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By S. Eck

In previous work the influence of the casting speed on the flow field and the shape of the solidification front in an industrial 0.82 x 0.25 x 0.8 m³ bronze caster had been investigated. Both numerical and experimental model represented 1:1 the real caster geometry. A comparison of the results of both numerical and experimental models for the flow during the casting process showed a good agreement in the qualitative velocity fields (flow direction and vortex formation). This work represents a parameter study of the numerical model with variations of the turbulence conditions at the inlet in order to clarify their influence on the flow field in the caster. In order to find the best boundary condition at the inlet, the numerical calculations for water have been compared with the measured flow fields in the water model. The new boundary conditions were then applied to the numerical model of the bronze casting process.

Jan 1, 2009

By A. Broussaud

An original methodology has been developed for steady state simulation of selective grinding and mineral liberation in rod and ball mills. Three fundamental aspects of the methodology are presented successively : modeling ore texture, modeling grinding and its selectivity, and modeling mineral liberation. The methodology for modeling ore texture includes the conversion of 2D data into 3D reconstructed information and the use of the BILCO coherent material balance software. The models for grinding Simulation are classified into three levels, corresponding to three levels of available experimental data. All models account for grinding selectivity and for variations of engineering para-meters and operating conditions. An algorithm has been introduced to forecast mineral liberation, compatible with accurate simulation of selective grinding, which generates reasonable results.

Jan 1, 1987

By Kazuteru Tozawa

Surface tension, density and viscosity coefficient of acidic copper sulfate solutions simulating electrolyte solution for electrolytic production of copper have been measured and are summarized as a function of the solution composition and temperature. Nickel sulfatc is taken to be a representative coexisting sulfate that affects the physical properties of the copper sulfate electrolyte solution. The sulfates in the solutions, including sulfuric acid, increase the physical properties under consideration. Gelatin, representing organic additives for electrolyte solution, was found to sensitively affect the surface tension of the solution at low concentration of up to 200mgIL. The surface tension was markedly lowered by the addition of gelatin and the increasing concentration of gelatin led to a more pronounced decrease in the observed values. The surface tension gradually increases with time after addition of gelatin and the increase is enhanced by higher acid concentration and higher temperature. The observed change in the surface tension is considered to reflect the preferential adsorption of gelatin to the bubble-solution interface and the decomposition of gelatin due to hydrolysis to form various molecules having smaller molecular weights.

Jan 1, 2003

By Meghan McGrath

Third generation advance high strength steels with microstructures of acicular ferrite and retained austenite were investigated and meet mechanical property goals. A good combination of strength and ductility were achieved with duplex ferrite and austenite microstructures where cementite formation was suppressed. Transformation induced plasticity (TRIP) behavior produced rapid work hardening. The mechanical properties of two hot-rolled steels with duplex microstructures were compared and had the following compositions: (1) Fe-0.14C-13.87Mn-1.42Si-3.51Al; and (2) Fe-0.06C-14.2Mn-1.85Si-2.38Al. These steels were cast, homogenized, and hot rolled at 900ºC to obtain a refined microstructure with ultimate tensile strengths and elongations to failure of 865 MPa and 39% and 1,217 MPa and 28%, respectively. The amount of metastable austenite in both compositions decreased after tensile testing from 58% and 28% to 6% and 0%, respectively. Microstructures were characterized using optical microscopy, scanning electron microscopy (SEM), and x-ray diffraction.

Jan 1, 2010

By Akihide Hosokawa

The void growth and coalescence in model materials involving a pre-existing three dimensional void array (i.e. multiple layers of a void array) was studied by X-ray computed tomography (XCT) coupled with in situ tensile deformation. To reduce the recording time, a new technique called fast tomography was employed. The model materials used in this paper were fabricated by the combination of an ultra-short pulsed laser machining system and a diffusion bonding technique, and two different types of arrays were prepared namely, FCC 1 and FCC 2 type array. This methodology allowed the authors to capture the entire process of growth and coalescence events of a void array embedded in the metal matrix. The failures in the both materials involved internal necking and shear localization. One of the highlights of this paper is that the plastic strain at the onset of void coalescence was measured for each model material. These values are in fact the adequate values to be compared with the coalescence strain predicted by existing void coalescence models such as the Brown and Embury model, the Thomason model and the Pardoen and Hutchinson model. The comparison suggested that the Brown and Embury model underestimated the coalescence in neither of the current model materials, while the Thomason model and the Pardoen and Hutchinson model showed a quite good agreement with the result for FCC 1 material. On the other hand the result from FCC 2 material agreed with none of the models probably due to the geometry of the void array that is not compatible with the existing models.

Jan 1, 2010

By Lijuan Chen

During the detoxification of chromium-containing slag by Achromobacter sp. CH-1, anionic surfactant Sodium Dodecyl Sulphate(SDS) and its mixed systems with different Tween surfactants(Tween 20, Tween 60 and Tween 80) were used to promote the interaction between the bacteria and the chromiumcontaining slag and the rate of acid-soluble Cr( ? ) leached from the slag. The effects were evaluated by the surface tension, the pH of the leaching solution and the leaching rate of total Cr( ? ) from the slag. The results showed that the surfactants systems improved Cr(VI) leaching and its detoxification of chromium-containing slag. The mixed surfactants of SDS combined with Tween surfactant revealed better effectiveness of detoxification than SDS only. When the mass ratio of SDS to Tween 80 was 1:1, the rate of Cr( ? ) leached from the slag increased by 12%.

Jan 1, 2009

By Fuqiang Guo

Scorodite (FeAsO4, 2H2O) is suitable mineral carrier for immobilization of arsenic-rich wastes. Its stability is, however, highly pH dependent (typically at 4 ≤ pH ≤ 7) and satisfactory only under oxic disposal conditions. In thiswork an encapsulation process using mineralized gels of aluminum hydroxy-oxides is developed to enhance the stability of scorodite under wider pH and redox potential range conditions. The encapsulation involves blending and ageing of synthetic scorodite produced by McGill’s atmospheric scorodite process with aluminum hydroxyl gels derived from controlled hydrolysis of aluminum salts. The amorphous hydrolyzed Al-gel encapsulates the scorodite particles,which upon short-term aging transforms into crystalline Al (OH)3/AlOOH mineral phases providing a robust protection microscopic barrier. Long-termstability testing demonstrates the encapsulation systemto be highly effective in suppressing arsenic release under either oxic or anoxic (100 mV < Eh < 600 mV) potential and neutral-alkaline pH (7 ≤ pH ≤ 9) ranges.

By M. E. Alam

In the present study, 1.1 volume percent of nano size copper was incorporated into pure tin using hybrid microwave sintering assisted powder metallurgy route. Microwave sintered samples were extruded both at room temperature and at 230 °C. Microstructural characterization studies were conducted on the extruded samples to investigate the distribution characteristics of secondary phase and grain morphology. Room temperature tensile test results revealed that hot extruded Sn-Cu samples exhibited higher strengths (~ 41%, in case of 0.2% yield strength and ~ 38%, in case of ultimate tensile strength) and ductility (~ 15%) when compared to room temperature extruded samples. On the contrary, the tensile properties of pure tin remained independent of extrusion temperature. An attempt is made in this study to correlate the effect of extrusion temperature on the microstructural evolution and tensile properties of Sn-Cu solder.

Jan 1, 2009

By Chen Song

Keywords: Co3O4, Cobalt Compounds, Morphology, Urea, Homogeneous Precipitation Depending on experimental condition, precipitation from cobalt nitrate and chloride solution in the presence of urea yield dispersed cobalt compounds with different chemical compositions and morphologies. The effects of concentration of cobalt solution and urea, agitation, on precipitation morphology were investigated experimentally. Generally in closed systems the particles are identified as cobalt (II) basic carbonate with needle type shape. In open system, spherical and plate-like precipitations of cobalt (II) basic cyanate are formed. The chemical formula of cobalt compounds was confirmed. They are CoII,III(OH)0.83(CO3)0.49 Ay?0.14 H2O (in tightly-capped reactor: A stands for NO3?, Cl?; y[A]molecular weight < 12.9) and CoII,III(OH)0.83(NCO)XAy?0.14 H2O. (in open reactor A stands for: NO3?, Cl?; 42 x + y[A]molecular weight < 44.82). The main reason was that the primary particles had different chemical compositions for the effects of the different kinds of anions and stoichio-chemical compositions of the primary particles. The effect degree of the anions depended on the co-existing anion radius in the reaction solution. According DTA-TG analysis of the cobalt compounds, the latter particles transform to Co3O4 powders on calcining. The shape of the Co3O4 particle with porous character has inheritance with precipitation. In this paper, it concludes that the particle formed by the principle of nucleation-aggregation in aqueous solution. The process of aggregation has played an important role in formation of particles. During calcination, the aggregation would be destroyed partly.

Jan 1, 2005

By Anne Kvithyld

Silicon solar cells, that convert the energy of sunlight into electric energy, are attractive sources of energy. In the production line wafers of solar cells are sliced from a multicrystaline ingot solidified unidirectionally. Recycling scrap from top and sides of such ingots is addressed. SiC and Si3N4 inclusions are a major problem. Scrap from Scan Wafer ASA is melted in a high vacuum furnace at around 1500ºC. The filters, from commercial producers, are C and SiC with 10, 20 and 30 ppi. Characterisation of inclusions before and after filtration, and in the filter itself, is performed by microscopy. Dissolution of silicon in acid and counting of the un-dissolved inclusions is also carried out. In the filter Si3N4 needles and SiC inclusions were identified. The amount of these inclusions in the filtered silicon is much less than in the input. In conclusion, filtration using SiC and C filters in vacuum system in argon atmosphere removes SiC and Si3N4 inclusions from solar cell scrap. Flow of metal through the filters is not a problem. These results are promising with scale-up to industrial application in mind.

Jan 1, 2006

By Peter Ehren

Global Geoscience is developing a Rhyolite Ridge project, a shallow boron-lithium resource deposit, located in Nevada about 25 km from Albermarle’s Silver Peak operation. The main minerals of interest are the boron mineral searlesite (40%wt) and lithium containing clay minerals. These minerals are found among principally calcite, feldspar, muscovite, dolomite, and quartz. The equivalent commercial value is about 7–9% boric acid (H3BO3) and 0.8–1.0% lithium carbonate (Li2CO3) equivalents. Selective agitated leach tests at SGS Lakefield laboratory showed that searlesite can be acid leached between 20 and 75 °C and at a pH lower than 4. On the other hand, lithium can be leached between 20 and 75 °C and at a pH lower than 1. In other words, lithium can be recovered at low temperatures if sufficient free acid is available, which gave the motivation to investigate heap leaching of the mineral. The PLS contains boric acid, magnesium, sodium, lithium, potassium aluminium, and iron sulfates.

By A. Kontopoulos

The Olympias Mine in Northern Greece is producing an extremely refractory gold-bearing arsenical pyrite concentrate, containing on the average 41 3 S, 40 3 Fe, 10-12 3 As, 25 ppm Au and 35 ppm Ag. During the process selection stage, more than a dozen alternative technologies? were considered and an in-depth analysis was prepared for the three most promising, ie roasting, pressure oxidation and biological oxidation. Detailed capital and operating cost estimates were prepared, based, where appropriate, on laboratory and pilot-plant tests. A number of criteria was used for process evaluation and selection, including capital and operating costs; environmental impact, gold&apos; recovery, stage of development, etc. Based on the above evaluation, the Sherritt Pressure Oxidation Process was finally selected. A detailed description of the process selection stage, supported with laboratory and pilot-plant test results on many of the processes considered, will be? presented.

Jan 1, 1989

By NRMR Bhargava

With the increasing use of lead-free solder alloys, low melting point alloy is often required due to the heat- sensitive parts or substrates in modern electronic devices. For such demand of low melting point, the nanostructure lead- free solder alloy, having excellent metallurgical characteristics and a melting point of <215oC, were developed by mechanical attrition of conventional lead free solder alloys (Sn-Ag-Cu, Sn-Ag and Sn-Cu). The decrease in melting point due to nanosize effect was calculated theoretically as function of particle size and the theoretical results were compared with experimental values measured by differential scanning calorimetry. The newly developed alloys have eutectic composition of Sn-3.5Ag-0.7Cu, Sn-3.5Ag and Sn-0.7Cu and the melting point depression found to be 5.10C, 4.10C and 6.20C when the bulk alloys reduced to 80 nm, 92nm and 96nm sizes respectively.

Jan 1, 2009

By A. R. Kiani-Rashid

Controlled graphitization has become known as a practical method for improvement of wear resistance and machining properties in steels. In this paper, the effect of heat treatment on microstructure of CK45 steel has been investigated. Austenitising was carried out at 920°C for 5 hours. Besides, isothermal transformation was conducted at 750°C in the time range of 1-20 hours. The microstructure of the steel considerably changes by this heat treatment process which exhibits the effects of temperature, appropriate austenitising duration and isothermal transformation. Conducted experiments show a suitable distribution of semi-spherical graphite particles especially on the surface of the steel. Also, analyses demonstrate that the amount of formed graphite in the austenitising temperature 920°C is more than graphite in single heat treatment temperature of 750°C.

Jan 1, 2010

By Zhiyun Li

Room temperature infrared reflection spectra of 2 n-type homo-epitaxial epifilms have been measured in the work. The effect of the refractive index on the determination of layer thickness using traditional calculation measurement is studied and some improvements have been added to the measurement to improve the accuracy and stability of the measured results. Results of the improved method have great agreement with the results from SEM and both variance and mean relative error decrease an order of magnitude.

Jan 1, 2010

By Z. Sun

Imposing a strong magnetic field is considered to be an attractive method to prepare materials with aligned or textured structures due to its intrinsic properties, e.g. non-contact and easily controllable. However, the nature of the strong magnetic field effect still remains unclear and further research is needed. In the present paper, the effect of a strong magnetic field on the solidification of a hypereutectic Al-Cu alloy was investigated. After magnetic field treatment, the primary phase was aligned parallel to the magnetic field direction. Meanwhile, the eutectic micro-structural constituent became elongated and thinner. A theoretical analysis was conducted to have a better understanding of the phenomena. During solidification, the magnetic Faraday and dipole-dipole interaction forces are considered to decrease the solute pile-up in front of the solid-liquid interface and modify the eutectic cell formation. The alignment of the phase is due to the shape magnetic anisotropy and crystal magnetic anisotropy.

Jan 1, 2010

By A. Kontopoulos

Refractory sulfide gold ores or concentrates require an oxidation pretreatment step to yield the contained gold amenable to the subsequent leaching step. The process options for oxidation pretreatment can be broadly classified as follows: roasting, high or low pressure oxidation bacterial oxidation, chemical oxidation, each with a number of alternative suboptions. Roasting and high pressure oxidation are being applied on an industrial scale; the stage of development of the other options range from preliminary laboratory to advanced pilot plant- In this paper, the major technical, environmental and economic aspects of the above processes are being discussed. Future industrial trends will also be considered. Particular emphasis will be placed on the treatment of arsenical ores and concentrates, where safe plant operation as well as, handling and disposal of the arsenic containing products and/or effluents &apos;and residues is of paramount importance.

Jan 1, 1990

By Ulises Crossa Archiopoli

We describe a technique that allows rapid imaging of the thermal diffusivity of the sample by a modified photo-thermal technique. The thermal diffusivity in hardened steels strongly correlates to the hardness. Hence in a noncontact manner and with optical microscope resolution, a 2D map exhibiting the crystallographic phases and hardness of the sample can be retrieved. Two almost collinear laser beams scan the surface, one as a modulated pump and a second as a CW probe. The deflection of the probe carries information on the thermal expansion of the sample and with it, on the thermal diffusivity. It is shown that a single determination of the time delay of the modulation of the probe beam can be used to retrieve the thermal diffusivity.

Jan 1, 2010

By A. Dadgar

The adsorption kinetics of AuBr4 on Dowex ® -21K ion-exchange resin were studied and found to be independent of the initial gold, bromine, and base metals concentrations. A commercially-available undivided hypochlorite generating cell was used to generate bromine from simulated mixed halide (Br-/CI-) solutions. Electrolyses were performed with solutions containing very low Br&apos; ion concentrations. The current efficiencies were 80-90%, and Br- ion utilization was maximized. A detailed economic assessment was made considering the capital and the operating costs for a 1000 mtpd gold ore processing plant. The toxicity and discharge levels of bromide, bromine, and cyanide were compared from a detailed analysis of the published literature data. Comparing bromine vapor with hydrogen cyanide gas for a given length of exposure, the lethal concentration of bromine is about 3 times less than hydrogen cyanide. The toxicity of sodium bromide is similar to that of sodium chloride. Acute poisoning to bromides and chlorides is rare because of their low toxicities. The allowed discharge levels of Br-, Br2, and CN- in fresh water are 250, 0.1, and 0.005 mg dm-3, respectively.

Jan 1, 1992

By Omid Marzoughi

Chromium has a wide range of applications, including as an alloy addition in various steels and also as a corrosion resistance coating. Carbothermal reduction of chromite ore (FeCr2O4) in a submerged arc furnace is an important industrial process for extracting chromium, but the energy consumption is excessive. It is suggested that one area for future research is the low temperature carbothermic solid state reduction of chromite to produce an intermediate product, which can subsequently be upgraded to ferrochromium. In this regard, a thermodynamic model has been developed to investigate this process and the effects of temperature, carbon additions and ore composition on the recovery of chromium and the grade of the ferrochromium, have been studied. Further development of the model may allow it to be applied to the simulation of other processes for the recovery of chromium from chromite ores.