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By P Card

“Let’s get discipline and quality into easy to understand evaluations!” Project Managers and MetPlant Operators accept poor quality evaluations because they are generally unaware of what they should expect.The 2010 draft AusIMM ‘Guidelines for Techno-Economic Evaluations’ were collated by a subcommittee of practitioners and are regarded as best practice.They apply directly to projects and metallurgical plant evaluations, including those with a heavy technical basis. They can be applied to technical problem solving where there are no monetary computations. Project Managers and MetPlant Operators should demand that economic models and evaluations follow the six principles. They should become working tools which are easy to understand, fit for purpose, consistent, rigorous, record sources of input data, have key graphs and are rapid to audit.

Aug 8, 2011

By C Bonini, A Markham, P Whittle, B Pearson

"Mine-derived sedimentation in rivers can have significant impacts on the processes and features of the receiving environment and impact on communities reliant on this environment. However, identifying and quantifying the contribution of mine-derived sediment to the receiving environment can be complex. This is particularly the case in remote environments and where little/no baseline assessments have been undertaken. One approach that can be used involves sediment fingerprinting, whereby a unique tracer is identified within the mine-derived sediment to discriminate between mine- and non-mine derived sediment sources downstream. The technique typically involves sampling of sediment at upstream, control and impact sites and sites within the mine deposit. Laboratory analyses are run on all the samples to determine whether the chemical signature (eg presence/concentration of specific metals) differs between each group of samples. In complex environments where the mine-derived signature may be difficult to detect from a basic review of the data, or where sampling constraints may limit the number of samples for analyses, statistical methods can be used to help identify sediment groups. This paper provides a mine case study to show how such an assessment can be undertaken despite the logistical challenges faced while working in remote environments.CITATION:Pearson, B, Markham, A, Bonini, C and Whittle, P, 2013. Fingerprinting and signatures - tracing mine impacts in complex aquatic systems, in Proceedings Water in Mining 2013, pp 287-292 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 26, 2013

By K J. Ward, C N. Hatton, J Scalia IV, C A. Bareither, D L. Spencer

The mining industry is experiencing change in the governance of tailings facilities (TFs). Guidance and regulations across many jurisdictions contribute to this amorphous change. The Canadian Dam Association, Mining Association of Canada, Australian National Committee on Large Dams, and the Global Industry Standard on Tailings Management, produced by the International Council on Mining and Metals, are establishing guidelines for more rigorous industry governance. Evolving guidance regarding TFs is developing concurrently with a shortage of experienced tailings engineers, which adversely affects the resource base available to support new governance. This paper presents an updated semi-quantitative estimate of the impending resource shortage of qualified tailings professionals. Updates are provided herein for the estimated number of TFs worldwide, which included available data on active and inactive TFs, as well as the estimated labor resources required to service these facilities. The tailings labor shortage is discussed in the context of academic and professional training currently available to increase the quantity of trained personnel. This paper represents a discrete moment in time as contributions to the available information and inventories accessed continue to improve, but as of today are incomplete. However, the data and information included provide insight into the resource deficiencies currently within our profession, training and education opportunities to address those resource deficiencies, and a snapshot of a recent professional training course offered on mine tailings.

Jul 1, 2021

By F Faraj, M Pal, M Haest, M Bradshaw, H Lang, K Hume

MineSense Technologies Ltd. is revolutionising grade control at mining operations by installing ShovelSense® sensors on buckets that measure the grade of every load before it is dumped in the truck. This allows the mine to exploit grade variations at a resolution that was not available before, reducing the amount of ore loss to the waste stream and removing waste from material destined for processing. These changes dramatically improve the profitability and sustainability of mining operations. ShovelSense relies on X-ray fluorescence analysis of the rocks as they flow in the bucket and is integrated with fleet management to direct the trucks to the right destination. Lab simulations of ShovelSense measurements on porphyry copper ores show correlations between predictions and lab measurements at 0.98 r-squared with a coefficient of variation of 10 per cent. Visualisation of copper grade predictions in three dimensions shows a reasonable match with the dig plan, but with local changes in the ore-waste contact due to more accurate contact identification, related to blast movement and other mining factors. Correct delineation of these contacts ensures ore trucks are not sent to the waste dump and waste trucks are diverted from the crusher, creating enormous value for the operation and the environment.

Mar 22, 2022

By M Haest, O Dominguez, D Mittrup

Technological innovations and emerging analytical capabilities are transforming the way drill samples are analysed, with real-time mineralogical analysis made possible. In addition, new business/technical requirements are challenging long standing processes to incorporate more sources of information during planning in order to improve compliance to plan during mining and processing. Unfortunately, the new sources of information that are added do not always have adequate protocols in place to ensure quality data is collected.Spectral data covering the visible – near – short wave – midwave – longwave range are routinely collected by the Geoscience and Exploration department at BHP Billiton Iron Ore for accurate mineralogical identification. These data are used for geological interpretations (logging and modelling) and prediction of physical variables (metallurgical and geotechnical properties).This paper introduces how sampling and quality assurance / quality control concepts have been applied in the spectral data process. The described routine for sampling, data collection/management and reconciliation has been developed to track system precision and accurately and consistently ensure the data is of high quality before it is used across the mining chain.CITATION:Mittrup, D, Dominguez, O and Haest, M, 2017. A new approach to implement quality assurance and quality control to technological innovations – quality of spectral data capture and processes in the minerals industry, in Proceedings Eighth World Conference on Sampling and Blending , pp 265–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By A A. Puhalovich

The placement of chemically reactive mine wastes in mined out pits (æpit backfillingÆ) is increasingly seen by industry as best practice to manage long-term environmental risks. This is primarily because leaving wastes at the surface, or allowing pit lakes to develop, can result in unacceptable environmental risks. The costs and practicality of mitigation options such as installation of covers and community expectations of landform re-construction to achieve a post-mining, beneficial land use are also important drivers for pit backfilling.Pit backfilling can significantly reduce the post-closure risks to receiving environments, by minimising seepage due to tailings, acid/solute generating waste rock and/or salts derived from mine water treatment. Environmental risks are often highest where wastes are located close to the ground surface, due to relatively high rates of groundwater movement in near-surface aquifers and/or failure of engineered structures due to rainfall/erosion processes. Placement of these wastes at significant depth in pits, subject to mine planning and environmental assessment, can address these risks by increasing the path length and resistance from contaminant source to receptor, thus enhancing encapsulation of the wastes.Pit backfilling can also be cost-effective for mining companies. This is because existing pits are developed on the basis of an economic return and thus provide an opportunity to store tailings in an existing æengineered structureÆ at little or no incremental cost when compared with building and operating a new tailings or waste rock storage facility, often encompassing complex cover/drainage management systems. Key issues for consideration are mine planning, the long-term geotechnical behaviour of the wastes (eg consolidation of tailings which leads to release of acid/solutes in tailings porewaters), seepage rates to downstream receptors/agreed end point criteria and potential resource sterilisation. Internationally, mine closure guidelines are also showing a greater recognition of pit backfilling in the context of allowing mining companies to meet agreed post-closure land use objectives.In summary, pit backfilling can enhance the encapsulation of chemically reactive mine wastes and environment protection, and with agreement on post-closure beneficial land use, can also help to deliver post-closure benefits to communities.CITATION:Puhalovich, A A, 2012. Pit backfilling - Managing chemically reactive mine wastes and achieving rehabilitation objectives, in Proceedings Life-of-Mine 2012 , pp 279-286 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

THE South Mine. owned by the Broken Hill South Limited, occupies mineral leases 7 and 8 on the Broken Hill lode. The ore reserves are 4,250,000 tons, and the ore hauled for the year ended June, 1930, was 387,000 tons, the total to date being 7,840,000.The mine, down to the 1070-ft. level, is naturally divided into two sections, the northern and southern ends. Ore extraction is practically completed in the northern end to this horizon, while the southern end is developed ready for a concentrated attack.Fig. 1 shows the state of the 8215-ft. level, after connection to the new shaft.The levels above and below to the 1070-ft. level are in a similar condition, while below the 1070-ft. level the stoping has been confined to the north end, but not completed. The south end on these levels is also partially developed.The ore at present is hauled up No. 1 shaft, which is centrally situated to the present workings. This shaft was put into use in 1909, and in 20 years has had approximately 5,000,000 tons of ore pulled through it.The company, having proved the existence of large ore-bodies in the southern end of the mine, decided to sink No. 7 shaft. This is a six-compartment frame-set shaft (see Fig. 2) equipped with two cages and two 5-ton skips, the remaining compartments being utilised for electric cables, pipes, and ladders. The surface arrangements will include a steel head frame, electric winders, and breaker station.

Jan 1, 1930

By M Paine

Work to date has shown that the use of Al2O3:SiO2 ratios is suitable for identifying potential gibbsite bearing samples. Subsequent confirmatory XRD analysis helps to refi ne this initial identification. Based on these methods, gibbsite has been mapped in two common settings:1. along steeply dipping faults, or2. in association with stratigraphic contacts where one unit is aluminous (eg dolerite dyke).On a microscale, the samples studied illustrate an association between haematite, and to a lesser extent goethite, and gibbsite. In these samples the dominant forms of haematite are discrete crystalline phases of either microplaty haematite or euhedral martite. Two dominant forms of gibbsite were observed:1. vein style gibbsite that cross-cuts (or infill’s cracks) in goethite ± martite iron oxide associations, or2. gibbsite intimately intergrown with and forming a matrix to microplaty haematite.Some of the gibbsite microstructures observed suggest that it may have formed during a very hydrous, possibly hypogene, stage of the deposit genesis. The presence of this crystalline gibbsite, and in particular its occasionally euhedral form, suggests that aluminium was at some stage remobilised, at least locally, and then precipitated from solution as gibbsite. These observations suggest that these has been a phase of gibbsite precipitation that may have had a close but complex relationship with regards to the timing of the mineralisation processes, rather than formation as a result of late stage lateritic weathering.

Jul 11, 2011

By D Hatton, S Wilson, F Orrante, M Taghimohammadi, F van der Walt, N Arslan, M Westcott

"Cayeli Bakir Isletmeleri is an underground copper-zinc mine in turkey. The ore is highly variable with feed grades ranging from 1–4 per cent copper and 1–10 per cent zinc. Due to this variability, ore characterisation and blending strategies are crucial for performance optimisation.This paper presents a case study for a multidisciplinary approach to process optimisation, integrating Geometallurgical and advanced control methods to achieve optimised plant performance. The results from comprehensive metallurgical tests and surveys were used to develop a mathematical model utilising SGS’s Integrated Geometallurgical Simulator® (version number 2.5.24.0). The model was employed to determine the most appropriate operational settings required to ensure that optimised grades and recoveries are achieved for each ore type.SGS’s Modular Expert Technology (MET) expert system was then implemented to target these optimum operational ranges utilising online grade and froth velocity measurements. The successful conversion and deployment of the modelled process parameters into an expert system has resulted in significant improvements in overall recovery and circuit stability.Citation:Arslan, N, Westcott, M, van der Walt, F, Hatton, D, Taghimohammadi, M, Orrante, F and Wilson, S, 2016. A Multidisciplinary Approach to the Optimisation and Control of a Copper-zinc Grinding and Flotation Circuit, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 115–122 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By A F. Cropp, D J. Bradshaw, W R. Goodall

Mineralogy and critically the texture of both the ore and gangue phases are of paramount importance in the flotation recovery of copper from porphyry ores. Mineralogy and texture will define the theoretical grade recovery curve for a feed ore. Actual grade-recovery falling below this may be due to texture and gangue influences, whilst desired grade-recovery above this line will not be possible unless the characteristics of the feed are altered.This review discusses examples of porphyry copper deposits where process mineralogy has been used to characterise these textural and gangue influences on recovery by flotation. More specifically, the influence exerted by grain size, liberation, association and elemental distribution is explored. The implications of these on overall plant philosophy and operation are highlighted, along with the subsequent potential impact on recovery.CITATION:Cropp, A F, Goodall, W R and Bradshaw, D J, 2013. The influence of textural variation and gangue mineralogy on recovery of copper by flotation from porphyry ore - a review, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 279-292 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By M Bellamy

The DeGrussa copper deposit was discovered by Sandfire Resources in April 2009. Construction of the 1.6 Mt/a concentrator, open pit and underground mining operations commenced in March 2011 with first concentrate production achieved in October 2012. Over the next ten years, DeGrussa grew to include both the DeGrussa and Monty underground mines, establishing itself as one of the world’s premier copper producers with total production of 663 000 t of contained copper by the time the mine closed. Final ore was trucked from Degrussa on 5 October 2022. This paper examines the mine closure experience from both a planning and operational perspective. The paper provides an overview of the site’s mine planning process including the factors involved in determining the end of the mine life and how this was tracked and communicated in the lead up to the end of mining operations. It will also look at some of the specific operational aspects involved in maintaining steady state production all the way through to the last day while facing increasingly challenging conditions. These factors, along with the external factors faced by most of the industry such as labour shortages and COVID related disruptions, contributed to making it an interesting journey to the end of operations at DeGrussa.

Mar 29, 2023

By D J. Williams, E M. Rykaart

Soil cover systems are routinely used to reduce acid rock drainage (ARD) from mine waste rock dumps and tailings impoundments. A technology for the analysis, design, instrumentation and monitoring of barrier-type (oxygen limiting) and store/release-type covers has rapidly developed and the number of covers under construction has grown extensively during the past ten years. Mine operators are currently investing in this relatively new technology with the expectation that these covers will reduce long-term liability with respect to acid generation, drainage and treatment costs. While the design life for cover systems may extend into hundreds of years, we have less than ten years of construction experience and proven performance. Some cover designs appear to be functioning well; however, the performance of many more is now being called into question. The paper presented herein evaluates the integrity of cover systems from a global perspective. Soil cover systems for the control of ARD are being constructed at mine sites located within high rainfall equatorial regions, deserts ranging from low to high latitude, humid temperate regions, and cold-continental climates. While the technology for analysis and design of soil cover systems is well developed, factors that compromise the performance of cover systems (in addition to the paramount issue of climate) relate to material selection and availability, cost and construction practices. Long-term performance is also strongly affected by physical stability (ie erosion), volume change (ie cracking, desiccation, settlement and freeze/thaw cycling), vegetation, soil evolution and ecological stability. This paper provides a review of the application of soil cover systems for the control of ARD. Cases where cover systems have been constructed with both success and failure are illustrated. General criteria and recommendations for cover selection, design, construction, and maintenance are provided.

Jan 1, 2003

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

At the beginning of the seventies pre- drainage of methane was introduced in West German coal mining in order to reduce the gas emission from the worked seam. After three pilot tests on the "Rheinland" Colliery (86 boreholes in seam "Prasident"), "Bergmannsgluck/ Westerholt" Colliery (23 boreholes in seam "Gustav") and "General Blumenthal" Colliery (27 boreholes in seam "Hugo" and 170 boreholes in seam "Karl") systematic large scale tests with extended investigations were carried out un the "Rheinland" Colliery (127 boreholes in the seams "Anna", "Blucher", Prasident"). During this time an analogous test was carried out on the "Consolidation" Colliery (21 bore- holes in seam "B"). In these studies and tests the technical feasibility, efficiency and economy could be proved, so that pre-drainage of methane starts spreading. On the "Rheinland" Colliery pre-drainage has become common practice in gassy seams. Mainly two points impede a faster spreading of method: 1. in many cases the necessary requirement, that one or both of the gate roads should ire driven 6 to 12 months before the face is worked, is missing. This is mainly due to the difficulty of retreat mining in passe seams.

Jan 1, 1982

By T Walton, C Perring, M Pepper, G Gerber

The Yandicoogina Channel Iron Deposit (CID) is an accumulation of iron pisolites cemented by a goethite-rich matrix. The Yandicoogina CID’s are found in a palaeochannel that meanders within a broad structural basin of the Yandicoogina Syncline in Pilbara region of Western Australia. RTIO Yandicoogina Mine Geology team contributed to a number of strategies maximising the iron ore reserves mined by Rio Tinto. Two strategies are discussed: the replacement of the Batter-Berm final pit walls by contour dozing; and upgrading the lower grade material to crusher feed. 1. Contour dozing – traditional Batter-Berm pit final wall configuration left kilometre long wedges of ore sterilised around bench margins. Contour dozing final walls (ie dozing of ore down the ore-waste contact) as internally defined by RTIO Yandicoogina Mine Geology (Mine Geology), enabled recovery of additional crusher feed. 2. Upgrade of lower grade material – the lower ore domain (GVL) within the Yandicoogina orebody contains numerous clay pods. Contaminant Al2O3 inherent within clay pods can result in CID material outside of crusher feed grade specifications, causing it to be flagged as ‘internal waste’ in mining models and permanently lost to waste dumps. In 2011, after multiple tests, Mine Geology demonstrated that this material could be upgraded to crusher feed via wet processing. With the support of the RTIO Metallurgical Development team new grade specifications were defined. The resulting material has been used to supplement higher grade ore. While increasing the mining ore output, these ongoing value-adding strategies also promote more sustainable mining via better use of the non-renewable iron ore commodity. The initiatives extend mine life, reduce waste movement, improve strip ratio and increase productivity

Mar 22, 2022

By Mosusu N

Geothermal anomalies of different types occur within distinct geological/structural settings in Papua New Guinea. According to R.F. Herring, geothermal occurrences in Papua New Guinea can be classified into two types, those related to vulcanism (Lihir, Rabaul and other series of islands along the volcanic arc) and those resulting from a regional heat flow probably caused by radiogenic sources, for instance those in the Wau/Bulolo area. The manifestation of this potential source of energy generally coincides with either converging or diverging tectonic plate boundaries. Previous inventories on thermal waters were carried out by vulcanologists from the Rabaul Observatory in the early 1960s. However, these studies rarely included chemical analyses of water and gas emissions and the investigations were carried out in an ad hoc manner, generally as a secondary activity. The most recent investigation on thermal waters was conducted on Lihir Island in connection with the development of the open pit gold mine. These studies included detailed exploratory drilling to a maximum depth of 730 m, and a water chemistry isotopic sampling and analysis programme. The hydrothermal waters were not considered as an energy source but as a hazard during the development stage of the mine. Nevertheless, the geothermal anomaly observed at Lihir includes hot springs emerging along the coastal zones with temperatures that approach 100¦C, steam, and thermal borehole waters with temperatures that exceed 200¦C. Chemical analysis results of thermal fluids from Rabaul, Talasea and other areas in Papua New Guinea generally show high total dissolved solids and low pH. In contrast, recent results from the deepest and hottest thermal source at Lihir shows a neutral pH, a Na-CI-SO4 composition and temperatures above 200¦C. Despite the concentration of chloride being similar to that of sea water, other chemical results and stable hydrogen and oxygen isotopic compositions of thermal fluids imply the source to be mixture of local meteoric water and deep thermal water rather than sea water. Results of geothermal modelling suggests that the total geothermal uptlow is equivalent to 54 MW.

Jan 1, 1997

By D R. Andrew, K T. Morrison, J F. Tiedgen

Waste blasting in iron ore operations can pose a number of technical challenges, including blasting through variable geology and blasting soft ground in wet conditions. Blast patterns are designed to be loaded with a specific range of explosives with unique characteristics and properties. Each explosive product will produce an optimal blast outcome for a given set of blast parameters and ground conditions. Sites characterised by softer rock typically require low-density, low-energy explosives. Historically, these products have contained a high ratio of porous ammonium nitrate prill and are only suitable for dry blastholes. When blastholes within a pattern are found to be unsuitable for such explosives due to wet, damp or muddy blasthole conditions, a new product is selected. While it is easy to switch products to match blasthole conditions, the different properties of the new non-ideal product can impact blast performance and increase loading times and costs.Flexigel™ is a solids-sensitised emulsion blend suitable for loading at variable densities and energies in dry, damp, muddy or wet blastholes. It is a universal product that can be loaded to match ground and blasthole conditions or complement other explosive products.At Fortescue Metals Group’s Cloudbreak site, Flexigel™ was trialled through a series of matched pair blasts in order to optimise blast outcomes in conditions that were non-ideal for existing explosive products and to reduce the overall cost of drill and blast operations. Flexigel™ yielded improved instantaneous dig rates and improved loading efficiency when compared to a traditional emulsion blend. The results also indicated that variable-density and variable-energy products afford greater flexibility for optimising blast outcomes across all ground and blasthole conditions trialled.Trials of Flexigel™ at Cloudbreak have shown that a variable-density solution is available for conditions where traditional explosive products are non-ideal. As such, Flexigel™ is able to fill a major void at any operation where the desired low-density, low-energy explosive product must be substituted for a more expensive traditional emulsion blend or heavy ammonium nitrate/fuel oil.CITATION:Andrew, D R, Morrison, K T and Tiedgen, J F, 2015. Flexigel™ – a variable-density solution, in Proceedings Iron Ore 2015, pp 413–418 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By J B Tucker, A T. McGrath

Situated in north-west Queensland, Australia, the Ernest Henry Mine (EHM) has been producing copper and gold since 1996. Owned and operated by Glencore Xstrata, ore is currently sourced from a newly developed underground sublevel cave (SLC) mine below the old EHM open pit (the pit). Ore feed to the concentrator is supplemented by satellite open pits comprising the Mount Margaret operation.The transition from open pit to a producing underground mine involved a complex extraction sequence for the first two production sublevels on RL1650 and RL1625. Underground mining during cave initiation was further complicated when south wall instability prevented completion of the final open pit shell. The transition mining phase included mass firing of an inclined crown pillar between the initial SLC void and the pit followed by a combination of transverse and longitudinal SLC mining.The inclined crown pillar mass firing was the first significant milestone in the extraction of the transition ore block. Comprising approximately 890 000 t of in situ material; 70 000 m of drilling was charged with 351 t of emulsion and 6026 electronic detonators to initiate the single mass firing. The firing contained five direction changes over 19 seconds making it one of the largest and most complex underground blasts ever conducted in Australia.Risk management was integrated into every facet of the technical and operational planning and execution of the transition mining phase, whilst maintaining daily mine construction and production commitments. This paper provides a detailed overview of the transition objectives and constraints, mining method selection, post mass blast outcomes and the journey ahead.CITATION:McGrath, A T, Campbell, A D and Tucker, J B, 2014. Transition of the Ernest Henry Mine from open pit to an underground sublevel cave, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 297–308 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

A new approach to resource estimation at the exploration stage is emerging, based on the application of simple software techniques. The techniques combine the power of interactive graphics with proven database, analysis and estimation tools. With effective use of these tools the geologist now has maximum chance of deriving a reliable structural and grade model from the limited exploration data. Unlike cutoff-based polygonal methods, the resultant geological model can immediately be used to evaluate any economic scenario.These modelling techniques are embodied in MINEX-3D, an Australian software system. With the emergence of the 386-based PC and high resolution (VGA or better) graphics, MINEX-3D makes the power of this new 'desktop geological modelling' accessible to most exploration geologists.

Jan 1, 1990

Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991