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By G. A. Apell

Completion of 18 churn-drill holes totaling 2,218 feet and 3 diamond-drill holes aggregating 421.5 feet of drilling in the M.C. mine area, near Truman, Wis., provided information indicating the existence and trend of a zone of zinc mineralization extending for 1,000 feet west of the old M. C. shaft.

Jan 1, 1949

By E. S. Shedd

The Bureau of Mines investigated electrowinning and tapping lanthanum metal from lanthanum oxide in a fluoride bath. The electrolyte was composed of LaF3, BaF2, and LiF. Metal containing 0.2 percent impurities was produced at a rate of over 2 pounds per hour. Principal impurities were carbon, aluminum, and silicon. Low-carbon metal was produced by continually discharging the carbon oxide gases and maintaining 0.1-atmosphere pressure. Anode reactions and cell design were found to be important factors in cell operation. Both frozen electrolyte skulls and tungsten metal crucibles proved satisfactory for collecting the metal and did not react with the molten lanthanum.

Jan 1, 1966

By J. C. Franklin

The Spokane Mining Research Center of the Federal Bureau of Mines is placing major emphasis on chemical stabilization as part of the ground support program. Development of polymeric material suitable for bonding rock fractures around the mine opening is one phase of the program. Some of the problems that must be considered are viscosity, applicability, adhesion, cure times, strength, toxicity, and flammability. Epoxies and polyesters were investigated, but shrinkage in polyesters caused redirected effort toward epoxies. Test results with the latter showed that bonded fractures in mine-roof strata were stronger than the virgin rock. Further tests showed that polymeric materials have good potential for bonding, and in conjunction with polymer roof bolts, are expected to result in an economic and useful new support concept.

Jan 1, 1974

By D. W. Richardson

This Bureau of Mines publication provides the enthalpy of formation of malachite [Cua(COs)(OH)2] as determined by hydrochloric acid solution calorimetry. At 298.15 K the enthalpy of formation from the component oxides is -15.l0±0.30 kcal/mole and from the elements, -251.9±0.5 kcal/mole.

Jan 1, 1974

By E. L. Rawlins

Pipe lines through which natural gas is flowing should be buried in order to minimize fluctuations in the temperature of the gas, as these fluctuations have several harmful effects. One of these effects is to decrease the accuracy of measurements of gas volume. In order to meter properly the quantity of gas flowing past any point in a transmission system, it is necessary to how the temperature of the gas. If the temperature remains fairly constant, the gas flow can be measured with a close degree of accuracy, but if it fluctuates rapidly, close measurement is impossible.

Jan 1, 1926

By Charles L. Kimbell

In 1990, the aggregate value of world international export trade in mineral commodities was estimated at more than $64 billion in current (1990) dollars, about 8.4% higher than that in 1989, but still 8.7% below the record high set in 1980. Table 8 provides a data series for the estimated value of world export trade in all mineral commodities from 1979 through 1990, as well as a breakdown of this total into fuel and nonfuel commodities. It is noteworthy that for this 1990 edition, trade data for the year of review were available in time for inclusion, whereas in previous editions, the latest available global trade data were for the year prior to the year of review. Hence, as regards trade, this edition of Minerals in the World Economy updates the 1989 edition by 2 years rather than by only 1. For this reason, it is appropriate to note that the 1989 global total value for inter-national export trade in mineral commodities was almost $596 billion, 11.1 % above the revised 1988 level of more than $536 billion, both figures expressed in current dollars for the appropriate year. Despite the considerable increase in the dollar value of mineral commodity exports, their share of total export merchandise trade declined to 19.1 % in 1990 from 19.7% in 1989. At 19.1%, this share was very near the recent year record low of 19.0% reached in 1988. The year 1990 was the fourth in a row in which the total value of world mineral commodity export trade increased.

Jan 1, 1993

By G. Esterhuizen, C. Karacan

Methane can be a significant hazard in coal mine longwalling operations and extensive methane mitigation techniques are employed by coal mine operators. Reservoir modeling techniques are used to better understand the liberation and migration of methane from the surrounding rocks towards the mine ventilation system. The caved rock behind the advancing longwall face, known as the gob, can contain high void ratios, providing high permeability flow paths to the methane. The gob is progressively compacted by the weight of the overburden, resulting in a reduction in the void ratio and associated permeability. Estimating the permeability distribution within the gob poses challenges due to its complexity. The authors have developed a new methodology to determine both horizontal and vertical variations in the permeability of the gob. Variations of the permeability in the vertical direction are based on a model of caving and block rotation, which considers the effect of block dimensions and fall height on the void ratio. Gob compaction by the overburden and associated permeability changes are determined from a three-dimensional geo-mechanical model which simulates the gob as a strain hardening granular material. The resulting three-dimensional permeability distribution in the gob is then transferred to a reservoir model. The paper demonstrates the application of the method and shows that reasonable results are obtained when compared to empirical experience and measurements.

Four actual coal mine waters were used in various phases of the research program. All were from the Sewickley Creek area In Westmoreland County, Pennsylvania. The BCR designations, site locations, and nature of the mine water samples are described briefly in the following paragraphs.

Jan 1, 1971

By J. P. Powell

Systematic waterflooding was first tried in Washington County, Okla., in 1937, when a 40-acre project was begun in secs. 24, 29, 32, and 33, T. 27 N., R. 13 E., jointly by the Keener Oil Co. and the Phillips Petroleum Co. The property later was sold to Lee Morrison. A second project was begun in 1941 in sec. 14, T. 6 N., R. 12 E., by the Oklahoma Oil Corp. Both projects were abandoned by the end of 1942. A third project was begun in 1945 and the fourth in 1948, but 1949 actually was the beginning of intensive waterflooding development in Washington County. The results of previous waterflooding projects are described in Bureau of Mines Reports of Investigations.2 3 4/ Oil production in the county followed a similar trend, dropping to a low of 990,000 barrels in 1945, then steadily increasing until 1956, when more than 4 mil-lion barrels of oil was produced. Most of the increase in oil production is directly attributable to water injection.

Jan 1, 1957

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By Charles C. Myers, Robert M. Doerr

The apparatus described was developed for determining the kinetics of gas - solid reactions at high temperatures by measuring the volume of gas consumed with respect to time . This apparatus consists essentially of a horizontal precision- bore glass tube connecting a small reaction chamber in a furnace to a large constant - temperature reservoir . A drop of mercury in the tube separates the two sides of the system and serves as an indicator that moves at a speed proportional to the rate of gas consumption . The sensitivity of the apparatus depends inversely on both the density of the gas in the system and the cross - sectional area of the tube ; with a tube having an area of 0.079 cm² , the sensitivity for oxygen at 308 ° K and 0.5 atm is 20 cm/mg . The reproducibility of data with the volumetric apparatus is good .

Jan 1, 1964

By S. R. Borrowman

Physical beneficiation, leaching, and solvent extraction investigations were made to recover a high-grade thorium oxide product from Bald Mountain, Wyo., conglomerate. The monazite in the Bald Mountain deposit contains 8.8 percent Th02 and, therefore, is higher in thorium content than the usual domestic or foreign monazite. A sample of composited drill cuttings for the study contained 4.3 pounds of monazite per ton of are. The work showed that the monazite, although unusually fine grained and friable, could be concentrated by tabling and magnetic treatment to yield a product assaying 5.65 percent Th02 with a recovery of 61 percent of the thorium. Subsequent decomposition of the concentrate by treatment with sulfuric acid and solvent extraction of the resultant solution with a primary aliphatic amine yielded a thorium oxide product of 99-percent grade.

Jan 1, 1962

By Clinton C. Knox

During the latter part of 1943, a magnetometric survey was conducted by the Geophysical Division of the Bureau of Mines at the Mahopac magnetite mine, Putnam County, N. Y., in an endeavor to locate a segment of the ore body that reports state was cut off by a fault. The Mahopac mine was abandoned about 1895 after producing nearly 1,000,000 tons of high-grade magnetite iron ore. The results of the investigation indicate the termination of the ore body by "pinching", or a displacement of such magnitude as to place any extension at a considerable distance from the original are body. This report describes the work done on the project and presents the data obtained.

Jan 1, 1948

By C. W. Owings

"PURPOSE OF REPORTThe safety and efficacy of permissible storage—battery gathering locomotives are becoming recognized more and more in coal mines. The great mobility of this type of haulage equipment is due to the fact that no trolley wire and bonding of rails are needed; hence wherever there is track and adequate ventilation to dilute properly any dangerous gases, the storage—battery gathering locomotive may go. As coal near the outcrop or the surface is mined out, coal farther from the outcrop or deeper in the ground must be mined, and gassiness of the coal bed often increases under these conditions. The use of electrical equip¬ment capable of giving off arcs or sparks while operating near or at the coal faces constitutes a serious explosion hazard. Often, it is uneconomical or impracticable to use animal haulage, and locomotives must be employed. The operator should consider the safest and most economical unit; permissible equipment is the answer to this problem, and storage—battery locomotives are the only permissible electric haulage units.A comparison of permissible storage—battery locomotives with cable—reel locomotives of the latest enclosed ""explosion—tested"" type has been made at the Keystone No. 1 mine of the Houston Collieries Co., at Keys one, W. Va. The information and data contained in this publication were obtained by the writer during an inspection of haulage at this mine.ACKNOWLEDGMENTSThe writer is indebted to P. C. Thomas, vice president and general manager, the Koppers Coal Co., operator of the Keystone mines, who granted permission for making the study. W. A. Wilson, general superintendent, Houston Collieries Co., arranged for the investigation and for obtaining the data. C. E. Zuspan, chief electrical inspector, and J. C. Newman, division electrical inspector, accompanied the writer underground and assisted materially in obtaining information and data upon the haulage methods and performance of the locomotives. The assistance or general mine Foreman Pierman and of mine foreman White is gratefully acknowledged."

Aug 1, 1931

By Phillip N. Yasnowsky

This Bureau of Mines report examines the percentage depletion allowance rate structure in relation to several criteria that are indicative of U.S. mineral import dependence. These criteria are the minerals considered as strategic and critical for stockpiling purposes, the ratio of reserves to forecast cumulative demand (1976-2000) for selected minerals, and the U.S. net import reliance as a percentage of apparent consumption (1978), also for selected minerals in general, it was Found that there does exist a direct, although not perfect, relationship between the percentage depletion allowance rates and the degree of import dependence as indicated by these three criteria. The higher percentage rates tend to he associated with those minerals for which the United States is, or will likely he, heavily dependent on foreign sources. In addition, a basic discussion of the mineral depletion allowance is provided, including numerical examples illustrating the computation of the allowance under several assumptions. Also, the percentage depletion allowance rates for individual minerals are tabulated.

Jan 1, 1980

By Jon C. Volkwein

The U.S. Bureau of Mines has developed a method to measure methane and other gases during the auger mining of coal. An intrinsically safe commercial gas detector with a built-in data logger was mounted in the center of the hollow conveying auger. A sampling head through the wall of the auger conducted a gas sample to the detector. Results showed that gas levels can be monitored on a continuous basis during the auger mining of coal and the data retrieved upon completion of the hole.

Jan 1, 1994

By P. D. Kovscek

High-pressure streams of water, known as water jets, can be used to improve the cutting efficiency of mechanical bits. During prior testing by the Bureau of Mines, the cutting performance of a longwall shearer, equipped for water-jet-assisted cutting, was evaluated. The performance of the shearer did not improve while using water jet assist because the pressure of the water delivered to the rock surface was inadequate. The study, described in this report, resulted in a determination of the major cause of water pressure loss on the shearer, and an evaluation of the techniques for increasing the water pressure at the rock surface. The results show that the major pressure loss, which occurred between the nozzle and rock surface, is directly affected by the amount of fluid turbulence that develops just upstream from the nozzle. Preventing a sudden change in the direction of the flow channel can increase the stagnation pressure as much as 400 pct. Smoothing the surface of the flow channel in the shearer bit block would increase the stagnation pressure delivered to the rock surface by 35 pet.

Jan 1, 1989

By E. P. Youngman

The mining law of May 16, 1884, is still the basic mining legislation in Smeden. To satisfy a demand for a revision of the entire mining law, special commissions have been at work for a number of years; but present indications are that the work will require several more years for its completion. The changes contemplated would affect mainly the relations between the nine operator and the landemer, as the present law, according to general opinion, tends unduly to jeopardize the landowner's right in favor of the miner. The socialist party desires additional changes, especially in the direction of giving more direct control of the industry to the State, a control that it now seems to exercise through individual agreements with mining companies. Its control of the Lapland iron mines comes through its sharing the ownership with the Luossavaara-iirunavaara Altb. In this instance, the Government should be Considered as a private commercial body, since the agreement with the company

Apr 1, 1933

Objective The Roof Monitoring Safety System (RMSS) introduced in late 1997 has been modified to improve durability and simplify the measurement of roof or rib movement. Greater knowledge about the stability of roof and rib rock is expected to result in safer conditions for the mine worker. Developing safety tools and methods is part of NIOSH’s mission to prevent work-related injuries and deaths. A mining operation with a proactive approach to control ground conditions is in a better position to make essential decisions related to mine development and take remedial actions in the event of roof or rib falls. Background Falls of roof and rib rock are responsible for a high number of mining injuries and fatalities. Visual inspections and the sound of breaking or cracking rock are often relied upon to indicate unstable roof conditions. In some mines, roof bolt holes are checked for separations or gaps with a scratch tool; this provides further information about the stability of the roof. Monitors such as the RMSS can confirm roof movement that was surmised only by eye or ear, or potentially detect movement that was missed by these means. An added safety feature of the RMSS is the capability of locating the measurement station at a distance from where the monitor is placed in the roof. Stone and other industrial minerals are the basic raw materials used in construction. Continuing economic growth and highway building in particular have resulted in record demand for stone. This high demand, coupled with increasing constraints on surface mining, have caused many new .stone mines to be developed underground. These new mines in many cases will be employing new and inexperienced miners who may not have the ability to recognize unstable ground conditions using just sight and sound. From the initial introduction of the RMSS, it was anticipated that improvements and modifications would occur. We correctly assumed that, once miners and operators were exposed to the monitor. suggestions would evolve. In one case, the RMSS was used to determine if an impact hammer used on a mechanical scaler was causing or increasing instability of roof rock. The test showed little or no movement resulted from this method of scaling under the particular conditions at this mine. In another instance, an operator needed to monitor the stability of a haulageway in a benched area that had very high ceilings. The RMSS requires a 2-in-diam hole for installation; however, only roof bolt holes of a smaller diameter were available, and it was impossible to drill new holes at that height. The operator attached a 2-in collar at the roof line and was able to install the RMSS. These examples illustrate the potential for further enhancements of this tool. NIOSH continues to seek additional candidate sites for use of the RMSS. As usage increases, we anticipate further refinements and additional applications. How It Works The new RMSS, cable, and read-out box are shown in figure l. The read-out box has a green light that stays lit until battery replacement is needed. The red light is set to conic on to indicate movement. The red light can he adjusted for increments of movement as low as .010 inches. The RMSS red light should not be considered as a primary or only means of determining the stability of roof or rib. It is intended to serve as a supplement to existing methods or procedures for determining stability. An overview of the RMSS components is shown in figure 2. Movement of rock layers within the mine roof is measured relative to a fixed-point calibration at the monitor housing. The housing contains a potentiometer, roller switch, plastic rack, and spur gear. Movements are detected by the transfer of electromotive forces

Jun 1, 2000

By J. C. Edwards

To have the capability to predict the development of localized spontaneous heating within a porous coalbed that is subjected to forced air ventilation or in an otherwise quiescent environment in which buoyancy develops, the Bureau of Mines developed three time-dependent mathematical models, which were used to calculate the temperature increase associated with chemisorption of oxygen by the coal. In each model, spontaneous heating is driven by an Arrhenius first-order reaction between the oxygen and coal. Two models are two-dimensional, and one is one-dimensional. In the first two-dimensional model, a constant-velocity forced convection airflow is specified; and in the other, buoyant flow is allowed to develop in the absence of forced convection. The third model evaluates the airflow from Darcy's law and a specification of the pressure at the surface of a one-dimensional porous coalbed. Numerical computations demonstrated how each model could be used to predict the onset of spontaneous heating when the porous coalbed was subjected to constraints of an imposed internal heat source or a high temperature airflow. The effects of particle size and coalbed compaction upon spontaneous heating were examined with the third model.

Jan 1, 1990