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By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

By S Jeon, K Haga, A Shibayama, L Godirilwe, C B. Tabelin, I Park, A Buronov

Open pit/underground mining and mineral processing can generate large amounts of waste that contains sulfide-type minerals such as pyrite (FeS2), and it can produce acid mine drainage (AMD) when exposed to oxygen and water. This highly acidic wastewater contains heavy metals and this is one of the most serious environmental issues after mining operations taking several decades to completely remediate with high costs. For green mining, the present study focused on the development of a recovery technique for gold from an eco-friendly solvent, thiosulfate, by utilising mine wastes, tailings. First, gold recovery experiments in ammonium thiosulfate system were carried out using model samples representatively present in tailings (ie SiO2, Al2O3, FeS2, Fe2O3, and Fe3O4). The results showed that gold recoveries were negligible when using Al2O3, SiO2, Fe2O3, and Fe3O4 while pyrite shows a recovery efficiency three-fold as high as the maximum recovery efficiency when using others. Subsequently, the study also addressed the identification of the recovery mechanisms and post-recover process. The results indicate that tailings can be sufficiently utilised for gold recovery in the hydrometallurgy process and a further sustainable process can be established.

Sep 1, 2024

By J A. Rumball

Measuring cyanide in the leach liquors associated with high copper and/or sulfide ores is a non-trivial exercise. It is well known that copper complexes with cyanide and reduces the amount of cyanide available for gold leaching. What is not so well known is that the rhodanine end point overestimates the amount of cyanide available for leaching in the presence of copper. Sulfide ions also interfere with a rhodanine end point titration, although this is less of a problem as the black silver sulfide precipitate formed clearly indicates to the operator that something is wrong. Thiosulfate, which forms readily from the alkaline oxidation of sulfides, causes an overestimation of the cyanide available for leaching due to the formation of Ag(S2O3)-. The net result of these observations is that rhodanine is rarely of value as an end point indicator in complex solutions. It generally overestimates the amount of cyanide available, providing plant metallurgists with a false sense of security. Potentiometric titrations are generally much more capable of accurately measuring cyanide in complex solutions. The interfering effect of copper can be resolved and it is even possible to estimate the copper concentration using the inflexions associated with the titration of CN- + Cu(CN)43- versus Cu(CN)32-. Using the potentiometric method sulfide ions can be determined before the cyanide measurement is made due to the formation of AgS2, although the electrode will foul with repeated measurements. Thiosulfate can also be distinguished from cyanide with a potentiometric titration. Rhodanine and potentiometric titrations are both affected by the pH of the liquor. At pH 9.2 half the cyanide will be present as CN- and half as HCN(aq) with only the CN- being titratable. This does not hold in the presence of a buffer active around pH 9. In the presence of sufficient buffer, both the CN- and HCN(aq) are titrated. Ca(OH)+ may buffer the pH when large amounts of lime have been added.

Jan 1, 2007

By H Mischo, M Ferber, M Donner, B Jung, S Grehl, A Dietze

Mobile robots have been making impressive inroads in a variety of domains. Within the Mining-RoX project, Technical University Bergakademie Freiberg is exploring a further frontier for mobile and autonomous robots: underground mines. The potential benefits of mobile robots in underground mining are plentiful as underground mines are strenuous and potentially dangerous working environments for humans. A higher degree of automation, with robots either acting as helpers for human miners or even replacing all human personnel deployed underground, could help to significantly reduce mining costs. In disaster cases, rescue robots could help to find missing personnel. Unmanned mines operated by robots alone would not endanger human lives at all. Further use cases, and a particular focus of the Mining-RoX project, are mobile robots that gather sensory information of the underground mine (eg for the purpose of creating detailed 2D and 3D maps) as well as monitoring environmental conditions such as air and water quality. This paper presents the design of a prototypical mobile robot for mapping and monitoring underground mines. A generic robotic platform was extended with various 2D and 3D imaging devices as well as other sensors. First results from test runs in an underground mine are reported. Maps of two sections of the mine enhanced with localised sensor measurements were successfully created.CITATION:Grehl, S, Donner, M, Ferber, M, Dietze, A, Mischo, H and Jung, B, 2015. Mining-RoX – mobile robots in underground mining, in Proceedings Third International Future Mining Conference, pp 57–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By B J. Wight, R Mackay, S Kim

Improving the understanding of the processes governing ground movements in and around brown coal open cuts is of significant interest for both operating stability and rehabilitation. Brown coal, lignite, is a low-rank coal that is best described as a soft rock, with geotechnical characteristics that derive from its organic origin. It is well-known that low-rank coals exhibit creep behaviour; however, little has been reported on the impacts of chemical processes on brown coal creep behaviour even though organic substances are susceptible to chemical alterations and mining processes will contribute to changes to the geochemical environment; around most mines, groundwater flow patterns are altered leading to enhanced surface water infiltration. Here we study the deformation behaviour of brown coal in response to ion exchange reaction. Our experimental results show that for different ion exchange conditions different characteristics of secondary compression are observed. With the addition of Ca2+, the ratio between coefficients of secondary and primary compression (Ca /Cc) initially decreased, presenting a minimum value at the concentration of 0.005?M, then increased significantly. This implies the importance of ion exchange process for the long-term deformation of brown coal. On the other hand, increasing Na+ concentration did not affect Ca /Cc values significantly over all tested concentrations. The suppression of diffuse double layer was still observed for Na+-treated samples as increasing Na+ concentration decreases Ca values. From a practical perspective, this study did not consider the tertiary creep behaviour and eventual creep failure.CITATION:Kim, S, Mackay, R and Wight, B J, 2014. Creep due to chemical alteration of rocks – a case study in brown coal, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 61–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By L Dubron

This study details a mineralogical and textural characterisation of West African iron ores with an emphasis on their behaviour during mineral processing. By means of both qualitative and quantitative characterisation, a simulation of the beneficiation process applied to these iron ores is performed. A series of different analytical tools are used, including:X-Ray Diffraction (XRD) for qualitative mineralogical analysis;• qualitative optical microscopy (phase identifi cation, description of micro-textures) and (semi)• quantitative optical microscopy (counting of particles, phases and textural types); and• chemical analysis.All the information provided by these analytical methods are combined into a quantitative mineralogical and textural analysis, here called ‘modal analysis’, which enables us to simulate the capability of West African iron ores to be benefi ciated by magnetic and gravimetric separation techniques.On one hand, both qualitative XRD and optical microscopy have revealed the presence of the following mineralogical phases: magnetite, haematite, goethite and quartz. On the other hand, the chemical analyses provide us with quantitative inputs expressed as oxides. We have converted the oxides into mineralogical contents expressed as magnetite, haematite, goethite and quartz. In this way, we build a simple quantitative mineralogical analysis.Beside this, the semi-quantitative approach of the characterisation by optical microscopy also provides us with a liberation study, enabling us to split the gangue-bearing content between two types of particles:1. liberated gangue-bearing particles, and2. composite particles composed by both iron (oxhydr) oxides and gangue-bearing minerals.We have assumed that we could anticipate the behaviour of these two kinds of particles through a mineral process, by simulating the removal of at least the liberated particles of gangue. Optical microscopy also revealed a trend in the weathering profi le of the Tokadeh ore horizon with a decrease from bottom to top of magnetite and an increase of both goethite and martite showing a higher level of oxidation and hydration in the upper ore horizon.We have applied this removal extent upon the quartz content of the mineralogical quantitative analysis and we have re-calculated the quantitative mineralogical analysis considering the expected decrease in the quartz content. Finally, by converting the re-calculated (oxhydr) oxides contents into iron grades and summing them, we do obtain a fi nal simulated iron grade for the upgraded products.

Jul 11, 2011

By Sen A. K

The Chiria Iron Ore deposit falls within the well-known Horse-shoe-shaped Singhbhum-Bonai-Keonjhar belt in India, where most of the deposits supplying ore to various steel works of Steel Authority of India Limited (SAIL) and Tata Iron and Steel Company (TISCO) are located. With an estimated reserve of about 2000 million tonnes of ore (at 55 per cent Fe cut-off) spread over four contiguous blocks, it is the largest iron ore deposit in India and one of the largest in world. The present study is confined to only one of the four blocks of Chiria viz North Block, comprising an area of 2.11 km2. `Corporate Plan 2005' of SAIL envisages development of a large open cast mine at Chiria to meet its enhanced requirement of iron ore by 2001-02 AD.

Jan 1, 1995

By J P. van Dijk, M Munro

Discrete vein modelling presents an innovative geology driven 3D modelling method for quantification of vein hosted mineral deposits, with far reaching potential for critical mineral supply and low impact resource extraction. By integrating key geological drivers with advanced discrete fracture network modelling, the DMX protocol (launched in 2019) converges to a more realistic representation of complex vein systems in three-dimensional space. The approach insights greater geologic reasoning in distributing mineral grades where vein boundaries are already defined. This presents a viable alternative to existing modelling and estimation methods and has important implications for mineral resource estimation and reporting. Further implications are discussed, where the enhanced understanding of complex orebody characteristics can potentially be used in optimising mining and mineral processing, supporting more sustainable and efficient mining practices.

Sep 1, 2024

By McOnie A. W, Rutherford PG

A volcanic sequence is described from the Golden Cross Mine, Waihi, New Zealand. The sequence includes seven lithostratigraphic units comprising flow and pyroclastic units of Coromandel Group andesite and dacite and overlying Whitianga Group dacite and rhyolite which is intruded by the Golden Cross dacite porphyry and rhyolite dykes. The sequence is mineralized and is unconformably overlain bv_ two post-mineral units, the lacustnne Waitekauri beds and Omahine Subgroup andesite. Detailed structural analysis of mine data has identified four deformational events (D 1-D4) and related these to the gold-silver mineralizing events. Faulting was coeval with the mineralization and directly controlled the development, localization, style and geometry of the ore shoots. Mineralization developed in competent lithologies where dilation occurred during faulting. The Empire Fault is the master shear which controlled fluid flow. Mineralized veining developed in response to tectonic pulses occurring at slightly different stages as represented by the underground Empire vein complex and the open pit vein array. The mineralizing events culminated with the deposition of barren calcite veins. Post-mineral movement along the Western Boundary fault appears to have offset the ore body.

Jan 1, 1995

The Quiruvilca district, located 80 km east of Trujillo in north central Peru (Fig. 1), has produced over eight million tons of Cu-Pb- Zn-Ag ore from approximately 60 veins since 1789. "Quiruvilca means "sacred tooth" in Quechua, the lingua franca of the Incas. The expression refers to a prominent volcanic neck exposed several kilometers northeast of the district. The district covers an area of approx- imately 24 km2. The mines occupy the eastern quarter; workings underlie 6.7 km2 with a developed vertical range of 280 m. All pres- ently operating workings are owned by Corpora- cion Minera Nor Peru S.A., a subsidiary of ASARCO Incorporated. The oldest rocks in the area are Lower Cretaceous clastic sedimentary rocks exposed 7 km to the east. Lithologies include sand- stone, siltstone, shale, coal seams, and carbonates (Cossio, 1964). These rocks were folded and affected by regional low-grade metamorphism during the early Tertiary, 40-65 m.y. (Hollister, 1977).

Jan 1, 1987

By Jackson GS

Since 1983 Cobar Mines Pty Ltd has madea concerted effort to improve the performance of its long hole open stopes, especially in the areas of dilution and fragmentation.This has resulted in modifications to stope design, drilling and blasting practice.

Jan 1, 1985

By Cullen JF

Australia has a large resource of manganese at BHP's Groote Eylandt mine which has been progressively developed over the last two decades. While much of the product is marketed internationally to the iron and steel industry, substantial quantities are processed in Australia at the Company's ferro alloy works in Tasmania. In addition, small but increasing quantities of ore are being consumed by the non-metallurgical industry. Fluctuating fortunes in the steel industry produce similar trends in the marketing of manganese. The increasing cost of freight and power together with strict environmental control is further affecting the market balance. Mine operators are expanding into the alloy making field. Reduction in usage in less developed countries is occurring.

Jan 1, 1982

By Richards JR, Herbert HK

A basic question in preparing this review was how to define sulphur mineral occurrences as being associated with the Pacific Rim. This question will be reconsidered later. The isotope composition of sulphur- containing minerals may be considered in terms of two primary sources - 1. deep- seated sulphur, devoid of crustal contam- ination with a 634S value near 00/0o and 2. oceanic sulphate which fluctuated in value between +10 and +300/00 over geological time (Claypool et al., 1980). However, minerals have seldom been directly derived from these primary sources as even evaporites have been dissolved and reprecipitated. The marine source is differentiated biochemically and isotopically in recent sediments where sulphide from bacterial sulphate reduction may be significantly depleted in 31S. The question of chemical interaction of ascend- ing magma with upper crustal rocks has become one of degree rather than whether or not it occurs. Mineral deposition is considered increasingly in terms of mixing of fluids and their chemical reactions with rocks rather than direct precipitation from magmas or hydrothermal fluids derived from them.

Jan 1, 1987

By D François-Bongarçon

The link between geostatistics and Theory of Sampling (TOS) is examined again in view of new findings made while trying to compare predicted sampling variances and estimated grades (using geostatistics) on the same material, and this provides an important consistency requirement whenever calculations are made that involve both theories in a comparative way. It also briefly explores the relationship to De Wijs fractal model of mineralisation and eventually provides new support for the use of consistency theory for calibrating TOS variance formulas.CITATION:François-Bongarçon, D, 2017. Theory of Sampling and geostatistics – the ultimate link, in Proceedings Eighth World Conference on Sampling and Blending , pp 391–394 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By A van As

This paper serves to outline the circumstances and causes of the air-blast that occurred at Northparkes Mines in November 1999. It describes the design of the mine, the geotechnical issues surrounding cave propagation and the cave monitoring systems that were in place prior to the event. A short description of the air-blast that followed a sudden collapse is given. Details of the risk assessment process that evolved during the rectification process are provided with their subsequent modification to form the core of a major hazard monitoring process. The system is in line with the recommendations given by the Coroner resulting from the inquest into the deaths of the four people who lost their lives during the air-blast.

Jan 1, 2005

By P F. Hodkiewicz

"Our understanding of mineral resources relies on three basic steps: data capture data interpretation model construction. Until recently, all three of these steps required significant time and manual effort to produce a single resource model for mine planning, typically taking more than a year to progress from drilling to the final block model. Over the past several years, BHP Billiton has been developing innovative workflows in rapid resource modelling projects to significantly reduce these time constraints and make the process more productive by replacing manual activities with automated ones. Rapid resource modelling is the process of combining recently developed off-the-shelf technology with internal technology developments to fundamentally change the way we collect, interpret, model and evaluate geoscience data. Initiatives include automated systems and standardised workflows to make it safer, faster and cheaper to continuously update multidiscipline resource models. Specifically, rapid resource modelling workflows combine: real-time analysis of drill holes and drill samples with downhole tools and hyperspectral scanning systemsautomated interpretation of drill hole intervals based on pattern-recognition algorithmscontinuous modelling workflows using implicit modelling software. This paper outlines technology developments and workflows that provide a more thorough understanding of mineral resources to support faster and more informed strategic, planning and production decisions.CITATION:Hodkiewicz, P F, 2014. Rapid resource modelling – a vision for faster and better mining decisions, in Proceedings Ninth International Mining Geology Conference 2014 , pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 18, 2014

The first mining in Western Australia probably commenced some 40 000 years ago when Aborigines arrived and began quarrying stone for tools and weapons, and ochre for decoration. The earliest documented mining by European settlers took place in 1850 on a small lead vein in the bed of the Murchison River, reported by the explorer A C Gregory. However, it was the discovery of gold in the Kimberley region in 1885 that first drew wider attention to the State's mineral potential.

Jan 1, 1992

By Xu C

This paper describes the structure and operation of an interacth.. computer program for mineral industry financial analysis and production planning. It includes comprehensive risk analysis with correlated variables and optimal production scheduling using Lane's balancing cut-off grades and the general dynamic programming approach.

Jan 1, 1995

By Y Mita, T Iwama, R Inoue, S Ueda

In the iron and steel manufacturing industries, efforts are being made to achieve carbon neutrality by 2050, and the transition from a coal-based steelmaking process to that utilising renewable energy is being pursued. An alternative process in which directly hydrogen-reduced iron is melted in an electric furnace is being investigated. It is known that foaming slag reduces heat loss from the steel bath in electric arc furnace, but iron loss due to the suspension of steel particles in the slag is indispensable. To improve the separation of steel particles from the slag, the control of the slag viscosity is important. Although the slag viscosity has been extensively studied, in those studies the slag was considered to be a simple liquid. However, in actual operations, slag is a multiphase fluid consisting of solid, gas and liquid phases. Therefore, in this study, by measuring the sedimentation velocity of titanium, stainless steel and glass spheres in an aqueous glycerin solution containing bubbles generated by the reaction between NaHCO3 and C2H2O4, the apparent viscosity of the gas-liquid fluid was evaluated based on Stoke’s law. It was found that the apparent viscosity of the gas-liquid fluid is larger than the viscosity of liquid phase and depends on both the bubble volume ratio in solution and the density of the falling solid sphere, and the apparent viscosity was different from that previously obtained by the rotation method. The apparent viscosity derived from the sedimentation velocity of solid spheres changed depending on the specific gravity of the ball. This is because the apparent viscosity is derived from the velocity of a ball falling in a static bubble in this method, whereas that is derived from the force applied by a stationary flow in the rotational method.

Aug 21, 2024

By Collins DN, Hollick CT

Conventional processing of heavy mineral deposits containing radioactive rare earth minerals such as monazite and xenotime may cause industrial hygiene problems through atmospheric dust and contamination of product concentrates. An alternative procedure has been developed in which such minerals are removed from bulk heavy mineral concentrates by flotation with little loss of other economic minerals. With fine ores, recoveries of over 95% have been achieved and with coarse ores over 80%,in both cases at high grade. Several flotation regimes have proven effective. The potential for generation of radioactive dust or product contamination is subsequent processing -is correspondingly reduced.

Jan 1, 1990