at some of the drivers for the change in explosive supplierûconsumer relationships and examines the æprosÆ and æconsÆ of a few of the options.

Jan 1, 2004

By Fukuichi K, Matsukawa H, Nakagawa M

The Myojin Tunnel, located on the Shikoku Expressway being constructed by the Japan Highway Public Corporation, is 3,770 m long with a cross sectional area of 80 m2. Kajima Corporation, the contractor for the northern construction section of this tunnel, adopted here its newly developed "mini-bench" method of excavation. The objectives of this method were 1. to be able to perform all tunnelling operations using the whole cross sectional area of the tunnel under any ground conditions, and 2. to be able to vary the length of the mini-bench within the range of 0 to 7 m according to ground conditions. In order to achieve these objectives, original, sophisticated equipment was developed and employed in the work. One of the newly developed machines is a special jumbo, a hydraulic crawler jumbo with five rotary type booms. This machine is capable of accommodating variation in the length of the mini-bench accompanying changes in ground conditions and is equipped with a special mechanism by which the positions of the booms can be controlled by means of hydraulic cylinders. Also developed was a shotcrete robot for use with the mini-bench method which has the control board near the shotcrete nozzle for close control of application.

Jan 1, 1987

By Paine GG

The in-situ retorting of shallow oil shale deposits is an attractive alternative to the material handling problems of conventional open pit mining techniques, which involve removing overburden, fragmenting and transporting the shale to a fixed retort, and finally disposing of the hot spent shale.For in-situ retorting to be successful, the oil shale has to be fractured and the fragmented rock expanded into a void, to allow controlled propagation of a flame front through the in-situ retort. The principles of cratering with explosives have been used to develop a process for the in-situ fracturing of a thin oil shale deposit overlain by a formation of porous rock. The overlying porous rock formation is first compressed by explosive charges to create voids in the porous rock. The oil shale is then fragmented and pushed in to the voids with separate explosive charges. This paper discusses methods of creating voids in porous rocks with minimal surface disturbance, and then methods of obtaining the most uniform fragmentation of the shale. The whole process can be completed, in practice, in one blast. The results of an experimental blast are presented, and possible modifications are then discussed.

Jan 1, 1985

Since the announcement of early experimental work on rotating magnetic field (RMF) separation at the Sixth Mill OperatorsÆ Conference in 1997, the concept of RMF separation has been developed and tested further, and a range of separator designs is now being developed for the mineral processing industry. Shortened, but full diameter, prototypes of these designs are now available for test separations. The main advantage of RMF low and medium intensity attraction separation is the significant reduction in particle entrapment. This reduction is so significant that RMF separators are capable of operating very close to their theoretical limit for separator precision. This makes small laboratory RMF attraction separators ideal for low to medium intensity magnetic sample analysis, and larger separators ideal for applications requiring sharp magnetic susceptibility splits. Feedrates and separation rates are comparable to those of conventional attraction separators. Although RMF attraction separators are now well advanced in development, RMF rotation separation is still in the early experimental stage. The exception to this is the dry particle rotation eddy current separator that offers eddy current separation of small non-ferrous metallic particles from about 2 mm down to about 100 microns. Wet small particle eddy current separation is also possible, but has not yet been developed to a practical stage.

Jan 1, 2000

By Myers I. A, Peters S. G, Bultitude R. J, Dowling K

Gold-quartz and antimony-gold-quartz veins in the Hodgkinson Province are hosted by subgreenschist to greenschist facies metasediments and show no spatial association with granitic rocks. They commonly parallel axial plane foliations or occur in brittle to brittle-ductile shear zones. Detailed mapping in the Hodgkinson goldfield indicates that vein systems are isolated in distinct structural and lithologic domains by post-mineralization faulting. Gold-quartz and antimony-gold-quartz veins have distinctive mesoscopic textures characteristic of the mesothermal vein environment. Some of the antimony-gold-quartz veins are located on domain boundaries which truncate the gold mineralization. In. some areas, tin and tungsten-tin mineralization which are spatially related to Late Palaeozoic granitoids appear to postdate the gold-quartz and antimony-gold-quartz mineralization.Oxygen and hydrogen isotopic studies of vein and alteration assemblages associated with these diverse ores provide constraints on fluid sources and have implications for the origin of mesothermal gold mineralization. The available isotopic data are consistent with a dominantly magmatic source for tin and tungsten-tin mineralization although there is evidence of a late-stage meteoric component in some tin-mineralizing systems. Although a distal magmatic contribution cannot be entirely discounted, the gold-quartz and antimony-gold-quartz veins were probably deposited from deeply

Jan 1, 1990

By M Pomery

BHP’s Western Australian Iron Ore Operations (WAIO) move approximately 250 million tons of ore per annum. The magnitude of the constant changes to the terrain models along with the diverse output and presentation requirements of numerous stakeholders presents significant challenges for the geospatial team. This paper describes how the WAIO Survey team use a combination of technology and optimised workflows to capture, ingest, publish and access large data sets for diverse stakeholder requirements. Machine learning for processing of data and the use of web based systems to track and prioritise task allocation of resources will be discussed in detail, in addition to the changes to the traditional roles of surveyors from the use of automation and mobile technology.

Sep 18, 2023

By M Alston

Many organisations struggle to yield meaningful outcomes from incident investigations. This paper will demonstrate that we can discover systemic issues by rethinking the ‘Why’ and ‘How’ of investigations, fostering genuine risk reduction. Key points: 1. Shift from ‘prevent recurrence’ to ‘learn and reduce risk’: conventional investigations focus narrowly on recurrence prevention, resulting in narrowly focused investigations with limited ability to identify and reduce organisational risk. Redirecting our objective to learning and improvement opens avenues for broader risk mitigation. 2. Understanding daily work for risk insights: recognise that work is not always completed in full compliance with procedures. Workers will adapt how they complete tasks influenced by the conditions and management systems that exist every day. Understanding the conditions and systems affecting everyday work is vital for uncovering systemic risks. 3. Unearth systemic issues through in-depth exploration: many investigations address surface concerns such as lack of training, incorrect procedures, equipment not being maintained, and missing overarching organisational risks. Systemic, organisation-wide risks are not identified. To discover these systemic issues and create shared learnings, investigators must question management systems, including resourcing, planning and risk management. 4. Design actions for safe failure: common actions like discipline and training fall short and do not reduce risk. Resilience emerges from well-designed controls. Incorporate planning, better resources, interlocks, and guarding to bridge the gap between task execution and risk. 5. Investigation Reports as a Business Case: Investigation reports should not simply state historical information regarding an incident. They are to facilitate decision-making and be presented as a business case to drive change. Organisations can move beyond localised risk and ineffective administrative actions by changing investigation objectives and methods. They can facilitate learning, understand daily work intricacies, identify systemic issues, and enhance the capacity for safety, driving lasting risk reduction.

Apr 16, 2024

By M Dohm, L Pretorius

This paper provides a brief historical background to the approximately 12-year project that led to the revision of rope selection factors in the South African regulations, thus providing the ability to hoist economical payloads from single lift ultra-deep shafts. The efforts over the past 20 years have led to the revision of the legislation pertaining to rope selection factors, the redesign of rope constructions to meet the required duties associated with ultra-deep shafts, codes of practice for the design, operation and maintenance of winding plants, and a code of practice for the condition assessment of winder ropes. As a consequence the Moab Khotsong ultra-deep hoisting system could be developed and installed, with the assurance of predictable performance. Access to deep orebodies by means of single lift, ultra-deep shafts has a critical impact on the life cycle costs and efficiencies of ultra-deep mining complexes. A brief description of the main components of the hoisting system at Moab Khotsong is presented. An in-depth review of the development process applied to ensure a stable, safe and cost-effective rope construction for the ultra-deep Moab Khotsong shaft follows. The paper concludes with an overview of the experiences gained during the installation and commissioning phases of the winder, as well as operational and maintenance issues.

Jan 1, 2005

By Jowett A

To compare open circuit lead primary rougher results at Mount Isa Mines Ltd., eleven surveys were made over five weeks of plant operation with varying ore sources, including a specially hauled sample of 100% Black Star ore. Three of the surveys which represented extremes in performance were selected for sizing, cyclosizing and assaying for lead, zinc and iron. A comparison of the flotation kinetics has revealed the similarities (including common problems) and differences for the surveyed ores. The concepts of entrainment and collectorless flotability are used to aid interpretation of the kinetic data.

Jan 1, 1978