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By John W. Cole

The Butte district has been the principal producer of metallurgical-grade manganese in the United States since World War I. Manganese dioxide nodules are produced from rhodochrosite ore by concentrating the rhodochrosite and roasting the concentrate in rotary "cement-type" kilns. The Anaconda Copper Mining Co. is the only producer at present. Under the stimulus of a purchasing program administered by Metals Reserve Company during World War II, however, several independently owned or operated mines (including the Norwich) produced manganese carbonate ore. These mines were examined in Juno 1949 by John W. Taber, mining engineer, Bureau of Mines. A core-drilling program to develop ore in the Norwich mine was recommended and approved. drilling was completed early in 1950. This report gives factual data obtained.

Jan 1, 1951

By S. A. Matthes

This Bureau of Mines report describes analysis of a copper slag for 13 elements from a single sample solution by flame atomic absorption spectroscopy. Samples are dissolved with 7 ml of an HC1-HF-HN03 (3:1.5:2) mixture in heated plastic pressure vessels. A 1.5-pct boric acid solution is added to dissolve precipitated fluorides and to reduce matrix effects that interfere with atomic absorption analysis. Preparation time is less than 1 hour per batch of 10 samples. Total analysis time is less than 6 person-hours for 130 determinations with an average relative standard deviation of 1.83 pct for the 13 elements. Simple acid standards were used for all determinations. Values obtained by this method are in excellent agreement with values obtained by slower, more costly procedures.

Jan 1, 1980

By V. T. Dow

In April 1957 the Bureau of Mines instituted a reconnaissance of titanium-and zirconium-bearing heavy sandstone deposits in the Four-State area of Utah, Wyoming, New Mexico, and Colorado. This report summarizes the study. Eighty-two deposits or groups of deposits, containing an estimated 27,920,000 tons of titaniferous sandstone, were examined in the Four-State area; 16 in southern Utah, 19 in Wyoming, 33 in New Mexico, and 14 in southwestern Colorado. The 16 deposits examined in Utah contain an estimated 1,043,000 tons with an average grade of 17.98 percent TiO2, 5.67 percent ZrO2, 20.98 percent Fe, and 0.09 percent equivalent Th02. The 19 deposits investigated in Wyoming are estimated to contain 21,873,000 tons of titaniferous sandstone having a weighted grade of 5.22 percent 702, 0.55 percent ZrO2, 24.8 percent Fe, and 0.01 percent equivalent Th02.

Jan 1, 1961

By John Nagy

The effect of low percentages of methane (0 to 5 pet.) in an air atmosphere on spark initiated explosions of coal dust was investigated. With low dust concentrations (0.1 to 0.4 oz./cu, ft.), small amounts of methane increase the explosion pressure; with larger dust concentrations (0.5 to 2.0 oz./cu. ft.), small amounts of methane decrease the explosion pressure. The rate of pressure rise of a coal dust explosion increases with increase in methane concentration; about 3 to 4 pct. further addition of methane yields a decrease in the rate of pressure rise. Convection currents created by the air or gas blast used to disperse dust produce an increase in explosion pressure and rate of pressure rise. The minimum explosive concentration of the coal dust decreases about linearly as the concentration of methane increases from 0 to 5 pct. The explosion pressure increases linearly as the initial pressure within the chamber increases. Similarities between coal dust and methane explosions are indicated, INTRODUCTION During coal mining, methane occluded in coal or adjoining strata is liberated into the mine atmosphere,4 Normally, the methane is diluted and swept away by the ventilating air. Under some conditions, through accidental disruption of the ventilation system, sudden outburst, or because insufficient fresh air is supplied to a working place, low percentages of methane may be present during mining operations. If it is permitted to accumulate, methane itself presents an explosion hazard; its limits of explosibility arc approximately 5 and 15 pct. The effect of low percentages of methane on the explosibility of coal dust was studied to provide a broader understanding of the hazards of ignition and explosion and thus to facilitate development of control

Jan 1, 1961

By Joseph M. Singer

Having established that sodium chloride reduces the incendivity of explosives, the Bureau of Mines studied the effect of sodium nitrate in reducing ignition hazards. Gallery experiments showed that sodium nitrate reduced the incendivity of certain explosives to 8 percent natural gas in air but increased their incendivity to coal dust predispersed in air. Laboratory experiments using hot jets from explosions of stoichiometric mixtures of methane-oxygen-nitrogen showed that both sodium chloride and sodium nitrate reduced the incendivity to methane, to mixtures of coal dust and methane) and to coal dust. The difference between the gallery and laboratory results with respect to coal dust is attributed to temperature-time effects.

Jan 1, 1967

By P. M. Sullivan

Galvanizers' sal skimmings have been treated by two methods of leaching in attempts to produce preflux solutions suitable for use in galvanizing operations. Both water-leaching and acid-leaching procedures are effective, except in severely exhausted skimmings when water-leaching becomes impractical. A preliminary analysis of the skimmings is not required. Solutions in the recommended concentration range can be produced conveniently by control of pH, specific gravity, and chlorine content. A technician would require only a short period of training to be able to perform the operations described.

Jan 1, 1958

By E. C. Perkins

Preliminary experiments are reported utilizing bacteria to leach manganese from a variety of domestic low grade manganiferous materials. In two large leaches manganese extraction ranged from 71.7 to 92.5 percent, and the products analyzed over 48 percent manganese. Nutrient requirements and leaching time experiments were made. The mechanism of leaching is not understood, but is different than the mechanism encountered in the microorganism accelerated leaching of copper in the presence of sulfide minerals.

Jan 1, 1962

By R. E. Morgan, Barkleym J. F.

"INTRODUCTION Wood burned for commercial heat and power usually is waste material from some manufacturing process. The amount of it reaches substantial proportions. It is estimated that over 50 percent of the timber cut for lumber becomes ""waste"" in the process - sawdust, shavings, trimmings, slabs, and bark. Woodworking manufacturing processes also produce much waste. The incentive to use this waste has resulted in much development of wood-burning equipment to produce heat and power. To answer general inquiries received by the Bureau, this publication covering developments along these lines was written. There is included a bibliography of additional information on the subject.COMPOSITION AND BURNING CHARACTERISTICS OF WOODThe approximate composition of moisture-free wood is, in even figures:PercentHydrogen 6Carbon 49Oxygen 44Ash 1Total 100This composition corresponds to about C6H1005. Moisture is essentially always associated with wood. Green wood contains approximately 30 to 50 percent moisture; air-dried or seasoned wood contains 15 to 25 percent and kiln-dried about 8 percent. Exposed to the weather, wood absorbs and gives off moisture depending on weather conditions and water contact.""Dry"" wood ignites relatively quickly and readily gives off volatile matter when heated. Long flames and smoke easily occur during burning. The burning action is substantially retarded, however, by appreciable moisture content; ignition is more difficult. When the moisture content is more than about 70 percent, an auxiliary fuel is required to maintain combustion. One of the main factors in the problem of the satisfactory and smokeless combustion of wood is its moisture content."

Sep 1, 1950

By C. P. Fang, V. A. Marple, K. L. Rubow, P. H. McMurry

"It has been known for some time that sizes of aqueous particles may be affected by flow-induced relative humidity (RH) changes. The RH of air flowing through an impactor decreases as a result of pressure drop through the impactor and increases because of aerodynamic cooling within the high-speed jets, as illustrated in Figure 1. Because the sizes of aqueous particles depend on RH, the impaction stage on which such particles are collected may be different from the stage where they ought to be col¬lected, based on the particle size at the sampler inlet.Fuchs (1980) reviewed literature on water vapor condensation in impactors. The reviewed impactors operated at jet velocities of 100-250 m/s. Particle size increases ow¬ing to water vapor condensation were found in all cases. In one case (Khorguani et al., 1970), it was found that very small droplets (Dp <_ 0.02 um) containing sodium chloride and silver iodide were collected in an impactor with a cut point of 0.32 µm and a jet velocity of 100 m/s. Fuchs believed that such particles could not be captured in an impactor without having been enlarged by condensation. Winkler (1974) sampled at¬mospheric dust with a rectangular nozzle impactor that had a nozzle cross section of 0.3 x 15 mm, a cut size of 0.4 um, and an average jet velocity of 100 m/s. No adhesive was used on the impaction plate. The collection efficiency increased as air humidity was increased from 20% to 100%. The effect was especially noticeable in the increased collection efficiency for hygroscopic particles, and was attributed to condensation.Extensive theoretical and experimental research work on the distortion of the particle size distributions in impactors was done by Biswas and coworkers (1985, 1987). The impactors employed in the study were a low-pressure impactor with high jet velocity stages (Hering et al., 1978, 1979) and a conventional six-stage impactor, Sierra's model 226, operated in the incompressible regime. Ammonium sulfate aerosols were chosen for the study. In the low-pressure impactor, an orifice operating at a Mach number of 1 causes a sudden pressure drop, significantly reducing the RH in the next two stages (stages 5 and 6). This results in a 0.15-um diameter ammonium sulfate droplet shrinking to about 0.07 um at stage 5 when the inlet RH is 95%. In stage 7, the tempera¬ture drop is considerable because the jet speed is sonic. For an inlet RH of 95%, a 0.03 um droplet grows to about 0.06 um. However, the same size droplet at an inlet RH of 25% grows to only 0.04 um. For the Sierra model 226 cascade impactor that is operated with a Mach number of 0.27 at the last stage (stage VI), it was found that for an inlet RH of about 67%, particle growth would occur in stage VI. At 80% RH, both stages V and VI were affected. Biswas et al. (1987) stated that Mach number alone does not determine the size biasing; the type of aerosol, the inlet conditions, the temperature and pressure ratio, and the impactor geometry (throat length, jet-to-plate distance, etc.) must be considered for each stage in evaluating the distortion of the particle size distribution."

Mar 1, 1992

By D. A. Reynolds, C. R. Holmes

The Bureau of Mines - American Gas Association ( EM - AGA) carbonization test has been used to determine the carbonizing properties of 66 American coals and a larger number of coal blends . A summary of the results obtained for the first 30 coals , including 6 blends , has been published ,4/ and results for individual coals have been reported as the investigations were completed . A bibliography of all publications pertaining to this work has been issued recently . Many of the coals were carbonized at 800 ° and 900° C. in two sizes of retorts ( 13- and 18 - inch diameters ) ; and , because the quality of coke is affected by changing the size of the retort , this report has been prepared to show the average physical properties of coke from the two sizes . This report also purposes to extend the correlation of the physical properties of coke with the rank of coal made by Fieldner and Davis in their summary of the EM-AGA tests on the first 30 coals .

Jun 1, 1942

By G. S. Scott

The Bureau of Mines is engaged in research to assess the hazards associated with the handling, storage, and use of combustible gases, vapors, and. liquids encountered in mines and in industry. As a part of this general pro-gram, numerous limits of flammability and ignition temperatures are being investigated for a wide variety of combustible materials, and methods are being developed to minimize the explosion hazards of these combustibles. The Bureau receives numerous requests for information on the explosion hazards of specified combustible mixtures under various conditions of use. This information circular has been prepared to assist those who may have similar requests. Destined primarily for the layman with a limited technical knowledge of the subject, it considers rather briefly the numerous factors that enter into the general problem of gaseous explosions and their prevention.

Jan 1, 1951

By J. F. Barkley

Field tests were made on the rate of corrosion of 30 materials used in air preheaters under regular operating conditions, and the buildup of deposits was observed. Twenty-three materials were tested with coal as the fuel on an underfeed stoker and seven with oil, including a short period with pulverized coal as fuel, The plant equipment is described, and pertinent plant operating data are tabulated. Figures 17 and 19 (pp. 24 and 27) give the results of corrosion tests on the uncoated metal test specimens. The information obtained from these tests follows the general pattern described in Bureau of Mines Report of Investigations 4996, Corrosion and Deposits in Regenerative Air Preheaters. The deposits were similar, and the corrosion rates of Cor-Ten and Mayari-R steel (previously found to be essentially the same at the Harding Street Station using coal) continued to show little difference at the Marion Generating Station using principally oil. The one high-alloy steel tested, type 321, showed a much higher corrosion rate than the low-alloy steel, Cor-Ten.

Jan 1, 1959

By Heine Kenworthy

"INTRODUCTION In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral content of this ore was considerably higher than in, the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently, tailing losses, especially with respect to lead, were high. A few years later, in order to study the possibilities of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill, feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Sta¬tion for testing-. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values was present.A résumé of the ore-dressing treatment used in the Shenandoah-Dives mill follows. After crushing, the ore passes through a ball mill, the minus 5-mesh discharge of which is distributed to three tables. A finished lead concentrate is made on the tables, and the table tailing goes to the classifier which is in closed circuit with the ball mill. The classifier overflow is treated -by flotation to obtain a bulk sulfide concentrate at a relatively coarse size. The bulk concentrate is thickened and reground to about 95 percent minus 325-mesh before flotation treatment to separate a lead-copper and a zinc concentrate. A typical monthly average showed that the table concentrate contained about 45 percent lead, 1 percent copper, 4 percent zinc, 12 ounces of gold, and 40 ounces of silver; that the lead flotation concentrate contained '35 percent load, 6 percent copper, 7 percent zinc, 3.5 ounces of gold, and 50 ounces of silver; and that the zinc flotation concentrate contained 2 percent lead, 0.5 percent copper, 60 percent zinc, 0.15 ounces of gold, and 4 ounces of silver. Recoveries in salable products were roughly b5 percent of the lead, 70 percent of the copper, 45 percent of the zinc, 85 percent of the gold, and b5 percent of the silver."

May 1, 1948

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United states was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United states Department of the Interiors This paper is a continuation of a series made in cooperation with the Coordinating Fuel Research (CFR) Committee of the Coordinating Research Council (CRC), Inc. The first of this series of reports presented data on motor gasolines sold during the winter of 1935-36, and succeeding reports described motor gasolines sold during the summers and winters to and including the summer of 1941.£1 No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942. However, starting with the winter of 1942-43, the semiannual reports were resumed

Jan 1, 1949

By J. P. Hansen

Reducibility tests were run by the Bureau of Mines on an open hearth lump ore and four groups of pellets whose smelting characteristics had been deter-mined previously in the Bureau&apos;s experimental blast furnace. When reduction data from various tests were plotted on specially prepared paper l-(l-percent reduction/100)1/3 against time, the plots were linear. The iron-wustite inter-face therefore advances at a constant rate. The rate of the interface advance in mm/min was used as a reducibility index. The reducibility index measured at 900° C, using 0.45 cu ft hydrogen per minute varied inversely with the surface area of the sample. Even with carefully controlled surface areas, how-ever, duplicate reducibility indices varied considerably. When enough tests were run to give a stable mean, the mean reducibility index did correlate with blast furnace production for the four pellet groups. Results indicated that if the interface speed itself were to be used for correlation with blast furnace production, a sample size of about 180 grams of minus 0.742-plus 0.525-inch particles should be used with a test temperature of 900° C and a flow of 0.45 cu ft hydrogen per minute.

Jan 1, 1966

By M. J. Ferrante

A process was investigated for preparing Specification-grade nickel (containing less than 1 percent cobalt) by stripping it electrolytically from a nickel sulfate-boric acid solution and using the stripped electrolyte for the preferential dissolution of nickel from basic carbonates of nickel and cobalt. The basic carbonates were produced at the plant at Nicaro, Cuba, owned by the U.S. Government. Determination of the optimum conditions for deposition of Specification-grade nickel indicated that the upper limit of cobalt concentration was 0.1 gram per liter. The pH, temperature, and concentrations of nickel and boric acid in the electrolyte were not critical. An aluminum cathode and two lead anodes were used at a cathode current density of 1.2 amperes per square decimeter.

Jan 1, 1959

By E. G. King

THIRD-LAW entropy data for zirconium-containing compounds are sparse. Kelley a lists entropies at 298° K. for the oxide, tetrachloride, nitride, and silicate, as well as for the metal. The present paper presents heat capacities between 51° and 298° K. and entropies at 298.15° K. for the zirconates of the alkaline-earth metals-calcium, strontium, and barium. The authors believe magnesium zirconate does not exist as a stable compound at room temperature. Entropies of formation from the constituent oxides also are given. MATERIALS The materials used in this investigation were synthesized and analyzed in the Berkeley Laboratory of the Bureau of Mines. Calcium zirconate was prepared by heating an intimate mixture of reagent-grade calcium carbonate and pure zirconia for 30 hours between 1,200° and 1,300° C. and for 32 hours between 1,400° and 1,500° C. As part of the heating schedule, the sample was ground and mixed seven times. Periodic analyses and minor adjustments of composition were made. Analysis of the final product gave 31.19 percent calcium oxide (theoretically 31.28 percent) and 68.67 percent zirconia (theoretically 68.72 percent). The X-ray diffraction pattern agreed with that in the ASTM catalog.

Jan 1, 1960

By Joseph A. DeCarlo, Eugene T. Sheri dan

The process of converting coal into coke is known as carbonization. Essentially, carbonization is destructive distillation in which the volatile matter of coal is released when coal is heated above its decomposition temperature and passes through a plastic stage before solidifying and forming coke. The mechanics of coke formation are complex, and the specific properties of certain coals that allow them to "cake" or form coke are still unknown. Coke is a hard, cellular, carbonaceous mass, formed by heating coal in the absence of air. It is porous, irregular in size and shape, and is similar in appearance to wood charcoal. Coke, however, is denser, more porous, and more abrasive than charcoal. Coke has been in use for several thousand years. History has recorded its use in Greece before the birth of Christ, and it is thought to have been used in China even before that time. It was not until the l6th century, however, that a method for coking was developed in Europe that subsequent ly evolved into the coking process that is known today. The coke industry in the United States began in the latter half of the 19th century when beehive-coke ovens were built to supply fuel for iron blast furnaces. Before this time, an iron industry fueled principally by charcoal had been in existence for several hundred years. With the depletion of timber resources, coke gradually replaced charcoal as blast-furnace fuel, and by 1875 more iron was made with coke than with any other fuel. Before 1893 a 11 coking was done in beehive ovens. These ovens are refractory kilns with arched roofs, sometimes joined together to form batteries.

Jul 1, 1964

By Wallace W. Roepke

The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60&apos; and 90&apos; (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate.

Jan 1, 1983

By Lloyd Williams

1. The investigation shows that the Pewee, Big Mary, and Windrock are the most important beds in Anderson County. About 73 percent of the known recoverable reserves of coal in the county are in these beds, and from them comes 94 percent of the production. The remaining reserves tabulated in this report are in the Joyner, Jellico, Coal Creek, and Poplar Creek beds, and 6 percent of the county production comes from these beds. No production is being reported at present from the Jellico bed, although it was mined years ago. 2. Known measured and indicated reserves in all beds, bared on a minimum thickness of 1/4 inches and on 1,800 short tons put acre-foot of coal in place, are estimated to be 170 million torts as of January 1, 1953 Of this total, 155 million tons is in beds 2S inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to permit making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to they total estimated reserves.

Jan 1, 1955