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By A. C. Fielder

It is with some diffidence that I venture to address the Montreal Section of the Society of Chemical industry on the subject of motor fuel from coal at a time when crude petroleum is produced in greater quantities than at any time in history, and at a time when the known reserves exceed all expectations, even the optimistic estimates of the Committee of Eleven of the American Petroleum Institute. Not only are new fields being discovered in America a -an embarrassing frequency but sources outside of the North American Continent show, unmistakable signs of adding materially to the world's sources of oil. Were it not for the tremendous scientific and technical importance of the work done in the past few years in transforming coal into liquid motor fuels, I should prefer to let this subject rest until a more propitious time, such as prevailed some years ago, when the gasoline consumption curve was rising rapidly and the production curve was slowing in its upward rise. That was the period which stimulated the researches which resulted in tetra ethyl lead and anti-knock gasolines on this side of the Atlantic and in methanol, synthetic gasoline and hydrogenation of coal on the other side. Some of you will recall a symposium on Motor Fuels and Oil Conservation held at the Chemists' Club n New York in September; 1925. Dr. R. L. Brown and I presented a paper at this meeting on "Complete Utilization of Coal and Motor, Fuel, in which we pointed out that coal was the most likely raw material source of gasoline substitutes if and when needed. We grouped the present and future, processes' for obtaining motor fuel from coal in three classes, namely:

Jan 1, 1928

This part of the final report treats some problems related to coal mine carrier frequency communication systems using the trolley wire/track transmission line. This work was undertaken for a brief period of time during the summer of 1972 to help understand, quantify, and improve some of the trolley wire carrier system behavior observed and/or predicted. Calculations and estimates of transmission line characteristic impedance, inductance and capacitance per unit length, mine motor loading effects, parallel line effects, and connection impedances are presented in Chapter I. Chapter II treats the design of r-f isolators for reducing the undesired and troublesome r-f loading that mine motors present to the trolley transmission line. Chapter III treats a diversity method for combatting standing wave nulls. I. CALCULATIONS RELATED TO TROLLEY WIRE COMMUNICATIONS A. ESTIMATION OF INDUCTANCE AND CAPACITANCE PER UNIT LENGTH OF TROLLEY LINES To estimate the L and C per unit length of trolley lines, we use the eccentric line model of Section G of this Chapter, "Characteristic Imped¬ance Estimates for Mine Trolley Lines." The capacitance per unit length for an eccentric line is given by (1)

Jan 1, 1974

By M. L. Whisman

Radiotracer techniques were developed for stoichiometric studies of photochemical reactions associated with atmospheric smog formation. Stock blends of separate hydrocarbon and oxygenated compounds were prepared and calibrated. 14C-labeled reactants and products in reaction systems involving hydrocarbons and nitrogen oxides at the ppm level were analyzed for qualitative and quantitative data. Precision and accuracy of these methods developed by the Bureau were determined by replication and statistical treatment of data, and these methods are described.

Jan 1, 1969

By Manuel Gomez

The mean and the standard deviation were used to describe general sulfur and ash populations as well as specific populations of these variables from one coal seam. Both the mean and the standard deviation were incorporated in the exploration process to determine the number of drill cores necessary for seam evaluation and to guide the sequential drilling plan. Probability regions were computed to establish a basis for predicting probable ranges of average sulfur and ash concentrations that may be expected upon continued or future drilling. A computerized plot program was utilized to interpolate sulfur and ash concentrations between grid points. The plot program, which is essentially a moving average technique, permits a rapid evaluation of sulfur, sulfur forms, and ash spatial distributions as a drilling program progresses sequentially. This information, in the form of contour plots, can be made available to both the mining engineer and the fuel technologist in advance of mining to outline reserves, to improve selective mining, and to anticipate preparation facilities.

Jan 1, 1972

By Stuart Lipoff, John E. Trombly, Paul Brien, O&apos

System objectives and design criteria for an in-mine ULF radio paging system are discussed. Coding formats, frequency and bandwidth selection criteria leading to the system design are discussed. The prototype call alert transmitter and pocket page receiver is functionally described. The report includes circuit descriptions, schematics, parts lists, printed circuit fabrication and assembly drawings. The report concludes with an estimate of the manufacturing cost for each assembly.

By Launa Mallett, Charles Vaught, Michael J. Bmick

Since 1991 the Pittsburgh Research Center (PRC formerly part of the U. S. Bureau of Mines) has been tapping u valuable resource-researchers have recorded extensive interviews will, 30 individuals who are recognized as experts in the area of mine emergency response. These veterans related stories and observations from events experienced during as many as 47 years of response activities. Overall, the response veterans averaged 29 years of mine emergency response experience and 35 years mining experience. Individuals [ ] interviewed included representatives from mining companies, the UMWA and state and federal government agencies. This information was gathered so dial it could he provided to today's miners and to tomorrow's emergency response personnel. It is hoped the collective wisdom that has been obtained can be used to help train new responders and guide those decisions which mill have to be made on the scenes of future events. During interviews file emergency response experts were asked to discuss lessons they had learned through experience. The interviewers asked them to tell what they had learned that would cause them to handle similar situations differently and to tell about things they saw at past events shat the would warn others not to do in the future. In response the experts discussed a variety of things. Most of their responses, however, touched on some of the same topics including: preparedness, experience people on-site mine rescue teams, and decision making. A summary of their responses provides alt overview of [lie lessons learned on-site at tile largest mine disasters in the country.

By C. O. Hawk

As an exploratory effort to produce useful products from coal by a new path, the Bureau has made a few experiments on the fast heating of finely ground coal particles by irradiation with a flash of high intensity light. The flash was produced by an electrical discharge at high voltage through a xenon-filled tube. The flashes lasted from 2 to 3 milliseconds. The reaction took place in small sample tubes, ½ inch-dimeter by 4 inches long, and with small amounts of coal (total amount charged 0.1 gram, probable effective amount not more than 20 milligrams). Average particle size of the coal, estimated on a numerical basis, was 20 microns. Temperatures reached were evidently quite high, because all products obtained in quantity were characteristic of high temperature pyrolysis. Apparently, conversion of the coal was extensive where isolated particles received the full benefit of a flash. It seems particularly significant that acetylene was present in appreciable amounts--comprising almost 3 percent of the total gaseous product in one case. This is good evidence of a short heating period to very high temperature (well above 1,000° C) followed by rapid quenching. Although the results are interesting, they do not suggest any immediate practical application.

Jan 1, 1963

By I. O. Salyer

This research was conducted with the objective of suppressing the respirable dust in coal mines by foam application. A formulation was developed for making a water-based, high-expansion, and limited stability foam. A horizontal boring machine was used as a laboratory coal mining model for generating coal dust. A modified laboratory foam generator was built. Foam was applied directly to the point at which dust was being formed by the cutter of the boring machine working against a block of coal. Coal dust was sampled with an impinger and analyzed for the particle count and particle size distribution. Coal dust suppression test results on freshly generated dust have demonstrated very clearly that in laboratory scale experiments over 90% of the respirable coal dust can be suppressed by foam. These tests were run when initial coal du t concentrations were 10 and 70 million particles per cubic foot (mppcf).

Jan 1, 1970

By R. R. Hornor

BIBLIOGRAPHY OF ARTICLES RELATING TO THE PRESERVATION

Apr 1, 1922

By L. E. Geyer, W. W. Adams, M. G. Parry

"More than 73 million pounds of rock dust were used by the bituminous-coal-mining companies in the United States during 1930 to present or limit loss of life and destruction of property from explosions of gas and coal dust in underground mining operations, according to statistics compiled by the United States Bureau of Mines from reports furnished by mine operators. The mines using rock dust produced 65. 691, 753 tons of coal during the year, more than 30 percent of the total production of bituminous coal from underground mines in the United States that year. Although only 382 out of a total of 5,629 active underground bituminous mines applied rock dust to underground working as a precaution against explosions, they were chiefly the larger producing mines, employing 25.4 percent of all of the underground bitumious mine workers in the United States and accounting for 27.4 percent of the total number of man-hours worked underground at bituminous mines.a summary of the reports for the 382 mines using rock dust showed a total production of 96,691,755 tons of bituminous coal, 89,503 men employed underground, and 129,718,965 man-hours worked by the underground employees. (See tables 1 and 2.) These mines averaged 8.76 pounds of rock dust per ton of coal shown by reports from 385 mines using rock dust in 1932 (See table 3.)"

Nov 1, 1935

By S. J. Page, W. R. Reed, J. A. Organiscak

NIOSH continues to conduct respirable dust control research for surface mine blasthole drilling operations. Research areas have included testing variables (shroud leakage area, drill deck cross-sectional area, shroud height, collector-to-bailing airflow ratio, etc.) that have the most impact on respirable dust control, development of a dust collector inlet hood, development of a dust collector dump point shroud, and testing of a small diameter water separating sub. This paper summarizes the results of the aforementioned research that has been completed. Additionally, past dust control research for drilling operations of both underground and surface mines completed by the U.S. Bureau of Mines, created in 1910 and incorporated into NIOSH in 1997, is reviewed.

By A. J. Kraemer

[During the past several years a great deal of discussion has centered around the question of the permissible limit of sulphur content in fuels for automotive and aviation motors. Under certain conditions of operation, sulphur in motor fuels causes the formation of corrosive substances which attach bearings, wrist pins, and other parts of engines. On the other hand, in making gas¬oline from certain stocks, the gasoline fraction normally contains a relatively large proportion of sulphur compounds. By the generally used processes of reducing the sulphur content, a significant part of the gasoline fraction is lost as motor fuel, and added expenses are entailed for chemicals, labor, and other process costs. This condition has been an economic burden to some refiners of high-sulphur crudes. In some instances the treating losses have been rather severe and the treating costs relatively high, but the data presented in this paper indicate that the reduction of sulphur content of motor fuel is a problem to a relatively small number of refiners and of little or no concern to the remainder; in fact, more then 90 per cent of the 153 samples analyzed passed the Federal specification requirement, which limits the sulphur content to 0.10 -nor cent. 3 This report is based upon the results of an examination for sulphur content, Doctor test, copper strip corrosion, and color of the samples collected during January, 1930, for the twenty-first semiannual gasoline survey of the Bureau of Mines. The results of the gravity and distillation tests of the survey were published as Report of Investigations 2995. The numbering of the samples given in this report is the same' as in Report of Investigations 2995; for example, No. 25 of this report is the same sample as No. 25 of Report of Investigations 2995.]

Jan 1, 1930

By John M. Dower, Ralph W. Plummer, Terrence J. Stobbe, Hyunwook Kim

"The relationship between exposure to coal mine dust and the development of various respiratory diseases is well recognized. The cause of these diseases however. Is still uncertain. To study this cause-effect relationship, It Is necessary to characterize the coal mine dust In terms of the quantity of dust present and mineral content of the dust. Dust samples were collected using a Portable Continuous Aerosol Monitor (PCAM) and 4-stage cassette Impactors at various locations in an upper Freeport seam coal mine In West Virginia. The samples were analyzed using an X-ray microdiffraction film technique and energy dispersive scanning electron microscopy. This paper presents the results of the first phase of this characterization work which Includes determining the size distribution of the dust and the mineral content of the size intervals.IntroductionDiseases associated with dusts in coal mine environments continue to afflict miners in today's modem mines. These diseases still persist because, as Olishifski points out an employee rarely experiences exposures to a single environmental stress but rather to an Intricate Interplay of multiple stresses.(1) In the case of coal mining the multiple stresses are varying sizes of dust particles originating from coal imbedded minerals. Immediate roof strata bottom strata. Incombustible rock and the coal itself. The site of this Intricate Interplay Is the miner's lungs and the resulting diseases are a function of the composite dust exposures.The proper study of coal mine dust toxicity requires that the dusts used replicate existing coal and mineral dust compositions in their relevant size fractions. The purpose of this project is to develop the size and mineral content data necessary to support this ongoing toxicological effort.Existing coal mining standards and regulations also address total and respirable dust exposures. These dust terms refer to both the quality and quantity of the dust segment in the mine atmosphere. Dust quality addresses its coal and mineral content. whereas dust quantity Is described by mass per unit volume (mg/m3) The comprehensive characterization of coal mine dust exposures will enable revision of these standards and regulations to address the specific minerals and size fractions found to be toxic to human lung tissue."

Mar 1, 1989

By Jeffrey Shawn Peterson

The testing procedures of the U.S. Mine Safety and Health Administration specify that intrinsic safety acceptance tests be conducted using a standard tungsten-cadmium electrode configuration in the break- flash apparatus. However, in realistic mining environments, other materials may be more likely sources of sparking. Information defining the probability of spark ignition between common materials such as aluminum, brass, copper, lead, tin, cold-rolled steel, and stainless steel is of more practical value in determining ignition hazards. The U.S. Bureau of Mines has completed an investigation of the influence of material on the ignition probability using the breakflash apparatus. By comparing ignition currents or ignition voltages corresponding to a probability of one ignition per thousand sparks to those found previously for cadmium, a margin of safety may be estimated for each material. This report presents the results of an investigation into the influence of disk electrode material on the probability of ignition.

Jan 1, 1992

By N. S. Dalal, X. Shi

"SUMMARYElectron spin resonance (ESR) measurements provide direct evidence for the involvement of the glutathionyl radical, as well as an isolable Cr(V)-glutathione intermediate in the Cr(VI) glutathione redox reactions. These results indicate a new mechanism for the reduction of Cr(VI) by glutathione in relationship to cellular environment and suggest that synergistic reactions of Cr(V) and GS· might be responsible for the (unexpected) increase in the Cr(VI)-induced DNA-strand breaks at high glutathione levels.INTRODUCTIONWhile the reduction of Cr(VI) by glutathione (GSH) is thought to be a critical' step in the pathogenesis of the Cr(VI)-exposure related carcinogenesis1- 4, the exact reduction mechanism is not yet understood. The following reaction steps have been suggested :(A) Initial step:Cr04 2- + GSH - GSCrOa - (1)(B) At high GSH levels:GSCroa- + GSH - Cr( IV) + GSSG (2)(C) At low GSH levels: GSC rO a - - Cr ( V ) + GS ·(3)Thus far, however, in these reactions, the GS· radical has eluded spectroscopic detection, while the evidence for the Cr(V) formation has been reported positives as well as negative2·. Her~ we present spin-trap ESR evidence for the formation of the GS· radical, and a definitive ESR detection of an isolable cr(V)-GSH intermediate in Cr(VI)-GSH reactions.MATERIALS. AND METHODSESR spectra were obtained at X-band (-9.7 GHz) using a Bruker ER200D ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR Gaussmeter (Bruker, Model ER035M) and the microwave frequency was measured with a Hewlett-Packard (Model 5340A) frequency counter. The spin probes, a-(4-pyridyl-1-oxide) -N -tert-butylnitrone (4-POBN) and 5,5-dimethyl~1-pyrroline-1-ox1de (DMPO) were purchased from Aldrich, K2Cr201 from Fisher and used without further purification. All experiments were done at room temperature."

Jan 1, 1989

By D. E. Hirsch

The Bureau of Mines, as a part of American Petroleum Institute Research Project 60, Characterization of the Heavy Ends of Petroleum, has made extensive use of gel permeation chromatography (GPC). Data developed in this study were used to develop several correlations that greatly expanded the usefulness of GPC and the data have been used as an aid in the interpretation of mass spectra (MS). GPC retention volume data on pure compounds were used with molecular structure to develop correlations that can be used to accurately predict retention volumes, molecular volumes, densities, chain lengths, and ring numbers of many components of petroleum without resorting to further laboratory experimentation. Conversely, the correlation can be used to select or reject some compounds from several possible compounds that are indicated on the basis of MS analysis. The utility of these correlations in compound type characterization is demonstrated by showing their application to 330° to 550° C fractions from a low-sulfur and a high-sulfur crude oil.

Jan 1, 1974

By R. V. Subramanian

This project financed by the Bureau of Mines investigated the use of polymers to achieve rock bonding and reinforce coal mine structures for better or permanent ground support. Support was achieved by pumping the polymers into the rock interstices to bond the mass together for increased structural competence. Holes were drilled in the mine roof, after which the polymers were injected at about 100 psi to permeate the cracks. Initial laboratory work indicated that of all the resin systems tested, the epoxy resins could most likely be modified to be suitable for rock injection. This was confirmed when several potentially suitable resin systems underwent intensive evaluation. In a series of three field tests, two conducted in a copper mine with coal mine-type shale and the third in a coal mine, it was shown that the polymers penetrated cracks less than 0.005 inch wide. The fast-setting epoxy systems, cured out in thin films under mine conditions, produced a bond exceeding the strength of the uncracked virgin rock.

Jan 1, 1974

By T. M. Nasiatka

This report sterns from a study undertaken by the Federal Bureau of Mines to determine the possibility of reducing filter-cake moisture by applying radiant heat. Suitable laboratory equipment was set up to study the effect of heat, heating time, proximity of the heater to the filter cake, cake thickness, and other variables related to the final filter-cake moisture. A minus-48-mesh coal slurry and application of heat for 60 seconds resulted in filter-cake moistures 5.6 to 13.2 percentage points lower than could be accomplished by filtration alone at 24 inches of Hg for 1-1/4-and 1 1/2-inch cake thickness, respectively. The moisture reduction can be attributed to the combined effect of lower fluid viscosity and evaporation.

Jan 1, 1959

By M. W. Price, Joseph V. Mather, E. H. McCleary

"INTRODUCTION The asphyxiation or poisoning of workmen in underground mines by noxious gases from blasting in adjacent strip mines can be prevented.Considerable progress has been made in eliminating or reducing hazards to the health and safety of underground workmen in anthracite mines, but seldom does a year pass without reported cases of underground workmen being poisoned by the fumes from blasts of explosives in strip-mining operations. In the early days of the anthracite industry, the coal near the surface was only partly mined, and many small stumps of pillars and barrier pillars were left standing; these pillars are now being recovered by stripping. It has become necessary to give more consideration to the effects of blasting at strip mines upon the quality of the air in underground mines adjacent to stripping operations.Special precautions are taken by the .personnel of the Jeddo-Highland Coal Co., whose mines are near Jeddo, Luzerne County, and near Centralia in Columbia and Schuylkill Counties in the anthracite region of Pennsylvania, to prevent asphyxiation of workmen by carbon monoxide or other toxic gases resulting from blasting in strip mines. The procedures established by the Jeddo-Highland Coal Co., are given in this circular so that others may benefit thereby and thus avoid hazards to underground workmen where mining is carried on under similar circumstances."

May 1, 1949

By T. J. Ballard, Austin B. Clayton

"The Union Copper mine is in the Gold Hill district, Rowan and Cabarrus Counties, N. C.The mine was discovered in 1799 and first worked as a gold mine; but copper was encountered at depth, and the property became an important producer of copper. It is estimated that the mine produced 5,000,000 pounds of copper before operations were discontinued in 1907.As part of the strategic minerals program, the Bureau of Mines conducted a development project on the property from July 1943 to November 1943. Eight diamond-drill holes, totaling 2,500 linear feet, were drilled to delineate the ore body. Analyses of 205 core samples were made.Tabulations of sample analyses and drill-hole logs are presented in this report.The project work embodied in this report was under the immediate supervision of Austin B. Clayton, project engineer, and the general supervision of H. B. Ewoldt, district engineer for North Carolina and Tennessee. The preliminary report, written by Austin B. Clayton, was revised and the various figures redrawn for publication by T. J. Ballard under the general supervision of M. H. Kline, chief, Raleigh Branch, Mining Division.Acknowledgment is due the Metallurgical Branch for analytical determinations of the samples.The mine property is 1.5 miles southwest of the village of Gold. Hill, N. C. (fig. 1). Gold Hill is on U. S. Highway 52 between Salisbury and Albemarle and on a branch line of the Southern Railway. The latitude is 350 30' and longitude 80° 21 The tract consists of 553-1/2 acres in Cabarrus and Rowan Counties.A tentative list of the surface-rights ownership is as follows: William Hoy Barringer - 16 acres, A. W. Tucker - 1 acre, Frank Wagoner - 4 acres, and George Barringer - 3-1/2 acres, in Cabarrus County; A. W. Tucker - 2 acres, H. N. Hedrick - 54 acres, and William Atkins - 473 acres, in, Rowan County, N. C.The mineral rights are owned by Alfred Rossiter, Alice R. Hesslein? and the estate of the late Bella Rosenblatt. The attorneys for the owners are Neidle & Taylor, 6 East 45th Street, New York City.The Union Copper mine is in the Cold Hill mining district of North Carolina where gold was first discovered in 1799. The upper parts of the veins in the district were first worked for gold; however, the increase in the sulfide content of the veins with depth rendered the amalgamation process for gold recovery ineffective, and the mines were closed.The period of greatest activity at the Union Copper mine was from 1899 to 1906. At an earlier period the oxidized and leached part of the lode near the surface was mined from a working known as the ""big cut,"" the reported yield of which was $300,000 in gold.3/ The mine has not been operated since 1907.J. T. Pardee3/ lists the probable value of the production of the Union Copper mine as $1,050,000, of which about $675,000 was the value of some 5,000,000 pounds of copper produced."

Oct 1, 1948